Microstructure and Properties of AlCoCrFeNiTi High-Entropy Alloy Coatings Prepared by Laser Cladding

21-4N(5Cr21Mn9Ni4N)is extensively employed in the production of engine valves,operating under severe conditions.Apart from withstanding high-temperature gas corrosion,it must also endure the impact of cylinder explosion pressure.The predominant failure mode of 21-4N valves is abrasive wear.Surface coatings serve as an effective approach to prevent such failures.In this investigation,Laser cladding technology was utilized to fabricate AlCoCrFeNiTi high entropy alloy coatings onto the surfaces of 21-4N valves.According to the findings,the cladding zone has a normal dendritic microstructure,a good substrate-to-cladding layer interaction,and no obvious flaws.In terms of hardness,the cladding demonstrates an average hardness of 620 HV.The hardness has increased by 140%compared to the substrate.The average hardness of the cladding remains at approximately 520 HV even at elevated temperatures.Regarding frictional wear performance,between 400℃and 800℃,the cladding layer exhibits an average friction coefficient of 0.4,with the primary wear mechanisms being abrasive wear,adhesive wear,and a minor degree of plastic deformation.

Preparation of Laser Cladding Coating Undercooling Cu-based Alloy and Co on Non-equilibrium Solidification Structure

The effect of the gradient content of Co element on the solidification process of Cu-based alloy under deep under cooling conditions was explored.The non-equilibrium solidification structure of the under cooled alloy samples were analyzed.It is found that the rapidly solidified alloy has undergone twice grain refinement during the undercooling process.Characterization and significance of the maximum undercooling refinement structure of Cu60Ni35Co5 at T=253 K were analyzed.High-density defects were observed,such as dislocations,stacking faults networks,and twinning structures.The standard FCC diffraction pattern represents that it is still a single-phase structure.Based on the metallographic diagram,EBSD and TEM data analysis,it is illustrated that the occurrence of grain refinement under high undercooling is due to stress induced recrystallization.In addition,the laser cladding technology is used to coat Co-based alloy(Stellite12) coating on 304 stainless steel substrate;the microstructure of the coating cross-section was analyzed.It was found that the microstructure of the cross-section is presented as columnar crystals,planar crystals,and disordered growth direction,so that the coating has better hardness and wear resistance.By electrochemical corrosion of the substrate and coating,it can be seen that the Co and Cr elements present in the coating are more likely to form a dense passivation film,which improved the corrosion resistance of the coating.

Ultra wear resistant TiC-Fe coating prepared by high efficient and economic plasma cladding method

The key components of engineering machinery frequently failed due to working in the high load and high wear operating envir-onment.And the performance of the Fe-based alloy coatings typically employed need to be improved for fulfilling the service requirements.Herein,a TiC strengthened Fe-based alloy cladding layer,named TiC-Fe coating,was designed and prepared by plasma cladding technology.The frictional wear performance of coating under various loads was tested.The wear morphology of the coating was observed,and its wear mechanism was examined.The results indicated that the TiC-Fe coating was well formed and metallurgically bonded to the Q345C substrate.Its microstructure mainly consisted of Fe-Cr solid solution,α-Fe phase,(Fe,Cr)_(7)C_(3) phase and TiC phase.The coating exhibited an average microhardness of 980 HV0.2,which was about 5.4 times that of the Q345C substrate.The wear mass loss of the TiC-Fe coatings was much smaller than that of the Q345C substrate,which indicated that the wear resistance of the Q345C coating was superior to the substrate,and the wear mechanism of the coating was mainly attributed to the abrasive wear.

Process Parameters Optimization of Laser Cladding for HT200 with 316L Coating Based on Response Surface Method

In order to improve the sealing surface performance of gray cast iron gas gate valves and achieve precise molding control of the cladding layer,as well as to reveal the influence of laser cladding process parameters on the morphology and structure of the cladding layer,we prepared the 316L coating on HT 200 by using Design-Expert software central composite design(CCD)based on response surface analysis.We built a regression prediction model and analyzed the ANOVA with the inspection results.With a target cladding layer width of 3.5 mm and height of 1.3 mm,the process parameters were optimized to obtain the best combination of process parameters.The microstructure,phases,and hardness variations of the cladding layer from experiments with optimal parameters were analyzed by the metallographic microscope,confocal microscope,and microhardness instrument.The experimental results indicate that laser power has a significant impact on the cladding layer width,followed by powder feed rate;scan speed has a significant impact on the cladding layer height,followed by powder feed rate.The HT200 substrate and 316L can metallurgically bond well,and the cladding layer structure consists of dendritic crystals,columnar crystals,and equiaxed crystals in sequence.The optimal process parameter combination satisfying the morphology requirements is laser power(A)of 1993 W,scan speed(B)of 8.949 mm/s,powder feed rate(C)of 1.408 r/min,with a maximum hardness of 1564.3 HV0.5,significantly higher than the hardness of the HT200 substrate.

Evaluation of Textured Concrete as an Alternative for Stone as a Cladding Material

Along with the increasing demand on exterior wall cladding as a protective cover for the interior elements and an indicator for modernity and architectural innovation,comes the need to develop new cladding materials that can replace the old ones and overcome their setbacks.This paper discusses the possibility of replacing stone by textured concrete as a cladding material in order to overcome the main challenges faced stone cladding by comparing them together.The comparison was made based on the main requirements of the cladding materials namely:economic,environmental,social,functional and structural aspects.

Effect of Reduction on Bonding Interface of Hot-rolled Wear-resistant Steel BTW1/Q345R Cladding Plate

Wear-resistant cladding plates consisting of a substrate（Q345 R） and a clad layer（BTW1） were bonded through hot rolling at the temperature of 1 200 ℃ and a rolling speed of 0.5 m/s. The microhardness of the cladding plate was also tested after being heat treated. The microstructure evolution on the interface of BTW1/Q345 R sheets under various reduction rates was investigated with a scanning electron microscope（SEM） and EBSD. It is found that the micro-cracks and oxide films on the interface disappear when the reduction is 80%, whereas the maximum uniform diffusion distance reaches 10 μm. As a result, a wide range of metallurgical bonding layers forms, which indicates an improved combination between the BTW1 and the Q345 R. Additionally, it is discovered that the unbroken oxide films on the interface are composed of Mn, Si or Cr at the reductions of 50% and 65%. The SEM fractography of tensile specimen demonstrates that the BTW1 has significant dimple characteristics and possesses lower-sized dimples with the increment in reduction, suggesting that the toughness and bonding strength of the cladding plates would be improved by the increase of reduction. The results reveal that a high rolling reduction causes the interfacial oxide film broken and further forms a higher-sized composite metallurgical bonding interface. The peak microhardness is achieved near the interface.

Effect of heat treatment on microstructure and mechanical properties of Ti-containing low alloy martensitic wear-resistant steel

Effects of quenching temperature and cooling conditions(water cooling and 10%NaCl cooling)on microstructure and mechanical properties of a 0.2%Ti low alloy martensitic wear-resistant steel used for die casting ejector plate were investigated.The results show that lath martensite can be obtained after austenitizing in the range of 860-980℃and then water cooling.With an increase in austenitizing temperature,the precipitate content gradually decreases.The precipitates are mainly composed of TiC and Ti4C2S2,and their total content is between 1.15wt.%and 1.64wt.%.The precipitate phase concentration by water-cooling is higher than that by10%NaCl cooling due to the lower cooling rate of water cooling.As the austeniting temperature increases,the hardness and tensile strength of both water cooled and 10%NaCl cooled steels firstly increase and then decrease.The experimental steel exhibits the best comprehensive mechanical properties after being austenitized at 900℃,cooled by 10%NaCl,and then tempered at 200℃.Its hardness,ultimate tensile strength,and wear rate reach551.4 HBW,1,438.2 MPa,and 0.48×10^(-2)mg·m^(-1),respectively.

Fretting Wear Characteristics of Nuclear Fuel Cladding in High-Temperature Pressurized Water

In pressurized water reactor(PWR),fretting wear is one of the main causes of fuel assembly failure.Moreover,the operation condition of cladding is complex and harsh.A unique fretting damage test equipment was developed and tested to simulate the fretting damage evolution process of cladding in the PWR environment.It can simulate the fretting wear experiment of PWR under different temperatures(maximum temperature is 350℃),displacement amplitude,vibration frequency,and normal force.The fretting wear behavior of Zr-4 alloy under different temperature environments was tested.In addition,the evolution of wear scar morphology,profile,and wear volume was studied using an optical microscope(OM),scanning electron microscopy(SEM),and a 3D white light interferometer.Results show that higher water temperature evidently decreased the cladding wear volume,the wear mechanism of Zr-4 cladding changed from abrasive wear to adhesive wear and the formation of an oxide layer on the wear scar reduced the wear volume and maximum wear depth.

Effects of process parameters and annealing on microstructure and properties of CoCrFeMnNi high-entropy alloy coating prepared by plasma cladding

Plasma cladding was used to prepare a CoCrFeMnNi high-entropy alloy(HEA)coating under different conditions.The process parameters were optimized using an orthogonal experiment design based on surface morphology quality characteristics,dilution rate,and hardness.The optimal process parameters were determined through range and variance analysis to be a cladding current of 70 A,a cladding speed of 7 cm·min^(-1),and a powder gas flow rate of 8 L·s^(-1).During the optimized experiments,both the cladded and annealed CoCrFeMnNi HEA coatings exhibit some pores,micro-voids,and a small amount of aggregation.However,the aggregation in the annealed coating is more dispersed than that in the cladded coating.The cladded CoCrFeMnNi HEA coating consists of simple FCC phases,while a new Cr-rich phase precipitates from the FCC matrix after annealing the coating at a temperature range of 550°C-950°C.After annealing at 850°C,the proportion of the FCC phase decreases compared to the cladded coating,and the number of large-angle grain boundaries is significantly reduced.However,the proportion of grains with sizes below 50μm increases from 61.7%to 74.3%.The micro-hardness and wear resistance of the cladded coating initially increases but then decreases with an increase in annealing temperature,indicating that appropriate annealing can significantly improve the mechanical properties of the CoCrFeMnNi HEA coatings by plasma cladding.The micro-hardness of the CoCrFeMnNi HEA coatings after annealing at 650°C increases to 274.82 HV_(0.2),while the friction coefficient decreases to below 0.595.

Transient fuel performance analysis of UO_(2)–BeO fuel with composite SiC coated with Cr cladding based on multiphysics method

The transient multiphysics models were updated in CAMPUS to evaluate the accident-tolerant fuel performance under accident conditions.CAMPUS is a fuel performance code developed based on COMSOL.The simulated results of the UO_(2)–Zircaloy fuel performance under accident conditions were compared with those of the FRAPTRAN code and the experimental data to verify the correctness of the updated CAMPUS.Subsequently,multiphysics models of the UO_(2)–BeO fuel and composite SiC coated with Cr(SiC_(f)/SiC-Cr)cladding were implemented in CAMPUS.Finally,the fuel performance of the three types of fuel cladding systems under Loss of Coolant Accident(LOCA)and Reactivity Insertion Accident(RIA)conditions was evaluated and compared,including the temperature distribution,stress distribution,pressure evolution,and cladding failure time.The results showed that the fuel temperature of the UO_(2) fuel under accident conditions without pre-irradiation was lower after being combined with SiC_(f)/SiC-Cr cladding.Moreover,the centerline and outer surface temperatures of the UO_(2)–BeO fuel combined with SiC_(f)/SiC-Cr cladding reduced further under accident conditions.The cladding temperature increased after the combination with the SiC_(f)/SiC-Cr cladding under accident conditions with pre-irradiation.In addition,the use of SiC_(f)/SiC-Cr cladding significantly reduced the cladding hoop strain and plenum pressure.

Fiber cladding dual channel surface plasmon resonance sensor based on S-type fiber

Fiber cladding surface plasmon resonance(SPR)sensors have few structures,and a clad SPR sensor based on S-type fiber is proposed in this paper.This new type of fiber cladding SPR sensor was formed by electrofusing an S-shaped structure on the fiber to couple the light in the fiber core to the cladding.In this paper,the effects of fiber parameters on the performance of the sensor were studied by simulation and experiment.Based on the conclusion that the smaller the core diameter is,the closer the working band of the SPR resonance is to long wavelengths,and that the geometric characteristics mean that a multimode fiber can receive the fiber cladding light from a small core diameter few-mode fiber,a dual channel SPR sensor with a double S-type fiber cascade was proposed.In the refractive index detection range of 1.333–1.385refractive index units(RIU),the resonant working band of channel I is 627.66 nm–759.78 nm,with an average sensitivity of 2540.77 nm/RIU,and the resonant working band of channel II is 518.24 nm–658.2 nm,with an average sensitivity of2691.54 nm/RIU.The processing method for the S-type fiber cladding SPR sensor is simple,effectively solving the problem of this type of SPR sensor structure and the difficult realization of a dual channel.The sensor is expected to be used in the fields of medical treatment and biological analysis.

A cladding-pumping based power-scaled noise-like and dissipative soliton pulse fiber laser

We report a high-average-power noise-like pulse(NLP) and dissipative soliton(DS) pulse fiber laser. Average power as high as 4.8 W could be obtained at the fundamental mode-locked repetition rate. The NLP can also be transformed into a more powerful DS mode-locking state by optimizing the polarization and losses of intra-cavity pulses in the nonlinear polarization evolution regime. The operation mode between the NLP and DS can be switched, and the laser output performance in both modes has been studied. The main advantage of this work is switchable high-power operation between the NLP and DS. In comparison with conventional single-mode NLP fiber lasers, the multi-function high-power optical source will greatly push its application in supercontinuum generation, coherence tomography, and industrial processing.

Numerical simulation of a truncated cladding negative curvature fiber sensor based on the surface plasmon resonance effect

A refractive index(RI)sensor based on the surface plasmon resonance effect is proposed using a truncated cladding negative curvature fiber(TC-NCF).The influences of the TC-NCF structure parameters on the sensing performances are investigated and compared with the traditional NCF.The simulation results show that the proposed TC-NCF RI sensor has an ultra-wide detection range from 1.16 to 1.43.The maximum wavelength sensitivity reaches 12400 nm/RIU,and the corresponding R^(2)of the polynomial fitting equation is 0.9999.The maximum and minimum resolutions are 2.56×10^(-5)and 8.06×10^(-6),respectively.In addition,the maximum amplitude sensitivity can reach-379.1 RIU^(-1)when the RI is chosen as 1.43.The proposed TC-NCF RI sensor could be useful in biochemical medicine,environmental monitoring,and food safety.

Microstructure and tribological properties of laser cladding Fe-based coating on pure Ti substrate

Fe-based coating was produced on pure Ti substrate by the laser cladding technology. The composition and microstructure of the fabricated coating were analyzed by scanning electron microscopy （SEM）, X-ray diffraction （XRD） and transmission electron microscopy （TEM） technique. The tribological properties were tested through sliding against AISI52100 steel ball at different normal loads and sliding speeds. Besides, the morphologies of the worn surfaces and wear debris were analyzed by scanning electron microscopy （SEM） and three dimensional （3D） non-contact surface mapping. The results show that the prepared Fe-based coating has a high hardness of about 860 HV0.2 and exhibits an average wear rate of （0.70-2.32）×10-6 mm3/（N-m）, showing that the Fe-based coating can greatly improve the wear resistance of pure Ti substrate. The wear mechanism of the coating involves moderate adhesive and abrasive wear.

Microstructure and high temperature tribological behavior of laser cladding Ni60A alloys coatings on 45 steel substrate

The crack-free Ni60 A coating was fabricated on 45 steel substrate by laser cladding and the microstructure including solidification characteristics, phases constitution and phase distribution was systematically investigated. The high temperature friction and wear behavior of the cladding coating and substrate sliding against GCr15 ball under different loads was systematically evaluated. It was found that the coating has homogenous and fine microstructure consisting of γ（Ni） solid solution, a considerable amount of network Ni-Ni3 B eutectics, m^23C6 with the floret-shape structure and Cr B with the dark spot-shape structure uniformly distributing in interdendritic eutectics. The microhardness of the coating is about 2.6 times as much as that of the substrate. The coating produces higher friction values than the substrate under the same load condition, but the friction process on the coating keeps relatively stable. Wear rates of the coating are about 1/6.2 of that of the substrate under the higher load（300 g）. Wear mechanism of the substrate includes adhesion wear, abrasive wear, severe plastic deformation and oxidation wear, while that of the coating is merely a combination of mild abrasive wear and moderate oxidation wear.

Synthesis of Y_2O_3 particle enhanced Ni/TiC composite on TC4 Ti alloy by laser cladding

A Y2O3 particle enhanced Ni/TiC composite coating was fabricated in-situ on a TC4 Ti alloy by laser surface cladding. The phase component, microstructure, composition distribution and properties of the composite layer were investigated. The composite layer has graded microstructures and compositions, due to the fast melting followed by rapid solidification and cooling during laser cladding. The TiC powders are completely dissolved into the melted layer during melting and segregated as fine dendrites when solidified. The size of TiC dendrites decreases with increasing depth. Y2O3 fine particles distribute in the whole clad layer. The Y2O3 particle enhanced Ni/TiC composite layer has a quite uniform hardness along depth with a maximum value of HV1380, which is 4 times higher than the initial hardness. The wear resistance of the Ti alloy is significantly improved after laser cladding due to the high hardness of the composite coating.

Microstructure and properties at bonding interface of AA4045/AA3003 aluminum alloy cladding billet prepared by semi-continuous casting

AA4045/AA3003 cladding billet was prepared by direct chill semi-continuous casting process. The macrostructures, microstructures, temperature distribution, compositions distribution and the mechanical properties at the bonding interface were investigated in detail. The results show that the cladding billet with few defects could be obtained by semi-continuous casting process. At the interface, diffusion layer of about 10μm on average formed between the two alloys due to the diffusion of alloy elements in the temperature range from 596 to 632 °C. From the side of AA4045 to the side of AA3003, the Si content has a trend to decrease, while the Mn content has a trend to increase gradually. Tensile strength of the cladding billet reaches 103.7 MPa, the fractured position is located on the AA3003 side, and the shearing strength is 91.1 MPa, revealing that the two alloys were combined metallurgically by mutual diffusion of alloy elements.

Interface characteristics of Al_2O_3－13%TiO_2 ceramic coatings prepared by laser cladding

Al2O3-13%TiO2 （mass fraction） coatings, prepared by laser cladding on nickel-based alloy, were heated using high frequency induction sources. The coating microstructure and the interface between bond coating and ceramic coating were characterized by SEM, XRD and EDS. The results show that two-layer substructure exists in the ceramic coating： one layer evolving from fully melted region where the sintered grains grow fully; another layer resembling the liquid-phase-sintered structure consisting of three-dimensional net where the melted Al2O3 particles are embedded in the TiO2-rich matrix. The mechanism of the two-layer substructure formation is also explained in terms of the melting and flattening behavior of the powders during laser cladding processing. The spinel compounds NiAl2O4 and acicular compounds Cr2O3 are discovered in the interface between bond coating and ceramic coating. It proves that the chemical reactions in the laser cladding process will significantly enhance the coating adhesion.

Corrosion behavior of Hastelloy C22 coating produced by laser cladding in static and cavitation acid solution

The Hastelloy C22 coatings on Q235 steel substrate were produced by high power diode laser cladding technique. Their corrosion behaviors in static and cavitation hydrochloric, sulfuric and nitric acid solutions were investigated. The electrochemical results show that corrosion resistance of coatings in static acid solutions is higher than that in cavitation ones. In each case, coating corrosion resistance in descending order is in nitric, sulfuric and hydrochloric acid solutions. Obvious erosion-corrosion morphology and serious intercrystalline corrosion of coating are noticed in cavitation hydrochloric acid solution. This is mainly ascribed to the aggressive ions in hydrochloric acid solution and mechanical effect from cavitation bubbles collapse. While coating after corrosion test in cavitation nitric acid solution shows nearly unchanged surface morphology. The results indicate that the associated action of cavitation and property of acid solution determines the corrosion development of coating. Hastelloy C22 coating exhibits better corrosion resistance in oxidizing acid solution for the stable formation of dense oxide film on the surface.

Segregation of niobium in laser cladding Inconel 718 superalloy

Inconel 718 superalloy is widely used in the aerospace and turbine industry. Segregation of niobium appears in the laser cladding Inconel 718 superalloy and consequently influences the phase transformation during the rapid solidification. In order to control the microstructure and improve the mechanical properties of the deposited coating, the the influence of solidification conditions on the segregation of niobium and the resultant formation of Nb-rich Laves phase was studied using the microstructure observation and EDS analysis. The results show that the cooling rate has considerable influence on the microstructure of the deposited coating. High cooling rate is beneficial for suppressing the segregation of Nb and reducing the formation of Laves phase, which is believed to be detrimental to the performance of the Inconel 718 alloy.