Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption

Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is considered an effective means to achieve high-efficiency EMW absorption.However,interface modulation engineering has not been fully discussed and has great potential in the field of EMW absorption.In this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal reduction.By utilizing the different properties of different substances,rich heterogeneous interfaces are constructed.This effectively promotes charge transfer and enhances interfacial polarization and conduction loss.The prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy resin.The minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 GHz.Moreover,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel surfaces.Therefore,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.

Defects‑Rich Heterostructures Trigger Strong Polarization Coupling in Sulfides/Carbon Composites with Robust Electromagnetic Wave Absorption

Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.

Integration of Electrical Properties and Polarization Loss Modulation on Atomic Fe–N‑RGO for Boosting Electromagnetic Wave Absorption

Developing effective strategies to regulate graphene’s conduction loss and polarization has become a key to expanding its application in the electromagnetic wave absorption(EMWA)field.Based on the unique energy band structure of graphene,regulating its bandgap and electrical properties by introducing heteroatoms is considered a feasible solution.Herein,metal-nitrogen doping reduced graphene oxide(M–N-RGO)was prepared by embedding a series of single metal atoms M–N_(4) sites(M=Mn,Fe,Co,Ni,Cu,Zn,Nb,Cd,and Sn)in RGO using an N-coordination atom-assisted strategy.These composites had adjustable conductivity and polarization to optimize dielectric loss and impedance matching for efficient EMWA performance.The results showed that the minimum reflection loss(RL_(min))of Fe–N-RGO reaches−74.05 dB(2.0 mm)and the maximum effective absorption bandwidth(EAB_(max))is 7.05 GHz(1.89 mm)even with a low filler loading of only 1 wt%.Combined with X-ray absorption spectra(XAFS),atomic force microscopy,and density functional theory calculation analysis,the Fe–N_(4) can be used as the polarization center to increase dipole polarization,interface polarization and defect-induced polarization due to d-p orbital hybridization and structural distortion.Moreover,electron migration within the Fe further leads to conduction loss,thereby synergistically promoting energy attenuation.This study demonstrates the effectiveness of metal-nitrogen doping in regulating the graphene′s dielectric properties,which provides an important basis for further investigation of the loss mechanism.

Low‑Temperature Oxidation Induced Phase Evolution with Gradient Magnetic Heterointerfaces for Superior Electromagnetic Wave Absorption

Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.

Graphene Aerogel Composites with Self‑Organized Nanowires‑Packed Honeycomb Structure for Highly Efficient Electromagnetic Wave Absorption

With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.

Effect of Berm Width and Elevation on Irregular Wave Run-Up

This paper discusses the effect of berm width and elevation of composite slope on irregular wave run-up. Based on the data obtained from model tests, the formula and distribution of irregular wave run-up on composite slope are derived. The changing of wind speed, width and elevation of the berm are considered comprehensively. The wave run-up with various exceedance probability can be es-timated utilizing the distribution curves of irregular wave run-up.

Impedance Analytical Method of Wave Run-up and Reflection from A Slotted-Wall Caisson Breakwater

An impedance analytical method （IAM） is developed to study the interaction of plane water wave with a slotted-wall caisson breakwater. The non-linear boundary condition at the slotted-wall is expressed in terms of flow resistance. A set of algebraic expressions are obtained for free surface elevation inside and outside chamber, and reflection coefficient. The prediction of the reflection coefficients shows that the relative widths of the chamber inducing the minimum reflection coefficient for a slotted-wall caisson breakwater are in a range of 0.10～0.20, which are smaller than that （0.15～0.25） for a perforated-wall caisson breakwater. The reflection coefficients and free surface elevation obtained by the present model are compared with that of laboratory experiments carried out by previous researchers.

Experimental Investigation of Wave Load and Run-up on the Composite Bucket Foundation Influenced by Regular Waves

In the design of wind turbine foundations for offshore wind farms, the wave load and run-up slamming on the supporting structure are the quantities that need to be considered. Because of a special arc transition, the interaction between the wave field and the composite bucket foundation(CBF) becomes complicated. In this study, the hydrodynamic characteristics, including wave pressure, load, upwelling, and run-up, around the arc transition of a CBF influenced by regular waves are investigated through physical tests at Shandong Provincial Key Laboratory of Ocean Engineering, Ocean University of China. The distributions of the wave pressures and upwelling ratios around the CBF are described, and the relationship between the wave load and the wave parameters is discussed. New formulae based on the velocity stagnation head theory with linear wave theory and the second-order Stokes wave theory for wave kinematics are proposed to estimate the wave run-up. Moreover, the multiple regression method with nonlinear technology is employed to deduce an empirical formula for predicting run-up heights. Results show that the non-dimensional wave load increases with the increase in the values of the wave scattering parameter and relative wave height. The wave upwelling height is high in front of the CBF and has the lowest value at an angle of 135? with the incoming wave direction. The performance of the new formulae proposed in this study is compared using statistical indices to demonstrate that a good fit is obtained by the multiple regression method and the analytical model based on the velocity stagnation head theory is underdeveloped.

Experimental Study on 2-D Focusing Wave Run-up on A Vertical Cylinder

In this paper,the focused wave groups with different parameters and their actions on a vertical cylinder are experimentally studied. The harmonic wave characteristics of the focusing waves are analyzed by the addition and subtraction of the crest and trough focusing waves. The analyzed results show that higher order harmonics can be generated because of the interaction of component waves. Nonlinearity increases with the inputted wave amplitude and the frequency width increment. Further, the wave run-up around the vertical circular cylinder is experimentally studied. It increases with the wave steepness and the relative cylinder diameter increase. However, the variations of wave run-up around the circular cylinder are different. The researches provide a reference for further numerical studies.

Wave Run-up on A Coaxial Perforated Circular Cylinder

This paper describes a plane regular wave interaction with a combined cylinder which consists of a solid inner column and a coaxial perforated outer cylinder. The outer perforated surface is a thin porous cylinder with an annular gap between it and the inner cylinder. The non-linear boundary condition at the perforated wall is a prime focus in the study; energy dissipation at the perforated wall occurs through the resistance to the fluid across the perforated wall. Explicit analytical formulae are presented to calculate the wave run-up on the outer and inner surfaces of the perforated cylinder and the surface of the inner column. The theoretical results of the wave run-up are compared with previous experimental data. Numerical results have also been obtained： when the ratio of the annular gap between the two cylinders to incident wavelength （b-a）/L≤0. 1, the wave run-up on the inner surface of the perforated cylinder and the surface of inner column can partially or completely exceed the incident wave height.

Wave Run-up on A Vertical Seawall Protected by An Offshore Submerged Barrier

Submerged barriers are constructed in coastal zones for shoreline or harbor protection or to prevent the beach erosion. In the present study, the wave run-up on a vertical seawall protected by a submerged barrier is analyzed. The physical configurations include a rigid barrier and a long channel of finite depth. For linear water waves, by matching the velocity along the barrier and along the gap, the systems of linear equations about the velocity potentials are obtained. The wave rim-up is further analyzed for various settings of barrier height and distance between the barrier and the wall, i.e. the chamber length. For nonlinear waves and random sea waves, a numerical model is extended to investigate the effect parameters of the barrier on the wave rim-up against the seawall. Not only the numerical simulations, but also the analytical results illustrate that the wave run-up on the seawall depends very much on the distance between the barrier and the vertical seawall.

Numerical Investigation of Run-ups on Cylinder in Steep Regular Wave

The run-up on offshore structures induced by the steep regular wave is a highly nonlinear flow with a free surface. This article focuses on the investigation of the steep regular wave run-up on a single vertical cylinder by solving the Navier-Stokes equations. A numerical wave tank is established based on the open-source package to simulate the wave scattering induced by a vertical cylinder. The VOF method is applied to capture the large deformation and breaking of the free surface. The numerical model is validated by experimental results. The relative wave run-ups on the front face and the back face along the centerline of a cylinder are analyzed. The changes of the relative run-ups with the wave steepness, the relative diameter and the relative depth are studied. It is found that the relative run-ups on the front face and the back face of the cylinder depend mainly on the wave steepness and the relative diameter, while the dependence on the relative depth is weak. The empirical formulae are proposed to calculate the relative run-ups in terms of the wave steepness of incident regular waves and the relative diameter of a cylinder.

Numerical Study of the Impact of Climate Change on Irregular Wave Run-up Over Reef-Fringed Coasts

Wave hydrodynamics over fringing reefs is largely controlled by the reef surface roughness and hydrodynamic forcing.It is believed that climate change will result in a net increase in the water depth over the reef flat,a degrading of the surface roughness of coral reefs and changes in extreme incident wave heights.For an accurate assessment of how climate change affects the safety of reef-fringed coasts,a numerical study of the impact of climate change on irregular wave run-up over reef-fringed coasts was carried out based on a Boussinesq wave model,FUNWAVE-TVD.Validated with experimental data,the present model shows reasonable prediction of irregular wave evolution and run-up height over fringing reefs.Numerical experiments were then implemented based on the anticipated effects of climate change and carried out to investigate the effects of sea level rise,degrading of the reef surface roughness and increase of extreme incident wave height on the irregular wave run-up height over the backreef beach respectively.Variations of run-up components(i.e.,spectral characteristics of run-up and mean water level)were examined specifically and discussed to better understand the influencing mechanism of each climate change-related effect on the run-up.

Application of artificial neural network to calculation of solitary wave run-up

The prediction of solitary wave run-up has important practical significance in coastal and ocean engineering, but the calculation precision is limited in the existing models. For improving the calculation precision, a solitary wave run-up calculation model was established based on artificial neural networks in this study. A back-propagation （BP） network with one hidden layer was adopted and modified with the additional momentum method and the auto-adjusting learning factor. The model was applied to calculation of solitary wave run-up. The correlation coefficients between the neural network model results and the experimental values was 0.996 5. By comparison with the correlation coefficient of 0.963 5, between the Synolakis formula calculation results and the experimental values, it is concluded that the neural network model is an effective method for calculation and analysis of solitary wave ran-up.

RANS-VOF Solver for Solitary Wave Run-up on A Circular Cylinder

Simulation of solitary wave run-up on a vertical circular cylinder is carried out in a viscous numerical wave tank developed based on the open source codes Open FOAM. An incompressible two-phase flow solver naoe-FOAM-SJTU is used to solve the Reynolds-Averaged Navier–Stokes（RANS） equations with the SST k ？？ turbulence model. The PISO algorithm is utilized for the pressure-velocity coupling. The air-water interface is captured via Volume of Fluid（VOF） technique. The present numerical model is validated by simulating the solitary wave run-up and reflected against a vertical wall, and solitary wave run-up on a vertical circular cylinder. Comparisons between numerical results and available experimental data show satisfactory agreement. Furthermore, simulations are carried out to study the solitary wave run-up on the cylinder with different incident wave height H and different cylinder radius a. The relationships of the wave run-up height with the incident wave height H, cylinder radius a are analyzed. The evolutions of the scattering free surface and vortex shedding are also presented to give a better understanding of the process of nonlinear wave-cylinder interaction.

Numerical investigation of solitary wave run-up attenuation by patchy vegetation

Coastal vegetation is capable of decreasing wave run-up.However,because of regrowth,decay or man-made damage,coastal vegetation is always distributed in patches,and its internal distribution is often non-uniform.This study investigates the effects of patchy vegetation on solitary wave run-up by using a numerical simulation.A numerical model based on fully nonlinear Boussinesq equations is established to simulate the wave propagation on a slope with patchy vegetation.By using the model,the process of solitary wave run-up attenuation due to patchy vegetation is numerically analysed.The numerical results reveal that patchy vegetation can considerably attenuate the wave run-up in an effective manner.In addition,high-density patched vegetation can attenuate the solitary wave run-up more effectively than low-density patched vegetation can.For the same density,patchy vegetation with a uniform distribution has a better attenuation effect on wave run-up compared to that of patchy vegetation with a non-uniform distribution.

WavewatchⅢ模拟和统计方法在最大波高预报方面的评测分析

为了研究WavewatchⅢ(WWⅢ)海浪模型对最大波高的模拟能力及其与传统统计关系方法的差异,通过对两次台风浪过程的后报模拟和半年的业务化预报,分析了WWⅢ数值模拟的准确度及其与统计关系方法的精度差异。研究结果表明:WWⅢ数值模拟的最大波高(Hmax)的精度略低于有效波高(Hs),但也达到了24 h预报相对误差(H_(max)≥1 m)低于18%、相关系数高于0.94的水平,模拟精度可靠,可以用于业务化预报;与两种统计关系方法(H_(max)和H_(s)分别为1.42和1.52)计算的最大波高相比,数值模拟的精度总体与其相当,但在H_(max)和H_(s)比值大于1.65这种易出现危险的海况下,数值模拟具有更高的准确性,更适合应用于海浪预警报服务。

Prediction on Irregular Wave Run-up and Overtopping

A series of hydraulic model tests are carried out to investigate random wave run-up and overtopping on smooth, impermeable single slope and composite slope. Based on the analysis of the influences of wave steepness, structure slope, incident wave angle, width of the berm and water depth on the berm and the wave run-up, empirical formulas for wave run-up on dike are proposed. Moreover, empirical formula on estimating the wave run-up on composite slope with multiple berms is presented for practical application of complex dike cross-section. The present study shows that the influence factors for wave overtopping are almost the same as those for wave run-up and the trend of the wave overtopping variation with main influence parameters is also similar to that for wave run-up. The trend of the wave overtopping variations can be well described by two main factors, i.e. the wave run-up and the crest freeboard of the structure. A new prediction method for wave overtopping is proposed for random waves. The proposed prediction formulas are applied to case study of over forty cases and the results show that the prediction methods are good enough for practical design purposes.

Experiments on Transformation and Run-Up of Wave Trains

This paper. details experiments undertaken in the UK Coastal Research Facility (CRF)at Hy draulies Research (HR), Wallingford, on transformation and run-up of wave trains. The purpose of these experiments is to provide verification data for numerical models of wave transformation in shoaling. surf and swash zones. This is the kind of data ih:lt flume experiments are unable to provide, and is collected in the highly controlled environment of CRF where extrinsic factors present in the field are not an issue. The experiments concerning wave trains are undertaken by use of existing wave generation software, and the run-up measurements are made with large experimental run-up gauges.

Effect of Wave Groups on Wave Run-up

-The effect of wave group on wave run-up on a slope dike is mainly discussed in this paper. Two simulating methods of wave group and their applications in laboratory are introduced. Synthesizing the research results of wave run-up on a slope dike, the effect of wave group on wave run-up on a slope dike in coastal protection engineering is studied as the main point.