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Composition optimization and performance prediction for ultra-stable water-based aerosol based on thermodynamic entropy theory
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作者 Tingting Kang Canjun Yan +6 位作者 Xinying Zhao Jingru Zhao Zixin Liu Chenggong Ju Xinyue Zhang Yun Zhang Yan Wu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期437-446,共10页
Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of th... Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of the water-based aerosol is always unsatisfactory due to the rapid evaporation and sedimentation of the aerosol droplets.Great efforts have been devoted to improve the stability of water-based aerosol by using additives with different composition and proportion.However,the lack of the criterion and principle for screening the effective additives results in excessive experimental time consumption and cost.And the stabilization time of the aerosol is still only 30 min,which could not meet the requirements of the perdurable interference.Herein,to improve the stability of water-based aerosol and optimize the complex formulation efficiently,a theoretical calculation method based on thermodynamic entropy theory is proposed.All the factors that influence the shielding effect,including polyol,stabilizer,propellant,water and cosolvent,are considered within calculation.An ultra-stable water-based aerosol with long duration over 120 min is obtained with the optimal fogging agent composition,providing enough time for fighting the electro-optic weapon.Theoretical design guideline for choosing the additives with high phase transition temperature and low phase transition enthalpy is also proposed,which greatly improves the total entropy change and reduce the absolute entropy change of the aerosol cooling process,and gives rise to an enhanced stability of the water-based aerosol.The theoretical calculation methodology contributes to an abstemious time and space for sieving the water-based aerosol with desirable performance and stability,and provides the powerful guarantee to the homeland security. 展开更多
关键词 Ultra-stable water-based aerosol Thermodynamic entropy Composition optimization Performance prediction
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Improving the anti-collapse performance of water-based drilling fluids of Xinjiang Oilfield using hydrophobically modified silica nanoparticles with cationic surfactants 被引量:1
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作者 He Li Xian-Bin Huang +3 位作者 Jin-Sheng Sun Kai-He Lv Xu Meng Zhen Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1768-1778,共11页
Wellbore instability,especially drilling with water-based drilling fluids(WBDFs)in complex shale for-mations,is a critical challenge for oil and gas development.The purpose of this paper is to study the feasibility of... Wellbore instability,especially drilling with water-based drilling fluids(WBDFs)in complex shale for-mations,is a critical challenge for oil and gas development.The purpose of this paper is to study the feasibility of using hydrophobically modified silica nanoparticle(HMN)to enhance the comprehensive performance of WBDFs in the Xinjiang Oilfield,especially the anti-collapse performance.The effect of HMN on the overall performance of WBDFs in the Xinjiang Oilfield,including inhibition,plugging,lu-bricity,rheology,and filtration loss,was studied with a series of experiments.The mechanism of HMN action was studied by analyzing the changes of shale surface structure and chemical groups,wettability,and capillary force.The experimental results showed that HMN could improve the performance of WBDFs in the Xinjiang Oilfeld to inhibit the hydration swelling and dispersion of shale.The plugging and lubrication performance of the WBDFs in the Xinjiang Oilfield were also enhanced with HMN based on the experimental results.HMN had less impact on the rheological and filtration performance of the WBDFs in the Xinjiang Oilfield.In addition,HMN significantly prevented the decrease of shale strength.The potential mechanism of HMN was as follows.The chemical composition and structure of the shale surface were altered due to the adsorption of HMN driven by electrostatic attraction.Changes of the shale surface resulted in significant wettability transition.The capillary force of the shale was converted from a driving force of water into the interior to a resistance.In summary,hydrophobic nanoparticles presented afavorable application potential for WBDFs. 展开更多
关键词 Hydrophobic nanoparticle Wetting alteration Wellbore stability water-based drilling fluids SHALE
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Hydrophobic Small-Molecule Polymers as High-Temperature-Resistant Inhibitors in Water-Based Drilling Fluids
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作者 Xuyang Yao Kecheng Liu +5 位作者 Zenan Zhou Jun Zhou Xianbin Huang Tiemei Lu Yongsheng Yu He Li 《Fluid Dynamics & Materials Processing》 EI 2023年第7期1775-1787,共13页
Water-based drilling fluids can cause hydration of the wellbore rocks,thereby leading to instability.This study aimed to synthesize a hydrophobic small-molecule polymer(HLMP)as an inhibitor to suppress mud shale hydra... Water-based drilling fluids can cause hydration of the wellbore rocks,thereby leading to instability.This study aimed to synthesize a hydrophobic small-molecule polymer(HLMP)as an inhibitor to suppress mud shale hydration.An infrared spectral method and a thermogravimetric technique were used to characterize the chemical composition of the HLMP and evaluate its heat stability.Experiments were conducted to measure the linear swelling,rolling recovery rate,and bentonite inhibition rate and evaluate accordingly the inhibition performance of the HLMP.Moreover,the HLMP was characterized through measurements of the zeta potential,particle size distribution,contact angles,and interlayer space testing.As confirmed by the results,the HLMP could successfully be synthesized with a favorable heat stability.Furthermore,favorable results were found for the inhibitory processes of the HLMP on swelling and dispersed hydration during mud shale hydration.The positively charged HLMP could be electrically neutralized with clay particles,thereby inhibiting diffusion in the double electron clay layers.The hydrophobic group in the HLMP molecular structure resulted in the formation of a hydrophobic membrane on the rock surface,enhancing the hydrophobicity of the rock.In addition,the small molecules of the HLMP could plug the spaces between the layers of bentonite crystals,thereby reducing the entry of water molecules and inhibiting shale hydration. 展开更多
关键词 water-based drilling fluids hydrophobic polymers shale inhibitor temperature resistance
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Water-based synthesis of nanoscale hierarchical metal-organic frameworks:Boosting adsorption and catalytic performance
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作者 Yi Yu Zewei Liu +3 位作者 Xiaofei Chen Shujun Liu Chongxiong Duan Hongxia Xi 《Nano Materials Science》 EI CAS CSCD 2023年第4期361-368,共8页
The combination of nano sizes,large pore sizes and green synthesis is recognized as one of the most crucial and challenging problems in constructing metal-organic frameworks(MOFs).Herein,a water-based strategy is prop... The combination of nano sizes,large pore sizes and green synthesis is recognized as one of the most crucial and challenging problems in constructing metal-organic frameworks(MOFs).Herein,a water-based strategy is proposed for the synthesis of nanoscale hierarchical MOFs(NH-MOFs)with high crystallinity and excellent stability.This approach allows the morphology and porosity of MOFs to be fine tuned,thereby enabling the nanoscale crystal generation and a well-defined hierarchical system.The aqueous solution facilitates rapid nucleation kinetics,and the introduced modulator acts as a deprotonation agent to accelerate the deprotonation of the organic ligand as well as a structure-directing agent(SDA)to guide the formation of hierarchical networks.The assynthesized NH-MOFs(NH-ZIF-67)were assessed as efficient adsorbents and heterogeneous catalysts to facilitate the diffusion of guest molecules,outperforming the parent microZIF-67.This study focuses on understanding the NH-MOF growth rules,which could allow tailor-designing NH-MOFs for various functions. 展开更多
关键词 Nanoscale hierarchical metal-organic framework water-based synthesis Volatile organic compounds Olefins oxidation
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Water-Based Environmentally Friendly Pesticide Formulations Based on Cyclodextrin/Pesticide Loading System
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作者 Xinyu Guo Zhe Sun +5 位作者 Rui Zhao Hongyi Shang Jiangyu Liu Yong Xu Laihua Liu Xuemin Wu 《Journal of Renewable Materials》 SCIE EI 2023年第2期777-789,共13页
Difenoconazole(DIF)is a representative variety of broad-spectrum triazole fungicides and liposoluble pesticides.However,the water solubility of DIF is so poor that its application is limited in plant protection.In add... Difenoconazole(DIF)is a representative variety of broad-spectrum triazole fungicides and liposoluble pesticides.However,the water solubility of DIF is so poor that its application is limited in plant protection.In addition,the conventional formulations of DIF always contain abundant organic solvents,which may cause pollution of the environment.In this study,two DIF/cyclodextrins(CDs)inclusion complexes(ICs)were successfully prepared,which were DIF/β-CD IC and DIF/hydroxypropyl-β-CD IC(DIF/HP-β-CD IC).The effect of cyclodextrins on the water solubility and the antifungal effect of liposoluble DIF pesticide were investigated.According to the phase solubility test,the molar ratio and apparent stability constant of ICs were obtained.Fourier transform infrared spectroscopy,thermal gravity analysis,X-ray diffraction and scanning electron microscopy were used systematically to characterize the formation and characteristics of ICs.The results noted that DIF successfully entered the cavities of two CDs.In addition,the antifungal effect test proved the better performance of DIF/HP-β-CD IC,which exceeded that of DIF emulsifiable concentrate.Therefore,our study provides informative direction for the intelligent use of liposoluble pesticides with cyclodextrins to develop water-based environmentally friendly formulations. 展开更多
关键词 water-based environmentally friendly pesticide formulations DIFENOCONAZOLE Β-CYCLODEXTRIN HYDROXYPROPYL-Β-CYCLODEXTRIN inclusion complex preparation characterization
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Clinical Analysis and Mental Health Survey of Hemophilia Carriers:a Cross-sectional Study
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作者 Wen WANG Li-juan JIANG +4 位作者 Dong-yan CUI Ai ZHANG Xiong WANG Ai-guo LIU Qun HU 《Current Medical Science》 SCIE CAS 2024年第2期435-440,共6页
Objective:Hemophilia carriers(HCs),who are heterozygous for mutations in the clotting factor VIII/clotting factor IX gene(F8 or F9),may have a wide range of clotting factor levels,from very low,similar to afflicted ma... Objective:Hemophilia carriers(HCs),who are heterozygous for mutations in the clotting factor VIII/clotting factor IX gene(F8 or F9),may have a wide range of clotting factor levels,from very low,similar to afflicted males,to the upper limit of normal,and may experience mental health issues.The purpose of this study was to provide genetic information on mothers of hemophilia patients and to understand the clotting factor activity and phenotype of HCs.Additionally,we aimed to investigate the mental health status of HCs in China.Methods:A total of 127 hemophilia mothers,including 93 hemophilia A(HA)mothers and 34 hemophilia B(HB)mothers,were enrolled in this study.Long distance PCR,multiplex PCR,and Sanger sequencing were used to analyze mutations in F8 or F9.Coagulation factor activity was detected by a one-stage clotting assay.The Symptom Checklist 90(SCL-90,China/Mandarin version)was given to HCs at the same time to assess their mental health.Results:A total of 90.6%of hemophilia mothers were diagnosed genetically as carriers,with inversion in intron 22 and missense mutations being the most common mutation types in HA and HB carriers,respectively.The median clotting factor level in carriers was 0.74 IU/mL(ranging from 0.09 to 1.74 IU/mL)compared with 1.49 IU/mL(ranging from 0.93 to 1.89 IU/mL)in noncarriers,of which 14.3%of HCs had clotting factor levels of 0.40 IU/mL or below.A total of 53.8%(7/13)of HA carriers with low clotting factor levels(less than 0.50 IU/mL)had a history of bleeding,while none of the HB carriers displayed a bleeding phenotype.The total mean score and the global severity index of the SCL-90 for surveyed HCs were 171.00(±60.37)and 1.78(±0.59),respectively.A total of 67.7%of the respondents had psychological symptoms,with obsessive-compulsive disorder being the most prevalent and severe.The pooled estimates of all nine factors were significantly higher than those in the general population(P<0.05).Conclusions:The detection rate of gene mutations in hemophilia mothers was 90.6%,with a median clotting factor level of 0.74 IU/mL,and 14.3%of HCs had a clotting factor level of 0.40 IU/mL or below.A history of bleeding was present in 41.2%of HCs with low clotting factor levels(less than 0.50 IU/mL).Additionally,given the fragile mental health status of HCs in China,it is critical to develop efficient strategies to improve psychological well-being. 展开更多
关键词 hemophilia A hemophilia B MUTATION carrier mental health
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Vertical plane depth-resolved surface potential and carrier separation characteristics in flexible CZTSSe solar cells with over 12% efficiency
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作者 Dae-Ho Son Ha Kyung Park +11 位作者 Dae-Hwan Kim Jin-Kyu Kang Shi-Joon Sung Dae-Kue Hwang Jaebaek Lee Dong-Hwan Jeon Yunae Cho William Jo Taeseon Lee JunHo Kim Sang-Hoon Nam Kee-Jeong Yang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第3期36-52,共17页
Cu2ZnSn(S,Se)4(CZTSSe)solar cells have resource distribution and economic advantages.The main cause of their low efficiency is carrier loss resulting from recombination of photo-generated electron and hole.To overcome... Cu2ZnSn(S,Se)4(CZTSSe)solar cells have resource distribution and economic advantages.The main cause of their low efficiency is carrier loss resulting from recombination of photo-generated electron and hole.To overcome this,it is important to understand their electron-hole behavior characteristics.To determine the carrier separation characteristics,we measured the surface potential and the local current in terms of the absorber depth.The elemental variation in the intragrains(IGs)and at the grain boundaries(GBs)caused a band edge shift and bandgap(Eg)change.At the absorber surface and subsurface,an upward Ec and Ev band bending structure was observed at the GBs,and the carrier separation was improved.At the absorber center,both upward Ec and Ev and downward Ec-upward Ev band bending structures were observed at the GBs,and the carrier separation was degraded.To improve the carrier separation and suppress carrier recombination,an upward Ec and Ev band bending structure at the GBs is desirable. 展开更多
关键词 carrier separation CZTSSe flexible solar cell local current surface potential
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Ultrafast carrier dynamics in GeSn thin film based on time-resolved terahertz spectroscopy
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作者 黄盼盼 张有禄 +3 位作者 胡凯 齐静波 张岱南 程亮 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期164-169,共6页
We measure the time-resolved terahertz spectroscopy of GeSn thin film and studied the ultrafast dynamics of its photo-generated carriers.The experimental results show that there are photo-generated carriers in GeSn un... We measure the time-resolved terahertz spectroscopy of GeSn thin film and studied the ultrafast dynamics of its photo-generated carriers.The experimental results show that there are photo-generated carriers in GeSn under femtosecond laser excitation at 2500 nm,and its pump-induced photoconductivity can be explained by the Drude–Smith model.The carrier recombination process is mainly dominated by defect-assisted Auger processes and defect capture.The firstand second-order recombination rates are obtained by the rate equation fitting,which are(2.6±1.1)×10^(-2)ps^(-1)and(6.6±1.8)×10^(-19)cm^(3)·ps^(-1),respectively.Meanwhile,we also obtain the diffusion length of photo-generated carriers in GeSn,which is about 0.4μm,and it changes with the pump delay time.These results are important for the GeSn-based infrared optoelectronic devices,and demonstrate that Ge Sn materials can be applied to high-speed optoelectronic detectors and other applications. 展开更多
关键词 GeSn thin film time-resolved THz spectroscopy ultrafast dynamics carrier recombination
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Experimental Study on Gas Flow Uniformity in a Diesel Particulate Filter Carrier
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作者 Zhengyong Wang Jianhua Zhang +5 位作者 Guoliang Su Peixing Yang Xiantao Fan Shuzhan Bai Ke Sun Guihua Wang 《Fluid Dynamics & Materials Processing》 EI 2024年第1期193-204,共12页
A Diesel Particulate Filter(DPF)is a critical device for diesel engine exhaust products treatment.When using active-regeneration purification methods,on the one hand,a spatially irregular gas flow can produce relative... A Diesel Particulate Filter(DPF)is a critical device for diesel engine exhaust products treatment.When using active-regeneration purification methods,on the one hand,a spatially irregular gas flow can produce relatively high local temperatures,potentially resulting in damage to the carrier;On the other hand,the internal temperature field can also undergo significant changes contributing to increase this risk.This study explores the gas flow uniformity in a DPF carrier and the related temperature behavior under drop-to-idle(DTI)condition by means of bench tests.It is shown that the considered silicon carbide carrier exhibits good flow uniformity,with a temperature deviation of no more than 2%with respect to the same radius measurement point at the outlet during the regeneration stage.In the DTI test,the temperature is relatively high within r/2 near the outlet end,where the maximum temperature peak occurs,and the maximum radial temperature gradient is located between r/2 and the edge.Both these quantities grow as the soot load increases,thereby making the risk of carrier burnout greater.Finally,it is shown that the soot load limit of the silicon carbide DPF can be extended to 11 g/L,which reduces the frequency of active regeneration by approximately 40%compared to a cordierite DPF. 展开更多
关键词 DPF flow uniformity DTI silicon carbide carrier soot load
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Atomic Ni directional-substitution on ZnIn_(2)S_(4) nanosheet to achieve the equilibrium of elevated redox capacity and efficient carrier-kinetics performance in photocatalysis
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作者 Haibin Huang Guiyang Yu +5 位作者 Xingze Zhao Boce Cui Jinshi Yu Chenyang Zhao Heyuan Liu Xiyou Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期272-281,I0007,共11页
It is a challenge to coordinate carrier-kinetics performance and the redox capacity of photogenerated charges synchronously at the atomic level for boosting photocatalytic activity.Herein,the atomic Ni was introduced ... It is a challenge to coordinate carrier-kinetics performance and the redox capacity of photogenerated charges synchronously at the atomic level for boosting photocatalytic activity.Herein,the atomic Ni was introduced into the lattice of hexagonal ZnIn_(2)S_(4) nanosheets(Ni/ZnIn_(2)S_(4))via directionalsubstituting Zn atom with the facile hydrothermal method.The electronic structure calculations indicate that the introduction of Ni atom effectively extracts more electrons and acts as active site for subsequent reduction reaction.Besides the optimized light absorption range,the elevation of Efand ECBendows Ni/ZnIn_(2)S_(4) photocatalyst with the increased electron concentration and the enhanced reduction ability for surface reaction.Moreover,ultrafast transient absorption spectroscopy,as well as a series of electrochemical tests,demonstrates that Ni/ZnIn_(2)S_(4) possesses 2.15 times longer lifetime of the excited charge carriers and an order of magnitude increase for carrier mobility and separation efficiency compared with pristine ZnIn_(2)S_(4).These efficient kinetics performances of charge carriers and enhanced redox capacity synergistically boost photocatalytic activity,in which a 3-times higher conversion efficiency of nitrobenzene reduction was achieved upon Ni/ZnIn_(2)S_(4).Our study not only provides in-depth insights into the effect of atomic directional-substitution on the kinetic behavior of photogenerated charges,but also opens an avenue to the synchronous optimization of redox capacity and carrier-kinetics performance for efficient solar energy conversion. 展开更多
关键词 ZnIn_(2)S_(4) SUBSTITUTION carrier kinetics Redox capacity PHOTOCATALYSIS
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CO_(2)capture costs of chemical looping combustion of biomass:A comparison of natural and synthetic oxygen carrier
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作者 Benjamin Fleiß Juraj Priscak +3 位作者 Martin Hammerschmid Josef Fuchs Stefan Müller Hermann Hofbauer 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期296-310,共15页
Chemical looping combustion has the potential to be an efficient and low-cost technology capable of contributing to the reduction of the atmospheric concentration of CO_(2) in order to reach the 1.5/2°C goal and ... Chemical looping combustion has the potential to be an efficient and low-cost technology capable of contributing to the reduction of the atmospheric concentration of CO_(2) in order to reach the 1.5/2°C goal and mitigate climate change.In this process,a metal oxide is used as oxygen carrier in a dual fluidized bed to generate clean CO_(2) via combustion of biomass.Most commonly,natural ores or synthetic materials are used as oxygen carrier whereas both must meet special requirements for the conversion of solid fuels.Synthetic oxygen carriers are characterized by higher reactivity at the expense of higher costs versus the lower-cost natural ores.To determine the viability of both possibilities,a techno-economic comparison of a synthetic material based on manganese,iron,and copper to the natural ore ilmenite was conducted.The synthetic oxygen carrier was characterized and tested in a pilot plant,where high combustion efficiencies up to 98.4%and carbon capture rates up to 98.5%were reached.The techno-economic assessment resulted in CO_(2) capture costs of 75 and 40€/tCO_(2) for the synthetic and natural ore route respectively,whereas a sensitivity analysis showed the high impact of production costs and attrition rates of the synthetic material.The synthetic oxygen carrier could break even with the natural ore in case of lower production costs and attrition rates,which could be reached by adapting the production process and recycling material.By comparison to state-of-the-art technologies,it is demonstrated that both routes are viable and the capture cost of CO_(2) could be reduced by implementing the chemical looping combustion technology. 展开更多
关键词 Chemical looping combustion BECCS Techno-economic assessment CO_(2)capture costs Oxygen carrier development Synthetic materials ILMENITE
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Mitochondrial carrier homolog 2 increases malignant phenotype of human gastric epithelial cells and promotes proliferation,invasion,and migration of gastric cancer cells
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作者 Jing-Wen Zhang Ling-Yan Huang +3 位作者 Ya-Ning Li Ying Tian Jia Yu Xiao-Fei Wang 《World Journal of Gastrointestinal Oncology》 SCIE 2024年第3期991-1005,共15页
BACKGROUND The precise role of mitochondrial carrier homolog 2(MTCH2)in promoting malignancy in gastric mucosal cells and its involvement in gastric cancer cell metastasis have not been fully elucidated.AIM To determi... BACKGROUND The precise role of mitochondrial carrier homolog 2(MTCH2)in promoting malignancy in gastric mucosal cells and its involvement in gastric cancer cell metastasis have not been fully elucidated.AIM To determine the role of MTCH2 in gastric cancer.METHODS We collected 65 samples of poorly differentiated gastric cancer tissue and adjacent tissues,constructed MTCH2-overexpressing and MTCH2-knockdown cell models,and evaluated the proliferation,migration,and invasion of human gastric epithelial cells(GES-1)and human gastric cancer cells(AGS)cells.The mito-chondrial membrane potential(MMP),mitochondrial permeability transformation pore(mPTP)and ATP fluorescence probe were used to detect mitochondrial function.Mitochondrial function and ATP synthase protein levels were detected via Western blotting.RESULTS The expression of MTCH2 and ATP2A2 in gastric cancer tissues was significantly greater than that in adjacent tissues.Overexpression of MTCH2 promoted colony formation,invasion,migration,MMP expression and ATP production in GES-1 and AGS cells while upregulating ATP2A2 expression and inhibiting cell apoptosis;knockdown of MTCH2 had the opposite effect,promoting overactivation of the mPTP and promoting apoptosis.CONCLUSION MTCH2 can increase the malignant phenotype of GES-1 cells and promote the proliferation,invasion,and migration of gastric cancer cells by regulating mitochondrial function,providing a basis for targeted therapy for gastric cancer cells. 展开更多
关键词 Gastric cancer Mitochondrial carrier homolog 2 ATP synthase ATP2A2 Mitochondrial permeability transformation pore
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The Extended Hybrid Carrier-Based Multiple Access Technology for High Mobility Scenarios
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作者 Ge Song Xiaojie Fang Xuejun Sha 《China Communications》 SCIE CSCD 2024年第1期53-68,共16页
The hybrid carrier(HC)system rooted in the carrier fusion concept is gradually garnering attention.In this paper,we study the extended hybrid carrier(EHC)multiple access scheme to ensure reliable wireless communicatio... The hybrid carrier(HC)system rooted in the carrier fusion concept is gradually garnering attention.In this paper,we study the extended hybrid carrier(EHC)multiple access scheme to ensure reliable wireless communication.By employing the EHC modulation,a power layered multiplexing framework is realized,which exhibits enhanced interference suppression capability owing to the more uniform energy distribution design.The implementation method and advantage mechanism are explicated respectively for the uplink and downlink,and the performance analysis under varying channel conditions is provided.In addition,considering the connectivity demand,we explore the non-orthogonal multiple access(NOMA)method of the EHC system and develop the EHC sparse code multiple access scheme.The proposed scheme melds the energy spread superiority of EHC with the access capacity of NOMA,facilitating superior support for massive connectivity in high mobility environments.Simulation results have verified the feasibility and advantages of the proposed scheme.Compared with existing HC multiple access schemes,the proposed scheme exhibits robust bit error rate performance and can better guarantee multiple access performance in complex scenarios of nextgeneration communications. 展开更多
关键词 extended hybrid carrier system high mo-Received:Jun.09 2023 Revised:Nov.20 2023 Editor:Yuanwei Liu bility communications multiple access
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High temperature and high pressure rheological properties of high-density water-based drilling fluids for deep wells 被引量:9
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作者 Wang Fuhua Tan Xuechao +3 位作者 Wang Ruihe Sun Mingbo Wang Li Liu Jianghua 《Petroleum Science》 SCIE CAS CSCD 2012年第3期354-362,共9页
To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines... To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids (fresh water-based and brine-based) under high temperature and high pressure (HTHP) with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site. 展开更多
关键词 High-density water-based drilling fluid rheological behavior CLAY high temperature high pressure linear fitting rheological model mathematical model
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Solidification and utilization of water-based drill cuttings to prepare ceramsite proppant with low-density and high performance 被引量:2
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作者 Hang Yang Yun-Li Liu +3 位作者 Guo-Liang Bai Zhen Feng Yi Zhang Shi-Bin Xia 《Petroleum Science》 SCIE CAS CSCD 2022年第5期2314-2325,共12页
Water-based drill cuttings(WBDC)and bauxite are used as raw materials to prepare proppants with low density and high performance.The effects of sintering temperature,sintering period,mixture ratios of materials,doping... Water-based drill cuttings(WBDC)and bauxite are used as raw materials to prepare proppants with low density and high performance.The effects of sintering temperature,sintering period,mixture ratios of materials,doping with iron oxide,and acid modification of WBDC on the properties of proppants are discussed.The proppant performance is evaluated according to the national standard SY/T5108-2014.The morphology of the proppant is analyzed using scanning electron microscopy(SEM).The crystal phase structure of the proppant is studied using X-ray diffraction(XRD).Thermal analysis of the proppant sintering process is performed using thermogravimetry(TG).Proppant Z-23 completely satisfied the SY/T5108-2014 standard.This study provides a new perspective for the resource utilization of water-based drill cuttings and preparation of low-density proppants. 展开更多
关键词 water-based drill cuttings PROPPANT Thermal analysis Solid waste
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Carbon nanotube enhanced water-based drilling fluid for high temperature and high salinity deep resource development 被引量:2
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作者 Jing-Ping Liu Xian-Fa Zhang +6 位作者 Wen-Chao Zhang Kai-He Lv Yin-Rui Bai Jin-Tang Wang Xian-Bin Huang Jia-Feng Jin Jin-Sheng Sun 《Petroleum Science》 SCIE CAS CSCD 2022年第2期916-926,共11页
Drilling fluids face failure during drilling deep reservoir with high temperature and high salt.The experimental results show that high temperature and salinity reduce the negative charge on the surface of bentonite i... Drilling fluids face failure during drilling deep reservoir with high temperature and high salt.The experimental results show that high temperature and salinity reduce the negative charge on the surface of bentonite in the drilling fluid and cause the coalescence of bentonite particles.As a result,the particles coalesce,the grid structure is destroyed,and the rheological properties,rock-carrying capacity and filtration properties are lost.To resolve the foregoing,in this study,0.05-wt%carbon nanotubes are introduced into a 4%bentonite drilling fluid under conditions where the temperature and concentration of added Na Cl reach 180°C and 10 wt%,respectively.The carbon nanotubes adsorb on the bentonite surface and increase the space among bentonite particles.The steric hindrance prevents the coalescence of bentonite in high temperature and high salt environment.Thus bentonite maintains the small size distribution of bentonite and supports the bentonite grid structure in the drilling fluid.As a result,the rock-carrying capacity of the drilling fluid increases by 85.1%.Moreover,the mud cake formed by the accumulation of small-sized bentonite particles is dense;consequently,the filtration of bentonite drilling fluid reduced by 30.2%. 展开更多
关键词 High temperature water-based drilling fluid High salinity Carbon nanotube Deep resources
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Investigation of regulating rheological properties of water-based drilling fluids by ultrasound 被引量:1
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作者 Wei-An Huang Jing-Wen Wang +4 位作者 Ming Lei Gong-Rang Li Zhi-Feng Duan Zhi-Jun Li Shi-Fu Yu 《Petroleum Science》 SCIE CAS CSCD 2021年第6期1698-1708,共11页
Regulating rheological properties of water-based drilling fluids has always been a hot topic.This paper proposed a new method for regulating rheological properties of water-based drilling fluids by ultrasonic field.Th... Regulating rheological properties of water-based drilling fluids has always been a hot topic.This paper proposed a new method for regulating rheological properties of water-based drilling fluids by ultrasonic field.The experimental results showed that the ultrasound increased the viscosity and yield point of bentonite suspension by reducing the particle size of clay,destroying the network structure between clay particles,increasing the mud yield and the cation exchange capacity of bentonite,and promoting the hydration dispersion of bentonite.The change of rheological property showed a memory effect at room temperature and high temperature.Besides,the ultrasonic energy affected the network structure between clays and polymer chains,thus regulating the rheological properties of the bentonite-polymer system.For two types of drilling fluids investigated,the rheology of the poly-sulfonate drilling fluid was regulated by damaging the grid structure between additives and clays by low-power ultrasound and reducing the clay particle size by high-power ultrasound,while the rheology of the deep-water drilling fluid was mainly regulated by disentangling the spatial grid structure between additives.Additionally,ultrasound showed no effect on the lubricity,inhibition and stability of drilling fluids,which proved the feasibility of ultrasound to regulate rheological properties of water-based drilling fluids. 展开更多
关键词 ULTRASOUND SUSPENSION water-based drilling fluid Rheological property
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Notoginsenoside as an environmentally friendly shale inhibitor in water-based drilling fluid 被引量:1
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作者 Jin-Sheng Sun Zong-Lun Wang +6 位作者 Jing-Ping Liu Kai-He Lv Fan Zhang Zi-Hua Shao Xiao-Dong Dong Zhi-Wen Dai Xian-Fa Zhang 《Petroleum Science》 SCIE CAS CSCD 2022年第2期608-618,共11页
The demand for non-toxic and biodegradable shale inhibitors is growing in the drilling industry.In this paper,the effect of notoginsenoside(NS)as a new,environmentally friendly inhibitor of shale hydration is systemat... The demand for non-toxic and biodegradable shale inhibitors is growing in the drilling industry.In this paper,the effect of notoginsenoside(NS)as a new,environmentally friendly inhibitor of shale hydration is systematically studied for the first time.The inhibition performance of NS was evaluated via inhibition evaluation tests,including mud ball immersion tests,linear expansion tests,shale rolling recovery tests,and compressive strength tests.The inhibition mechanism of NS was analyzed using Fourier transform infrared spectroscopy(FTIR),contact angle measurements,particle size distribution determination,thermogravimetric analysis(TGA),and scanning electron microscopy(SEM).The experimental results demonstrate that NS is able to adhere to the clay surface,forming a hydrophobic film that prevents the entry of water molecules and inhibiting the hydration dispersion of the clay.Because of this,NS can maintain the original state of bentonite pellets in water,which can effectively reduce the swelling rate of bentonite,increase the recovery rate of shale drill cuttings,maintain the strength of the shale,and therefore maintain the stability of the borehole wall during drilling.In addition,NS is non-toxic,degradable,and compatible with water-based drilling fluids.The above advantages make NS a promising candidate for use as an environmentally friendly shale inhibitor. 展开更多
关键词 Notoginsenoside Shale inhibition Environmentally friendly water-based drilling fluid Inhibition mechanism
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Double-layer Modifi cation of Water-based Aluminum with SiO2 and Polyacrylic Acid by Solgel Process and in situ Polymerization 被引量:4
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作者 何宇航 黎厚斌 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2016年第2期231-235,共5页
A double-layer aluminum consisting of an aluminum core and a shellof SiO2 and polyacrylic acid was synthesized.This modified aluminum was used to improve the corrosion resistance and dispersive property of aluminum in... A double-layer aluminum consisting of an aluminum core and a shellof SiO2 and polyacrylic acid was synthesized.This modified aluminum was used to improve the corrosion resistance and dispersive property of aluminum in waterborne media.TEM,FTIR,XPS,and EDX determination showed that PAA and SiO2 were coated on the surface of aluminum.Evolved hydrogen detection showed that the corrosion resistance of composite particle had been markedly improved.Maximum corrosion inhibition efficiency of SiO2 coated aluminum(SiO2@Al)was 95.1% while that of double-layer coated aluminum(PAA/SiO2@Al)was 98.8%.Meanwhile,polyacrylic acid layer improved the agglomeration of aluminum significantly.According to the dispersibility test,the particle size of 50% volume fraction [d(0.5)] of aluminum,SiO2@Aland PAA/SiO2@Alwere 42,53,and 34 μm,respectively. 展开更多
关键词 flaky aluminum water-based pigments polymer coating alkaline corrosion
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Application of sustainable basil seed as an eco-friendly multifunctional additive for water-based drilling fluids 被引量:1
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作者 Xin Gao Han-Yi Zhong +3 位作者 Xian-Bin Zhang An-Liang Chen Zheng-Song Qiu Wei-An Huang 《Petroleum Science》 SCIE CAS CSCD 2021年第4期1163-1181,共19页
Basil seed,containing anionic heteropolysaccharides in its outer pericarp,swells as gelatinous hydrocolloid when soaked in water.In this study,basil seed powder(BSP)was used as a multifunctional additive for water-bas... Basil seed,containing anionic heteropolysaccharides in its outer pericarp,swells as gelatinous hydrocolloid when soaked in water.In this study,basil seed powder(BSP)was used as a multifunctional additive for water-based drilling fluids.The chemical composition,water absorbency,rheological properties of aqueous suspension of BSP were tested.The effect of BSP on the rheological and filtration of bentonitebased drilling fluid before and after thermal aging was investigated.The inhibition characteristics were evaluated by linear swelling,shale cuttings dispersion and shale immersion test.Lubricity improvement by BSP was measured with extreme pressure lubricity test.The results revealed that incorporation of BSP into bentonite suspension improved rheological and filtration properties effectively after thermal aging of 120℃.BSP exhibited superior inhibitive capacity to xanthan and synergistic effect with KCl.BSP could reduce friction by forming hydration layer.The nanoscale three-dimensional network structures enable BSP to maintain high water retention and absorb strongly on bentonite and metal surface,contributing to enhanced rheology,filtration,inhibition and lubrication properties.The versatile characteristic of BSP,as well as biodegradation makes it a promising additive using in high performance water-based drilling fluid and a potential alternative to conventional synthetic polymers. 展开更多
关键词 Basil seed Water absorbency MULTIFUNCTION water-based drilling fluid Three-dimensional network
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