The strength of water-bearing rock cannot be obtained in real time and by nondestructive experiments,which is an issue at cultural relics protection sites such as grotto temples.To solve this problem,we conducted a ne...The strength of water-bearing rock cannot be obtained in real time and by nondestructive experiments,which is an issue at cultural relics protection sites such as grotto temples.To solve this problem,we conducted a near-infrared spectrum acquisition experiment in the field and laboratory uniaxial compression strength tests on sandstone that had different water saturation levels.The correlations between the peak height and peak area of the nearinfrared absorption bands of the water-bearing sandstone and uniaxial compressive strength were analyzed.On this basis,a strength prediction model for water-bearing sandstone was established using the long short-term memory full convolutional network(LSTM-FCN)method.Subsequently,a field engineering test was carried out.The results showed that:(1)The sandstone samples had four distinct characteristic absorption peaks at 1400,1900,2200,and 2325 nm.The peak height and peak area of the absorption bands near 1400 nm and 1900 nm had a negative correlation with uniaxial compressive strength.The peak height and peak area of the absorption bands near 2200 nm and 2325 nm had nonlinear positive correlations with uniaxial compressive strength.(2)The LSTM-FCN method was used to establish a strength prediction model for water-bearing sandstone based on near-infrared spectroscopy,and the model achieved an accuracy of up to 97.52%.(3)The prediction model was used to realize non-destructive,quantitative,and real-time determination of uniaxial compressive strength;this represents a new method for the non-destructive testing of grotto rock mass at sites of cultural relics protection.展开更多
We systemically investigate optical trapping capability of a kind of tornado waves on Rayleigh particles.Such tornado waves are named as tornado circular Pearcey beams(TCPBs)and produced by combining two circular Pear...We systemically investigate optical trapping capability of a kind of tornado waves on Rayleigh particles.Such tornado waves are named as tornado circular Pearcey beams(TCPBs)and produced by combining two circular Pearcey beams with different radii.Our theoretical exploration delves into various aspects,including the propagation dynamics,energy flux,orbital angular momentum,trapping force,and torque characteristics of TCPBs.The results reveal that the orbital angular momentum,trapping force,and torque of these beams can be finely tuned through the judicious manipulation of their topological charges(l_(1)and l_(2)).Notably,we observe a precise control mechanism wherein the force diminishes with|l_(1)+l_(2)|and|l_(1)-l_(2)|,while the torque exhibits enhancement by decreasing solely with|l_(1)+l_(2)|or increasing with|l_(1)-l_(2)|.These results not only provide quantitative insights into the optical trapping performance of TCPBs but also serve as a valuable reference for the ongoing development of innovative photonic tools.展开更多
おhe water-bearing numerical model is undergone all round examinations during the operational forecasting experiments from 1994 to 1996. A lot of difficult problems arising from the model′s water-bearing are successf...おhe water-bearing numerical model is undergone all round examinations during the operational forecasting experiments from 1994 to 1996. A lot of difficult problems arising from the model′s water-bearing are successfully resolved in these experiments through developing and using a series of technical measures. The operational forecasting running of the water-bearing numerical model is realized stably and reliably, and satisfactory forecasts are obtained.展开更多
In first paper of articles, the physical and calculating schemes of the water-bearing numerical model are described. The model is developed by bearing all species of hydrometeors in a conventional numerical model in ...In first paper of articles, the physical and calculating schemes of the water-bearing numerical model are described. The model is developed by bearing all species of hydrometeors in a conventional numerical model in which the dynamic framework of hydrostatic equilibrium is taken. The main contributions are: the mixing ratios of all species of hydrometeors are added as the prognostic variables of model, the prognostic equations of these hydrometeors are introduced, the cloud physical framework is specially designed, some technical measures are used to resolve a series of physical, mathematical and computational problems arising from water-bearing; and so on. The various problems (in such aspects as the designs of physical and calculating schemes and the composition of computational programme) which are exposed in feasibility test, in sensibility test, and especially in operational forecasting experiments are successfully resolved using a lot of technical measures having been developed from researches and tests. Finally, the operational forecasting running of the water-bearing numerical model and its forecasting system is realized stably and reliably, and the fine forecasts are obtained. All of these mentioned above will be described in second paper.展开更多
The emergence of Y6-type nonfullerene acceptors has greatly enhanced the power conversion efficiency(PCE)of organic solar cells(OSCs).However,which structural feature is responsible for the excellent photovoltaic perf...The emergence of Y6-type nonfullerene acceptors has greatly enhanced the power conversion efficiency(PCE)of organic solar cells(OSCs).However,which structural feature is responsible for the excellent photovoltaic performance is still under debate.In this study,two Y6-like acceptors BDOTP-1 and BDOTP-2 were designed.Different from previous Y6-type acceptors featuring an A–D–Aʹ–D–A structure,BDOTP-1,and BDOTP-2 have no electron-deficient Aʹfragment in the core unit.Instead,there is an electron-rich dibenzodioxine fragment in the core.Although this modification leads to a marked change in the molecular dipole moment,electrostatic potential,frontier orbitals,and energy levels,BDOTP acceptors retain similar three-dimensional packing capability as Y6-type acceptors due to the similar banana-shaped molecular configuration.BDOTP acceptors show good performance in OSCs.High PCEs of up to 18.51%(certified 17.9%)are achieved.This study suggests that the banana-shaped configuration instead of the A–D–Aʹ–D–A structure is likely to be the determining factor in realizing high photovoltaic performance.展开更多
The apparent resistivity of the samples with water-bearing configuration was measured by an electrode-array and 2-D resistivity images of these samples were reconstructed then. The obtained series of tomograms reveal ...The apparent resistivity of the samples with water-bearing configuration was measured by an electrode-array and 2-D resistivity images of these samples were reconstructed then. The obtained series of tomograms reveal the dis tribution and its variation of true resistivity within the samples caused by the changes of crack and liquid distribu tion. Applying this method to the simulation experiment on the electrical properties of rocks, the fracturing and water filling process, which produces the electrical changes, can be brought to light clearly.展开更多
The effective plugging of artificial fractures is key to the success of temporary plugging and diverting fracturing technology,which is one of the most promising ways to improve the heat recovery efficiency of hot dry...The effective plugging of artificial fractures is key to the success of temporary plugging and diverting fracturing technology,which is one of the most promising ways to improve the heat recovery efficiency of hot dry rock.At present,how temporary plugging agents plug artificial fractures under high temperature remains unclear.In this paper,by establishing an improved experimental system for the evaluation of temporary plugging performance at high temperature,we clarified the effects of high temperature,injection rate,and fracture width on the pressure response and plugging efficiency of the fracture.The results revealed that the temporary plugging process of artificial fractures in hot dry rock can be divided into four main stages:the initial stage of temporary plugging,the bridging stage of the particles,the plugging formation stage,and the high-pressure dense plugging stage.As the temperature increases,the distribution distance of the temporary plugging agent,the number of pressure fluctuations,and the time required for crack plugging increases.Particularly,when the temperature increases by 100℃,the complete plugging time increases by 90.7%.展开更多
Antimony(Sb) is an attractive cathode for liquid metal batteries(LMBs) because of its high theoretical voltage and low cost.The main obstacles associated with the Sb-based cathodes are unsatisfactory energy density an...Antimony(Sb) is an attractive cathode for liquid metal batteries(LMBs) because of its high theoretical voltage and low cost.The main obstacles associated with the Sb-based cathodes are unsatisfactory energy density and poor rate-capability.Herein,we propose a novel Sb_(64)Cu_(36)cathode that effectively tackles these issues.The Sb_(64)Cu_(36)(melting point:525℃) cathode presents a novel lithiation mechanism involving sequentially the generation of Li_(2)CuSb,the formation of Li_(3)Sb,and the conversion reaction of Li_(2)CuSb to Li_(3)Sb and Cu.The generated intermetallic compounds show a unique microstructure of the upper floated Li_(2)CuSb layer and the below cross-linked structure with interpenetrated Li_(2)CuSb and Li_(3)Sb phases.Compared with Li_(3)Sb,the lower Li migration energy barrier(0.188 eV) of Li_(2)CuSb significantly facilitates the lithium diffusion across the intermediate compounds and accelerates the reaction kinetics.Consequently,the Li‖Sb_(64)Cu_(36)cell delivers a more excellent electrochemical performance(energy density:353 W h kg^(-1)at 0.4 A cm^(-2);rate capability:0.59 V at 2.0 A cm^(-2)),and a much lower energy storage cost of only 38.45 $ kW h^(-1)than other previously reported Sb-based LMBs.This work provides a novel cathode design concept for the development of high-performance LMBs in applications for large-scale energy storage.展开更多
基金supported by the Zhejiang Provincial Collaborative Innovation Center of Mountain Geological Hazard Prevention(PCMGH-2021-05)the Special Fund for Fundamental Research Business Expenses of Central Universities(Grant No.600101110102)。
文摘The strength of water-bearing rock cannot be obtained in real time and by nondestructive experiments,which is an issue at cultural relics protection sites such as grotto temples.To solve this problem,we conducted a near-infrared spectrum acquisition experiment in the field and laboratory uniaxial compression strength tests on sandstone that had different water saturation levels.The correlations between the peak height and peak area of the nearinfrared absorption bands of the water-bearing sandstone and uniaxial compressive strength were analyzed.On this basis,a strength prediction model for water-bearing sandstone was established using the long short-term memory full convolutional network(LSTM-FCN)method.Subsequently,a field engineering test was carried out.The results showed that:(1)The sandstone samples had four distinct characteristic absorption peaks at 1400,1900,2200,and 2325 nm.The peak height and peak area of the absorption bands near 1400 nm and 1900 nm had a negative correlation with uniaxial compressive strength.The peak height and peak area of the absorption bands near 2200 nm and 2325 nm had nonlinear positive correlations with uniaxial compressive strength.(2)The LSTM-FCN method was used to establish a strength prediction model for water-bearing sandstone based on near-infrared spectroscopy,and the model achieved an accuracy of up to 97.52%.(3)The prediction model was used to realize non-destructive,quantitative,and real-time determination of uniaxial compressive strength;this represents a new method for the non-destructive testing of grotto rock mass at sites of cultural relics protection.
基金Project supported by the National Natural Science Foundation of China(Grant No.11604058)the Guangxi Natural Science Foundation(Grant Nos.2020GXNSFAA297041 and 2023JJA110112)the Innovation Project of Guangxi Graduate Education(Grant No.YCSW2023083)。
文摘We systemically investigate optical trapping capability of a kind of tornado waves on Rayleigh particles.Such tornado waves are named as tornado circular Pearcey beams(TCPBs)and produced by combining two circular Pearcey beams with different radii.Our theoretical exploration delves into various aspects,including the propagation dynamics,energy flux,orbital angular momentum,trapping force,and torque characteristics of TCPBs.The results reveal that the orbital angular momentum,trapping force,and torque of these beams can be finely tuned through the judicious manipulation of their topological charges(l_(1)and l_(2)).Notably,we observe a precise control mechanism wherein the force diminishes with|l_(1)+l_(2)|and|l_(1)-l_(2)|,while the torque exhibits enhancement by decreasing solely with|l_(1)+l_(2)|or increasing with|l_(1)-l_(2)|.These results not only provide quantitative insights into the optical trapping performance of TCPBs but also serve as a valuable reference for the ongoing development of innovative photonic tools.
文摘おhe water-bearing numerical model is undergone all round examinations during the operational forecasting experiments from 1994 to 1996. A lot of difficult problems arising from the model′s water-bearing are successfully resolved in these experiments through developing and using a series of technical measures. The operational forecasting running of the water-bearing numerical model is realized stably and reliably, and satisfactory forecasts are obtained.
文摘In first paper of articles, the physical and calculating schemes of the water-bearing numerical model are described. The model is developed by bearing all species of hydrometeors in a conventional numerical model in which the dynamic framework of hydrostatic equilibrium is taken. The main contributions are: the mixing ratios of all species of hydrometeors are added as the prognostic variables of model, the prognostic equations of these hydrometeors are introduced, the cloud physical framework is specially designed, some technical measures are used to resolve a series of physical, mathematical and computational problems arising from water-bearing; and so on. The various problems (in such aspects as the designs of physical and calculating schemes and the composition of computational programme) which are exposed in feasibility test, in sensibility test, and especially in operational forecasting experiments are successfully resolved using a lot of technical measures having been developed from researches and tests. Finally, the operational forecasting running of the water-bearing numerical model and its forecasting system is realized stably and reliably, and the fine forecasts are obtained. All of these mentioned above will be described in second paper.
基金the open research fund of the Songshan Lake Materials Laboratory(2021SLABFK02)the National Key Research and Development Program of China(2017YFA0206600)the National Natural Science Foundation of China(51922032 and 21961160720).
文摘The emergence of Y6-type nonfullerene acceptors has greatly enhanced the power conversion efficiency(PCE)of organic solar cells(OSCs).However,which structural feature is responsible for the excellent photovoltaic performance is still under debate.In this study,two Y6-like acceptors BDOTP-1 and BDOTP-2 were designed.Different from previous Y6-type acceptors featuring an A–D–Aʹ–D–A structure,BDOTP-1,and BDOTP-2 have no electron-deficient Aʹfragment in the core unit.Instead,there is an electron-rich dibenzodioxine fragment in the core.Although this modification leads to a marked change in the molecular dipole moment,electrostatic potential,frontier orbitals,and energy levels,BDOTP acceptors retain similar three-dimensional packing capability as Y6-type acceptors due to the similar banana-shaped molecular configuration.BDOTP acceptors show good performance in OSCs.High PCEs of up to 18.51%(certified 17.9%)are achieved.This study suggests that the banana-shaped configuration instead of the A–D–Aʹ–D–A structure is likely to be the determining factor in realizing high photovoltaic performance.
文摘The apparent resistivity of the samples with water-bearing configuration was measured by an electrode-array and 2-D resistivity images of these samples were reconstructed then. The obtained series of tomograms reveal the dis tribution and its variation of true resistivity within the samples caused by the changes of crack and liquid distribu tion. Applying this method to the simulation experiment on the electrical properties of rocks, the fracturing and water filling process, which produces the electrical changes, can be brought to light clearly.
基金supported financially by the Beijing Natural Science Foundation Project(No.3222030)the National Natural Science Foundation of China(No.51936001,No.52274002 and No.52192622)+1 种基金the PetroChina Science and Technology Innovation Foundation Project(2021DQ02–0201)Award Cultivation Foundation from Beijing Institute of Petrochemical Technology(No.BIPTACF-002).
文摘The effective plugging of artificial fractures is key to the success of temporary plugging and diverting fracturing technology,which is one of the most promising ways to improve the heat recovery efficiency of hot dry rock.At present,how temporary plugging agents plug artificial fractures under high temperature remains unclear.In this paper,by establishing an improved experimental system for the evaluation of temporary plugging performance at high temperature,we clarified the effects of high temperature,injection rate,and fracture width on the pressure response and plugging efficiency of the fracture.The results revealed that the temporary plugging process of artificial fractures in hot dry rock can be divided into four main stages:the initial stage of temporary plugging,the bridging stage of the particles,the plugging formation stage,and the high-pressure dense plugging stage.As the temperature increases,the distribution distance of the temporary plugging agent,the number of pressure fluctuations,and the time required for crack plugging increases.Particularly,when the temperature increases by 100℃,the complete plugging time increases by 90.7%.
基金financially supported by the National Natural Science Foundation of China(52074023)the Beijing Natural Science Foundation(2222062)+1 种基金the National Key R&D Program of China(2018YFB0905600)the Interdisciplinary Research Project for Young Teachers of USTB(Fundamental Research Funds for the Central Universities)(FRF-IDRY-21-023)。
文摘Antimony(Sb) is an attractive cathode for liquid metal batteries(LMBs) because of its high theoretical voltage and low cost.The main obstacles associated with the Sb-based cathodes are unsatisfactory energy density and poor rate-capability.Herein,we propose a novel Sb_(64)Cu_(36)cathode that effectively tackles these issues.The Sb_(64)Cu_(36)(melting point:525℃) cathode presents a novel lithiation mechanism involving sequentially the generation of Li_(2)CuSb,the formation of Li_(3)Sb,and the conversion reaction of Li_(2)CuSb to Li_(3)Sb and Cu.The generated intermetallic compounds show a unique microstructure of the upper floated Li_(2)CuSb layer and the below cross-linked structure with interpenetrated Li_(2)CuSb and Li_(3)Sb phases.Compared with Li_(3)Sb,the lower Li migration energy barrier(0.188 eV) of Li_(2)CuSb significantly facilitates the lithium diffusion across the intermediate compounds and accelerates the reaction kinetics.Consequently,the Li‖Sb_(64)Cu_(36)cell delivers a more excellent electrochemical performance(energy density:353 W h kg^(-1)at 0.4 A cm^(-2);rate capability:0.59 V at 2.0 A cm^(-2)),and a much lower energy storage cost of only 38.45 $ kW h^(-1)than other previously reported Sb-based LMBs.This work provides a novel cathode design concept for the development of high-performance LMBs in applications for large-scale energy storage.