Study on Industrial Application of Hydrogen Sulfide Removal by Wet Oxidation Method with High Gravity Technology

The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a rotating packed bed was investigated in a scale for treating 10 000 Nm3/h of gas. On the basis of studying the influence of the species and con- centration of alkali source, the liquid/gas volume ratio, the high gravity factor, and the hydrogen sulfide content in feed gas on the desulfurization effect, the suitable technological conditions were obtained. The hydrogen sulfide removal efficiency could reach 98.0% under these conditions. The results of continuous operation of process facilities showed that the high gravity method has many merits including higher desulfurization rate, good stability in operation, lower liquid/gas volume ratio, greater operation elasticity, and apparent energy saving effects.

Simulation of Wetting and Drying Processes in A Depth Integrated Shallow Water Flow Model by Slot Method

A particular porosity method named ＂slot method＂ is implemented in a depth-integrated shallow water flow model （DIVAST） to simulate wetting and drying processes. Discussed is the relationship between the shape factors of the ＂slot＂ and the preset depth used in ＂wetting-drying＂ algorithm. Two typical tests are conducted to examine the performance of the method with the effect of the shape factors of the ＂slot＂ being checked in detail in the first test. Numerical results demonstrate that： 1 ） no additional effort to improve the finite difference scheme is needed to implement ＂slot method＂ in DIVAST, and 2） ＂slot method＂ will simulate wetting and diying processes correctly if the shape factors of the ＂slot＂ being selected properly.

Preparation of calcium stannate by modified wet chemical method

A modified wet chemical route for low-temperature synthesis of the calcium stannate CaSnO3, a potentialmaterial for dielectric applications is reported. Firstly, a precursor CaSn(OH)6 was prepared using tin tetrachloride,calcium chloride and sodium hydroxide at room temperature. Then the precursor was annealed at relatively low tem-perature of 600 ℃ to obtain CaSnO3. The phase identification, thermal behavior and surface morphology of the sam-ples were characterized by element analysis, X-ray diffraction (XRD), thermo-gravimetric (TG) analysis and deriva-tive thermo-gravimetric (DTG) analysis, Fourier transform infrared spectroscopy (FTIR) and scanning electron mi-croscopy (SEM) in detail. The results show that CaSnO3 obtained by this method possesses a cubic perovskitestructure with average grain size of 5 μm.

Synthesis and characteristics of large-scale ZnO rods by wet chemical method

The large-scale ZnO rods of submicrometer were prepared on the bare glass using a wet chemical method under different experimental parameters,such as the reactant concentration and the growth time.The microstructure of the ZnO rods was characterized by X-ray diffractometry(XRD) and field emission scanning electron microscopy (FESEM) with the energy dispersive X-ray spectroscopy(EDX),and the optical property was investigated by the room-temperature photoluminescence (PL) spectra.XRD and FESEM results show that the wurtzite structure and rod-like ZnO is obtained.The length (3-8 μm) and the diameter (400 nm-3 μm) vary with the experimental parameters.A strong UV emission at 384 nm and a weak visible yellow-green emission around 570 nm are observed in the PL spectrum.After annealing at 600 ℃ in air,the UV peak intensity increases obviously and the yellow-green peak intensity decreases greatly.The near-band-edge UV emission is attributed to the exciton recombination; the yellow-green emission can be associated with the defect recombination; and some defect complexes may be responsible for the latter emission.

Preparation of microsized silver crystals with different morphologies by a wet-chemical method

A wet-chemical method was presented for preparation of spherical, flowerlike, hexagonal, and triangular microsized silver crystals. Well-defined particles were prepared by mixing of iron（II） sulfate heptahydrate solution with silver nitrate solution at the presence of different modifiers with high-speed stirring at 8-20℃. It is found that the diameters of resulting products are 0.6-6.0 um and the morphologies of the silver microcrystals are greatly affected by the introduced modifiers. It is concluded that the microsized silver crystals with different morphologies can be synthesized by introducing appropriate modifiers at appropriate experimental parameters. Scanning electron microscopy and X-ray diffraction were used to characterize the resulting products.

Elimination of hard aggregation of bismuth-doped tin dioxide nanometer powders prepared by wet chemical method

Bismuth-doped tin dioxide （BTO） nanometer powders were prepared by the wet chemical method using tin tetrachloride （SnCl4）, bismuth nitrate [Bi（NO3） 3 ] and ammonia as raw materials. Non-bridge hydroxides and capillary force between particles were found to be key factors causing hard aggregation of BTO through analyzing the formation mechanism of hard aggregation. The hard aggregation of BTO was eliminated effectively when the Bi-Sn precursor （BSP） was treated with post processing including dispersing with ultrasonic wave, refluxing and distilling with addition of n-butanol and benzene （DRD） and drying by microwave. Characterized with X-ray diffraction （XRD） and transmission electron microscopy （TEM）, BTO spherical particles with tetragonal phase structure are well crystallized, dispersed easily and the average size was less than 10 nm.

Triangle Method for Estimating Soil Surface Wetness from Satellite Imagery in Allahabad District, Uttar Pradesh, India

Soil surface wetness is indispensable land surface parameter in agriculture, hydrology and environmental engineering. This paper explores the relationship between surface radiant temperature and fractional vegetation cover derived from satellite imagery to estimate soil surface wetness (triangle method) in Allahabad district. The pixel distributions create triangular shapes because the range of surface radiant temperature decreases as the amount of vegetation cover increases and sufficient number of pixels exists. A very weak correlation is found between the simulated soil surface wetness and ground measured soil moisture at deeper soil layers (R2 < 0.15) on all the dates under investigation. This is because the drying rates at the surface discontinue to be linearly correlated to that at lower levels (depths). The standing water pixels distort the shape of the triangle especially at lower left edge of the triangle. This distortion is removable. The spatial and temporal inhomogeneity of soil surface wetness is examined.

Synthesis of PZT power by wet-dry method and its structure

To prepare PZT powder at lower temperature, lead zirconate titanate (PZT) powder (x(Zr)/x(Ti)=56?44) was prepared by wet-dry method. Glycol was used as the solvent, and zirconium oxychloride was used as zirconium source. The properties and structure of the powder were analyzed by XRD, SEM and Sedimentograph. The effects of sintering parameter such as sintering temperature, keeping time and heating-up velocity on structure of PZT power were investigated. The results show that homogeneous PZT with single-phase perovskite structure can be obtained after sintering at 730 ℃ for 2 h, and the average size of PZT powder is about 113 nm.

Wet-lab教学模式提升眼科生临床教学质量的研究

目的探讨wet-lab的教学法在眼科生临床教学中的应用价值。方法选取2016年9月—2017年7月到本院眼科进行临床实习的85名医学生作为研究对象,将其分为两组,即对照组及实验组。实验组的学生采用wet-lab教学法,完成眼科学临床的教学任务,对照组的学生采取传统教学法,完成眼科学临床的教学任务。考核包括眼科临床实践考核采用随堂现场考核方法,眼科理论考核采用统一试卷考核。结果实验组总成绩、临床实践操作及理论成绩优于对照组,差异具有统计学意义(P <0.05)。结论 Wet-lab的教学模式可以明显提高学生的学习热情及积极性,提高眼科临床的教学质量。

CBL+Wet Lab教学结合云资源在眼科住院医师教学中的实践

目的探索一套符合眼科住院医师规范化培训特点并结合钉钉云课堂资源的实践模式,分析其在眼科住院医师教学中的应用及优势。方法浙江大学医学院附属第二医院眼科住培基地通过以病例为基础的教学(CBL)联合小班化模拟实验室操作实践(Wet Lab),同时利用网络云资源,探索了一套眼科住院医师学员培训的实践教学模式,并对这一套实践教学模式进行了初步评估和效果评价。结果本规培基地2017级参加此CBL+Wet Lab综合实践培训的学生临床思维决策和专科操作技能测试的学习效果均高于2016级普通授课的学生(P=0.006)。学生问卷教学评价结果显示CBL联合Wet Lab教学法的学生在教学满意程度上有更高评价,差异有统计学意义(P<0.05)。结论CBL+Wet Lab实践模式能将眼科住院医师规范化培训中的主体从教员转化为学生,帮助眼科住院医师在自主学习中提高临床思辨能力和实践操作能力,通过系统性的实践教学为眼科住院医师完成培训后进入临床工作做好衔接。

采用WET溶剂抑制方法对mHCN1孔隙多肽~1H谱线进行归属

孔隙部分是离子通道选择性控制的关键部分 与Ｋ＋通道相似，ＨＣＮ离子通道孔隙区域包括ＧＹＧ特征序列 ．但除了Ｋ＋外，Ｎａ＋也能选择性通过ＨＣＮ离子通道 对ｍＨＣＮ１孔隙多肽的构象研究将有助于对ＨＣＮ离子通道选择性的理解． 本文利用新开发的ＷＥＴ溶剂抑制方法并综合运用ｗｅｔ－ＴＯＣＹＳ和ｗｅｔ－ＮＯＥＳＹ ＮＭＲ方法对ｍＨＣＮ１孔隙多肽（９５％水＋５％重水）进行了１Ｈ谱线归属．

Different surface modification methods and coating materials of zinc metal anode

Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.

Effects of Ga,Al,Ag,and Ce multi-additions on the wetting characteristics of Sn-9Zn lead-free solder

An orthogonal method was used to evaluate the effects of Ga, Al, Ag, and Ce multi-additions on the wetting characteristics of Sn-9Zn lead-free solders by wetting balance method. The results show that the optimal loading of Ga, Al, Ag, and Ce was 0.2 wt.%, 0.002 wt.%, 0.25 wt.%, and 0.15 wt.%, respectively. Intermetallic compounds （IMCs） formed at the interface between Sn-9Zn-0.2Ga-0.002Al-0.25Ag- 0.15Ce solder and Cu substrate were investigated by scanning electron microscope （SEM） and energy dispersive spectroscopy （EDS） analysis. The SEM images illustrate that the IMCs can be divided into two portions from the substrate side to the solder side： a planar CusZns layer and an additional continuous scallop-like AgZn3 layer. The EDS analysis also shows that Ga segregates in the solder abutting upon the interface. X-ray photoelectron spectroscopy （XPS） and Auger electron spectroscopy （AES） of the surface components of Sn-9Zn-0.2Ga-0.002Al- 0.25Ag-0.15Ce solder indicate that Al aggregates at the surface in the form of Al203 protective fdm, which prevents the further oxidation of the solder surface. On the other hand, Ce aggregates at the subsurface, which may reduce the surface tension of the solder and improve the wettability in consequence.

DEM modeling of high shear wet granulation of a simple system

High shear wet granulation(HSWG) is one of the most poorly understood processes with known difficulties in optimization and scale up. The purpose of the current study is to develop a DEM model which can be applied under dynamic process conditions with high predictive capacity to improve process insight. The DEM model is used to predict agglomeration as a function of impeller speed and liquid addition rate in a high shear wet granulator. The DEM model tracks dynamic formation and breakage of liquid bridges between particles as liquid binder in the system is added, and corrects for the change in material properties as a function of the binder content.

Dissolutive wetting process and interfacial characteristic of molten Sn–17Bi–0.5Cu alloy on copper substrate

The reactive spreading processes of Sn–17Bi–0.5Cu melt alloy on Cu substrate were studied by sessile drop method in the temperature range of 523–673 K.Dynamic contact angles between the solder and Cu substrate at different times were recorded with high-resolution CCD digital video.The smallest contact angle was observed at623 and 673 K.Ultimate spreading radius does not increase monotonously with the temperature increasing.These can be attributed to the strong dissolution of Cu substrate into the liquid solder,which hinders the solder from spreading.Triple line area configuration of the Sn–17Bi–0.5Cu/Cu system was discussed by the description of the equilibrium state.The calculated results based on experiments of the tension balances along each of the three interfaces show good agreement with theoretical analysis.Intermetallic compounds at the Sn–17Bi–0.5Cu/Cu interface are identified as Cu6Sn5adjacent to the solder and Cu3Sn adjacent to the Cu substrate,respectively.These results are of practical interest for composite lead-free solders’preparations and joining of Sn–17Bi–0.5Cu to Cu substrate.

Wetting of Au and Ag particles on monocrystalline graphite substrates

The wetting behavior of Au and Ag particles on a monocrystalline graphite substrate was investigated using the microscopic sessile drop method under a purified Ar atmosphere at 1300 K. The measured contact angles of the liquid Au and Ag on monocrystalline graphite substrates of （0001） face were 129° and 124°, respectively. It is believed that the interaction at the interface is dominated by the physical bonding （van der Waal＇s interaction）.

Comparative study of two lattice Boltzmann multiphase models for simulating wetting phenomena: implementing static contact angles based on the geometric formulation

Wetting phenomena are widespread in nature and industrial applications. In general, systems concerning wetting phenomena are typical multicomponent/multiphase complex fluid systems. Simulating the behavior of such systems is important to both scientific research and practical applications. It is challenging due to the complexity of the phenomena and difficulties in choosing an appropriate numerical method. To provide some detailed guidelines for selecting a suitable multiphase lattice Boltzmann model, two kinds of lattice Boltzmann multiphase models, the modified S-C model and the H-C-Z model, are used in this paper to investigate the static contact angle on solid surfaces with different wettability combined with the geometric formulation(Ding, H. and Spelt, P.D. M. Wetting condition in diffuse interface simulations of contact line motion. Physical Review E, 75(4), 046708(2007)). The specific characteristics and computational performance of these two lattice Boltzmann method(LBM) multiphase models are analyzed including relationship between surface tension and the control parameters, the achievable range of the static contact angle, the maximum magnitude of the spurious currents(MMSC), and most importantly, the convergence rate of the two models on simulating the static contact angle. The results show that a wide range of static contact angles from wetting to non-wetting can be realized for both models. MMSC mainly depends on the surface tension. With the numerical parameters used in this work, the maximum magnitudes of the spurious currents of the two models are on the same order of magnitude. MMSC of the S-C model is universally larger than that of the H-C-Z model. The convergence rate of the S-C model is much faster than that of the H-C-Z model. The major foci in this work are the frequently-omitted important details in simulating wetting phenomena. Thus, the major findings in this work can provide suggestions for simulating wetting phenomena with LBM multiphase models along with the geometric formulation.

Fabrication of pillar-array superhydrophobic silicon surface and thermodynamic analysis on the wetting state transition

Textured silicon （Si） substrates decorated with regular microscale square pillar arrays of nearly the same side length, height, but different intervals are fabricated by inductively coupled plasma, and then silanized by self-assembly octadecyl- trichlorosilane （OTS） film. The systematic water contact angle （CA） measurements and micro/nanoscale hierarchical rough structure models are used to analyze the wetting behaviors of original and silanized textured Si substrates each as a function of pillar interval-to-width ratio. On the original textured Si substrate with hydrophilic pillars, the water droplet possesses a larger apparent CAs （〉 90~） and contact angle hysteresis （CAH）, induced by the hierarchical roughness of microscale pil- lar arrays and nanoscale pit-like roughness. However, the silanized textured substrate shows superhydrophobicity induced by the low free energy OTS overcoat and the hierarchical roughness of microscale pillar arrays, and nanoscale island-like roughness. The largest apparent CA on the superhydrophobic surface is 169.8~. In addition, the wetting transition of a gently deposited water droplet is observed on the original textured substrate with pillar interval-to-width ratio increasing. Furthermore, the wetting state transition is analyzed by thermodynamic approach with the consideration of the CAH effect. The results indicate that the wetting state changed from a Cassie state to a pseudo-Wenzel during the transition.

Free flexural vibration of a partially wet tapered Timoshenko beam with intermittent mass and stiffness variations, eccentric tip mass and non-classical foundation

A compliant tower is modeled as a partially dry, partially tapered, damped Timoshenko beam with the superstructure modeled as an eccentric tip mass, and a non-classical damped boundary at the base. The foundation is modeled as a combination of a linear spring and a torsional spring, along with parallel linear and torsional dampers(Kelvin-Voigt model). The superstructure adds to the kinetic energy of the system without affecting the potential energy, thereby reducing the natural frequencies. The weight of the superstructure acts as an axial compressive load on the beam, reducing its natural frequencies further. The empty space factor due to the truss-type structure of the tower is included. The effect of shear deformation and rotary inertia are included in the vibration analysis; with the non-uniform beam mode-shapes being a weighted sum of the uniform beam mode-shapes satisfying the end condition. The weights are evaluated by the Rayleigh-Ritz(RR) method, and verified using finite element method(FEM). The weight of the superstructure acts as an axial compressive load on the beam. Kelvin-Voigt model of structural damping is included.A part of the structure being underwater, the virtual added inertia is included to calculate the wet natural frequencies. A parametric study is done for various magnitudes of tip mass and various levels of submergence. The computational efficiency and accuracy of the Rayleigh-Ritz method, as compared to the FEA, has been demonstrated. The advantage of using closed-form trial functions is clearly seen in the efficacy of calculating the various energy components in the RR method.

咽瘘伤口湿性治疗评估指标体系构建的研究

目的构建咽瘘伤口湿性治疗评估指标体系。方法以整体护理理念为理论框架,检索PubMed、CINAHL、中国知网、万方数据知识服务平台、维普网数据库自建库至2023年1月的相关文献,经专家小组讨论后初步制订咽瘘伤口湿性治疗评估指标体系库、设计专家函询问卷。2023年4月至6月,采用目的抽样法,邀请来自中国东北、华北、华东、华南、华中、西南地区12个省市及自治区的15所三级甲等医院的25名专家进行函询,专家小组针对函询结果进行讨论并最终修订指标体系,应用层次分析法确定各层级指标权重并检验各层级指标逻辑一致性。结果专家函询问卷全部回收,有效回收率为100%。专家熟悉系数为0.912、判断系数为0.960、权威系数为0.936、肯德尔协调系数为0.392(P<0.001)。最终构建的咽瘘伤口湿性治疗评估指标体系包括一级指标3个、二级指标6个及三级指标28个,一级指标权重分别为0.7029(生理因素)、0.1149(心理因素)和0.1822(社会因素),各层级指标一致性检验系数均<0.100。结论初步构建的咽瘘伤口湿性治疗评估指标体系具有较高的权威性和科学性,可作为伤口治疗师评估咽瘘伤口的有效工具,指标体系的适用性和应用效果仍有待进一步验证。