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Micro/nano structured oleophobic agent improving the wellbore stability of shale gas wells
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作者 GENG Yuan SUN Jinsheng +7 位作者 CHENG Rongchao QU Yuanzhi ZHANG Zhilei WANG Jianhua WANG Ren YAN Zhiyuan REN Han WANG Jianlong 《Petroleum Exploration and Development》 CSCD 2022年第6期1452-1462,共11页
Through embedding modified nano-silica particles on the surface of polystyrene using the method of Pickering emulsion polymerization,a kind of nano/micro oleophobic agent named OL-1 was developed.The effects of OL-1 o... Through embedding modified nano-silica particles on the surface of polystyrene using the method of Pickering emulsion polymerization,a kind of nano/micro oleophobic agent named OL-1 was developed.The effects of OL-1 on the rock surface properties and its performance in inhibiting the oil phase imbibition into the rock were explored.The performance and mechanisms of OL-1 in improving the wellbore stability of shale gas wells were evaluated and analyzed.OL-1 could absorb on the surface of the shale core to form a membrane with a micro-nano two-stage roughness,making the surface energy of the core decrease to 0.13 mN/m and the contact angle of the white oil on the core surface increase from 16.39°to 153.03°.Compared with the untreated capillary tube,when immersed into 3#white oil,the capillary tube treated by OL-1 had a reversal of capillary pressure from 273.76 Pa to-297.71 Pa,and the oil imbibition height inside the capillary tube decreased from 31 mm above the external liquid level to 33 mm below the external liquid level.The amount of oil invading into the rock core modified by OL-1 decreased by 64.29%compared with the untreated one.The shale core immersed into the oil-based drilling fluids with 1%OL-1 had a porosity reduction rate of only 4.5%.Compared with the core immersed in the drilling fluids without OL-1,the inherent force of the core treated by 1%OL-1 increased by 24.9%,demonstrating that OL-1 could effectively improve the rock mechanical stability by inhibiting oil phase imbibition. 展开更多
关键词 SHALE wellbore stability oil-based drilling fluids oleophobic agent micro-nano composites wettability reversal
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Ultrahigh quantum efficiency photodetector and ultrafast reversible surface wettability transition of square In2O3 nanowires 被引量:3
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作者 Ming Meng Xinglong Wu +4 位作者 Xiaoli Ji Zhixing Gan Lizhe Liu Jiancang Shen Paul K. Chu 《Nano Research》 SCIE EI CAS CSCD 2017年第8期2772-2781,共10页
Due to a large surface-to-volume ratio, the optoelectronic performance of low- dimensional semiconductor nanostructure-based photodetectors depends in principle on chemisorption/photodesorption at the exposed surface,... Due to a large surface-to-volume ratio, the optoelectronic performance of low- dimensional semiconductor nanostructure-based photodetectors depends in principle on chemisorption/photodesorption at the exposed surface, but practical examples that show such an effect are still unavailable. Some theoretical calculations have predicted that the {001} facets of In2O3 can effectively accumulate photogenerated holes under irradiation, providing a model material to examine whether the facet cutting of nanowires (NWs) can boost their optoelectronic performance. Herein, we present the design and construction of a novel nanowire-based photodetector using square In2O3 NWs with four exposed {001} crystal facets. The photodetector delivers excellent optoelectronic performance with excellent repeatability, fast response speed, high spectral responsivity (Rλ), and high external quantum efficiency (EQE). The Rλ and EQE values are as high as 4.8 × 10^6 A/W and 1.46 × 10^9%, respectively, which are larger than those of other popular semiconductor photodetectors. In addition, the square In2O3 NWs show hydrophobic wettability as manifested by a contact angle of 118° and a fast photoinduced reversible switching behavior is observed. 展开更多
关键词 square In2O3 nanowires crystal facet PHOTODETECTOR reversible wettability transition
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