High-rate electrochemical H_(2)O_(2) production over multimetallic atom catalysts under acidic–neutral conditions

Hydrogen peroxide(H_(2)O_(2))production by the electrochemical 2-electron oxygen reduction reaction(2e−ORR)is a promising alternative to the energy-intensive anthraquinone process,and single-atom electrocatalysts show the unique capability of high selectivity toward 2e−ORR against the 4e−one.The extremely low surface density of the single-atom sites and the inflexibility in manipulating their geometric/electronic configurations,however,compromise the H_(2)O_(2) yield and impede further performance enhancement.Herein,we construct a family of multiatom catalysts(MACs),on which two or three single atoms are closely coordinated to form high-density active sites that are versatile in their atomic configurations for optimal adsorption of essential*OOH species.Among them,the Cox–Ni MAC presents excellent electrocatalytic performance for 2e−ORR,in terms of its exceptionally high H_(2)O_(2) yield in acidic electrolytes(28.96 mol L^(−1) gcat.^(−1) h^(−1))and high selectivity under acidic to neutral conditions in a wide potential region(>80%,0–0.7 V).Operando X-ray absorption and density functional theory analyses jointly unveil its unique trimetallic Co2NiN8 configuration,which efficiently induces an appropriate Ni–d orbital filling and modulates the*OOH adsorption,together boosting the electrocatalytic 2e−ORR capability.This work thus provides a new MAC strategy for tuning the geometric/electronic structure of active sites for 2e−ORR and other potential electrochemical processes.

Mechanized Seed Production of Xinhunyou No.6 through Mixed Seeding of Parents' Seeds

Hybrid rice Xinhunyou No. 6 could be cultivated by mixing male and fe- male parents and performing seedling raising followed by transplanting, mechanical planting or mechanical direct seeding according to the production methods of com- mercial rice. During flowering stage, leaf cutting, application of ＂920＂ and pollination were conducted; after pollination, bentazon with a certain concentration was sprayed to kill the male parent; and the hybrid rice was harvested mechanically. Before storage, color separation was performed to remove little remaining male parent, thereby achieving whole-process mechanization of hybrid rice seed production. This study introduced mechanized seed production of Xinhunyou No. 6 through mixed- seeding from the aspects including mechanical direct seeding, seeding raising fol- lowed by transplanting and mechanical planting.

Strategies and Suggestions for the Development of Mechanized Rapeseed Production in Sichuan

Mechanization is the future direction of rapeseed production in Sichuan. A series of technology tests for rapeseed mechanized production have been carried out in terms of variety selection, key agronomic measures and machinery in the main production area of Sichuan in recent years. In the research, the agronomic techniques, including variety selection for mechanical production, key agronomic measures and mechanical harvesting were analyzed. Based on the present condi- tions, strategy and suggestions for the development of mechanized rapeseed produc- tion in Sichuan also were presented.

Research Progress on Mechanized Mixed Sowing Seed Production Technology of Hybrid Rice

Hybrid rice planting has been widely popularized and applied in the world. However, the high cost of seed production and the complicated procedures have become a bottleneck in the development of hybrid rice. The research progress on mixed sowing seed production techniques of hybrid rice was introduced from the aspects of rice resources creation, breeding, sowing seed technology research and cost benefit analysis. The production technology of the new mixed seeding combina- tion ＂Xinhunyou 6＂ was investigated, including the research and validation of benta- zon treatment period and dosage, mixing ratio of male and female parents, and the comparative test of different different sowing methods, which revealed that the mechanization technology of seed production of hybrid rice was mature and feasible and would be one of the most important development trend of technological devel- opment of hybrid rice production.

Effects of Mechanized Transplanting and Fertilization Mode on Population Growth and Development of Male Parent in Seed Production of Hybrid Rice

In order to study the effects of mechanized transplanting and fertilization mode on population growth and development of the male parent in seed production of hybrid rice, three male parents, Huazhan, Shuhui 527 and R9311 were selected as materials. The male parents were transplanted by rice transplanter with two kinds of line spacing design, six lines with equal row spacing （20/25 cm x 30 cm） and wide and narrow spacing （20/25 cm x 40, 20 cm）, and artificial transplanting with equal row spacing （20/25 cm x 30 cm） was set as the control. The three fer- tilization modes were applying for one, two and three times. The flowering stage and panicle-spikelet structure of the male parent were investigated. The results showed that the effects of mechanized transplanting and fertilization mode were little on the duration from seeding to heading; the panicles and spikelets of the three male parents were significantly increased by mechanized transplanting. The tiller number was increased by mechanized transplanting and fertilizing for two and three times. Wide and narrow spacing by machine planting and fertilizing for three times were suitable for Huazhan, which significantly increased the number of spikelets per unit area. Furthermore, the number of spikelets per unit area of Shuhui 527 and R9311 were significantly increased by mechanized transplanting and fertilizing for three times.

Research on Mechanisms for University Connotation Construction and High-Quality Employment in the Context of New Quality Productivity

The introduction of the concept of new quality productivity has attracted a great deal of attention in the educational community.However,there is an urgent need to align it with policy orientation and advancements in science and technology moving forward.Colleges and universities themselves should be the leaders of advanced thinking and scientific and technological development,and play their due roles in line with the development of the times to provide quality and urgent talents and intellectual support.For this reason,this paper proposes that universities should consciously establish a set of regular operation mechanisms,namely,the linkage mechanism between“social demand”and“connotation construction,”and operate regularly under the guarantee of the system.This enables universities to lead or grasp the pulse of scientific and technological development,constantly improve the level of connotation construction,promote high-quality employment,and provide high-quality services for modernization and the great rejuvenation of the Chinese nation.

Production characteristics and displacement mechanisms of infilling polymer-surfactant-preformed particle gel flooding in post-polymer flooding reservoirs:A review of practice in Ng3 block of Gudao Oilfield

The pilot test of infilling polymer-surfactant-preformed particle gel(PPG)flooding has been successfully implemented after polymer flooding in Ng3 block of Gudao Oilfield in China.However,the production characteristics and displacement mechanisms are still unclear,which restricts its further popularization and application.Aiming at this problem,this paper firstly analyzes the production performance of the pilot test and proposed four response types according to the change of water cut curves,including W-type,U-type,V-type response,and no response.Furthermore,the underlying reasons of these four types are analyzed from the aspects of seepage resistance and sweep efficiency.The overall sweep efficiency of gradual-rising W-type,gradual-decreasing W-type,and early V-type response increases from 0.81 to 0.93,0.55 to 0.89,and 0.94 to 1,respectively.And the sum of seepage resistance along the connection line between production well and injection well for U-type and delayed V-type response increases from 0.0994 to 0.2425,and 0.0677 to 0.1654,respectively.Then,the remaining oil distribution after polymer flooding is summarized into four types on the basis of production and geological characteristics,namely disconnected remaining oil,streamline unswept remaining oil,rhythm remaining oil,and interlayer-controlled remaining oil.Furthermore,the main displacement mechanisms for each type are clarified based on the dimensionless seepage resistance and water absorption profile.Generally,improving connectivity by well pattern infilling is the most important for producing disconnected remaining oil.The synergistic effect of well pattern infilling and polymer-surfactant-PPG flooding increases the dimensionless seepage resistance of water channeling regions and forces the subsequent injected water to turn to regions with streamline unswept remaining oil.The improvement of the water absorption profile by polymer-surfactant-PPG flooding and separated layer water injection contributes to displacing rhythm remaining oil and interlayer-controlled remaining oil.Finally,the paper analyzes the relationships between the remaining oil distribution after polymer flooding and production characteristics of infilling polymer-surfactant-PPG flooding.The study helps to deepen the understanding of infilling polymer-surfactant-PPG flooding and has reference significance for more commercial implementations in the future.

Full Mechanized Production Technology for Double-Low Rapeseed in Xianning City

This paper standardizes the operation of rapeseed production including variety choosing,field preparation,mechanical seeding,field management,mechanical harvesting etc.,to realize full mechanization of rapeseed production. The key technologies: the optimum sowing date was from mid-September to mid-October in rapeseed-rice（corn） double cropping system region,and from mid-October to late October in rapeseed-rice-rice triple-cropping region; seeding rate was 4. 5 kg/ha-6. 0 kg/ha; the optimum density was 450000-750000 plants per ha;150-240 kg N fertilizer,60-90 kg P2O5 fertilizer,90-135 kg K2O fertilizer and 7. 5-15 kg B fertilizer were used per ha,50% of N fertilizer and the rest of fertilizer were used as basal fertilizer; segmented harvesting was done when 70%-80% of siliques per plant was yellow and combined harvesting was done when more than 90% of siliques per plant was yellow or brown.

Effect and Analysis of Mechanized Production on Ratooning Ability of Guitang 47

[Objectives] This study was conducted to explore the effect of machine harvesting on ratooning ability of Guitang 47, and to provide basis for mechanized production of Guitang 47. [Methods] On the basis of mechanized planting and management of newly planted sugarcane Guitang 47, a comparative test of machine harvesting and manual harvesting was conducted, during which the plant generation rate, sugarcane yield, sucrose content and related agronomic traits of ratoon cane were continuously investigated in two years after machine harvesting of the newly planted sugarcane. [Results] There were no significant differences in the plant generation rate, plant height, stalk diameter, millable cane, sugarcane yield and sucrose content from manual harvesting of Guitang 47 in the first and second years after machine harvesting. In the second year after machine harvesting, the yields of ratoon cane and the sugar content reached 101.70 and 15.32 t/hm^2, respectively, which were equivalent to those of manual harvesting. [Conclusions] Guitang 47 has strong ratooning ability and lodging resistance and strong resistance to rolling and crushing, and is adaptive to full mechanized production. It should be promoted and accelerated in sugarcane areas lacking labor to reduce costs and increase benefits.

Breeding of Yuetang 08776,a New Sugarcane Variety Suitable for Mechanized Production

[Objectives]To study the breeding of a new sugarcane variety Yuetang 08776 suitable for mechanized production.[Methods]With Yuetang 96-86 as the female parent and Yuetang 99-66 as the male parent,Yuetang 08776 was bred by the Bioengineering Institute of Guangdong Academy of Sciences.It was approved as a non-major crop variety by the Ministry of Agriculture and Rural Affairs in December,2019.Through many years of multi-pilot trials,the characters,traits and disease resistance of Yuetang 08776 were investigated,and the key points of its cultivation technique were summarized.[Results]Yuetang 08776 is characterized by medium maturity,high sugar content,high and stable yield,strong cold and drought resistance,large number of effective stems,strong ratooning ability and lodging resistance.Yuetang 08776 has excellent agronomic traits,and has been identified as moderately resistant to smut and mosaic disease.The average cane yield of Yuetang 08776 was 119.89 t/ha,18.50 t/ha higher than that of CK,an increase of 18.25%.The average sugar yield was 17.15,2.11 t/ha higher than that of CK,an increase of 14.03%.The average sucrose content of Yuetang 08776 in the early period(November to December)was 13.20%,0.71 percentage points lower than that of CK;in the middle and late period(January to March of the following year),the average sucrose content was 15.23%,0.22 percentage points lower than that of CK;and the average sucrose content of the whole period was 14.21%,0.47 percentage points lower than that of CK.[Conclusions]Yuetang 08776 is a sugarcane variety with medium maturity,high sugar,high and stable yield,strong resistance and good ratooning.It is suitable for mechanized seeding,management and harvesting,and suitable for planting and popularizing in most sugarcane production areas of Guangdong,Guangxi and Yunnan.

Study on Mechanization Hybrid Rice Seed Production Technology and Combine Breeding Advances

[Objectives]Current hybrid rice seed production mechanization and a new kind of hybrid rice seed production mechanization using Bentazone sensitive lethal genes for mechanized seed production technology are introduced in this paper.[Method]Sensitive Restorer Bentazone lethal dose of filtering,parental and seed weight are bred combinations of several aspects of the system described,and presented mechanized seed technology new research directions.[Results]The method of using Bentazone sensitive lethal genes for mechanized seed production technology is feasible,economic,seed production and combination advantages.[Conclusions] Using Bentazone sensitive lethal genes for mechanized seed production technology is the new study direction of mechanic production.

Applying Technique Assembly to Raise the Production Level of Mechanized Agriculture

On the basis of accomplishment obtained in the course of mechanized crop production owing to the progress of science and technology,the authors propose further in this paper the target and prineiples of technique assembly in agricultural production.A typical high yield model of technique assembly for soybean and wheat production is given as an example.

Effects of Mechanical Sowing and Transplanting on Characteristics of Dry Matter Production in Middle-season Hybrid Rice

To clarify the effects of mechanical sowing and transplanting on dry mat- ter production of middle-season hybrid rice, a two-factor split plot design was used to study the effects of different sowing and transplanting methods and their interac- tion with the seedling number per hill or seeding time on dry matter accumulation, distribution and transformation of F You 498, a middle-season hybrid rice variety, under field conditions in 2012 and 2013. The results showed that there was a marked effect of the sowing and transplanting methods and their interaction with the seedling number per hill or seeding time on dry matter accumulation, distribution and transformation. The total population dry matter accumulation of the treatments with mechanical direct seeding （MDS） and machine-based transplanting （MT） was lower than that of the treatment with traditional manual transplanting （TMT）. How- ever, MDS had higher dry matter accumulation and accumulating rate in the joint- ing-earing stage,and maintained higher stem-sheath exportation, export rate and transformation than MT and TMT; MT had higher dry matter accumulation and ac- cumulating rate in the heading-maturity period than MDS and TMT. Moreover, the treatments with low seedling number per hill or early seeding enhanced the assimi- lation of dry matter after heading,the ratio of dry matter accumulation after earing to biomass yield and the contribution rate of dry matter accumulation after earing, and a reasonable early sowing was favorable to increase the harvest index of middle- season hybrid rice under mechanical sowing and transplanting conditions.

Establishment of value-realization mechanism for ecological products in provincial management level:A case study in Yunnan

Ecological products value-realization is regarded as one of the keys of transferring clear waters and green mountains to mountains of gold and silver.In 2021,the central government has issued a guideline on setting up and improving the mechanism to realize the value of ecological products,which has encouraged the local governments to explore the path of ecological products value-realization.At provincial management level,four national ecological civilization pilot zones systematically implemented ecological civilization structural reform in administrative and social and economic aspects.Meanwhile,other provinces started to try first regionally to explore the ways of ecological products value-realization.By taking Yunnan as a case study,the obstacles to improving the establishment of the ecological products value-realization mechanism in Yunnan province were examined and analyzed.The suggestions for the establishment of ecological products value-realization mechanism in Yunnan were put forward,which would become practical references for other provinces in China.

Shale oil enrichment evaluation and production law in Gulong Sag,Songliao Basin,NE China

Based on the results of drilling,tests and simulation experiments,the shales of the Cretaceous Qingshankou Formation in the Gulong Sag of the Songliao Basin are discussed with respect to hydrocarbon generation evolution,shale oil occurrence,and pore/fracture evolution mechanism.In conjunction with a substantial amount of oil testing and production data,the Gulong shale oil enrichment layers are evaluated and the production behaviors and decline law are analyzed.The results are drawn in four aspects.First,the Gulong shales are in the stage of extensive hydrocarbon expulsion when R_(0) is 1.0%-1.2%,with the peak hydrocarbon expulsion efficiency of 49.5%approximately.In the low-medium maturity stage,shale oil migrates from kerogen to rocks and organic pores/fractures.In the medium-high maturity stage,shale oil transforms from adsorbed state to free state.Second,the clay mineral intergranular pores/fractures,dissolution pores,and organic pores make up the majority of the pore structure.During the transformation,clay minerals undergo significant intergranular pore/fracture development between the minerals such as illite and illite/smectite mixed layer.A network of pores/fractures is formed by organic matter cracking.Third,free hydrocarbon content,effective porosity,total porosity,and brittle mineral content are the core indicators for the evaluation of shale oil enrichment layers.Class-I layers are defined as free hydrocarbon content equal or greater than 6.0 mg/g,effective porosity equal or greater than 3.5%,total porosity equal or greater than 8.0%,and brittle mineral content equal or greater than 50%.It is believed that the favourable oil layers are Q2-Q3 and Q8-Q9.Fourth,the horizontal wells in the core area of the light oil zone exhibit a high cumulative production in the first year,and present a hyperbolic production decline pattern,with the decline index of 0.85-0.95,the first-year decline rate of 14.5%-26.5%,and the single-well estimated ultimate recovery(EUR)greater than 2.0×10^(4)t.In practical exploration and production,more efforts will be devoted to the clarification of hydrocarbon generation and expulsion mechanisms,accurate testing of porosity and hydrocarbon content/phase of shale under formation conditions,precise delineation of the boundary of enrichment area,relationship between mechanical properties and stimulated reservoir volume,and enhanced oil recovery,in order to improve the EUR and achieve a large-scale,efficient development of shale oil.

Spatial-Temporal Changes in Grain Production, Consumption and Driving Mechanism in China

The spatial-temporal patterns of grain production and consumption have an important influence on the effective national grain supply on condition of tight balance in the total grain amount in China. In this paper, we analyze the spatial-temporal pattems of grain production, consumption and the driving mechanism for their evolution processes in China. The results indicate that both gravity centers of grain production and consumption in China moved toward the northern and eastern regions, almost in the same direction. The coordination of grain production and consumption increased slightly from 1995 to 2007 but decreased from 2000 to 2007. There is a spatial difference between the major districts of output increase and the strong growth potential in grain consumption, which indicates an increasing difficulty in improving the regional coordination of grain production and consumption. The movement of the gravity center of grain production is significantly correlated with regional differences in grain production policy, different economic development models, and spatial disparity of land and water resource use. For grain consumption, the main driving factors include rapid urbanization, the upgrade of food consumption structure, and distribution of food industries.

Characteristics and control mechanisms of coalbed permeability change in various gas production stages

According to dimensionless analysis of the coalbed methane （CBM） production data of Fanzhuang block in southern Qinshui basin, the dimensionless gas production rate is calculated to quantitatively divide the CBM well production process into four stages, i.e., drai- nage stage, unstable gas production stage, stable gas pro- duction stage, and gas production decline stage. By the material balance method, the coal reservoir permeability change in different stages is quantitatively characterized. The characteristics and control mechanisms of change in coalbed permeability （CICP） during different production stages are concluded on five aspects, i.e., permeability trend variation, controlling mechanism, system energy, phase state compositions, and production performance. The study reveals that CICP is characterized by first decline, then recovery, and finally by increase and is controlled directly by effective stress and matrix shrinkage effects. Further, the duration and intensity of the matrix shrinkage effect are inherently controlled by adsorption and desorp- tion features.

Kinetic mechanism of magnesium production by silicothermic reduction of CaO·MgO in vacuum

The investigation of silicothermic reduction of CaO·MgO was carried out using a self-developed thermogravimetric analysis(TGA)instrument under vacuum and high temperature conditions.The TG data of pellets prepared with calcined dolomite,ferrosilicon and fluorite were determined at the heating rates of 1.5,2.0,2.5 and 3.0℃/min in 5 Pa vacuum at 300−1400℃,respectively.Model-free analysis and model-based analysis were applied for simulating the kinetic mechanism.By analyzing the characteristics of the initial and final reaction temperatures of TG curve,ratio of half-width of derivative TG curve and kinetic parameters,a conclusion was made that the most probable mechanism function is the first order formal chemical reaction with activation energy of 233.42 kJ/mol and pre-exponential factor of 5.14×1010 s−1.This study provides the basic data of dynamics of silicothermic magnesium production under vacuum conditions.

Recent advances in cobalt phosphide-based materials for electrocatalytic water splitting:From catalytic mechanism and synthesis method to optimization design

Electrochemical water splitting has long been considered an effective energy conversion technology for trans-ferring intermittent renewable electricity into hydrogen fuel,and the exploration of cost-effective and high-performance electrocatalysts is crucial in making electrolyzed water technology commercially viable.Cobalt phosphide(Co-P)has emerged as a catalyst of high potential owing to its high catalytic activity and durability in water splitting.This paper systematically reviews the latest advances in the development of Co-P-based materials for use in water splitting.The essential effects of P in enhancing the catalytic performance of the hydrogen evolution reaction and oxygen evolution reaction are first outlined.Then,versatile synthesis techniques for Co-P electrocatalysts are summarized,followed by advanced strategies to enhance the electrocatalytic performance of Co-P materials,including heteroatom doping,composite construction,integration with well-conductive sub-strates,and structure control from the viewpoint of experiment.Along with these optimization strategies,the understanding of the inherent mechanism of enhanced catalytic performance is also discussed.Finally,some existing challenges in the development of highly active and stable Co-P-based materials are clarified,and pro-spective directions for prompting the wide commercialization of water electrolysis technology are proposed.

A New Elastoplastic 3D Sand Production Model for Fractured Gas Fields

Reservoirs characterized by high temperature,high-pressure,medium high cementation strength,low porosity,and low permeability,in general,are not affected by sand production issues.Since 2009,however,it is known that cases exists where sand is present and may represent a significant technical problem(e.g.,the the Dina II condensate gas field).In the present study,the main factors affecting sand production in this type of reservoir are considered(mechanical properties,stress fields,production system,completion method and gas flow pattern changes during the production process).On this basis,a new liquid-solid coupled porous elasto-plastic 3D sand production model is introduced and validated through comparison with effective sand production data.The related prediction errors are found to be within 15%,which represents the necessary prerequisite for the utilization of such a model for the elaboration of sand prevention measures.