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氨化水饱和预处理麦秸厌氧消化产气性能的研究 被引量:13
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作者 杨懂艳 李秀金 +2 位作者 冯亚君 张亚甜 袁海荣 《可再生能源》 CAS 北大核心 2012年第6期97-102,共6页
试验以氨水为预处理试剂,研究在水饱和状态下,氨水添加量及负荷率对麦秸厌氧消化产气性能的影响。对氨化预处理前后麦秸的主要组分进行测定,采用傅立叶变换红外光谱(FTIR)对氨化水饱和预处理秸秆及秸秆中木素、纤维素和半纤维素的... 试验以氨水为预处理试剂,研究在水饱和状态下,氨水添加量及负荷率对麦秸厌氧消化产气性能的影响。对氨化预处理前后麦秸的主要组分进行测定,采用傅立叶变换红外光谱(FTIR)对氨化水饱和预处理秸秆及秸秆中木素、纤维素和半纤维素的结构变化进行研究。结果表明,在3种负荷率下,氨化水饱和预处理后麦秸单位质量VS产气量分别提高了14%~23%,26%~36%和31%~45%。4%氨化预处理后的麦秸在65g/L负荷率下获得最大377mug的生物气产量。组分分析表明,氨化水饱和预处理可有效脱除39%~42%的半纤维素及11%.20%的纤维素,对木素含量影响较小。结构分析表明,氨化水饱和预处理可脱除细胞壁中的蜡质成分,使木素中部分官能团、纤维素中的氢键和糖苷键、半纤维素的部分氢键和糖单元之间的连接键发生断裂;从而使纤维索从木素的包裹中释放出来并发生溶胀,破坏其晶体结构;使半纤维素亲水性增强且更易于降解。这些秸秆内部结构的变化是提高麦秸厌氧消化产气性能的根本原因。 展开更多
关键词 氨化水饱和预处理 麦秸 厌氧消化 产气量 组分 结构
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氨化预处理提高麦秸厌氧消化产气量的研究(英文) 被引量:4
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作者 杨懂艳 庞云芝 +4 位作者 袁海荣 陈树林 马晶伟 郁亮 李秀金 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第5期576-582,共7页
Aqueous ammonia was used to pretreat wheat straw to improve biodegradability and provide nitrogen source for enhancing biogas production. Three doses of ammonia(2%, 4%, and 6%, dry matter) and three moisture contents(... Aqueous ammonia was used to pretreat wheat straw to improve biodegradability and provide nitrogen source for enhancing biogas production. Three doses of ammonia(2%, 4%, and 6%, dry matter) and three moisture contents(30%, 60%, and 80%, dry matter) were applied to pretreat wheat straw for 7 days. The pretreated wheat straws were anaerobically digested at three loading rates(50, 65, and 80 g·L-1) to produce biogas. The results indicated that the wheat straw pretreated with 80% moisture content and 4% ammonia achieved the highest methane yield of 199.7 ml·g-1(based on per unit volatile solids loaded), with shorter digestion time(T80) of 25 days at the loading rate of 65 g·L-1compared to untreated one. The main chemical compositions of wheat straw were also analyzed. The cellulose and hemicellulose contents were decomposed by 2%-20% and 26%-42%, respectively,while the lignin content was hardly removed, cold-water and hot-water extracts were increased by 4%-44%, and12%-52%, respectively, for the ammonia-pretreated wheat straws at different moisture contents. The appropriate C/N ratio and decomposition of original chemical compositions into relatively readily biodegradable substances will improve the biodegradability and biogas yield. 展开更多
关键词 秸秆预处理 小麦秸秆 沼气产量 厌氧消化 氨水 纤维素含量 生物降解性 化学成分
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