Overlapped peaks resolution for linear sweep polarography using Gaussian-like distribution

A resolution method based on Gaussian-like distribution for overlapped linear sweep polarographic peaks was proposed to simultaneously detect the polymetallic components, such as Zn（Ⅱ） and Co（Ⅱ）, coexisting in the leaching solution of zinc hydrometallurgy. A Gaussian-like distribution was constructed as the sub-model of overlapped peaks by analyzing the characteristics of linear sweep polarographic curve. Then, the abscissas of each peak and trough were pinpointed through multi-resolution wavelet decomposition, the curve and its derivative curves were fitted by using nonlinear weighted least squares （NWLS）. Finally, overlapped peaks were resolved into independent sub-peaks based on fitted reconstruction parameters. The experimental results show that the relative error of half-wave potential pinpointed by multi-resolution wavelet decomposition is less than 1% and the accuracy of Ip fitted by NWLS is higher than 96%. The proposed resolution method is effective for overlapped linear sweep polarographic peaks of Zn（Ⅱ） and Co（Ⅱ）.

An iterative algorithm of NWTLS-EC for three dimensional-datum transformation with large rotation angle

The Gauss-Markov （GM） model and the Errors-in-Variables （EIV） model are frequently used to perform 3D coordinate transformations in geodesy and engineering surveys. In these applications, because the observation errors in original coordinates system are also taken into account, the latter is more accurate and reasonable than the former. Although the Weighted Total Least Squares （WTLS） technique has been intro- duced into coordinate transformations as the measured points are heteroscedastic and correlated, the Variance- Covariance Matrix （VCM） of observations is restricted by a particular structure, namely, only the correlations of each points are taken into account. Because the 3D datum transformation with large rotation angle is a non- linear problem, the WTLS is no longer suitable in this ease. In this contribution, we suggested the nonlinear WTLS adjustments with equality constraints （NWTLS-EC） for 3D datum transformation with large rotation an- gle, which removed the particular structure restriction on the VCM. The Least Squares adjustment with Equality （LSE） constraints is employed to solve NWTLS-EC as the nonlinear model has been linearized, and an iterative algorithm is proposed with the LSE solution. A simulation study of 3D datum transformation with large rotation angle is given to insight into the feasibility of our algorithm at last.