Laboratory Investigation of Disintegration Characteristics of Purple Mudstone under Different Hydrothermal Conditions

Disintegration of rock is one of the primary processes of soil formation and geomorphology and is affected considerably by water and heat.This study focused on the disintegration characteristics under laboratory conditions of typical purple mudstone from the Tuodian group of Jurassic red beds(J3t) in Tuodian Town,Shuangbai county,Yunnan Province of southern China.The fresh mudstone was subjected to alternating applications of water,heat and hydrothermal interaction during five treatments:wetting-drying(WD),saturation(ST),refrigeration-heating(RH),a combination of wetting-drying and refrigeration-heating(WDRH),and a combination of saturation and refrigeration-heating(STRH).Each treatment was run in twenty-four cycles.The results showed that there are three types of disintegration:collapsing disintegration,exfoliation disintegration and imperceptible disintegration.The cumulative disintegration rate(percentage of cumulative disintegrated mass to the initiative sample mass passed through a 2 mm sieve) produced a 'S'-shape function when related to treatment cycle time and closely fit a logistic model(R2 > 0.99).The rank order of the cumulative disintegration rate resulting from the five treatments was as the following:WDRH > STRH > ST > WD > RH.Because of alternating periods of moisture and dryness,WD caused the most disintegration,while RH alone resulted in imperceptible disintegration.Additionally,there was a negative correlation between the disintegration rate of each treatment cycle(percentage of disintegrated mass to the treated sample mass) and treatment cycle number.There was a positive correlation between this rate and temperature change under moist conditions,indicating that a change in temperature greatly accelerates the disintegration of parent rock when water was supplied.

Weathering geochemistry and palaeoclimate implication of the Early Permian mudstones from eastern Henan Province, North China

Terrigenous clastic sediments are generated by the integration of the Earth surface processes and their deep-time counterparts provide a valuable archive for regional/global climatic, geographic and landscape evolution. It is thus important to read and interpret these deep-time sedimentary records, especially for reconstructing continent climate. Previous studies on the Early Permian sequences from the North China document a dominant control of source chemical weathering on mudstone compositions and its linkage with continent climate conditions. Based on the weathering geochemical data of these mudstones, element mobility during weathering can be ordered as Ca 〉 Na ≥ Mg 〉 Sr 〉 K ≥ Ba 〉 Rb. The weathering regime in the source area is inferred to be supply-limited according to the estimated continent physical erosion rate and regional tectonic evolution, sedimentation in North China. Further exploration of palaeoclimate implication is presented in terms of variation of high-to-low latitudinal temperature gradient across the Early Permian glacial to post-glacial climate transition.