Naturally fractured rocks contain most of the world's petroleum reserves.This significant amount of oil can be recovered efficiently by gas assisted gravity drainage(GAGD).Although,GAGD is known as one of the most...Naturally fractured rocks contain most of the world's petroleum reserves.This significant amount of oil can be recovered efficiently by gas assisted gravity drainage(GAGD).Although,GAGD is known as one of the most effective recovery methods in reservoir engineering,the lack of available simulation and mathematical models is considerable in these kinds of reservoirs.The main goal of this study is to provide efficient and accurate methods for predicting the GAGD recovery factor using data driven techniques.The proposed models are developed to relate GAGD recovery factor to the various parameters including model height,matrix porosity and permeability,fracture porosity and permeability,dip angle,viscosity and density of wet and non-wet phases,injection rate,and production time.In this investigation,by considering the effective parameters on GAGD recovery factor,three different efficient,smart,and fast models including artificial neural network(ANN),least square support vector machine(LSSVM),and multi-gene genetic programming(MGGP)are developed and compared in both fractured and homogenous porous media.Buckinghamπtheorem is also used to generate dimensionless numbers to reduce the number of input and output parameters.The efficiency of the proposed models is examined through statistical analysis of R-squared,RMSE,MSE,ARE,and AARE.Moreover,the performance of the generated MGGP correlation is compared to the traditional models.Results demonstrate that the ANN model predicts the GAGD recovery factor more accurately than the LSSVM and MGGP models.The maximum R^(2)of 0.9677 and minimum RMSE of 0.0520 values are obtained by the ANN model.Although the MGGP model has the lowest performance among the other used models(the R2 of 0.896 and the RMSE of 0.0846),the proposed MGGP correlation can predict the GAGD recovery factor in fractured and homogenous reservoirs with high accuracy and reliability compared to the traditional models.Results reveal that the employed models can easily predict GAGD recovery factor without requiring complicate governing equations or running complex and time-consuming simulation models.The approach of this research work improves our understanding about the most significant parameters on GAGD recovery and helps to optimize the stages of the process,and make appropriate economic decisions.展开更多
In oil and gas exploration,elucidating the complex interdependencies among geological variables is paramount.Our study introduces the application of sophisticated regression analysis method at the forefront,aiming not...In oil and gas exploration,elucidating the complex interdependencies among geological variables is paramount.Our study introduces the application of sophisticated regression analysis method at the forefront,aiming not just at predicting geophysical logging curve values but also innovatively mitigate hydrocarbon depletion observed in geochemical logging.Through a rigorous assessment,we explore the efficacy of eight regression models,bifurcated into linear and nonlinear groups,to accommodate the multifaceted nature of geological datasets.Our linear model suite encompasses the Standard Equation,Ridge Regression,Least Absolute Shrinkage and Selection Operator,and Elastic Net,each presenting distinct advantages.The Standard Equation serves as a foundational benchmark,whereas Ridge Regression implements penalty terms to counteract overfitting,thus bolstering model robustness in the presence of multicollinearity.The Least Absolute Shrinkage and Selection Operator for variable selection functions to streamline models,enhancing their interpretability,while Elastic Net amalgamates the merits of Ridge Regression and Least Absolute Shrinkage and Selection Operator,offering a harmonized solution to model complexity and comprehensibility.On the nonlinear front,Gradient Descent,Kernel Ridge Regression,Support Vector Regression,and Piecewise Function-Fitting methods introduce innovative approaches.Gradient Descent assures computational efficiency in optimizing solutions,Kernel Ridge Regression leverages the kernel trick to navigate nonlinear patterns,and Support Vector Regression is proficient in forecasting extremities,pivotal for exploration risk assessment.The Piecewise Function-Fitting approach,tailored for geological data,facilitates adaptable modeling of variable interrelations,accommodating abrupt data trend shifts.Our analysis identifies Ridge Regression,particularly when augmented by Piecewise Function-Fitting,as superior in recouping hydrocarbon losses,and underscoring its utility in resource quantification refinement.Meanwhile,Kernel Ridge Regression emerges as a noteworthy strategy in ameliorating porosity-logging curve prediction for well A,evidencing its aptness for intricate geological structures.This research attests to the scientific ascendancy and broad-spectrum relevance of these regression techniques over conventional methods while heralding new horizons for their deployment in the oil and gas sector.The insights garnered from these advanced modeling strategies are set to transform geological and engineering practices in hydrocarbon prediction,evaluation,and recovery.展开更多
Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling...Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling”paths usually suffer from either low injectivity or poor gelation control.Herein,we for the first time developed an in-situ high-pressure CO_(2)-triggered gel system based on a smart surfactant,N-erucamidopropyl-N,N-dimethylamine(UC22AMPM),which was introduced into the aqueous slugs to control gas channeling inWAG processes.The water-like,low-viscosity UC22AMPM brine solution can be thickened by high-pressure CO_(2) owing to the formation of wormlike micelles(WLMs),as well as their growth and shear-induced structure buildup under shear flow.The thickening power can be further potentiated by the generation of denser WLMs resulting from either surfactant concentration augmentation or a certain range of heating,and can be impaired via pressurization above the critical pressure of CO_(2) because of its soaring solvent power.Core flooding tests using heterogeneous cores demonstrated that gas channeling was alleviated by plugging of high-capacity channels due to the in-situ gelation of UC22AMPM slugs upon their reaction with the pre-or post-injected CO_(2) slugs under shear flow,thereupon driving chase fluids into unrecovered low-permeability areas and producing an 8.0% higher oil recovery factor than the conventional WAG mode.This smart surfactant enabled high injectivity and satisfactory gelation control,attributable to low initial viscosity and the combined properties of one component and CO_(2)-triggered gelation,respectively.This work could provide a guide towards designing gels for reducing CO_(2) spillover and reinforcing the CO_(2) sequestration effect during CO_(2) enhanced oil recovery processes.展开更多
This paper reviews the basic research means for oilfield development and also the researches and tests of enhanced oil recovery(EOR)methods for mature oilfields and continental shale oil development,analyzes the probl...This paper reviews the basic research means for oilfield development and also the researches and tests of enhanced oil recovery(EOR)methods for mature oilfields and continental shale oil development,analyzes the problems of EOR methods,and proposes the relevant research prospects.The basic research means for oilfield development include in-situ acquisition of formation rock/fluid samples and non-destructive testing.The EOR methods for conventional and shale oil development are classified as improved water flooding(e.g.nano-water flooding),chemical flooding(e.g.low-concentration middle-phase micro-emulsion flooding),gas flooding(e.g.micro/nano bubble flooding),thermal recovery(e.g.air injection thermal-aided miscible flooding),and multi-cluster uniform fracturing/water-free fracturing,which are discussed in this paper for their mechanisms,approaches,and key technique researches and field tests.These methods have been studied with remarkable progress,and some achieved ideal results in field tests.Nonetheless,some problems still exist,such as inadequate research on mechanisms,imperfect matching technologies,and incomplete industrial chains.It is proposed to further strengthen the basic researches and expand the field tests,thereby driving the formation,promotion and application of new technologies.展开更多
Background: Impurities are not expected in the final pharmaceutical products. All impurities should be regulated in both drug substances and drug products in accordance with pharmacopeias and ICH guidelines. Three dif...Background: Impurities are not expected in the final pharmaceutical products. All impurities should be regulated in both drug substances and drug products in accordance with pharmacopeias and ICH guidelines. Three different types of impurities are generally available in the pharmaceutical’s product specification: organic impurities, inorganic impurities, and residual solvents. Residual solvents are organic volatile chemicals used or generated during the manufacturing of drug substances or drug products. Purpose: The aim of this study is to develop a cost-effective gas chromatographic method for the identification and quantification of some commonly used solvents—methanol, acetone, isopropyl alcohol (IPA), methylene chloride, ethyl acetate, tetrahydrofuran (THF), benzene, toluene, and pyridine—in pharmaceutical product manufacturing. This method will be able to identify and quantify the multiple solvents within a single gas chromatographic procedure. Method: A gas chromatography (GC) equipped with a headspace sampler and a flame ionization detector, and a column DB 624, 30-meter-long × 0.32-millimeter internal diameter, 1,8 μm-thick, Brand-Agilent was used to develop this method. The initial GC oven temperature was 40°C and held for 5 minutes. It was then increase to 80˚C at a rate of 2˚C per minute, followed by a further increase to 225˚C at a rate of 30˚C per minute, with a final hold at 225˚C for 10 minutes. Nitrogen was used as a carrier gas at a flow rate of 1.20 mL per minute. Dimethyl sulfoxide (DMSO) was selected as sample solvent. Results: The developed method is precise and specific. The percent RSD for the areas of six replicate injections of this gas chromatographic method was within 10.0 and the recovery result found within 80.0% to 120.0%.展开更多
Objective:To investigate the effects of budesonide on blood gas and inflammation indexes in patients with chronic obstructive pulmonary disease(COPD)during remission.Methods:Fifty-one patients with COPD in remission,a...Objective:To investigate the effects of budesonide on blood gas and inflammation indexes in patients with chronic obstructive pulmonary disease(COPD)during remission.Methods:Fifty-one patients with COPD in remission,admitted to Zhongshan Hospital of Dalian University from July 2021 to December 2022,were selected and divided into two groups based on a randomized numerical table method.The control group(25 cases)received budesonide formoterol treatment,while the observation group(26 cases)received budesonide geforce treatment.Various indexes,including clinical efficacy,blood gas indexes,inflammation indexes,St.George’s Respiratory Questionnaire(SGRQ)scores,Chronic Obstructive Pulmonary Disease Assessment Test(CAT)scores,and 6-minute Walking Distance Test(6MWD)results,were compared between the two groups.Results:After 21 days of treatment,the total clinical effectiveness rate of the observation group was higher than that of the control group,with a statistically significant difference(P<0.05).Post-treatment,the PaO2 level and pH value in both groups were higher,and the PaCO_(2) level was lower compared to pre-treatment levels.The observation group showed better improvements in these indicators than the control group,with statistically significant differences(P<0.05).SGRQ and CAT scores for both groups were lower post-treatment,with the observation group scoring lower than the control group.Additionally,the 6MWD results were farther for both groups post-treatment,with the observation group achieving greater distances than the control group,with statistically significant differences(P<0.05).Conclusion:Budesonide can effectively improve blood gas indexes in patients with COPD in remission,alleviate related clinical symptoms,reduce inflammatory responses,and promote patient recovery.The treatment efficacy is significant.展开更多
The relative permeability curve has been measured with simulation oil (refined oil) and gas (nitrogen or air) at room temperature and a lowpressure, both of which are very important parameters for depicting the flow ...The relative permeability curve has been measured with simulation oil (refined oil) and gas (nitrogen or air) at room temperature and a lowpressure, both of which are very important parameters for depicting the flow of fluid through porous media in a hydrocarbon reservoir. This basic measurement is often applied in exploitation evaluation, but the underground conditions with high temperature and pressure, and the phase equilibrium of oil and gas, are not taken into consideration when the relative permeability curve is tested. There is an important theoretical and practical sense in testing the diphase relative permeability curve of the equilibrium of oil and gas under the conditions of high temperature and pressure. The test method for the relative permeability curve is proposed in this paper. The relative permeability of the equilibrium of oil and gas and the standard one are tested in two fluids, and the differences between these two methods are stated. The research results can be applied to the simulation and prediction of CVD in long cores and then the phenomenon can better explain that the recovery of condensate gas rich in condensate oil is higher than that of CVD test in PVT. Meanwhile, the research shows that the relative permeability curve of equilibrium oil and gas is sensitive to the rate of exploitation, and the viewpoint proves that an improved gas recovery rate can properly increase the recovery of condensate oil.展开更多
To change the undesirable present situation of recovering and using converter gas in steel plants in China, the basic approaches to improving the converter gas recovery rate were analyzed theoretically along with the ...To change the undesirable present situation of recovering and using converter gas in steel plants in China, the basic approaches to improving the converter gas recovery rate were analyzed theoretically along with the change curves of the converter gas component content, based on the converter gas recovery system of Baosteel No. 2 steel- making plant. The effects of converter device, raw material, air imbibed quantity, recovery restricted condition, and intensity of oxygen blowing on the converter gas recovery rate were studied. Among these, the effects of the air im bibed quantity, recovery restricted condition, and intensity of oxygen blowing are remarkable. Comprehensive measures were put forward for improving the converter gas recovery from the point of devices, etc. , and good results were achieved.展开更多
The estimated ultimate recovery(EUR)of shale gas wells is influenced by many factors,and the accurate prediction still faces certain challenges.As an artificial intelligence algorithm,deep learning yields notable adva...The estimated ultimate recovery(EUR)of shale gas wells is influenced by many factors,and the accurate prediction still faces certain challenges.As an artificial intelligence algorithm,deep learning yields notable advantages in nonlinear regression.Therefore,it is feasible to predict the EUR of shale gas wells based on a deep-learning algorithm.In this paper,according to geological evaluation data,hydraulic fracturing data,production data and EUR evaluation results of 282 wells in the WY shale gas field,a deep-learning-based algorithm for EUR evaluation of shale gas wells was designed and realized.First,the existing EUR evaluation methods of shale gas wells and the deep feedforward neural network algorithm was systematically analyzed.Second,the technical process of a deep-learning-based algorithm for EUR prediction of shale gas wells was designed.Finally,by means of real data obtained from the WY shale gas field,several different cases were applied to testify the validity and accuracy of the proposed approach.The results show that the EUR prediction with high accuracy.In addition,the results are affected by the variety and number of input parameters,the network structure and hyperparameters.The proposed approach can be extended to other shale fields using the similar technic process.展开更多
A novel process to recovery natural gas liquids from oil field associated gas with liquefied natural gas (LNG)cryogenic energy utilization is proposed.Compared to the current electric refrigeration process,the propose...A novel process to recovery natural gas liquids from oil field associated gas with liquefied natural gas (LNG)cryogenic energy utilization is proposed.Compared to the current electric refrigeration process,the proposed process uses the cryogenic energy of LNG and saves 62.6%of electricity.The proposed process recovers ethane, liquid petroleum gas(propane and butane)and heavier hydrocarbons,with total recovery rate of natural gas liquids up to 96.8%.In this paper,exergy analysis and the energy utilization diagram method(EUD)are used to assess the new process and identify the key operation units with large exergy loss.The results show that exergy efficiency of the new process is 44.3%.Compared to the electric refrigeration process,exergy efficiency of the new process is improved by 16%.The proposed process has been applied and implemented in a conceptual design scheme of the cryogenic energy utilization for a 300 million tons/yr LNG receiving terminal in a northern Chinese harbor.展开更多
In order to overcome the heavy casualties caused by gas explosion, we verified the propagation law of shock wave in pipeline and the overpressure distribution of gas explosion by similar experiments according to the a...In order to overcome the heavy casualties caused by gas explosion, we verified the propagation law of shock wave in pipeline and the overpressure distribution of gas explosion by similar experiments according to the analyses of reasons for casualty and ventilation system model destroyed by gas explosion in the mining face. We summarized the gas composition after the explosion and its danger, analyzed the effects of the gas explosion shock wave to ventilation system and facilities and the laws of toxic gas spread and diffusion in the ventilation network after the explosion. We presented a technical proposal to control the smoke and recover the ventilation system after a gas explosion and developed a reserve air door and control system that were embed in the lane, and could close automatically in conditions of no pressure and electricity. The results showed that the reserve air door normally opened and could close automatically controlling the smoke flow and resuming the ventilation system when the gas explosion shock wave destroyed the original shutting air door which resulted in the air short circuit.展开更多
A two-pulse method is used to determine the insulation recovery time of the gas spark gap switch with different types of gas applied in a high power accelerator with a water dielectric pulse forming line. At the break...A two-pulse method is used to determine the insulation recovery time of the gas spark gap switch with different types of gas applied in a high power accelerator with a water dielectric pulse forming line. At the breakdown voltage of 450 kV, with the vacuum diode voltage of about 200 kV, and a current of 30 kA, recovery characteristics of H2, N2, SF6 were studied. The recovery percentages of the gas breakdown voltage and vacuum diode voltage were determined. The results show that hydrogen has the best recovery characteristics. At a pulse interval of 8.8 ms, the recovery percentages of both the gas breakdown voltage and vacuum diode voltage for hydrogen exceed 95%. For SF6 and N2 with an interval of 25 ms and 50 ms respectively, a 90% voltage recovery was obtained. The experiments also proved that the repetitive rate of the high power accelerator with a pulse forming line is mainly restricted by the gas switch repetitive rate; the recovery percentages of the vacuum diode voltage are limited by the recovery percentages of the gas switch breakdown voltage. The hydrogen switch can be employed for a high repetitive rate-high power accelerator with a pulse forming line.展开更多
Flue gas fooding is one of the important technologies to improve oil recovery and achieve greenhouse gas storage.In order to study multicomponent fue gas storage capacity and enhanced oil recovery(EOR)performance of f...Flue gas fooding is one of the important technologies to improve oil recovery and achieve greenhouse gas storage.In order to study multicomponent fue gas storage capacity and enhanced oil recovery(EOR)performance of fue gas water-alternating gas(fue gas-WAG)injection after continuous waterfooding in an oil reservoir,a long core fooding system was built.The experimental results showed that the oil recovery factor of fue gas-WAG fooding was increased by 21.25%after continuous waterfooding and fue gas-WAG fooding could further enhance oil recovery and reduce water cut signifcantly.A novel material balance model based on storage mechanism was developed to estimate the multicomponent fue gas storage capacity and storage capacity of each component of fue gas in reservoir oil,water and as free gas in the post-waterfooding reservoir.The ultimate storage ratio of fue gas is 16%in the fue gas-WAG fooding process.The calculation results of fue gas storage capacity showed that the injection gas storage capacity mainly consists of N_(2) and CO_(2),only N_(2) exists as free gas phase in cores,and other components of injection gas are dissolved in oil and water.Finally,injection strategies from three perspectives for fue gas storage,EOR,and combination of fue gas storage and EOR were proposed,respectively.展开更多
In this work, a novel thermal–hydraulic–mechanical (THM) coupling model is developed, where the real geological parameters of the reservoir properties are embedded. Accordingly, nine schemes of CO_(2) injection well...In this work, a novel thermal–hydraulic–mechanical (THM) coupling model is developed, where the real geological parameters of the reservoir properties are embedded. Accordingly, nine schemes of CO_(2) injection well (IW) and CH_(4) production well (PW) are established, aiming to explore the behavior of free gases after CO_(2) is injected into the depleted Wufeng–Longmaxi shale. The results indicate the free CH4 or CO2 content in the shale fractures/matrix is invariably heterogeneous. The CO_(2) involvement facilitates the ratio of free CH_(4)/CO_(2) in the matrix to that in the fractures declines and tends to be stable with time. Different combinations of IW–PWs induce a difference in the ratio of the free CH4 to the free CO_(2), in the ratio of the free CH_(4)/CO_(2) in the matrix to that in the fractures, in the content of the recovered free CH_(4), and in the content of the trapped free CO_(2). Basically, when the IW locates at the bottom Wufeng–Longmaxi shale, a farther IW–PWs distance allows more CO2 in the free phase to be trapped;furthermore, no matter where the IW is, a shorter IW–PWs distance benefits by getting more CH_(4) in the free phase recovered from the depleted Wufeng–Longmaxi shale. Hopefully, this work is helpful in gaining knowledge about the shale-based CO_(2) injection technique.展开更多
CO_(2)emission mitigation is one of the most critical research frontiers.As a promising option of carbon capture,utilization and storage(CCUS),CO_(2)storage with enhanced gas recovery(CSEGR)can reduce CO_(2)emission b...CO_(2)emission mitigation is one of the most critical research frontiers.As a promising option of carbon capture,utilization and storage(CCUS),CO_(2)storage with enhanced gas recovery(CSEGR)can reduce CO_(2)emission by sequestrating it into gas reservoirs and simultaneously enhance natural gas production.Over the past decades,the displacement behaviour of CO_(2)—natural gas has been extensively studied and demonstrated to play a key role on both CO_(2)geologic storage and gas recovery performance.This work thoroughly and critically reviews the experimental and numerical simulation studies of CO_(2)displacing natural gas,along with both CSEGR research and demonstration projects at various scales.The physical property difference between CO_(2)and natural gas,especially density and viscosity,lays the foundation of CSEGR.Previous experiments on displacement behaviour and dispersion characteristics of CO_(2)/natural gas revealed the fundamental mixing characteristics in porous media,which is one key factor of gas recovery efficiency and warrants further study.Preliminary numerical simulations demonstrated that it is technically and economically feasible to apply CSEGR in depleted gas reservoirs.However,CO_(2)preferential flow pathways are easy to form(due to reservoir heterogeneity)and thus adversely compromise CSEGR performance.This preferential flow can be slowed down by connate or injected water.Additionally,the optimization of CO_(2)injection strategies is essential for improving gas recovery and CO_(2)storage,which needs further study.The successful K12—B pilot project provides insightful field-scale knowledge and experience,which paves a good foundation for commercial application.More experiments,simulations,research and demonstration projects are needed to facilitate the maturation of the CSEGR technology.展开更多
The recovery factor from tight gas reservoirs is typically less than 15%, even with multistage hydrauhc tractunng stimulation. Such low recovery is exacerbated in tight gas condensate reservoirs, where the depletion o...The recovery factor from tight gas reservoirs is typically less than 15%, even with multistage hydrauhc tractunng stimulation. Such low recovery is exacerbated in tight gas condensate reservoirs, where the depletion of gas leaves the valuable condensate behind. In this paper, three enhanced gas recovery (EGR) methods including produced gas injection, CO2 injection and water injection are investigated to increase the well productivity for a tight gas condensate reservoir in the Montney Formation, Canada. The production performance of the three EGR methods is compared and their economic feasibility is evaluated. Sensitivity analysis of the key factors such as primary production duration, bottom-hole pressures, and fracture conductivity is conducted and their effects on the well production performance are analyzed. Results show that, compared with the simple depletion method, both the cumulative gas and condensate production increase with fluids injected. Produced gas injection leads to both a higher gas and condensate production compared with those of the CO2 injection, while waterflooding suffers from injection difficulty and the corresponding low sweep efficiency. Meanwhile, the injection cost is lower for the produced gas injection due to the on-site available gas source and minimal transport costs, gaining more economic benefits than the other EGR methods.展开更多
This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization ...This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization approaches to detect and observe the CO2-formation fluid displacement mechanism at the micro-scale, namely, magnetic resonance imaging, X-ray computed tomography and fabricated micromodels, but they are not capable of investigating the dis- placement process at the nano-scale. Though a lab-on-chip approach for the direct visualization of the fluid flow behaviour in nanoscale channels has been developed using an advanced epi-fluorescence microscopy method combined with a nanofluidic chip, it is still a qualitative analysis method. The lattice Boltzmann method (LBM) can simulate the CO2 displacement processes in a two-dimensional or three-dimensional (3D) pore structure, but until now, the CO2 displace- ment mechanisms had not been thoroughly investigated and the 3D pore structure of real rock had not been directly taken into account in the simulation of the CO2 displacement process. The status of research on the applications of CO2 displacement to enhance shale gas recovery is also analyzed in this paper. The coupling of molecular dynamics and LBM in tandem is proposed to simulate the CO2-shale gas displacement process based on the 3D digital model of shale obtained from focused ion beams and scanning electron microscopy.展开更多
Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasificatio...Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasification of LNG gives out a huge amount of waste energy since plenty of high grade cold energy(-160℃)from LNG is released to sea water directly in most cases,and also sometimes LNG is burned for regasification.On the other hand,liquid air energy storage(LAES)is an emerging energy storage technology for applications such as peak load shifting of power grids,which generates 30%-40%of compression heat(-200℃).Such heat could lead to energy waste if not recovered and used.The recovery of the compression heat is technically feasible but requires additional capital investment,which may not always be economically attractive.Therefore,we propose a power plant for recovering the waste cryogenic energy from LNG regasification and compression heat from the LAES.The challenge for such a power plant is the wide working temperature range between the low-temperature exergy source(-160℃)and heat source(-200℃).Nitrogen and argon are proposed as the working fluids to address the challenge.Thermodynamic analyses are carried out and the results show that the power plant could achieve a thermal efficiency of 27%and 19%and an exergy efficiency of 40%and 28%for nitrogen and argon,respectively.Here,with the nitrogen as working fluid undergoes a complete Brayton Cycle,while the argon based power plant goes through a combined Brayton and Rankine Cycle.Besides,the economic analysis shows that the payback period of this proposed system is only 2.2 years,utilizing the excess heat from a 5 MW/40 MWh LAES system.The findings suggest that the waste energy based power plant could be co-located with the LNG terminal and LAES plant,providing additional power output and reducing energy waste.展开更多
In order to evaluate the heating performance of gas engine heat pump(GEHP) for air-conditioning and hot water supply, a test facility was developed and experiments were performed over a wide range of engine speed(1...In order to evaluate the heating performance of gas engine heat pump(GEHP) for air-conditioning and hot water supply, a test facility was developed and experiments were performed over a wide range of engine speed(1400-2600 r/min), ambient air temperature(2.4-17.8 ℃) and condenser water inlet temperature(30-50℃). The results show that as engine speed increases from 1400 r/min to 2600 r/min, the total heating capacity and energy consumption increase by about 30% and 89%, respectively; while the heat pump coefficient of performance(COP) and system primary energy ratio(PER) decrease by 44% and 31%, respectively. With the increase of ambient air temperature from 2.4 ℃ to 17.8 ℃, the heat pump COP and system PER increase by 32% and 19%, respectively. Moreover, the heat pump COP and system PER decrease by 27% and 15%, respectively, when the condenser water inlet temperature changes from 30 ℃ to 50 ℃. So, it is obvious that the effect of engine speed on the performance is more significant than the effects of ambient air temperature and condenser water inlet temperature.展开更多
Gas injection serves as a main enhanced oil recovery(EOR)method in fractured-vuggy carbonate reservoir,but its effect differs among single wells and multi-well groups because of the diverse fractured-vuggy configurati...Gas injection serves as a main enhanced oil recovery(EOR)method in fractured-vuggy carbonate reservoir,but its effect differs among single wells and multi-well groups because of the diverse fractured-vuggy configuration.Many researchers conducted experiments for the observation of fluid flow and the evaluation of production performance,while most of their physical models were fabricated based on the probability distribution of fractures and caves in the reservoir.In this study,a two-dimensional physical model of the karst fault system was designed and fabricated based on the geological model of TK748 well group in the seventh block of the Tahe Oilfield.The fluid flow and production performance of primary gas flooding were discussed.Gas-assisted gravity flooding was firstly introduced to take full use of gas-oil gravity difference,and its feasibility in the karst fault system was examined.Experimental results showed that primary gas flooding created more flow paths and achieved a remarkable increment of oil recovery compared to water flooding.Gas injection at a lower location was recommended to delay gas breakthrough.Gas-assisted gravity flooding achieved more stable gas-displacing-oil because oil production was at a lower location,and thus,the oil recovery was further enhanced.展开更多
文摘Naturally fractured rocks contain most of the world's petroleum reserves.This significant amount of oil can be recovered efficiently by gas assisted gravity drainage(GAGD).Although,GAGD is known as one of the most effective recovery methods in reservoir engineering,the lack of available simulation and mathematical models is considerable in these kinds of reservoirs.The main goal of this study is to provide efficient and accurate methods for predicting the GAGD recovery factor using data driven techniques.The proposed models are developed to relate GAGD recovery factor to the various parameters including model height,matrix porosity and permeability,fracture porosity and permeability,dip angle,viscosity and density of wet and non-wet phases,injection rate,and production time.In this investigation,by considering the effective parameters on GAGD recovery factor,three different efficient,smart,and fast models including artificial neural network(ANN),least square support vector machine(LSSVM),and multi-gene genetic programming(MGGP)are developed and compared in both fractured and homogenous porous media.Buckinghamπtheorem is also used to generate dimensionless numbers to reduce the number of input and output parameters.The efficiency of the proposed models is examined through statistical analysis of R-squared,RMSE,MSE,ARE,and AARE.Moreover,the performance of the generated MGGP correlation is compared to the traditional models.Results demonstrate that the ANN model predicts the GAGD recovery factor more accurately than the LSSVM and MGGP models.The maximum R^(2)of 0.9677 and minimum RMSE of 0.0520 values are obtained by the ANN model.Although the MGGP model has the lowest performance among the other used models(the R2 of 0.896 and the RMSE of 0.0846),the proposed MGGP correlation can predict the GAGD recovery factor in fractured and homogenous reservoirs with high accuracy and reliability compared to the traditional models.Results reveal that the employed models can easily predict GAGD recovery factor without requiring complicate governing equations or running complex and time-consuming simulation models.The approach of this research work improves our understanding about the most significant parameters on GAGD recovery and helps to optimize the stages of the process,and make appropriate economic decisions.
文摘In oil and gas exploration,elucidating the complex interdependencies among geological variables is paramount.Our study introduces the application of sophisticated regression analysis method at the forefront,aiming not just at predicting geophysical logging curve values but also innovatively mitigate hydrocarbon depletion observed in geochemical logging.Through a rigorous assessment,we explore the efficacy of eight regression models,bifurcated into linear and nonlinear groups,to accommodate the multifaceted nature of geological datasets.Our linear model suite encompasses the Standard Equation,Ridge Regression,Least Absolute Shrinkage and Selection Operator,and Elastic Net,each presenting distinct advantages.The Standard Equation serves as a foundational benchmark,whereas Ridge Regression implements penalty terms to counteract overfitting,thus bolstering model robustness in the presence of multicollinearity.The Least Absolute Shrinkage and Selection Operator for variable selection functions to streamline models,enhancing their interpretability,while Elastic Net amalgamates the merits of Ridge Regression and Least Absolute Shrinkage and Selection Operator,offering a harmonized solution to model complexity and comprehensibility.On the nonlinear front,Gradient Descent,Kernel Ridge Regression,Support Vector Regression,and Piecewise Function-Fitting methods introduce innovative approaches.Gradient Descent assures computational efficiency in optimizing solutions,Kernel Ridge Regression leverages the kernel trick to navigate nonlinear patterns,and Support Vector Regression is proficient in forecasting extremities,pivotal for exploration risk assessment.The Piecewise Function-Fitting approach,tailored for geological data,facilitates adaptable modeling of variable interrelations,accommodating abrupt data trend shifts.Our analysis identifies Ridge Regression,particularly when augmented by Piecewise Function-Fitting,as superior in recouping hydrocarbon losses,and underscoring its utility in resource quantification refinement.Meanwhile,Kernel Ridge Regression emerges as a noteworthy strategy in ameliorating porosity-logging curve prediction for well A,evidencing its aptness for intricate geological structures.This research attests to the scientific ascendancy and broad-spectrum relevance of these regression techniques over conventional methods while heralding new horizons for their deployment in the oil and gas sector.The insights garnered from these advanced modeling strategies are set to transform geological and engineering practices in hydrocarbon prediction,evaluation,and recovery.
基金Financial support from the Natural Science Foundation of Sichuan Province(2022NSFSC0030)National Natural Science Foundation of China(U1762218)is gratefully acknowledged.
文摘Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling”paths usually suffer from either low injectivity or poor gelation control.Herein,we for the first time developed an in-situ high-pressure CO_(2)-triggered gel system based on a smart surfactant,N-erucamidopropyl-N,N-dimethylamine(UC22AMPM),which was introduced into the aqueous slugs to control gas channeling inWAG processes.The water-like,low-viscosity UC22AMPM brine solution can be thickened by high-pressure CO_(2) owing to the formation of wormlike micelles(WLMs),as well as their growth and shear-induced structure buildup under shear flow.The thickening power can be further potentiated by the generation of denser WLMs resulting from either surfactant concentration augmentation or a certain range of heating,and can be impaired via pressurization above the critical pressure of CO_(2) because of its soaring solvent power.Core flooding tests using heterogeneous cores demonstrated that gas channeling was alleviated by plugging of high-capacity channels due to the in-situ gelation of UC22AMPM slugs upon their reaction with the pre-or post-injected CO_(2) slugs under shear flow,thereupon driving chase fluids into unrecovered low-permeability areas and producing an 8.0% higher oil recovery factor than the conventional WAG mode.This smart surfactant enabled high injectivity and satisfactory gelation control,attributable to low initial viscosity and the combined properties of one component and CO_(2)-triggered gelation,respectively.This work could provide a guide towards designing gels for reducing CO_(2) spillover and reinforcing the CO_(2) sequestration effect during CO_(2) enhanced oil recovery processes.
基金Supported by the PetroChina Science and Technology Major Project(2023ZZ04,2023ZZ08)。
文摘This paper reviews the basic research means for oilfield development and also the researches and tests of enhanced oil recovery(EOR)methods for mature oilfields and continental shale oil development,analyzes the problems of EOR methods,and proposes the relevant research prospects.The basic research means for oilfield development include in-situ acquisition of formation rock/fluid samples and non-destructive testing.The EOR methods for conventional and shale oil development are classified as improved water flooding(e.g.nano-water flooding),chemical flooding(e.g.low-concentration middle-phase micro-emulsion flooding),gas flooding(e.g.micro/nano bubble flooding),thermal recovery(e.g.air injection thermal-aided miscible flooding),and multi-cluster uniform fracturing/water-free fracturing,which are discussed in this paper for their mechanisms,approaches,and key technique researches and field tests.These methods have been studied with remarkable progress,and some achieved ideal results in field tests.Nonetheless,some problems still exist,such as inadequate research on mechanisms,imperfect matching technologies,and incomplete industrial chains.It is proposed to further strengthen the basic researches and expand the field tests,thereby driving the formation,promotion and application of new technologies.
文摘Background: Impurities are not expected in the final pharmaceutical products. All impurities should be regulated in both drug substances and drug products in accordance with pharmacopeias and ICH guidelines. Three different types of impurities are generally available in the pharmaceutical’s product specification: organic impurities, inorganic impurities, and residual solvents. Residual solvents are organic volatile chemicals used or generated during the manufacturing of drug substances or drug products. Purpose: The aim of this study is to develop a cost-effective gas chromatographic method for the identification and quantification of some commonly used solvents—methanol, acetone, isopropyl alcohol (IPA), methylene chloride, ethyl acetate, tetrahydrofuran (THF), benzene, toluene, and pyridine—in pharmaceutical product manufacturing. This method will be able to identify and quantify the multiple solvents within a single gas chromatographic procedure. Method: A gas chromatography (GC) equipped with a headspace sampler and a flame ionization detector, and a column DB 624, 30-meter-long × 0.32-millimeter internal diameter, 1,8 μm-thick, Brand-Agilent was used to develop this method. The initial GC oven temperature was 40°C and held for 5 minutes. It was then increase to 80˚C at a rate of 2˚C per minute, followed by a further increase to 225˚C at a rate of 30˚C per minute, with a final hold at 225˚C for 10 minutes. Nitrogen was used as a carrier gas at a flow rate of 1.20 mL per minute. Dimethyl sulfoxide (DMSO) was selected as sample solvent. Results: The developed method is precise and specific. The percent RSD for the areas of six replicate injections of this gas chromatographic method was within 10.0 and the recovery result found within 80.0% to 120.0%.
文摘Objective:To investigate the effects of budesonide on blood gas and inflammation indexes in patients with chronic obstructive pulmonary disease(COPD)during remission.Methods:Fifty-one patients with COPD in remission,admitted to Zhongshan Hospital of Dalian University from July 2021 to December 2022,were selected and divided into two groups based on a randomized numerical table method.The control group(25 cases)received budesonide formoterol treatment,while the observation group(26 cases)received budesonide geforce treatment.Various indexes,including clinical efficacy,blood gas indexes,inflammation indexes,St.George’s Respiratory Questionnaire(SGRQ)scores,Chronic Obstructive Pulmonary Disease Assessment Test(CAT)scores,and 6-minute Walking Distance Test(6MWD)results,were compared between the two groups.Results:After 21 days of treatment,the total clinical effectiveness rate of the observation group was higher than that of the control group,with a statistically significant difference(P<0.05).Post-treatment,the PaO2 level and pH value in both groups were higher,and the PaCO_(2) level was lower compared to pre-treatment levels.The observation group showed better improvements in these indicators than the control group,with statistically significant differences(P<0.05).SGRQ and CAT scores for both groups were lower post-treatment,with the observation group scoring lower than the control group.Additionally,the 6MWD results were farther for both groups post-treatment,with the observation group achieving greater distances than the control group,with statistically significant differences(P<0.05).Conclusion:Budesonide can effectively improve blood gas indexes in patients with COPD in remission,alleviate related clinical symptoms,reduce inflammatory responses,and promote patient recovery.The treatment efficacy is significant.
基金This paper was subsidized by the 15th National key Sci-Tech Project (NO.2001BA605A02-04-01)
文摘The relative permeability curve has been measured with simulation oil (refined oil) and gas (nitrogen or air) at room temperature and a lowpressure, both of which are very important parameters for depicting the flow of fluid through porous media in a hydrocarbon reservoir. This basic measurement is often applied in exploitation evaluation, but the underground conditions with high temperature and pressure, and the phase equilibrium of oil and gas, are not taken into consideration when the relative permeability curve is tested. There is an important theoretical and practical sense in testing the diphase relative permeability curve of the equilibrium of oil and gas under the conditions of high temperature and pressure. The test method for the relative permeability curve is proposed in this paper. The relative permeability of the equilibrium of oil and gas and the standard one are tested in two fluids, and the differences between these two methods are stated. The research results can be applied to the simulation and prediction of CVD in long cores and then the phenomenon can better explain that the recovery of condensate gas rich in condensate oil is higher than that of CVD test in PVT. Meanwhile, the research shows that the relative permeability curve of equilibrium oil and gas is sensitive to the rate of exploitation, and the viewpoint proves that an improved gas recovery rate can properly increase the recovery of condensate oil.
基金Item Sponsored by National Natural Science Foundation of China (50334020)
文摘To change the undesirable present situation of recovering and using converter gas in steel plants in China, the basic approaches to improving the converter gas recovery rate were analyzed theoretically along with the change curves of the converter gas component content, based on the converter gas recovery system of Baosteel No. 2 steel- making plant. The effects of converter device, raw material, air imbibed quantity, recovery restricted condition, and intensity of oxygen blowing on the converter gas recovery rate were studied. Among these, the effects of the air im bibed quantity, recovery restricted condition, and intensity of oxygen blowing are remarkable. Comprehensive measures were put forward for improving the converter gas recovery from the point of devices, etc. , and good results were achieved.
基金supported by the funding of National Science and Technology Major Projects of China(2016ZX05037-006-005,2016ZX05037-006,2016ZX05035-004)。
文摘The estimated ultimate recovery(EUR)of shale gas wells is influenced by many factors,and the accurate prediction still faces certain challenges.As an artificial intelligence algorithm,deep learning yields notable advantages in nonlinear regression.Therefore,it is feasible to predict the EUR of shale gas wells based on a deep-learning algorithm.In this paper,according to geological evaluation data,hydraulic fracturing data,production data and EUR evaluation results of 282 wells in the WY shale gas field,a deep-learning-based algorithm for EUR evaluation of shale gas wells was designed and realized.First,the existing EUR evaluation methods of shale gas wells and the deep feedforward neural network algorithm was systematically analyzed.Second,the technical process of a deep-learning-based algorithm for EUR prediction of shale gas wells was designed.Finally,by means of real data obtained from the WY shale gas field,several different cases were applied to testify the validity and accuracy of the proposed approach.The results show that the EUR prediction with high accuracy.In addition,the results are affected by the variety and number of input parameters,the network structure and hyperparameters.The proposed approach can be extended to other shale fields using the similar technic process.
基金Supported by the National Natural Science Foundation of China(20876056,20536020)the PhD Program Fund from Ministry of Education of China(20100172110016)
文摘A novel process to recovery natural gas liquids from oil field associated gas with liquefied natural gas (LNG)cryogenic energy utilization is proposed.Compared to the current electric refrigeration process,the proposed process uses the cryogenic energy of LNG and saves 62.6%of electricity.The proposed process recovers ethane, liquid petroleum gas(propane and butane)and heavier hydrocarbons,with total recovery rate of natural gas liquids up to 96.8%.In this paper,exergy analysis and the energy utilization diagram method(EUD)are used to assess the new process and identify the key operation units with large exergy loss.The results show that exergy efficiency of the new process is 44.3%.Compared to the electric refrigeration process,exergy efficiency of the new process is improved by 16%.The proposed process has been applied and implemented in a conceptual design scheme of the cryogenic energy utilization for a 300 million tons/yr LNG receiving terminal in a northern Chinese harbor.
基金the National Natural Science Foundation of China (Nos. 50674090 and 50804047)the Research Fund of the State Key Laboratory of Coal Resources and Mine Safety,CUMT (No. 3Y080015)the Key Program of the National Natural Science Foundation of China (No. 51134023)
文摘In order to overcome the heavy casualties caused by gas explosion, we verified the propagation law of shock wave in pipeline and the overpressure distribution of gas explosion by similar experiments according to the analyses of reasons for casualty and ventilation system model destroyed by gas explosion in the mining face. We summarized the gas composition after the explosion and its danger, analyzed the effects of the gas explosion shock wave to ventilation system and facilities and the laws of toxic gas spread and diffusion in the ventilation network after the explosion. We presented a technical proposal to control the smoke and recover the ventilation system after a gas explosion and developed a reserve air door and control system that were embed in the lane, and could close automatically in conditions of no pressure and electricity. The results showed that the reserve air door normally opened and could close automatically controlling the smoke flow and resuming the ventilation system when the gas explosion shock wave destroyed the original shutting air door which resulted in the air short circuit.
基金National Natural Science Foundation of China(No.10675168)
文摘A two-pulse method is used to determine the insulation recovery time of the gas spark gap switch with different types of gas applied in a high power accelerator with a water dielectric pulse forming line. At the breakdown voltage of 450 kV, with the vacuum diode voltage of about 200 kV, and a current of 30 kA, recovery characteristics of H2, N2, SF6 were studied. The recovery percentages of the gas breakdown voltage and vacuum diode voltage were determined. The results show that hydrogen has the best recovery characteristics. At a pulse interval of 8.8 ms, the recovery percentages of both the gas breakdown voltage and vacuum diode voltage for hydrogen exceed 95%. For SF6 and N2 with an interval of 25 ms and 50 ms respectively, a 90% voltage recovery was obtained. The experiments also proved that the repetitive rate of the high power accelerator with a pulse forming line is mainly restricted by the gas switch repetitive rate; the recovery percentages of the vacuum diode voltage are limited by the recovery percentages of the gas switch breakdown voltage. The hydrogen switch can be employed for a high repetitive rate-high power accelerator with a pulse forming line.
基金This work was supported by the Department of Science and Technology of Sichuan Province(2019YFG0457)the National Natural Science Foundation of China(5183000045)+1 种基金the National Major Science and Technology Project of CNPC"Research and Application of Key Technologies for Beneft Development of Volcanic Rock Reservoirs”(2017E-04-05)the PetroChina Major Science and Technology Project(2018E-1805).
文摘Flue gas fooding is one of the important technologies to improve oil recovery and achieve greenhouse gas storage.In order to study multicomponent fue gas storage capacity and enhanced oil recovery(EOR)performance of fue gas water-alternating gas(fue gas-WAG)injection after continuous waterfooding in an oil reservoir,a long core fooding system was built.The experimental results showed that the oil recovery factor of fue gas-WAG fooding was increased by 21.25%after continuous waterfooding and fue gas-WAG fooding could further enhance oil recovery and reduce water cut signifcantly.A novel material balance model based on storage mechanism was developed to estimate the multicomponent fue gas storage capacity and storage capacity of each component of fue gas in reservoir oil,water and as free gas in the post-waterfooding reservoir.The ultimate storage ratio of fue gas is 16%in the fue gas-WAG fooding process.The calculation results of fue gas storage capacity showed that the injection gas storage capacity mainly consists of N_(2) and CO_(2),only N_(2) exists as free gas phase in cores,and other components of injection gas are dissolved in oil and water.Finally,injection strategies from three perspectives for fue gas storage,EOR,and combination of fue gas storage and EOR were proposed,respectively.
基金This study was financially supported by the National Natural Science Foundation of China(Grant Nos.51704197 and 11872258)。
文摘In this work, a novel thermal–hydraulic–mechanical (THM) coupling model is developed, where the real geological parameters of the reservoir properties are embedded. Accordingly, nine schemes of CO_(2) injection well (IW) and CH_(4) production well (PW) are established, aiming to explore the behavior of free gases after CO_(2) is injected into the depleted Wufeng–Longmaxi shale. The results indicate the free CH4 or CO2 content in the shale fractures/matrix is invariably heterogeneous. The CO_(2) involvement facilitates the ratio of free CH_(4)/CO_(2) in the matrix to that in the fractures declines and tends to be stable with time. Different combinations of IW–PWs induce a difference in the ratio of the free CH4 to the free CO_(2), in the ratio of the free CH_(4)/CO_(2) in the matrix to that in the fractures, in the content of the recovered free CH_(4), and in the content of the trapped free CO_(2). Basically, when the IW locates at the bottom Wufeng–Longmaxi shale, a farther IW–PWs distance allows more CO2 in the free phase to be trapped;furthermore, no matter where the IW is, a shorter IW–PWs distance benefits by getting more CH_(4) in the free phase recovered from the depleted Wufeng–Longmaxi shale. Hopefully, this work is helpful in gaining knowledge about the shale-based CO_(2) injection technique.
基金financially supported by the National Natural Science Foundation of China(51906256 and 52074337)Fundamental Research Funds for the Central Universities(21CX06033A)
文摘CO_(2)emission mitigation is one of the most critical research frontiers.As a promising option of carbon capture,utilization and storage(CCUS),CO_(2)storage with enhanced gas recovery(CSEGR)can reduce CO_(2)emission by sequestrating it into gas reservoirs and simultaneously enhance natural gas production.Over the past decades,the displacement behaviour of CO_(2)—natural gas has been extensively studied and demonstrated to play a key role on both CO_(2)geologic storage and gas recovery performance.This work thoroughly and critically reviews the experimental and numerical simulation studies of CO_(2)displacing natural gas,along with both CSEGR research and demonstration projects at various scales.The physical property difference between CO_(2)and natural gas,especially density and viscosity,lays the foundation of CSEGR.Previous experiments on displacement behaviour and dispersion characteristics of CO_(2)/natural gas revealed the fundamental mixing characteristics in porous media,which is one key factor of gas recovery efficiency and warrants further study.Preliminary numerical simulations demonstrated that it is technically and economically feasible to apply CSEGR in depleted gas reservoirs.However,CO_(2)preferential flow pathways are easy to form(due to reservoir heterogeneity)and thus adversely compromise CSEGR performance.This preferential flow can be slowed down by connate or injected water.Additionally,the optimization of CO_(2)injection strategies is essential for improving gas recovery and CO_(2)storage,which needs further study.The successful K12—B pilot project provides insightful field-scale knowledge and experience,which paves a good foundation for commercial application.More experiments,simulations,research and demonstration projects are needed to facilitate the maturation of the CSEGR technology.
基金funding from Natural Sciences and Engineering Research Council of Canada (NSERC) for this researchsupport from the University of Calgary Beijing Research Site, a research initiative associated with the University of Calgary Global Research Initiative in Sustainable Low Carbon Unconventional Resources, the Kerui Group, and the Mitacs Accelerate program
文摘The recovery factor from tight gas reservoirs is typically less than 15%, even with multistage hydrauhc tractunng stimulation. Such low recovery is exacerbated in tight gas condensate reservoirs, where the depletion of gas leaves the valuable condensate behind. In this paper, three enhanced gas recovery (EGR) methods including produced gas injection, CO2 injection and water injection are investigated to increase the well productivity for a tight gas condensate reservoir in the Montney Formation, Canada. The production performance of the three EGR methods is compared and their economic feasibility is evaluated. Sensitivity analysis of the key factors such as primary production duration, bottom-hole pressures, and fracture conductivity is conducted and their effects on the well production performance are analyzed. Results show that, compared with the simple depletion method, both the cumulative gas and condensate production increase with fluids injected. Produced gas injection leads to both a higher gas and condensate production compared with those of the CO2 injection, while waterflooding suffers from injection difficulty and the corresponding low sweep efficiency. Meanwhile, the injection cost is lower for the produced gas injection due to the on-site available gas source and minimal transport costs, gaining more economic benefits than the other EGR methods.
基金The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Grant Nos. 51374213 and 51674251), the State Key Research Development Program of China (Grant No. 2016YFC0600705), the National Natural Science Fund for Distinguished Young Scholars of China (Grant No. 51125017), the Fund for Innovative Research and Development Group Program of Jiangsu Province (Grant No. 2014- 27), the Science Fund for Creative Research Groups of the National Natural Science Foundation of China (Grant No. 51421003), and the Priority Academic Program Development of the Jiangsu Higher Education Institutions (PAPD 2014).
文摘This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization approaches to detect and observe the CO2-formation fluid displacement mechanism at the micro-scale, namely, magnetic resonance imaging, X-ray computed tomography and fabricated micromodels, but they are not capable of investigating the dis- placement process at the nano-scale. Though a lab-on-chip approach for the direct visualization of the fluid flow behaviour in nanoscale channels has been developed using an advanced epi-fluorescence microscopy method combined with a nanofluidic chip, it is still a qualitative analysis method. The lattice Boltzmann method (LBM) can simulate the CO2 displacement processes in a two-dimensional or three-dimensional (3D) pore structure, but until now, the CO2 displace- ment mechanisms had not been thoroughly investigated and the 3D pore structure of real rock had not been directly taken into account in the simulation of the CO2 displacement process. The status of research on the applications of CO2 displacement to enhance shale gas recovery is also analyzed in this paper. The coupling of molecular dynamics and LBM in tandem is proposed to simulate the CO2-shale gas displacement process based on the 3D digital model of shale obtained from focused ion beams and scanning electron microscopy.
基金partial support of UK EPSRC under grants EP/V012053/1,EP/S032622/1,EP/P004709/1,EP/P003605/1 and EP/N032888/1the British Council under 2020-RLWK12-10478 and 2019-RLWK11-10724。
文摘Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasification of LNG gives out a huge amount of waste energy since plenty of high grade cold energy(-160℃)from LNG is released to sea water directly in most cases,and also sometimes LNG is burned for regasification.On the other hand,liquid air energy storage(LAES)is an emerging energy storage technology for applications such as peak load shifting of power grids,which generates 30%-40%of compression heat(-200℃).Such heat could lead to energy waste if not recovered and used.The recovery of the compression heat is technically feasible but requires additional capital investment,which may not always be economically attractive.Therefore,we propose a power plant for recovering the waste cryogenic energy from LNG regasification and compression heat from the LAES.The challenge for such a power plant is the wide working temperature range between the low-temperature exergy source(-160℃)and heat source(-200℃).Nitrogen and argon are proposed as the working fluids to address the challenge.Thermodynamic analyses are carried out and the results show that the power plant could achieve a thermal efficiency of 27%and 19%and an exergy efficiency of 40%and 28%for nitrogen and argon,respectively.Here,with the nitrogen as working fluid undergoes a complete Brayton Cycle,while the argon based power plant goes through a combined Brayton and Rankine Cycle.Besides,the economic analysis shows that the payback period of this proposed system is only 2.2 years,utilizing the excess heat from a 5 MW/40 MWh LAES system.The findings suggest that the waste energy based power plant could be co-located with the LNG terminal and LAES plant,providing additional power output and reducing energy waste.
基金Project(hx2013-87)supported by the Qingdao Economic and Technology Development Zone Haier Water-Heater Co.Ltd.,China
文摘In order to evaluate the heating performance of gas engine heat pump(GEHP) for air-conditioning and hot water supply, a test facility was developed and experiments were performed over a wide range of engine speed(1400-2600 r/min), ambient air temperature(2.4-17.8 ℃) and condenser water inlet temperature(30-50℃). The results show that as engine speed increases from 1400 r/min to 2600 r/min, the total heating capacity and energy consumption increase by about 30% and 89%, respectively; while the heat pump coefficient of performance(COP) and system primary energy ratio(PER) decrease by 44% and 31%, respectively. With the increase of ambient air temperature from 2.4 ℃ to 17.8 ℃, the heat pump COP and system PER increase by 32% and 19%, respectively. Moreover, the heat pump COP and system PER decrease by 27% and 15%, respectively, when the condenser water inlet temperature changes from 30 ℃ to 50 ℃. So, it is obvious that the effect of engine speed on the performance is more significant than the effects of ambient air temperature and condenser water inlet temperature.
基金the financial support from National Natural Science Foundation of China(51504268)National Technology Major Project of China(2016ZX05014).
文摘Gas injection serves as a main enhanced oil recovery(EOR)method in fractured-vuggy carbonate reservoir,but its effect differs among single wells and multi-well groups because of the diverse fractured-vuggy configuration.Many researchers conducted experiments for the observation of fluid flow and the evaluation of production performance,while most of their physical models were fabricated based on the probability distribution of fractures and caves in the reservoir.In this study,a two-dimensional physical model of the karst fault system was designed and fabricated based on the geological model of TK748 well group in the seventh block of the Tahe Oilfield.The fluid flow and production performance of primary gas flooding were discussed.Gas-assisted gravity flooding was firstly introduced to take full use of gas-oil gravity difference,and its feasibility in the karst fault system was examined.Experimental results showed that primary gas flooding created more flow paths and achieved a remarkable increment of oil recovery compared to water flooding.Gas injection at a lower location was recommended to delay gas breakthrough.Gas-assisted gravity flooding achieved more stable gas-displacing-oil because oil production was at a lower location,and thus,the oil recovery was further enhanced.