The luminogens with aggregation-induced emission(AIEgens) characteristics have been widely applied in diverse areas. However,the n-type AIEgens are to be further developed. In this paper, we designed and synthesized a...The luminogens with aggregation-induced emission(AIEgens) characteristics have been widely applied in diverse areas. However,the n-type AIEgens are to be further developed. In this paper, we designed and synthesized an n-type multifunctional AIEgen of tetraphenylethene-substituted 3,4,5-triphenyl-4H-1,2,4-triazole(BTPE-TAZ). This AIEgen can serve as both light-emitting and electron-transporting layers in organic light-emitting devices. Moreover, it also exhibits the interesting optical waveguide and reversible mechanochromic luminescence properties, which are of great potential for practical applications.展开更多
基金supported by the key project of the Ministry of Science and Technology of China(2013CB834702)the National Natural Science Foundation of China(21525417)+4 种基金the Natural Science Foundation of Guangdong Province(2016A030312002)the National Program for Support of Top-Notch Young Professionals,the Fundamental Research Funds for the Central Universities(2015ZY013)the Innovation and Technology Commission(ITC-CNERC14S01)China Postdoctoral Science Foundation Grant(2016M602463)the support from Guangdong Innovative Research Team Program(201101C0105067115)
文摘The luminogens with aggregation-induced emission(AIEgens) characteristics have been widely applied in diverse areas. However,the n-type AIEgens are to be further developed. In this paper, we designed and synthesized an n-type multifunctional AIEgen of tetraphenylethene-substituted 3,4,5-triphenyl-4H-1,2,4-triazole(BTPE-TAZ). This AIEgen can serve as both light-emitting and electron-transporting layers in organic light-emitting devices. Moreover, it also exhibits the interesting optical waveguide and reversible mechanochromic luminescence properties, which are of great potential for practical applications.