In this study,indium oxide（In2O3） thin-film transistors（TFTs） are fabricated by two kinds of low temperature solution-processed technologies（Ta ≤ 300℃）,i.e.,water-based（DIW-based） process and alkoxide-based...In this study,indium oxide（In2O3） thin-film transistors（TFTs） are fabricated by two kinds of low temperature solution-processed technologies（Ta ≤ 300℃）,i.e.,water-based（DIW-based） process and alkoxide-based（2-ME-based）process.The thickness values,crystallization properties,chemical structures,surface roughness values,and optical properties of In2O3 thin-films and the electrical characteristics of In2O3 TFTs are studied at different annealing temperatures.Thermal annealing at higher temperature leads to an increase in the saturation mobility（μsat） and a negative shift in the threshold voltage（VTH）.The DIW-based processed In2O3-TFT annealed at 300℃ exhibits excellent device performance,and one annealed at 200℃ exhibits an acceptable μsat of 0.86 cm^2/V·s comparable to that of a-Si：H TFTs,whereas the 2-ME-based TFT annealed at 300℃ exhibits an abundant μsat of 1.65 cm^2/Vs and one annealed at 200℃ is inactive.The results are attributed to the fact that the DIW-based process induces a higher degree of oxidation and less defect states than the 2-ME-based process at the same temperature.The DIW-based process for fabricating the In2O3 TFT opens the way for the development of nontoxic,low-cost,and low-temperature oxide electronics.展开更多
Songke Well No.2,one of the main part of the scientific drilling project in Songliao Basin,which was drilled 7018 m and acquired the part of cores continuously from the Low Cretaceous to the Carboniferous and the Perm...Songke Well No.2,one of the main part of the scientific drilling project in Songliao Basin,which was drilled 7018 m and acquired the part of cores continuously from the Low Cretaceous to the Carboniferous and the Permian from the 2843 m deep,can be considered as the deepest continental drilling project in Asia.Aiming at the features of longer well sections,larger diameters and multiple spud-ins for coring of Songke Well No.2,this project broke through the "coring in small diameter and reaming in large diameter"spud-in drilling-completion procedures which are always used in large-diameter-well coring for continental scientific drilling projects in domestic and overseas and the drilling method of short-singlecylinder roundtrip footage.At the same time,"coring in the same diameter and completing drilling at one single diameter"was achieved at all φ311 mm and φ216 mm coring sections of more than one thousand meters long,high-efficient operation with "drilling long footage with drill tools combined in multicylinders"was achieved at deep coring section.Four world drilling records were created which include more than a thousand meters continuous coring at φ311 mm,and the footage per roundtrip footage at φ311 mm,φ216 mm and φ152 mm is all more than 30 m,all of these breakthroughs reduced at least 300 days for this project;moreover,considering the characteristics of formations that the geothermal gradient is high in the drilled sections and the inside-well temperature is over 240℃ after drilling completion,a formate-polymer water-based mud system was developed by compounding attapulgite and sodium bentonite and by adding independently developed high-temperature stabilizer,which can provide critical technical support for successful well completion at 7018 m in the super-high-temperature environment It is the first time that the water-based mud is operated at the working temperature higher than 240℃ in China;Besides,considering the high-quality requirement on cores imposed by the project,the method "mechanical cored is charge"to discharge core nondestructively on the ground was worked out,and more than 4000 m scatheless cores were discharged out of the drill pipes while maintaining original stratum structures.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.61675024)the National Basic Research Program of China(Grant No.2014CB643600)
文摘In this study,indium oxide（In2O3） thin-film transistors（TFTs） are fabricated by two kinds of low temperature solution-processed technologies（Ta ≤ 300℃）,i.e.,water-based（DIW-based） process and alkoxide-based（2-ME-based）process.The thickness values,crystallization properties,chemical structures,surface roughness values,and optical properties of In2O3 thin-films and the electrical characteristics of In2O3 TFTs are studied at different annealing temperatures.Thermal annealing at higher temperature leads to an increase in the saturation mobility（μsat） and a negative shift in the threshold voltage（VTH）.The DIW-based processed In2O3-TFT annealed at 300℃ exhibits excellent device performance,and one annealed at 200℃ exhibits an acceptable μsat of 0.86 cm^2/V·s comparable to that of a-Si：H TFTs,whereas the 2-ME-based TFT annealed at 300℃ exhibits an abundant μsat of 1.65 cm^2/Vs and one annealed at 200℃ is inactive.The results are attributed to the fact that the DIW-based process induces a higher degree of oxidation and less defect states than the 2-ME-based process at the same temperature.The DIW-based process for fabricating the In2O3 TFT opens the way for the development of nontoxic,low-cost,and low-temperature oxide electronics.
文摘Songke Well No.2,one of the main part of the scientific drilling project in Songliao Basin,which was drilled 7018 m and acquired the part of cores continuously from the Low Cretaceous to the Carboniferous and the Permian from the 2843 m deep,can be considered as the deepest continental drilling project in Asia.Aiming at the features of longer well sections,larger diameters and multiple spud-ins for coring of Songke Well No.2,this project broke through the "coring in small diameter and reaming in large diameter"spud-in drilling-completion procedures which are always used in large-diameter-well coring for continental scientific drilling projects in domestic and overseas and the drilling method of short-singlecylinder roundtrip footage.At the same time,"coring in the same diameter and completing drilling at one single diameter"was achieved at all φ311 mm and φ216 mm coring sections of more than one thousand meters long,high-efficient operation with "drilling long footage with drill tools combined in multicylinders"was achieved at deep coring section.Four world drilling records were created which include more than a thousand meters continuous coring at φ311 mm,and the footage per roundtrip footage at φ311 mm,φ216 mm and φ152 mm is all more than 30 m,all of these breakthroughs reduced at least 300 days for this project;moreover,considering the characteristics of formations that the geothermal gradient is high in the drilled sections and the inside-well temperature is over 240℃ after drilling completion,a formate-polymer water-based mud system was developed by compounding attapulgite and sodium bentonite and by adding independently developed high-temperature stabilizer,which can provide critical technical support for successful well completion at 7018 m in the super-high-temperature environment It is the first time that the water-based mud is operated at the working temperature higher than 240℃ in China;Besides,considering the high-quality requirement on cores imposed by the project,the method "mechanical cored is charge"to discharge core nondestructively on the ground was worked out,and more than 4000 m scatheless cores were discharged out of the drill pipes while maintaining original stratum structures.
