In this study,FTIR and XPS spectroscopy,specific surface area and pore size analyses,wetting and other experimental means have been applied to investigate respirable coal dust surface properties and wetting mechanism....In this study,FTIR and XPS spectroscopy,specific surface area and pore size analyses,wetting and other experimental means have been applied to investigate respirable coal dust surface properties and wetting mechanism.The research shows that coal dust surface structures,chemical and element compositions are changed in the refining process of coal dust.Compared with large particle coal dust,respirable coal dust is a weak hydrophilic and strong hydrophobic substance.The reason:the smaller the particle size of coal dust,the more unsaturated its surface.The absorption of air is strong and it is easy to form an air film on coal dust surfaces. Coal dust contact with water is actually a compound contact of liquid in contact with a solid and gas in contact with a solid. The smaller the particle size,the larger the pore volume and the higher the degree of surface roughness,the larger the area of gas in contact with a solid and the worse the coal dust wettability.Another reason is that the changes in the composition of atoms on the dust surface and structures affect coal dust wettability.The results of this study establish a theoretical basis for the invention of effective reduced-dust technology.展开更多
16 samples of Chinese coal were tested for their flotation and hydropbilic properties. The two physico-chemical parameters, wetting heat and contact angle were compared as they were used in evaluating the flotability ...16 samples of Chinese coal were tested for their flotation and hydropbilic properties. The two physico-chemical parameters, wetting heat and contact angle were compared as they were used in evaluating the flotability of coal. The result shows that the wetting heat is in good accordance with flotability and is better than contact angle in reflecting the flotability. A new idea of classifying the flotability using wetting heat is put forward.展开更多
Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types...Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types of regional municipal sludge(sludge) in an orthogonal experiment. The sludge type,sludge mixing proportion, dosage of dispersant, and grinding time were tested in this study. The results show that water content and its occurrence characteristics in the sludge have primary hindering influences on slurry ability. The range of fixed-viscosity concentrations with raw wet sludge is from 50.78%to 44.40%(by weight), while the range is from 53.35% to 51.51%(by weight) with dry sludge. All of the CSSs exhibit shear-thinning behaviors with different variation trends, especially the CSSs with more than 15%(by weight) raw wet sludge in it. Adding the same proportion of raw wet sludge increases the thixotropic properties of CSSs and the highest area of thixotropy loop is 3065 Pa/s, while the highest value of dry sludge is 1798 Pa/s. Hydrophilic group plays an important role in adsorbing water and building three-dimension networks with other particles, which is the main reason for CSS properties.Therefore, the mechanism can be used to find the way for making high quality CSS.展开更多
The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to...The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to repeated freezing-thawing and wetting-drying, which determines the possibility of changing their grain-size composition and structure. Experimental studies in laboratory conditions on the influence of cyclic freezing-thawing (FTC) and wetting-drying (WDC) on the quality indicators of lignites have been carried out, their granulometric (fractional) composition has been studied. Freezing-thawing cycle conditions are as follows (FTC): minimum exposure temperature: -20°C;maximum: +5°C;relative humidity: 30%;number of processing cycles: 3. Wetting-drying cycles are as follows (WDC): drying temperatures are +20, +40, +60, +80°C, drying time 90 minutes, the coals are further subjected to rain (soaking) for a period of water saturation to humidity of 30% - 40% and dry again. The number of wetting-drying cycles is 3 times. The tests have revealed the destructive effects of FTC and WDC on the samples of lower metamorphic grade coal, and the cycles of wet-dry lead to the much higher yield of fine sizes (-6+0;-13+0 mm) than the cycles of freeze-thaw. Furthermore, it is found that the increase in the yield of fines depends on the heating temperature: coal disintegration proceeds more intensively at a higher temperature of drying.展开更多
The wetting heat and contact angle of sixteen coal samples were determined and the slurry-forming ability of coal were researched. Comparing the relationship of the wetting heat and contact angle with the slurry-formi...The wetting heat and contact angle of sixteen coal samples were determined and the slurry-forming ability of coal were researched. Comparing the relationship of the wetting heat and contact angle with the slurry-forming ability or coal, the auther has found out that the slurry-forming ability of coal can be measured by the wetting heat.展开更多
By using the fault tree analysis in reliability theory as the systematical analysis approach, the dust suppression mechanism in a spray system with wetting agent is shown in a logic tree and some graphical models. Fro...By using the fault tree analysis in reliability theory as the systematical analysis approach, the dust suppression mechanism in a spray system with wetting agent is shown in a logic tree and some graphical models. From these diagrams, all factors related to the spray system and their cause and effect relationship can be seen clearly. Based on the built logic tree, several mathematical models and new ideas for expressing the dust suppressing efficiency in the spray system are put forward. The significance of all factors related to the efficiency of suppressing dust is qualitatively described. Furthermore, the new concepts, such as, the effective reaction time between dust particle and droplet, the expansion phenomenon of laden dust droplet, the functions of volatile and the relative size distribution efficiency of wetting agent are presented. All this richenes the existing mechanism of dust abatement by spraying wetting agent. At last, several problems that need to be further investigated are also suggested in the paper.展开更多
Focusing on the phenomenon of gypsum rain while wet desulphurization(WFGD) were adopted in coal fired power plant without GGH, the paper studied and put forward the solutions : (1) desulfurization facilities related e...Focusing on the phenomenon of gypsum rain while wet desulphurization(WFGD) were adopted in coal fired power plant without GGH, the paper studied and put forward the solutions : (1) desulfurization facilities related equipment modification;(2) optimal operation of existing desulfurization facilities.展开更多
基金Financial support for this work,provided by the Science and Technology Project of the Education Department of Shandong Province(No.J08LC12),
文摘In this study,FTIR and XPS spectroscopy,specific surface area and pore size analyses,wetting and other experimental means have been applied to investigate respirable coal dust surface properties and wetting mechanism.The research shows that coal dust surface structures,chemical and element compositions are changed in the refining process of coal dust.Compared with large particle coal dust,respirable coal dust is a weak hydrophilic and strong hydrophobic substance.The reason:the smaller the particle size of coal dust,the more unsaturated its surface.The absorption of air is strong and it is easy to form an air film on coal dust surfaces. Coal dust contact with water is actually a compound contact of liquid in contact with a solid and gas in contact with a solid. The smaller the particle size,the larger the pore volume and the higher the degree of surface roughness,the larger the area of gas in contact with a solid and the worse the coal dust wettability.Another reason is that the changes in the composition of atoms on the dust surface and structures affect coal dust wettability.The results of this study establish a theoretical basis for the invention of effective reduced-dust technology.
文摘16 samples of Chinese coal were tested for their flotation and hydropbilic properties. The two physico-chemical parameters, wetting heat and contact angle were compared as they were used in evaluating the flotability of coal. The result shows that the wetting heat is in good accordance with flotability and is better than contact angle in reflecting the flotability. A new idea of classifying the flotability using wetting heat is put forward.
基金supported by the National Natural Science Foundation of China (Nos. 51204179, 51204182)the Natural Science Foundation of Jiangsu Province of China (No. BK20141242)the Fundamental Research Funds for the Central Universities of China (No. 2014XT05)
文摘Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types of regional municipal sludge(sludge) in an orthogonal experiment. The sludge type,sludge mixing proportion, dosage of dispersant, and grinding time were tested in this study. The results show that water content and its occurrence characteristics in the sludge have primary hindering influences on slurry ability. The range of fixed-viscosity concentrations with raw wet sludge is from 50.78%to 44.40%(by weight), while the range is from 53.35% to 51.51%(by weight) with dry sludge. All of the CSSs exhibit shear-thinning behaviors with different variation trends, especially the CSSs with more than 15%(by weight) raw wet sludge in it. Adding the same proportion of raw wet sludge increases the thixotropic properties of CSSs and the highest area of thixotropy loop is 3065 Pa/s, while the highest value of dry sludge is 1798 Pa/s. Hydrophilic group plays an important role in adsorbing water and building three-dimension networks with other particles, which is the main reason for CSS properties.Therefore, the mechanism can be used to find the way for making high quality CSS.
文摘The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to repeated freezing-thawing and wetting-drying, which determines the possibility of changing their grain-size composition and structure. Experimental studies in laboratory conditions on the influence of cyclic freezing-thawing (FTC) and wetting-drying (WDC) on the quality indicators of lignites have been carried out, their granulometric (fractional) composition has been studied. Freezing-thawing cycle conditions are as follows (FTC): minimum exposure temperature: -20°C;maximum: +5°C;relative humidity: 30%;number of processing cycles: 3. Wetting-drying cycles are as follows (WDC): drying temperatures are +20, +40, +60, +80°C, drying time 90 minutes, the coals are further subjected to rain (soaking) for a period of water saturation to humidity of 30% - 40% and dry again. The number of wetting-drying cycles is 3 times. The tests have revealed the destructive effects of FTC and WDC on the samples of lower metamorphic grade coal, and the cycles of wet-dry lead to the much higher yield of fine sizes (-6+0;-13+0 mm) than the cycles of freeze-thaw. Furthermore, it is found that the increase in the yield of fines depends on the heating temperature: coal disintegration proceeds more intensively at a higher temperature of drying.
文摘The wetting heat and contact angle of sixteen coal samples were determined and the slurry-forming ability of coal were researched. Comparing the relationship of the wetting heat and contact angle with the slurry-forming ability or coal, the auther has found out that the slurry-forming ability of coal can be measured by the wetting heat.
文摘By using the fault tree analysis in reliability theory as the systematical analysis approach, the dust suppression mechanism in a spray system with wetting agent is shown in a logic tree and some graphical models. From these diagrams, all factors related to the spray system and their cause and effect relationship can be seen clearly. Based on the built logic tree, several mathematical models and new ideas for expressing the dust suppressing efficiency in the spray system are put forward. The significance of all factors related to the efficiency of suppressing dust is qualitatively described. Furthermore, the new concepts, such as, the effective reaction time between dust particle and droplet, the expansion phenomenon of laden dust droplet, the functions of volatile and the relative size distribution efficiency of wetting agent are presented. All this richenes the existing mechanism of dust abatement by spraying wetting agent. At last, several problems that need to be further investigated are also suggested in the paper.
文摘Focusing on the phenomenon of gypsum rain while wet desulphurization(WFGD) were adopted in coal fired power plant without GGH, the paper studied and put forward the solutions : (1) desulfurization facilities related equipment modification;(2) optimal operation of existing desulfurization facilities.
