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Shear wave splitting analysis of local earthquakes from dense arrays in Shimian,Sichuan 被引量:2
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作者 Sha Liu Baofeng Tian 《Earthquake Science》 2023年第1期52-63,共12页
The Shimian area of Sichuan sits at the junction of the Bayan Har block.Sichuan-Yunnan rhombic block,and Yangtze block,where several faults intersect.This region features intense tectonic activity and frequent earthqu... The Shimian area of Sichuan sits at the junction of the Bayan Har block.Sichuan-Yunnan rhombic block,and Yangtze block,where several faults intersect.This region features intense tectonic activity and frequent earthquakes.In this study,we used local seismic waveform data recorded using dense arrays deployed in the Shimian area to obtain the shear wave splitting parameters at 55 seismic stations and thereby determine the crustal anisotropic characteristics of the region.We then analyzed the crustal stress pattern and tectonic setting and explored their relationship in the study area.Although some stations returned a polarization direction of NNW-SSE.a dominant polarization direction of NW-SE was obtained for the fast shear wave at most seismic stations in the study area.The polarization directions of the fast shear wave were highly consistent throughout the study-area.This orientation was in accordance with the direction of the regional principal compressive stress and parallel to the trend of the Xianshuihe and Daliangshan faults.The distribution of crustal anisotropy in this area was affected by the regional tectonic stress field and the fault structures.The mean delay time between fast and slow shear waves was 3.83 ms/km.slightly greater than the values obtained in other regions of Sichuan.This indicates that the crustal media in our study area had a high anisotropic strength and also reveals the influence of tectonic complexity resulting from the intersection of multiple faults on the strength of seismic anisotropy. 展开更多
关键词 shear wave splitting polarization direction of the fast shear wave regional principal compressive stress dense array Citation:Liu S and Tian BF(2023).Shear wave splitting analysis of local earthquakes from dense arrays in Shimian Sichuan.
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WAVELET ANALYSIS OF THE VECTOR MAGNITUDE WAVE FOR DETECTION OF VENTRICULAR LATE POTENTIALS
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作者 Wu shuicai Lin lan Lin Jiarui(Huazhong University of Science and technology, Wuhan 430074, China) 《Chinese Journal of Biomedical Engineering(English Edition)》 1999年第3期30-31,共2页
关键词 IEEE waveLET analysis OF THE VECTOR MAGNITUDE wave FOR DETECTION OF VENTRICULAR LATE POTENTIALS
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Influence of seismic wave type and incident direction on the dynamic response of tall concrete-faced rockfill dams 被引量:2
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作者 Chen-guang Zhou De-gao Zou Xiang Yu 《Earthquake Science》 2022年第5期343-354,共12页
Owing to the stochastic behavior of earthquakes and complex crustal structure,wave type and incident direction are uncertain when seismic waves arrive at a structure.In addition,because of the different types of the s... Owing to the stochastic behavior of earthquakes and complex crustal structure,wave type and incident direction are uncertain when seismic waves arrive at a structure.In addition,because of the different types of the structures and terrains,the traveling wave effects have different influences on the dynamic response of the structures.For the tall concrete-faced rockfill dam(CFRD),it is not only built in the complex terrain such as river valley,but also its height has reached 300 m level,which puts forward higher requirements for the seismic safety of the anti-seepage system mainly comprising concrete face slabs,especially the accurate location of the weak area in seism.Considering the limitations of the traditional uniform vibration analysis method,we implemented an efficient dynamic interaction analysis between a tall CFRD and its foundation using a non-uniform wave input method with a viscous-spring artificial boundary and equivalent nodal loads.This method was then applied to investigate the dynamic stress distribution on the concrete face slabs for different seismic wave types and incident directions.The results indicate that dam-foundation interactions behave differently at different wave incident angles,and that the traveling wave effect becomes more evident in valley topography.Seismic wave type and incident direction dramatically influenced stress in the face slab,and the extreme stress values and distribution law will vary under oblique wave incidence.The influence of the incident direction on slab stress was particularly apparent when SH-waves arrived from the left bank.Specifically,the extreme stress values in the face slab increased with an increasing incident angle.Interestingly,the locations of the extreme stress values changed mainly along the axis of the dam,and did not exhibit large changes in height.The seismic safety of CFRDs is therefore lower at higher incident angles from an anti-seepage perspective.Therefore,it is necessary to consider both the seismic wave type and incident direction during seismic capacity evaluations of tall CFRDs. 展开更多
关键词 tall CFRD wave analysis vibration analysis seismic wave type incident direction face slab stress
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Parametric study on contact sensors for MASW measurement-based interfacial debonding detection for SCCS
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作者 Chen Hongbing Pang Xin +3 位作者 Gan Shiyu Li Yuanyuan Gokarna Chalise Nie Xin 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第2期331-344,共14页
Steel-concrete composite structures(SCCS)have been widely used as primary load-bearing components in large-scale civil infrastructures.As the basis of the co-working ability of steel plate and concrete,the bonding sta... Steel-concrete composite structures(SCCS)have been widely used as primary load-bearing components in large-scale civil infrastructures.As the basis of the co-working ability of steel plate and concrete,the bonding status plays an essential role in guaranteeing the structural performance of SCCS.Accordingly,efficient non-destructive testing(NDT)on interfacial debondings in SCCS has become a prominent research area.Multi-channel analysis of surface waves(MASW)has been validated as an effective NDT technique for interfacial debonding detection for SCCS.However,the feasibility of MASW must be validated using experimental measurements.This study establishes a high-frequency data synchronous acquisition system with 32 channels to perform comparative verification experiments in depth.First,the current sensing approaches for high-frequency vibration and stress waves are summarized.Secondly,three types of contact sensors,namely,piezoelectric lead-zirconate-titanate(PZT)patches,accelerometers,and ultrasonic transducers,are selected for MASW measurement.Then,the selection and optimization of the force hammer head are performed.Comparative experiments are carried out for the optimal selection of ultrasonic transducers,PZT patches,and accelerometers for MASW measurement.In addition,the influence of different pasting methods on the output signal of the sensor array is discussed.Experimental results indicate that optimized PZT patches,acceleration sensors,and ultrasonic transducers can provide efficient data acquisition for MASW-based non-destructive experiments.The research findings in this study lay a solid foundation for analyzing the recognition accuracy of contact MASW measurement using different sensor arrays. 展开更多
关键词 steel-concrete composite structures(SCCS) interface debonding detection multi-channel analysis of surface waves(MASW) sensor selection comparative experimental study
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Effects of size and location of distal tear on hemodynamics and wave propagation in type B aortic dissection
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作者 Huimin CHEN Qingzhuo CHI +2 位作者 Ying HE Lizhong MU Yong LUAN 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2022年第9期1449-1468,共20页
The type B aortic dissection(TBAD)is a perilous disease with high morbidity and mortality rates.The hemodynamics of TBAD in different scenarios has been widely studied by computational fluid dynamics(CFD)research.Howe... The type B aortic dissection(TBAD)is a perilous disease with high morbidity and mortality rates.The hemodynamics of TBAD in different scenarios has been widely studied by computational fluid dynamics(CFD)research.However,the flow pattern and wave propagation characteristics in the cardiovascular system with TBAD are not yet clear,and the effect of the distal tear is still unknown.In this work,a onedimensional(1D)cardiovascular system model coupling with a zero-dimensional(0D)lumped-parameter model is introduced to study the hemodynamics and wave propagation in the cardiovascular system.The results show that the proposed 0D-1D method well captures the oscillation and retrograde characteristics for the flow in the false lumen(FL),and the smaller distal tear damps the retrograde flow.Besides,the distal tear should also be paid attention to,and the wave intensity(WI)can be used as an access mark of the degree of the aortic dissection(AD). 展开更多
关键词 type B aorta dissection(TBAD) zero-dimensional(0D)-one-dimensional(1D)coupling model distal tear flow pattern wave intensity analysis(WIA)
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Drivability of Large Diameter Steel Cylinders During Hammer-Group Vibratory Installation for the Hong Kong–Zhuhai–Macao Bridge
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作者 W.J.Lu B.Li +3 位作者 J.F.Hou X.W.Xu H.F.Zou L.M.Zhang 《Engineering》 SCIE EI CAS CSCD 2023年第1期180-191,共12页
The Hong Kong–Zhuhai–Macao Bridge(HZMB)involved the installation of 120 mega-cylinders with a diameter of 22 m,weights up to 513 t,and penetration depths up to 33 m using an eight-vibratory hammer group.Due to the l... The Hong Kong–Zhuhai–Macao Bridge(HZMB)involved the installation of 120 mega-cylinders with a diameter of 22 m,weights up to 513 t,and penetration depths up to 33 m using an eight-vibratory hammer group.Due to the lack of engineering experience on the drivability of large-diameter cylinders under multiple vibratory hammers,predicting the penetration rate and time of steel cylinders is an open challenge that has a considerable impact on the construction control of the HZMB.In this study,the vibratory penetration of large-diameter steel cylinders in the HZMB is investigated based on geological surveys,field monitoring,and drivability analysis.The vibratory penetration rate,installation accuracy,and dynamic responses of the steel cylinders at both the eastern and western artificial islands are analyzed.The dynamic soil resistance has a great influence on the cylinder drivability.However,the current design methods for estimating the vibratory driving soil resistance are proven inaccurate without considering the scale effects.Therefore,a modified method with a normalized effective area ratio A_(r,eff)is proposed in this study to calculate the vibratory soil resistance for open-ended thin-wall cylinders under unplugged conditions.Considering the scale effects on the vibratory driving soil resistance,the proposed method leads to closer results to the measured data,providing a reference for future engineering practice. 展开更多
关键词 Hong Kong-Zhuhai-Macao Bridge Vibratory pile driving wave equation analysis Large-diameter steel cylinder Artificial island offshore foundati ons
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Recognition of rock anisotropy using integrated seismic approach-A case in Strzegom and Podlesna,Poland
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作者 Iwona Stan-Kłeczek Artur Marciniak 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第7期1759-1767,共9页
This paper presents the integration of seismic refraction and multichannel analysis of surface wave(MASW)measurements to investigate the anisotropy of P-and S-wave velocities.Additionally,synthetic forward modelling i... This paper presents the integration of seismic refraction and multichannel analysis of surface wave(MASW)measurements to investigate the anisotropy of P-and S-wave velocities.Additionally,synthetic forward modelling is presented as a tool for supporting seismic anisotropy studies.The geophysical measurements of cracks allowed to recognise the fracturing of a granite rock mass in a Paleozoic granite quarry(Strzegom,Poland)and a dolomite rock mass in a Triassic dolomite quarry(Podlesna,Poland).Application of the forward modelling supports the interpretation of seismic methods,simplifying data processing and verifying the final results based on data from difficult seismic conditions.As a result of direct measurements,two crack systems were determined in granite rock mass:NNE-SSW and NNW-SSE,and two in dolomite rock mass:NNE-SSW and NW-SE.Furthermore,the numerical results show the relationship between the highest values of P-and S-wave velocities and separated crack systems which allowed an unequivocal interpretation of the direction of stress,resulting in the deformations.The obtained information is promising to be helpful in mining exploration for optimising excavation works. 展开更多
关键词 FRACTURING ANISOTROPY Seismic refraction Multichannel analysis of surface wave(MASW) Forward modelling
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Case studies of ERS-1 altimeter data applicating in China Sea
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作者 杨学联 季晓阳 +1 位作者 黄润恒 凌铁军 《海洋预报》 北大核心 2001年第z1期1-10,共10页
The impact of ERS-1 altimeter significant wave height on analysis of wave field and wave pre- dictions is tested through analysis of selected cases. Application of the altimeter data may modifg initial tield and thus ... The impact of ERS-1 altimeter significant wave height on analysis of wave field and wave pre- dictions is tested through analysis of selected cases. Application of the altimeter data may modifg initial tield and thus 24-hour prediction of significant wave height. However the variations in initial wave field almost make no effect on 48-hour predictions. 展开更多
关键词 ERS-1 altimeter data wave analysis wave predictions initial field for numerical ocean prediction model.
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Lepton mass correction in partial wave analyses of charmed meson semi-leptonic decays
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作者 张晗 柯百谦 +1 位作者 余耀 王恩 《Chinese Physics C》 SCIE CAS CSCD 2023年第6期1-4,共4页
We derive a parameterization formula for the partial wave analyses of charmed meson semi-leptonic decays while considering the effects of lepton mass.Because the proposed super-tau-charm factory will reach a significa... We derive a parameterization formula for the partial wave analyses of charmed meson semi-leptonic decays while considering the effects of lepton mass.Because the proposed super-tau-charm factory will reach a significantly enhanced luminosity and BESIII is collecting newψ(3770)→DD data,our results will help improve the measurement precision of future partial wave analyses of charmed meson semi-muonic decays. 展开更多
关键词 partial wave analysis charmed meson semi-leptonic decay
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Detection of water surface capillary wave by analysis of turning-point local signal data using a laser interferometer 被引量:1
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作者 张烈山 张晓琳 唐文彦 《Chinese Optics Letters》 SCIE EI CAS CSCD 2017年第7期36-41,共6页
A laser interferometry technique is developed to detect water surface capillary waves caused by an impinging acoustic pressure field. The frequency and amplitude of the water surface capillary waves can be estimated f... A laser interferometry technique is developed to detect water surface capillary waves caused by an impinging acoustic pressure field. The frequency and amplitude of the water surface capillary waves can be estimated from the local signal data at some special points of the phase modulated interference signal, which is called the turning points. Demodulation principles are proposed to explain this method. Experiments are conducted under conditions of different intensity and different frequency driving acoustic signals. The results show the local signal data analysis can effectively estimate the amplitude and frequency of water surface capillary waves. 展开更多
关键词 of de is as by Detection of water surface capillary wave by analysis of turning-point local signal data using a laser interferometer wave DATA
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Experimental analysis of acousto-ultrasonic wave propagation mode in thin plate 被引量:2
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作者 LIU Zhenqing HUANG Ruiju (Institute of Acoustics, Tongji University Shanghai 200092) 《Chinese Journal of Acoustics》 2000年第3期277-284,共8页
in the acousto-ultrasonic technique, a broadband ultrasonic wave is injected onto the surface at one location of the tested plate with the help of a longitudinal transducer and a receiving transducer is coupled to the... in the acousto-ultrasonic technique, a broadband ultrasonic wave is injected onto the surface at one location of the tested plate with the help of a longitudinal transducer and a receiving transducer is coupled to the same surface at another location. Thus, understanding the propagation characteristics of the ultrasonic wave is essential for successful application of the technique. It has been found that the dominant acousto-ultrasonic waves produced experimentally in thin plate are multi-mode Lamb waves. The broadband generation and detection of Lamb waves have been performed in two aluminum plates with different thickness using the acousto-ultrasonic method. 展开更多
关键词 wave MODE Experimental analysis of acousto-ultrasonic wave propagation mode in thin plate
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Theoretical analysis for sound wave scattering by parallel cylindrical tubes in boilers 被引量:1
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作者 JIANG Genshan (North China Electric Power University Baoding 071003) TIAN Jing LI Xiaodong (Institute of Acoustics, Academia Sinica Beijing 100080) 《Chinese Journal of Acoustics》 2000年第2期105-113,共9页
Although the sonic soot cleaning techniques have been applied in boilers in power plants, petrochemical works and general industries world wide, most of the correlated basic problems have not been well solved yet. By ... Although the sonic soot cleaning techniques have been applied in boilers in power plants, petrochemical works and general industries world wide, most of the correlated basic problems have not been well solved yet. By using Helmholtz integral equation, sound wave scattered by heat-exchanger tubes is numerically calculated. Sound field distribution characteristics on the tube surfaces and around the tube group is obtained. The results can be applied to the development of sonic soot cleaning techniques in boilers. 展开更多
关键词 wave Theoretical analysis for sound wave scattering by parallel cylindrical tubes in boilers
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Discrete Vector Calculus and Helmholtz Hodge Decomposition for Classical Finite Difference Summation by Parts Operators
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作者 Hendrik Ranocha Katharina Ostaszewski Philip Heinisch 《Communications on Applied Mathematics and Computation》 2020年第4期581-611,共31页
In this article,discrete variants of several results from vector calculus are studied for clas-sical finite difference summation by parts operators in two and three space dimensions.It is shown that existence theorems... In this article,discrete variants of several results from vector calculus are studied for clas-sical finite difference summation by parts operators in two and three space dimensions.It is shown that existence theorems for scalar/vector potentials of irrotational/solenoidal vector fields cannot hold discretely because of grid oscillations,which are characterised explicitly.This results in a non-vanishing remainder associated with grid oscillations in the discrete Helmholtz Hodge decomposition.Nevertheless,iterative numerical methods based on an interpretation of the Helmholtz Hodge decomposition via orthogonal projections are pro-posed and applied successfully.In numerical experiments,the discrete remainder vanishes and the potentials converge with the same order of accuracy as usual in other first-order partial differential equations.Motivated by the successful application of the Helmholtz Hodge decomposition in theoretical plasma physics,applications to the discrete analysis of magnetohydrodynamic(MHD) wave modes are presented and discussed. 展开更多
关键词 Summation by parts Vector calculus Helmholtz Hodge decomposition Mimetic properties wave mode analysis
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THEORETICAL ANALYSIS OF ATMOSPHERIC WAVES IN EQUATORIAL ZONE
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作者 周紫东 狄新武 杜行远 《Science China Mathematics》 SCIE 1980年第6期754-765,共12页
In the equatorial zone the dynamic equations of the atmospheric motion are written inthe β-plane.These equations are linearized according to the mean atmospheric conditions.Numerical method is used to obtain a charac... In the equatorial zone the dynamic equations of the atmospheric motion are written inthe β-plane.These equations are linearized according to the mean atmospheric conditions.Numerical method is used to obtain a characteristic wave solution. Results obtained showthat the easterly wind shear changes the phase speed of low frequency waves more strikinglythan that of high frequency waves. The structure of the characteristic disturbances is sim-ilar to that in middle latitudes only with some exceptions in the relationship of geopo-tential field with vorticity field. 展开更多
关键词 In THEORETICAL analysis OF ATMOSPHERIC waveS IN EQUATORIAL ZONE OC HIGH 卜工 OO
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The Initial Tangent of the Femoral Arterial Pressure Increase Is an Estimate of Left Ventricular Contractility in Patients Undergoing Cardiacsurgery
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作者 Matthias Langin Christian Kowalski +2 位作者 Frank Christ Bernhard Zwissler Hille Kisch-Wedel 《Open Journal of Anesthesiology》 2014年第9期207-216,共10页
Purpose: Assessment of contractile function is a major challenge in patients with left ventricular dysfunction, especially during cardiac surgery. The initial tangent of the femoral arterial pressure increase (tanin) ... Purpose: Assessment of contractile function is a major challenge in patients with left ventricular dysfunction, especially during cardiac surgery. The initial tangent of the femoral arterial pressure increase (tanin) has recently been described to be an estimate of left ventricular (LV) contractility. To confirm these findings tanin was compared to various indices of LV performance in patients undergoing cardiac surgery. Methods: Data from 17 patients were evaluated retrospectively. Myocardial performance was estimated by the echocardiographic indices ejection fraction (EF), shortening fraction (FS), circumferential fiber shortening velocity (Vcf), the parameters of pulse contour analysis area under the curve (AUC) and tanin. Measurements were taken before and after cardiopulmonary bypass (CPB). Results: Tanin increased significantly (813 ± 216 mmHg/s vs. 1490 ± 450 mmHg/s, p < 0.05) after CPB, as well as Vcf (0.89 ± 0.14 circ/s vs. 1.47 ± 0.27 circ/s, p < 0.05) and EF (65% ± 7% vs. 74% ± 6%, p < 0.05). FS did not change (40.7% ± 7% vs. 46.5% ± 5%, p = 0.30). AUC significantly dropped after CPB (435 ± 54 mmHg*s vs. 263 ± 27 mmHg*s). Tanin and Vcf correlated strongly (r = 0.70, p < 0.001), while tanin showed only weak correlation with EF (r = 0.36, p = 0.037). There was no significant correlation with FS (r = 0.31, p = 0.079). Tanin and AUC correlated inversely (r = -0.62, p < 0.001). Conclusions: While showing little or no correlation with EF and FS respectively, tanin correlated well with the less preload-dependent parameter Vcf, thus suggesting that tanin may be used as an easily accessible estimate of LV contractility during cardiac surgery. 展开更多
关键词 Arterial Pressure wave Form analysis Left Ventricular Contractility Cardiacsurgery
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A comparative study of 3D FZI and electrofacies modeling using seismic attribute analysis and neural network technique:A case study of Cheshmeh-Khosh Oil field in Iran 被引量:1
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作者 Mahdi Rastegarnia Ali Sanati Dariush Javani 《Petroleum》 2016年第3期225-235,共11页
Electrofacies are used to determine reservoir rock properties,especially permeability,to simulate fluid flow in porous media.These are determined based on classification of similar logs among different groups of loggi... Electrofacies are used to determine reservoir rock properties,especially permeability,to simulate fluid flow in porous media.These are determined based on classification of similar logs among different groups of logging data.Data classification is accomplished by different statistical analysis such as principal component analysis,cluster analysis and differential analysis.The aim of this study is to predict 3D FZI(flow zone index)and Electrofacies(EFACT)volumes from a large volume of 3D seismic data.This study is divided into two parts.In the first part of the study,in order to make the EFACT model,nuclear magnetic resonance(NMR)log parameters were employed for developing an Electrofacies diagram based on pore size distribution and porosity variations.Then,a graph-based clustering method,known as multi resolution graph-based clustering(MRGC),was employed to classify and obtain the optimum number of Electrofacies.Seismic attribute analysis was then applied to model each relaxation group in order to build the initial 3D model which was used to reach the final model by applying Probabilistic Neural Network(PNN).In the second part of the study,the FZI 3D model was created by multi attributes technique.Then,this model was improved by three different artificial intelligence systems including PNN,multilayer feed-forward network(MLFN)and radial basis function network(RBFN).Finally,models of FZI and EFACT were compared.Results obtained from this study revealed that the two models are in good agreement and PNN method is successful in modeling FZI and EFACT from 3D seismic data for which no Stoneley data or NMR log data are available.Moreover,they may be used to detect hydrocarbon-bearing zones and locate the exact place for producing wells for the future development plans.In addition,the result provides a geologically realistic spatial FZI and reservoir facies distribution which helps to understand the subsurface reservoirs heterogeneities in the study area. 展开更多
关键词 Electrofacies Nuclear magnetic resonance log Flow zone index Stoneley wave analysis Seismic attribute analysis
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An Optimized Correction Procedure via Reconstruction Formulation for Broadband Wave Computation
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作者 Yi Li Z.J.Wang 《Communications in Computational Physics》 SCIE 2013年第5期1265-1291,共27页
Recently,a new differential discontinuous formulation for conservation laws named the Correction Procedure via Reconstruction(CPR)is developed,which is inspired by several other discontinuous methods such as the disco... Recently,a new differential discontinuous formulation for conservation laws named the Correction Procedure via Reconstruction(CPR)is developed,which is inspired by several other discontinuous methods such as the discontinuous Galerkin(DG),the spectral volume(SV)/spectral difference(SD)methods.All of them can be unified under the CPR formulation,which is relatively simple to implement due to its finite-difference-like framework.In this paper,a different discontinuous solution space including both polynomial and Fourier basis functions on each element is employed to compute broad-band waves.Free-parameters introduced in the Fourier bases are optimized to minimize both dispersion and dissipation errors through a wave propagation analysis.The optimization procedure is verified with a mesh resolution analysis.Numerical results are presented to demonstrate the performance of the optimized CPR formulation. 展开更多
关键词 CPR(correction procedure via reconstruction) hybrid discontinuous space wave propagation analysis unstructured meshes
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Raman spectroscopy and quantum chemical calculation on YCl_(3)-KCl molten salt system
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作者 Can Xu Xian-Wei Hu +5 位作者 Jiang-Yu Yu Peng-Wei Li Ai-Min Liu Shao-Hua Luo Zhong-Ning Shi Zhao-Wen Wang 《Rare Metals》 SCIE EI CAS CSCD 2023年第11期3886-3896,共11页
The knowledge on the ionic structure of YCl_(3)-KCl molten system is of guiding significance for the practical production of yttrium metals and yttrium alloys via molten salt electrolysis using this system as electrol... The knowledge on the ionic structure of YCl_(3)-KCl molten system is of guiding significance for the practical production of yttrium metals and yttrium alloys via molten salt electrolysis using this system as electrolyte.In this paper,the theoretical Raman spectra of the ionic groups which may exist in YCl_(3)-KCl molten system are simulated by quantum chemical calculation using Gaussian09 and Gauss View 5.0 programs based on density functional theory(DFT).Then the ionic structures of 20 mol%-60 mol%YCl_(3)-KCl molten salt systems are studied by comparing the Raman shift values of the bands in the theoretical Raman spectra of different ionic groups with the experimental spectra of this system.YCl_(6)^(3-),Y_(2)Cl_(7)^(-),Y_(2)Cl_(8)^(2-)and Y_(2)Cl_(9)^(3-)are thought to exist in the molten system.With the increase of temperature,the relative content of YCl_(6)^(3-)ionic groups increases while those of Y_(2)Cl_(7)^(-),Y_(2)Cl_(8)^(2-)and Y_(2)Cl_(9)^(3-)ionic groups decrease.Moreover,the"lifetime"of all ionic groups decreases within the temperature range of 692-730℃.Meanwhile,the relative contents of Y_(2)Cl_(7)^(-),Y_(2)Cl_(8)^(2-)and Y_(2)Cl_(9)^(3-)increase with the increase of YCl_(3)content,while that of YCl_(6)^(3-)decreases.The wave function analysis of the four ionic groups(YCl_(6)^(3-),Y_(2)Cl_(7)^(-),Y_(2)Cl_(8)^(2-),and Y_(2)Cl_(9)^(3-))is carried out by Multiwfn program.The net charge in each group,the direction of electron migration during the formation of each group,the sites where electrophilic and nucleophilic reactions are most likely to occur in each ionic group,and the order of bond breaking during chemical reactions for the four groups are obtained. 展开更多
关键词 YCl_(3)-KCl molten salt Ionic structure Raman spectroscopy Quantum chemical calculation wave function analysis
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