Water swelling rubber (WSR) was prepared by reaction blending SBR and sodium polyacrylate (PAANa). The existing states of water in the WSR was studied by means of DSC and TG. It was found that water exists in three st...Water swelling rubber (WSR) was prepared by reaction blending SBR and sodium polyacrylate (PAANa). The existing states of water in the WSR was studied by means of DSC and TG. It was found that water exists in three states: nonfreezing water, bound freezable water and free water. The relationships between water states and structure of PAANa were investigated. The results showed that the amount of non-freezing water was related to total water content, and the ratio of non-freezing water versus -COONa groups on PAANa (mol/mol) was about 4. However, total water content slightly affected the content of bound freezable water and remarkably affected the amount of free waer.展开更多
This paper aims to investigate the water absorption of wood flour/polypropylene composites and its effects on dimensional stability and crystallization properties. Wood-plastic composites (WPCs) makes using polydopami...This paper aims to investigate the water absorption of wood flour/polypropylene composites and its effects on dimensional stability and crystallization properties. Wood-plastic composites (WPCs) makes using polydopamine modified wood flour (WF-D), virgin polypropylene, maleic anhydride-grafted polypropylene (MA) and antioxidant, by using hot-pressing moulding. Water absorption (WA), thickness swelling (TS) and failure of flexural properties of the composites have studied for a range of immersion times. It is found that the WA and TS have increased with WF content and immersion time. The water absorption and thickness swelling of WPCs are 0.85% and 0.99%, respectively, after 8 days immersion. With the prolonging of immersion time, the impact strength, flexural strength and flexural modulus of WPCs increase first and then decrease. The impact strength decreases from 3.32 kJ/m<sup>2</sup> to 2.94 kJ/m<sup>2</sup>, the retention rate is 88.55%;the flexural strength and flexural modulus by 68.58 Mpa and 3.92 Gpa, respectively. WPCs crystallization and thermal properties decrease slightly. Microstructures of the composites are examined to understand the mechanisms for the wood-plastic interaction which affects the water absorption and thickness swelling. Our work demonstrates that using polydopamine treatment wood flour for preparing WPCs can be an efficient way to improve the water resistance of WPCs.展开更多
The swelling and tribological behaviors of nitrile-butadience（NBR） rubbers with three acrylonitrile contents（N18,N26 and N41） in water with different CO 2 gas flows are investigated by immersion and wear experimen...The swelling and tribological behaviors of nitrile-butadience（NBR） rubbers with three acrylonitrile contents（N18,N26 and N41） in water with different CO 2 gas flows are investigated by immersion and wear experiments.The results show that the bubbles of CO 2 into water severely destroy the cross-linking network of rubber and form defects on the surface,such as cracks,holes and lamellar perks.These defects lead to an increase in the static and dynamic swelling increment.The dynamic swelling increment is almost three or four times larger than the static swelling increment.The hardness and wear resistance of rubbers in water with CO 2 gas remarkably decreases in contrast to that in water,and they gradually decrease with an increase in the gas flow in water.The bubbles of CO 2 decrease the steady frictional coefficient of rubber in water due to the presence of the gas in water lubricant film.The steady frictional coefficient in water with different CO 2 gas flow basically remains 0.1.N41 with high acrylonitrile content shows better swelling and wear resistances than N18 and N26 because of its dense molecular network.展开更多
The swelling particle grouting material has demonstrated remarkable plugging effectiveness in high-pressure and large-flow burst water within karst pipelines.Currently,current research on the rheolog-ical model,flow c...The swelling particle grouting material has demonstrated remarkable plugging effectiveness in high-pressure and large-flow burst water within karst pipelines.Currently,current research on the rheolog-ical model,flow computation theory,and plugging mechanism of this material is lacking.The conven-tional grouting slurry diffusion process,using the liquid-liquid two-phase flow method,fails to accurately simulate high solubility slurry and particle swelling.To address these limitations,this study established a precise constitutive model to describe the swelling particle slurry diffusion process in dynamic water.Additionally,a coupling calculation method was proposed to analyze the spatiotemporal heterogeneity of viscosity during slurry diffusion by considering the migration of slurry and the changes in viscosity.To investigate the interaction between particle swelling and flow field changes,a Compu-tational Fluid Dynamics-Discrete Element Method(CFD-DEM)coupling model was developed for the diffusion of swelling particle slurry.It is demonstrated that slurry viscosity increases exponentially within the diffusion front as the particle swelling rate rises,and the drag force exhibits an intriguing behavior of initially increasing and then decreasing as the slurry flows through the pipeline.Further-more,the CFD-DEM coupling model proved to be more accurate in describing viscosity distribution and diffusion distance compared to the finite element solution.The primary objective of this paper is to reveal the plugging mechanism and provide theoretical support for the engineering application of the swelling particle grouting material.展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘Water swelling rubber (WSR) was prepared by reaction blending SBR and sodium polyacrylate (PAANa). The existing states of water in the WSR was studied by means of DSC and TG. It was found that water exists in three states: nonfreezing water, bound freezable water and free water. The relationships between water states and structure of PAANa were investigated. The results showed that the amount of non-freezing water was related to total water content, and the ratio of non-freezing water versus -COONa groups on PAANa (mol/mol) was about 4. However, total water content slightly affected the content of bound freezable water and remarkably affected the amount of free waer.
文摘This paper aims to investigate the water absorption of wood flour/polypropylene composites and its effects on dimensional stability and crystallization properties. Wood-plastic composites (WPCs) makes using polydopamine modified wood flour (WF-D), virgin polypropylene, maleic anhydride-grafted polypropylene (MA) and antioxidant, by using hot-pressing moulding. Water absorption (WA), thickness swelling (TS) and failure of flexural properties of the composites have studied for a range of immersion times. It is found that the WA and TS have increased with WF content and immersion time. The water absorption and thickness swelling of WPCs are 0.85% and 0.99%, respectively, after 8 days immersion. With the prolonging of immersion time, the impact strength, flexural strength and flexural modulus of WPCs increase first and then decrease. The impact strength decreases from 3.32 kJ/m<sup>2</sup> to 2.94 kJ/m<sup>2</sup>, the retention rate is 88.55%;the flexural strength and flexural modulus by 68.58 Mpa and 3.92 Gpa, respectively. WPCs crystallization and thermal properties decrease slightly. Microstructures of the composites are examined to understand the mechanisms for the wood-plastic interaction which affects the water absorption and thickness swelling. Our work demonstrates that using polydopamine treatment wood flour for preparing WPCs can be an efficient way to improve the water resistance of WPCs.
基金financially supported,in part,by the National Natural Science Foundation of China (No.50878178)the Natural Science Foundation of Liaoning Province,China (No.2013020039)the Science and Technology Program of Shenyang Municipality,China (No.F13-077-2-00)
文摘The swelling and tribological behaviors of nitrile-butadience（NBR） rubbers with three acrylonitrile contents（N18,N26 and N41） in water with different CO 2 gas flows are investigated by immersion and wear experiments.The results show that the bubbles of CO 2 into water severely destroy the cross-linking network of rubber and form defects on the surface,such as cracks,holes and lamellar perks.These defects lead to an increase in the static and dynamic swelling increment.The dynamic swelling increment is almost three or four times larger than the static swelling increment.The hardness and wear resistance of rubbers in water with CO 2 gas remarkably decreases in contrast to that in water,and they gradually decrease with an increase in the gas flow in water.The bubbles of CO 2 decrease the steady frictional coefficient of rubber in water due to the presence of the gas in water lubricant film.The steady frictional coefficient in water with different CO 2 gas flow basically remains 0.1.N41 with high acrylonitrile content shows better swelling and wear resistances than N18 and N26 because of its dense molecular network.
基金supported by the National Natural Science Foundation of China for the Young Scientists Fund,China (grant No.52109126)the National Key Research and Development Program of China,China (grant No.202103AA080016).
文摘The swelling particle grouting material has demonstrated remarkable plugging effectiveness in high-pressure and large-flow burst water within karst pipelines.Currently,current research on the rheolog-ical model,flow computation theory,and plugging mechanism of this material is lacking.The conven-tional grouting slurry diffusion process,using the liquid-liquid two-phase flow method,fails to accurately simulate high solubility slurry and particle swelling.To address these limitations,this study established a precise constitutive model to describe the swelling particle slurry diffusion process in dynamic water.Additionally,a coupling calculation method was proposed to analyze the spatiotemporal heterogeneity of viscosity during slurry diffusion by considering the migration of slurry and the changes in viscosity.To investigate the interaction between particle swelling and flow field changes,a Compu-tational Fluid Dynamics-Discrete Element Method(CFD-DEM)coupling model was developed for the diffusion of swelling particle slurry.It is demonstrated that slurry viscosity increases exponentially within the diffusion front as the particle swelling rate rises,and the drag force exhibits an intriguing behavior of initially increasing and then decreasing as the slurry flows through the pipeline.Further-more,the CFD-DEM coupling model proved to be more accurate in describing viscosity distribution and diffusion distance compared to the finite element solution.The primary objective of this paper is to reveal the plugging mechanism and provide theoretical support for the engineering application of the swelling particle grouting material.
