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Application study of image segmentation methods on pattern recognition in the course of wood across-compression 被引量:1
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作者 曹军 孙丽萍 +1 位作者 张冬妍 姜宇 《Journal of Forestry Research》 CAS CSCD 2000年第1期57-59,共3页
Image segmentation is one of important steps on pattern recognition study in the course of wood across-compression. By comparing and studying processing methods in finding cell space and cell wall, this paper puts for... Image segmentation is one of important steps on pattern recognition study in the course of wood across-compression. By comparing and studying processing methods in finding cell space and cell wall, this paper puts forward some image segmentation methods that are suitable for study of cell images of wood crossgrained compression. The method of spline function fitting was used for linking edges of cell, which perfects the study of pattern recognition in the course of wood across-compression. 展开更多
关键词 Image segmentation Pattern recognition wood across-compression Spline function
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基于YOLOv7的木材缺陷检测模型Wood-Net的研究 被引量:1
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作者 王正 江莺 +3 位作者 严飞 孙佑鹏 张园 张柳磊 《林业工程学报》 CSCD 北大核心 2024年第1期132-140,共9页
为改善利用人工方式识别木材缺陷存在的效率低、人工成本高的问题,同时实现在木材加工过程中使用新兴方式对不同的缺陷进行快速准确检测以提高木材利用率,针对现有的目标检测网络在木材缺陷检测方面存在诸如检测精度低、报错率高以及识... 为改善利用人工方式识别木材缺陷存在的效率低、人工成本高的问题,同时实现在木材加工过程中使用新兴方式对不同的缺陷进行快速准确检测以提高木材利用率,针对现有的目标检测网络在木材缺陷检测方面存在诸如检测精度低、报错率高以及识别种类少等局限,设计了用于木材缺陷检测的深度学习网络Wood-Net。Wood-Net将注意力机制ECA(efficient channel attention module)引入YOLOv7的主干网络,以便更好地区分木材缺陷之间的细微差别;将ECA与Res2Net结合后形成ECA-Res2Net模块,ECA-Res2Net模块克服了单纯的Res2Net跨通道交流能力不足的问题,增强了网络对更细粒度特征的提取能力;将ECA-Res2Net模块与SPPCSPC(spatial pyramid pooling and channel spatial pyramid convolution)并联形成ResSPPCSPC模块,增加了描述图像本身特征数量的能力,由此构成新方法Wood-Net。本研究将准确度、召回值、mAP@0.5以及mAP@0.5∶mAP@0.95 4个数值作为系统性能的评价指标。利用自建数据集训练Wood-Net,得到试验数据。试验结果表明:Wood-Net模型比基准模型YOLOv7在木材优选上精确率提高了4.52%,mAP@0.5∶mAP@0.95提高了6.62%;比基准模型YOLOv5s在木材优选上精确率提高了6.79%,mAP@0.5∶mAP@0.95提高了5.67%。ECA注意力机制能够有效提升E-ELAN的通道间信息交互能力;Res2Net模块具有很强的细粒度特征提取能力,在网络中引入Res2Net模块后,网络各项性能指标收敛速度快,在Res2Net中加入ECA后能够使单纯的Res2Net考虑多通道特征之间的关系,完成信息融合,提高检测性能。 展开更多
关键词 wood-Net 木材优选 ECA-Res2Net ECA Res2Net
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UiO-66-NH_(2)/wood复合材料的制备及其甲醛吸附性能研究
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作者 房梦迪 丁佳蓉 +2 位作者 赵爱晨 胡泽文 刘玉 《现代化工》 CAS CSCD 北大核心 2024年第S02期269-273,共5页
以巴沙木为载体,通过溶剂热法在木材管道内原位生成UiO-66-NH_(2)/wood复合材料;以甲醛为降解目标,对复合材料的甲醛吸附性能进行研究。并借助XRD、FT-IR、SEM和热重分析表征手段探讨了材料结构对吸附动力学的影响。结果表明,以木材为... 以巴沙木为载体,通过溶剂热法在木材管道内原位生成UiO-66-NH_(2)/wood复合材料;以甲醛为降解目标,对复合材料的甲醛吸附性能进行研究。并借助XRD、FT-IR、SEM和热重分析表征手段探讨了材料结构对吸附动力学的影响。结果表明,以木材为载体制备的UiO-66NH_(2)/wood复合材料的比表面积和孔径尺寸为木材的2倍,且其在200℃以下热稳定性较UiO-66-NH_(2)材料有明显提高,UiO-66-NH_(2)/wood复合材料对甲醛有良好的吸附性能,在100 min内对甲醛最高吸附效率为95.64%,其对甲醛的吸附过程符合准二级动力学模型,主要表现为物理吸附,经颗粒内扩散模型分析,其甲醛的吸附过程以内部扩散为主。 展开更多
关键词 木材 UiO-66-NH_(2)/wood 甲醛 吸附
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Evolutionary history shapes variation of wood density of tree species across the world 被引量:1
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作者 Fangbing Li Hong Qian +7 位作者 Jordi Sardans Dzhamal Y.Amishev Zixuan Wang Changyue Zhang Tonggui Wu Xiaoniu Xu Xiao Tao Xingzhao Huang 《Plant Diversity》 SCIE CAS CSCD 2024年第3期283-293,共11页
The effect of evolutionary history on wood density variation may play an important role in shaping variation in wood density,but this has largely not been tested.Using a comprehensive global dataset including 27,297 m... The effect of evolutionary history on wood density variation may play an important role in shaping variation in wood density,but this has largely not been tested.Using a comprehensive global dataset including 27,297 measurements of wood density from 2621 tree species worldwide,we test the hypothesis that the legacy of evolutionary history plays an important role in driving the variation of wood density among tree species.We assessed phylogenetic signal in different taxonomic(e.g.,angiosperms and gymnosperms)and ecological(e.g.,tropical,temperate,and boreal)groups of tree species,explored the biogeographical and phylogenetic patterns of wood density,and quantified the relative importance of current environmental factors(e.g.,climatic and soil variables)and evolutionary history(i.e.,phylogenetic relatedness among species and lineages)in driving global wood density variation.We found that wood density displayed a significant phylogenetic signal.Wood density differed among different biomes and climatic zones,with higher mean values of wood density in relatively drier regions(highest in subtropical desert).Our study revealed that at a global scale,for angiosperms and gymnosperms combined,phylogeny and species(representing the variance explained by taxonomy and not direct explained by long-term evolution process)explained 84.3%and 7.7%of total wood density variation,respectively,whereas current environment explained 2.7%of total wood density variation when phylogeny and species were taken into account.When angiosperms and gymnosperms were considered separately,the three proportions of explained variation are,respectively,84.2%,7.5%and 6.7%for angiosperms,and 45.7%,21.3%and 18.6%for gymnosperms.Our study shows that evolutionary history outpaced current environmental factors in shaping global variation in wood density. 展开更多
关键词 wood density PHYLOGENY ANGIOSPERMS GYMNOSPERMS Climate factors Biophysical parameters
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Vibration properties of Paulownia wood for Ruan sound quality using machine learning methods
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作者 Yang Yang 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第5期216-222,共7页
As an important material for manufacturing resonant components of musical instruments,Paulownia has an important influence on the sound quality of Ruan.In this paper,a model for evaluating the sound quality of Ruan ba... As an important material for manufacturing resonant components of musical instruments,Paulownia has an important influence on the sound quality of Ruan.In this paper,a model for evaluating the sound quality of Ruan based on the vibration characteristics of wood is developed using machine learning methods.Generally,the selection of materials for Ruan manufacturing relies primarily on manually weighing,observing,striking,and listening by the instrument technician.Deficiencies in scientific theory have hindered the quality of the finished Ruan.In this study,nine Ruans were manufactured,and a prediction model of Ruan sound quality was proposed based on the raw material information of Ruans.Out of a total of 180 data sets,145 and 45 sets were chosen for training and validation,respec-tively.In this paper,typical correlation analysis was used to determine the correlation between two single indicators in two adjacent pairwise combinations of the measured objects in each stage of the production process in Ruan.The vibra-tion characteristics of the wood were tested,and a model for predicting the evaluation of Ruan’s acoustic qualities was developed by measuring the vibration characteristics of the resonating plate material.The acoustic quality of the Ruan sound board wood was evaluated and predicted using machine learning model generalized regression neural net-work.The results show that the prediction of Ruan sound quality can be achieved using Matlab simulation based on the vibration characteristics of the soundboard wood.When the model-predicted values were compared with the tradi-tional predicted results,it was found that the generalized regression neural network had good performance,achieving an accuracy of 93.8%which was highly consistent with the experimental results.It was concluded that the model can accurately predict the acoustic quality of the Ruan based on the vibration performance of the soundboards. 展开更多
关键词 Sound quality wood vibration performance Paulownia wood Machine learning methods
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Wood灯检查在白癜风治疗期间不同复色模式观察研究中的应用
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作者 金伟梅 马杰 +2 位作者 索翠平 车旭 赵建斌 《中国美容医学》 CAS 2024年第5期103-107,共5页
目的:通过观察Wood灯下白癜风患者治疗过程中皮损的复色模式,探究不同复色模式的相关影响因素,分析评估不同复色模式间的疗效差异。方法:收集选取2021年8月-2022年8月笔者医院就诊的90例(170块),采集患者基本信息及病情相关指标。治疗后... 目的:通过观察Wood灯下白癜风患者治疗过程中皮损的复色模式,探究不同复色模式的相关影响因素,分析评估不同复色模式间的疗效差异。方法:收集选取2021年8月-2022年8月笔者医院就诊的90例(170块),采集患者基本信息及病情相关指标。治疗后,观察Wood灯下皮损复色模式,将复色模式与收集指标进行统计分析,筛选出差异有统计学意义的指标后,采用Logistic回归分析阳性指标与复色模式的相关性。并将Wood灯下观察的皮损面积作为疗效判定标准,分析对比不同复色模式间的疗效差异。结果:One-way ANOVA分析、χ^(2)检验显示白癜风疾病分期、皮损部位、治疗方式与皮损复色模式有关(P<0.05)。Logistic回归分析显示:治疗方式与复色模式存在相关性(P<0.05)。不同复色模式达到有效复色面积的时间比较,差异有统计学意义(H=8.04,P<0.05)。结论:通过观察Wood灯下白癜风患者治疗过程中皮损的复色模式发现,治疗方式可能是白癜风皮损复色模式的决定因素;不同复色模式之间的复色速度存在差异,可作为临床医师调整治疗方案的参考依据。 展开更多
关键词 白癜风 复色模式 治疗方式 复色速度 wood
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Enhancing wood efficiency through comprehensive wood flow analysis:Methodology and strategic insights
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作者 Ruisheng Wang Peer Haller 《Forest Ecosystems》 SCIE CSCD 2024年第2期172-183,共12页
Wood,an essential natural resource in human civilization,remains widely used despite advances in technology and material substitution.The surge in greenhouse gas emissions and environmental concerns accentuates the ne... Wood,an essential natural resource in human civilization,remains widely used despite advances in technology and material substitution.The surge in greenhouse gas emissions and environmental concerns accentuates the need for optimizing wood utilization.Material flow analysis is a powerful tool for tracking material flows and stocks,aiding resource management and environmental decision-making.However,the full extent of its methodological dimensions,particularly within the context of the wood supply chain,remains relatively unexplored.In this study,we delve into the existing literature on wood flow analysis,discussing its primary objectives,materials involved,temporal and spatial scales,data sources,units,and conversion factors.Additionally,data uncertainty,data reconciliation and crucial assumptions in material flow analysis are highlighted in this paper.Key findings reveal the significance of wood cascading and substitution effects by replacing non-wood materials,where they can reduce greenhouse gas emissions more than the natural carbon sink of forests and wood products.The immediate impact of short-term wood cascading might not be as robust as the substitution effect,with energy substitution showcasing better results than material substitution.However,it's crucial to note that these conclusions could experience significant reversal from a long-term and global perspective.Strategies for improving wood efficiency involve maximizing material use,advancing construction technologies,extending product lifespans,promoting cascade use,and optimizing energy recovery processes.The study underscores the need for standardized approaches in wood flow analysis and emphasizes the potential of wood efficiency strategies in addressing environmental challenges. 展开更多
关键词 Material flow analysis wood METHODOLOGY Cascade use Substitution effects
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Wood By-Products as UV Protection:A Consequence Review
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作者 Naglaa Salem El‑Sayed Mohamed Hasanin Samir Kamel 《Journal of Renewable Materials》 EI CAS 2024年第4期699-720,共22页
In recent decades,the ozone layer has suffered considerable damage,increasing the entry of ultraviolet(UV)light into the atmosphere and reaching the earth’s surface,negatively affecting life.Accordingly,researchers a... In recent decades,the ozone layer has suffered considerable damage,increasing the entry of ultraviolet(UV)light into the atmosphere and reaching the earth’s surface,negatively affecting life.Accordingly,researchers aimed to solve this problem by synthesizing advanced UV-shielding materials.On the other hand,developing an easy and green strategy to prepare functional materials with outstanding properties based on naturally abundant and environmentally friendly raw materials is highly desirable for sustainable development.Because biomass-derived materials are sustainable and biodegradable,they present a promising substitute for petroleum-based polymers.The three main structural constituents of the plant biomass-based materials that are naturally available are cellulose,hemicellulose,and lignin.This review details current developments using wood-based products such as cellulose,hemicellulose,and lignin in UV-shielding applications.It will start with assembling the structure and chemistry of cellulose,hemicellulose,and lignin,followed by their contributions to preparing UV-shielding materials.Finally,it will briefly discuss the different processing methods for the design of UV-shielding materials.The wood by-products offer additional opportunities to use the whole tree harvest. 展开更多
关键词 UV-SHIELDING wood cellulose LIGNIN HEMICELLULOSE sunlight protection
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Configuring single-layer MXene nanosheet onto natural wood fiber via C-Ti-C covalent bonds for high-stability Li-S batteries
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作者 Yangyang Chen Yu Liao +5 位作者 Ying Wu Lei Li Zhen Zhang Sha Luo Yiqiang Wu Yan Qing 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期701-711,I0016,共12页
Lithium-sulfur batteries(LSBs)are considered promising candidates for next-generation battery technologies owing to their outstanding theoretical energy density and cost-effectiveness.However,the low conductivity and ... Lithium-sulfur batteries(LSBs)are considered promising candidates for next-generation battery technologies owing to their outstanding theoretical energy density and cost-effectiveness.However,the low conductivity and polysulfide shuttling effect of S cathodes severely hamper the practical performance of LSBs.Herein,in situ-generated single layer MXene nanosheet/hierarchical porous carbonized wood fiber(MX/PCWF)composites are prepared via a nonhazardous eutectic activation strategy coupled with pyrolysis-induced gas diffusion.The unique architecture,wherein single layer MXene nanosheets are constructed on carbonized wood fiber walls,ensures rapid polysulfide conversion and continuous electron transfer for redox reactions.The C-Ti-C bonds formed between MXene and PCWF can considerably expedite the conversion of polysulfides,effectively suppressing the shuttle effect.An impressive capacity of 1301.1 m A h g^(-1)at 0.5 C accompanied by remarkable stability is attained with the MX/PCWF host,as evidenced by the capacity maintenance of 722.6 m A h g^(-1)after 500 cycles.Notably,the MX/PCWF/S cathode can still deliver a high capacity of 886.8 m A h g^(-1)at a high S loading of 5.6 mg cm^(-2).The construction of two-dimensional MXenes on natural wood fiber walls offers a competitive edge over S-based cathode materials and demonstrates a novel strategy for developing high-performance batteries. 展开更多
关键词 Lithium-sulfur batteries S cathodes MXene nanosheets wood fiber C-Ti-C bonds
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Leakage Proof,Flame-Retardant,and Electromagnetic Shield Wood Morphology Genetic Composite Phase Change Materials for Solar Thermal Energy Harvesting
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作者 Yuhui Chen Yang Meng +7 位作者 Jiangyu Zhang Yuhui Xie Hua Guo Mukun He Xuetao Shi Yi Mei Xinxin Sheng Delong Xie 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期99-120,共22页
Phase change materials(PCMs)offer a promising solution to address the challenges posed by intermittency and fluctuations in solar thermal utilization.However,for organic solid-liquid PCMs,issues such as leakage,low th... Phase change materials(PCMs)offer a promising solution to address the challenges posed by intermittency and fluctuations in solar thermal utilization.However,for organic solid-liquid PCMs,issues such as leakage,low thermal conductivity,lack of efficient solar-thermal media,and flamma-bility have constrained their broad applications.Herein,we present an innova-tive class of versatile composite phase change materials(CPCMs)developed through a facile and environmentally friendly synthesis approach,leveraging the inherent anisotropy and unidirectional porosity of wood aerogel(nanowood)to support polyethylene glycol(PEG).The wood modification process involves the incorporation of phytic acid(PA)and MXene hybrid structure through an evaporation-induced assembly method,which could impart non-leaking PEG filling while concurrently facilitating thermal conduction,light absorption,and flame-retardant.Consequently,the as-prepared wood-based CPCMs showcase enhanced thermal conductivity(0.82 W m^(-1)K^(-1),about 4.6 times than PEG)as well as high latent heat of 135.5 kJ kg^(-1)(91.5%encapsula-tion)with thermal durability and stability throughout at least 200 heating and cooling cycles,featuring dramatic solar-thermal conversion efficiency up to 98.58%.In addition,with the synergistic effect of phytic acid and MXene,the flame-retardant performance of the CPCMs has been significantly enhanced,showing a self-extinguishing behavior.Moreover,the excellent electromagnetic shielding of 44.45 dB was endowed to the CPCMs,relieving contemporary health hazards associated with electromagnetic waves.Overall,we capitalize on the exquisite wood cell structure with unidirectional transport inherent in the development of multifunctional CPCMs,showcasing the operational principle through a proof-of-concept prototype system. 展开更多
关键词 wood PCMs MXene Solar thermal storage and conversion FLAME-RETARDANT Electromagnetic shielding
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Relating estimates of wood properties of birch to stem form, age and species
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作者 Grace Jones Maria Ulan +2 位作者 Mateusz Liziniewicz Johan Lindeberg Stergios Adamopoulos 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第3期1-11,共11页
Birch has long suffered from a lack of active forest management,leading many researchers to use mate-rial without a detailed management history.Data collected from three birch(Betula pendula Roth,B.pubescens Ehrh.)sit... Birch has long suffered from a lack of active forest management,leading many researchers to use mate-rial without a detailed management history.Data collected from three birch(Betula pendula Roth,B.pubescens Ehrh.)sites in southern Sweden were analyzed using regression analysis to detect any trends or differences in wood proper-ties that could be explained by stand history,tree age and stem form.All sites were genetics trials established in the same way.Estimates of acoustic velocity(AV)from non-destructive testing(NDT)and predicted AV had a higher correlation if data was pooled across sites and other stem form factors were considered.A subsample of stems had radial profiles of X-ray wood density and ring width by year created,and wood density was related to ring number from the pith and ring width.It seemed likely that wood density was negatively related to ring width for both birch species.Linear models had slight improvements if site and species were included,but only the youngest site with trees at age 15 had both birch species.This paper indicated that NDT values need to be considered separately,and any predictive models will likely be improved if they are specific to the site and birch species measured. 展开更多
关键词 Acoustic velocity Non-destructive testing Predictive models Regression analysis wood density
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BACNN: Multi-scale feature fusion-based bilinear attention convolutional neural network for wood NIR classification
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作者 Zihao Wan Hong Yang +2 位作者 Jipan Xu Hongbo Mu Dawei Qi 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第4期202-214,共13页
Effective development and utilization of wood resources is critical.Wood modification research has become an integral dimension of wood science research,however,the similarities between modified wood and original wood... Effective development and utilization of wood resources is critical.Wood modification research has become an integral dimension of wood science research,however,the similarities between modified wood and original wood render it challenging for accurate identification and classification using conventional image classification techniques.So,the development of efficient and accurate wood classification techniques is inevitable.This paper presents a one-dimensional,convolutional neural network(i.e.,BACNN)that combines near-infrared spectroscopy and deep learning techniques to classify poplar,tung,and balsa woods,and PVA,nano-silica-sol and PVA-nano silica sol modified woods of poplar.The results show that BACNN achieves an accuracy of 99.3%on the test set,higher than the 52.9%of the BP neural network and 98.7%of Support Vector Machine compared with traditional machine learning methods and deep learning based methods;it is also higher than the 97.6%of LeNet,98.7%of AlexNet and 99.1%of VGGNet-11.Therefore,the classification method proposed offers potential applications in wood classification,especially with homogeneous modified wood,and it also provides a basis for subsequent wood properties studies. 展开更多
关键词 wood classification Near infrared spectroscopy Bilinear network SE module Anti-noise algorithm
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Overview of the Synthesis, Characterization, and Application of Tannin-Glyoxal Adhesive for Wood-Based Composites
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作者 Awanda Wira Anggini Rita Kartika Sari +3 位作者 Efri Mardawati Tati Karliati Apri Heri Iswanto Muhammad Adly Rahandi Lubis 《Journal of Renewable Materials》 EI CAS 2024年第7期1165-1186,共22页
More than a century after its initial synthesis,urea-formaldehyde(UF)resins still have dominant applications as adhesives,paints,and coatings.However,formaldehyde in this industry produces formaldehyde emissions that ... More than a century after its initial synthesis,urea-formaldehyde(UF)resins still have dominant applications as adhesives,paints,and coatings.However,formaldehyde in this industry produces formaldehyde emissions that are dangerous to health.Scientists have spent the last decade replacing formaldehyde and phenol with environmentally friendly substances such as glyoxal and tannin to create bio-based adhesives.This review covers recent advances in synthesizing glyoxal tannin-based resins,especially those made from sustainable raw material substitutes and changes made to synthetic processes to improve mechanical properties.The efficacy of using tannin-glyoxal adhesives in producing wood-based composites has been proven.The glyoxylate reaction forms cross-linked bridges between the aromatic sites of the tannin and glyoxal molecular structures.Glyoxal tannin adhesive with a greater percentage of glyoxal than tannin will produce an adhesive with better characteristics.The gel time reduces as the hardener concentration rises from 7.5%to 15%when glyoxal is used in adhesives.However,excessive amounts of glyoxal will result in a decrease in viscosity values.Glyoxal exhibits faster delivery degradation when it reaches a maximum temperature of approximately 130°C,although it initiates the curing process slightly slower at 110°C.Adding glyoxal to tannin-based adhesives can improve the mechanical properties of composite boards.The wet shear strength of the resulting plywood is increased by 105.4%with the addition of 5-weight percent tannin-based resin with glyoxal as a cross-linker in Soy Protein Adhesive.With glyoxal as a hardener,the panels produced showed good internal bond strengths(>0.35 MPa)and met the international standard specifications for interior-grade panels. 展开更多
关键词 Bio-based adhesives GLYOXAL TANNIN wood adhesives wood-based composites
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Estimating wood quality attributes from dense airborne LiDAR point clouds
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作者 Nicolas Cattaneo Stefano Puliti +1 位作者 Carolin Fischer Rasmus Astrup 《Forest Ecosystems》 SCIE CSCD 2024年第2期226-235,共10页
Mapping individual tree quality parameters from high-density LiDAR point clouds is an important step towards improved forest inventories.We present a novel machine learning-based workflow that uses individual tree poi... Mapping individual tree quality parameters from high-density LiDAR point clouds is an important step towards improved forest inventories.We present a novel machine learning-based workflow that uses individual tree point clouds from drone laser scanning to predict wood quality indicators in standing trees.Unlike object reconstruction methods,our approach is based on simple metrics computed on vertical slices that summarize information on point distances,angles,and geometric attributes of the space between and around the points.Our models use these slice metrics as predictors and achieve high accuracy for predicting the diameter of the largest branch per log (DLBs) and stem diameter at different heights (DS) from survey-grade drone laser scans.We show that our models are also robust and accurate when tested on suboptimal versions of the data generated by reductions in the number of points or emulations of suboptimal single-tree segmentation scenarios.Our approach provides a simple,clear,and scalable solution that can be adapted to different situations both for research and more operational mapping. 展开更多
关键词 UAV laser scanning wood quality Machine learning Point cloud metrics
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Preparation of Environmentally Friendly Urea-Hexanediamine-Glyoxal(HUG)Resin Wood Adhesive
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作者 Qianyu Zhang Shi Chen +4 位作者 Long Cao Hong Lei Antonio Pizzi Xuedong Xi Guanben Du 《Journal of Renewable Materials》 EI CAS 2024年第2期235-244,共10页
Using non-toxic,low-volatile glyoxal to completely replace formaldehyde for preparing urea-glyoxal(UG)resin adhesive is a hot research topic that could be of great interest for the wood industry.However,urea-glyoxal(U... Using non-toxic,low-volatile glyoxal to completely replace formaldehyde for preparing urea-glyoxal(UG)resin adhesive is a hot research topic that could be of great interest for the wood industry.However,urea-glyoxal(UG)resins prepared by just using glyoxal instead of formaldehyde usually yields a lower degree of polymerization.This results in a poorer bonding performance and water resistance of UG resins.A good solution is to pre-react urea to preform polyurea molecules presenting already a certain degree of polymerization,and then to condense these with glyoxal to obtain a novel UG resin.Therefore,in this present work,the urea was reacted with hexamethylene diamine to form a polyurea named HU,and then this was used to react it with different amounts of glyoxal to synthesize hexamethylenediamine-urea-glyoxal(HUG)polycondensation resins,and to use this for bonding plywood.The results show that the glyoxal can well react with HU polyuria via addition and schiff base reaction,and also the HUG resin exhibits excellent bonding strength and water resistance.The shear strength of the plywood bonded with this HUG at 160°C hot press temperature as high as 1.93 MPa,2.16 MPa and 1.61 MPa,respectively,which meets the requirement of the China national standard GB/T 9846-2015(≥0.7 MPa),and can be a good choice as a wood adhesive for industrial application. 展开更多
关键词 Urea-glyoxal resin hexamethylene diamine wood adhesives water resistance
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Wood anatomy chronologies of Scots pine in the foothills of the Western Sayan(Siberia)
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作者 Elena A.Babushkina Dmitry R.Dergunov +6 位作者 Mikhail S.Zharkov Liliana V.Belokopytova Dina F.Zhirnova Bao Yang Jingjing Liu Xiaomei Peng Eugene A.Vaganov 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第3期13-27,共15页
Recent methodological advances in quantitative wood anatomy have provided new insights into the climatic responses of radial growth at the scale of cell structure of tree rings. This study considered long-term chronol... Recent methodological advances in quantitative wood anatomy have provided new insights into the climatic responses of radial growth at the scale of cell structure of tree rings. This study considered long-term chronologies of tracheid measurements, indexed by a novel approach to separate their specific climatic responses from signal recorded in cell production(closely reflected in tree-ring width). To fill gaps in understanding the impact of climate on conifer xylem structure, Scots pine(Pinus sylvestris L.)trees > 200 years old were selected within the forest-steppe zone in southern Siberia. Such habitats undergo mild moisture deficits and the resulting climatic regulation of growth processes. Mean and maximum values of cell radial diameter and cell wall thickness were recorded for each tree ring.Despite a low level of climatogenic stress, components of cell chronologies independent of cambial activity were separated to obtain significant climatic signals revealing the timing of the specific stages of tracheid differentiation. Cell expansion lasted from mid-April to July and was impacted similarly to tree-ring width(stimulated by precipitation and stressed by heat), maximum cell size formed late June. A switch in the climatic responses of mean anatomical traits indicated transition to latewood in mid-July. Secondary wall deposition lasted until mid-September, suppressed by end of season temperatures. Generally, anatomical climatic responses were modulated by a less dry May and September compared with summer months. 展开更多
关键词 Quantitative wood anatomy Cell radial size Cell wall thickness Pinus sylvestris Climatic response
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Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding
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作者 Jaewook Lee Byung-Dae Park Qinglin Wu 《Journal of Renewable Materials》 EI CAS 2024年第7期1187-1205,共19页
Lignin is the most abundant aromatic natural polymer,and receiving great attention in replacing various petro-leum-based polymers.The aim of this study is to investigate the feasibility of technical lignin as a polyol... Lignin is the most abundant aromatic natural polymer,and receiving great attention in replacing various petro-leum-based polymers.The aim of this study is to investigate the feasibility of technical lignin as a polyol for the synthesis of non-isocyanate polyurethane(NIPU)adhesives to substitute current polyurethane(PU)adhesives that have been synthesized with toxic isocyanate and polyols.Crude hardwood kraft lignin(C-HKL)was extracted from black liquor from a pulp mill followed by acetone fractionation to obtain acetone soluble-HKL(AS-HKL).Then,C-HKL,AS-HKL,and softwood sodium lignosulfonate(LS)were used for the synthesis of technical lignin-based NIPU adhesives through carbonation and polyamination and silane as a cross-linker.Their adhesion per-formance was determined for plywood.FTIR spectra showed the formation of urethane bonds and the reaction between lignin and silane.The NIPU adhesives prepared with C-HKL showed the highest adhesion strength among the three lignin-based NIPU adhesives.As the silane addition level increased,the adhesion strength of NIPU adhesives increased whereas formaldehyde emission decreased for all NIPU adhesives prepared.These results indicate that NIPU adhesives based on technical kraft lignin have a great potential as polyol for the synth-esis of bio-based NIPU adhesives for wood bonding. 展开更多
关键词 Technical lignin non-isocyanate polyurethane wood adhesives adhesion strength formaldehyde emission
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Novel wood-plastic composite fabricated via modified steel slag:Preparation,mechanical and flammability properties
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作者 Ling Zhao Kai Zhao +4 位作者 Zhenwei Shen Yifan Wang Xiaojie Xia Hao Zhang Hongming Long 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期2110-2120,共11页
A novel method was developed to enhance the utilization rate of steel slag(SS).Through treatment of SS with phosphoric acid and aminopropyl triethoxysilane(KH550),we obtained modified SS(MSS),which was used to prepare... A novel method was developed to enhance the utilization rate of steel slag(SS).Through treatment of SS with phosphoric acid and aminopropyl triethoxysilane(KH550),we obtained modified SS(MSS),which was used to prepare MSS/wood-plastic composites(MSS/WPCs)by replacing talcum powder(TP).The composites were fabricated through melting blending and hot pressing.Their mechanical and combustion properties,which comprise heat release,smoke release,and thermal stability,were systematically investigated.MSS can improve the mechanical strength of the composites through grafting reactions between wood powder and thermoplastics.Notably,MSS/WPC#50(16wt%MSS)with an MSS-to-TP mass ratio of 1:1 exhibited optimal comprehensive performance.Compared with those of WPC#0 without MSS,the tensile,flexural,and impact strengths of MSS/WPC#50 were increased by 18.5%,12.8%,and 18.0%,respectively.Moreover,the MSS/WPC#50 sample achieved the highest limited oxygen index of 22.5%,the highest vertical burning rating at the V-1 level,and the lowest horizontal burning rate at 44.2 mm/min.The formation of a dense and stable char layer led to improved thermal stability and a considerable reduction in heat and smoke releases of MSS/WPC#50.However,the partial replacement of TP with MSS slightly compromised the mechanical and flame-retardant properties,possibly due to the weak grafting caused by SS powder agglomeration.These findings suggest the suitability of MSS/WPCs for high-value-added applications as decorative panels indoors or outdoors. 展开更多
关键词 modified steel slag wood–plastic composites preparation method mechanical property flame retardant
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Physicochemical and Thermal Properties of Some Key Tropical Sawdust Woods for Energy Production
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作者 Davy Fiwa Kaoke Yann Le Brech +2 位作者 Emmanuel Talla Anthony Dufour Patrick Mountapmbeme Kouotou 《Journal of Sustainable Bioenergy Systems》 2024年第1期1-22,共22页
In South Saharan countries, 85% of the population uses biomass as a primary energy source. Cameroon presents one of the highest biomass energy and sawmills produce important sawdust resources which are not used and ar... In South Saharan countries, 85% of the population uses biomass as a primary energy source. Cameroon presents one of the highest biomass energy and sawmills produce important sawdust resources which are not used and are burnt in piles leading to significant air toxic emissions. Therefore, we have to valorize industrially these available sawdusts. This study focuses on the physicochemical and thermochemical analysis of Ayous, Sapelli and Tali sawdust. The proximate and ultimate analysis, particle size, structural composition, as well as heavy metal content and calorific value were determined. In addition, the thermogravimetric mass losses were also estimated. The results showed that high water contents (24% - 41%) were recorded in the raw sawdust, and the thermal treatment reduced these contents from 78% to values in the range of 4% - 9%. The values for ash and volatile matter content were respectively between 0.25% - 0.74% and 68% - 76%. The LHV is higher in Ayous (17.5 MJ/kg) and Sapelli (16.8 MJ/kg) than that of Tali (15.7 MJ/kg). The concentration of heavy metals is very low in each species. Extractives are more present in Tali (16.06%) than in the other sawdusts. Pyrolysis of sawdust shows the typical decomposition of hemicellulose (270˚C - 325˚C), cellulose (325˚C - 400˚C) and lignin (200˚C - 550˚C) with a maximum loss of 75% at 370˚C and the melting point is 320˚C. The results of the sawdust parameters determined in the paper can be valorized to reduce pollutants emissions by developing the efficiency and effectiveness of biomass energy processes and promoting the use of biomass as a sustainable alternative to traditional fossil fuels. 展开更多
关键词 wood SAWMILLS SAWDUST Combustion Energy
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Polyurethane Hybrid-Based Wood Adhesive: Review
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作者 Rahul Khandagale Sainath Gadhave Ravindra V. Gadhave 《Open Journal of Polymer Chemistry》 2024年第1期41-62,共22页
Based on commercially available polyvinyl alcohol (PVA) stabilised polyvinyl acetate (PVAc), emulsion adhesives are neither heat nor moisture-resistant and show weak strength at high relative humidity and high tempera... Based on commercially available polyvinyl alcohol (PVA) stabilised polyvinyl acetate (PVAc), emulsion adhesives are neither heat nor moisture-resistant and show weak strength at high relative humidity and high temperatures. Pre- or post-crosslinking is another method used to manufacture a conventional vinyl-based homopolymers or copolymers system with improved water resistance. Vinyl neodecanoate (VeoVa), N-methylolacrylamide (NMA), Methacrylamide, methacrylic acid (MAA), and other self-crosslinking comonomers are typically inserted to produce highly water-resistant vinyl based homopolymers or copolymers. Additionally, organic crosslinkers like glyoxal, glutaraldehyde, citric acid, tartaric acid, and the like, as well as inorganic crosslinkers like acidic metal salts like aluminium chloride, aluminium nitrate, boric acid, and the like, can be used to prepare the highly water-resistant vinyl based homopolymers or copolymers. It is also possible to combine the self-crosslinking comonomers with the organic crosslinkers. Recently, a different hybrid chemistry has been developed that improves lap shear strength, has outstanding water resistance, good durability, and doesn’t require any additional crosslinker agents. Two distinct polymers were combined to develop hybrid polymers. They usually involve mixing an organic polymer with a polymer. There are many capping agents that are used for polyurethanes to produce acrylics that are capped with polyurethane and used as an oligomer in PVAc wood glue. Here, in this paper, we reviewed the different hybrid chemistry based on polyurethane chemistry for wood bonding applications. 展开更多
关键词 Vinyl Acetate HYBRID POLYURETHANE wood ADHESIVE
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