Diffusion and Oxidation Wear of PCBN Tool based on Thermodynamics

The rules of diffusion wear and oxidation wear for PCBN cutting tools were analyzed based on thermodynamics theory. Dissolution concentrations in typical normal workpice materials of PCBN tool material at different temperature were then calculated. Diffusion reaction rules in high temperature were developed and analyzed using the Gibbs free energy criterion. The machining tests were conducted using the PCBN tools at different cutting speeds of 50, 95,100 and 180 m/min, feed of 0.1, 0.2 and depth of cut of 0.1, 0.8, 1, and 1.5 mm respectively on a PUMA300LM numerically-controlled lathe. It was found that the theoretical results were uniform with the experimental data, and the results will provide useful references for tool material design and selection.

Thermodynamics Analysis of Oxidation Wear Behavior of Cemented Carbide Tools in High Speed Machining

The essence of oxidation wear machanism of cenmented carbide tool was studied based on thermodynamics. Standard Gibbs free energy of possible reactions in cutting process at different temperature was calculated using substance Gibbs free energy function methods, and the sequence of reaction possibility order was researched as well as characteristics of every reaction. Theoretical calculation shows that WO3, Co3O4, TiO2 and CoWO4 are the main resultants, which are proved with the experiment results.

Wear behavior and dry sliding tribological properties of ultra-fine grained Al5083 alloy and boron carbide-reinforced Al5083-based composite at room and elevated temperatures

Tribological behavior and wear mechanisms of mechanically milled Al5083 alloy and Al5083−5wt.%B4C composite at room temperature and 200°C were discussed.Results revealed that due to the oxidative wear at room temperature,a mechanically mixed layer(MML)was formed to protect the surface of the samples.Under 80 N of load at room temperature,the milled Al5083 and the Al5083−5wt.%B4C samples showed evidence of abrasion with limited volume loss.In this case,the wear rates were 5.8×10−7 and 4.4×10−7 mm3/(m·N),respectively.At 200°C and under 80 N of applied load,severe wear occurred in the milled Al5083 sample,and wear rate reached 10.8×10−7 mm3/(m·N)while the Al5083−5wt.%B4C sample showed mild wear with local 3-body abrasion and the wear rate reached 5.3×10−7 mm3/(m·N).Strengthening mechanisms such as dislocation pinning and the Hall−Petch theory,high hardness and the load transfer effect were crucial in determining the wear behavior of the Al5083−5wt.%B4C composite.On the other hand,the milled Al5083 sample represented a relatively high wear rate at 200°C,which seemed to be related to the local grain growth and a drop in its hardness.

Effect of Attapulgite Added in Plating Bath on the Properties of Ni/TiC Nano-composite Coatings

Pure copper plates were coated by Ni-TiC dipulse current plating method. The effects of adding different concentration（ranging from 0.5 g/L to 3.0 g/L） of attapulgite nano particles to the plating bath on the surface morphology, wear resistance, and oxidation resistance of Ni/TiC/Attapulgite nano-composite coatings were investigated. The experimental results show that the composite coating is flat and compact with adding 3.0 g/L in the bath, and the coating preferred orientation is changed from the planes（111） to（200）. The coefficient of the composite coatings decreases from 0.68 to 0.18 with increasing content of attapulgite in the bath, a mixed mode of adhesive-abrasive wear occurs for all coatings, and the wear mechanism shows a transition from adhesive-abrasive to predominantly abrasive wear mechanism when the concentration of attapulgite is beyond 1.5 g/L in electrolyte. The oxidation resistance of composite coatings is the best prepared when adding attapulgite particles at 0.5 g/L in the bath, the oxide mainly consists of a NiO phase by X-ray analysis.

Microstructure and Tribological Behavior of a TiO_2/hBN Composite Ceramic Coating Formed via Micro-arc Oxidation of Ti–6Al–4V Alloy

A composite coating containing hexagonal boron nitride（hBN） particles and titanium oxide（TiO_2） was formed on the surface of Ti-6Al-4V alloy via micro-arc oxidation（MAO）. The effect of quantity of the hBN-particles added into electrolyte on microstructure, composition, and wear behavior of the resulting composite coatings was investigated. Microstructure, phase composition, and tribological behavior of the resulting MAO coatings were evaluated via scanning electron microscopy, X-ray diffraction, and ball-on-disc abrasive tests. The results reveal that the TiO_2/hBN composite coating consisting of rutile TiO_2, anatase TiO_2, and an hBN phase was less porous than particle-free coating. Furthermore, the presence of hBN particles in the MAO coating produced an improved anti-friction property. The composite coating produced in the electrolyte containing 2 g/L of hBN particles exhibited the best wear resistance.The outer loose layer of the MAO coatings was removed by a mechanical polishing process, which led to a significant improvement in the wear resistance and anti-friction properties of the MAO coatings and highlighted an essential lubricating role of hBN particles in the composite coatings. However, wear mechanism of the MAO coatings was not relevant to the presence of hBN particles, where fatigue wear dominated the anti-fraction properties of the MAO coatings with and without hBN particles.

Effect of Surface Mechanical Attrition Treatment on Tribological Behavior of the AZ31 Alloy

By surface mechanical attrition treatment（SMAT）,a gradient nano structure（GNS） from the surface to center was generated in the AZ31 alloy sheet.The tribological behavior of AZ31 alloy with GNS was systematically investigated by using dry sliding tests,a 3D surface profile-meter and a scanning electron microscope equipped with an energy-dispersive spectrometer.The experimental results indicate that the Mg alloy with GNS exhibits better wear resistance comparing to the as-received sample,which is associated to the alteration of wear mechanism at different sliding speeds.The Mg alloy with GNS presents the wear mechanism of the abrasive wear at 0.05 m/s and the oxidative wear at 0.5 m/s,respectively.Moreover,the GNS can effectively promote the reaction between the oxygen and worn surface,which leads to a compact oxidation layer at 0.5 m/s.The effect of oxidation layer on the wear resistance of the Mg alloy was also discussed.