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Layered Potassium Titanium Niobate/Reduced Graphene Oxide Nanocomposite as a Potassium‑Ion Battery Anode 被引量:3
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作者 Charlie A.F.Nason Ajay Piriya Vijaya Kumar Saroja +3 位作者 Yi Lu Runzhe Wei Yupei Han Yang Xu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期1-16,共16页
With graphite currently leading as the most viable anode for potassium-ion batteries(KIBs),other materials have been left relatively underexamined.Transition metal oxides are among these,with many positive attributes ... With graphite currently leading as the most viable anode for potassium-ion batteries(KIBs),other materials have been left relatively underexamined.Transition metal oxides are among these,with many positive attributes such as synthetic maturity,longterm cycling stability and fast redox kinetics.Therefore,to address this research deficiency we report herein a layered potassium titanium niobate KTiNbO5(KTNO)and its rGO nanocomposite(KTNO/rGO)synthesised via solvothermal methods as a high-performance anode for KIBs.Through effective distribution across the electrically conductive rGO,the electrochemical performance of the KTNO nanoparticles was enhanced.The potassium storage performance of the KTNO/rGO was demonstrated by its first charge capacity of 128.1 mAh g^(−1) and reversible capacity of 97.5 mAh g^(−1) after 500 cycles at 20 mA g^(−1),retaining 76.1%of the initial capacity,with an exceptional rate performance of 54.2 mAh g^(−1)at 1 A g^(−1).Furthermore,to investigate the attributes of KTNO in-situ XRD was performed,indicating a low-strain material.Ex-situ X-ray photoelectron spectra further investigated the mechanism of charge storage,with the titanium showing greater redox reversibility than the niobium.This work suggests this lowstrain nature is a highly advantageous property and well worth regarding KTNO as a promising anode for future high-performance KIBs. 展开更多
关键词 Potassium-ion batteries INTERCALATION Transition metal oxides Anodes nanocomposite
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A Generic Strategy to Create Mechanically Interlocked Nanocomposite/Hydrogel Hybrid Electrodes for Epidermal Electronics 被引量:1
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作者 Qian Wang Yanyan Li +7 位作者 Yong Lin Yuping Sun Chong Bai Haorun Guo Ting Fang Gaohua Hu Yanqing Lu Desheng Kong 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期120-133,共14页
Stretchable electronics are crucial enablers for next-generation wearables intimately integrated into the human body.As the primary compliant conductors used in these devices,metallic nanostructure/elastomer composite... Stretchable electronics are crucial enablers for next-generation wearables intimately integrated into the human body.As the primary compliant conductors used in these devices,metallic nanostructure/elastomer composites often struggle to form conformal contact with the textured skin.Hybrid electrodes have been consequently developed based on conductive nanocomposite and soft hydrogels to establish seamless skin-device interfaces.However,chemical modifications are typically needed for reliable bonding,which can alter their original properties.To overcome this limitation,this study presents a facile fabrication approach for mechanically interlocked nanocomposite/hydrogel hybrid electrodes.In this physical process,soft microfoams are thermally laminated on silver nanowire nanocomposites as a porous interface,which forms an interpenetrating network with the hydrogel.The microfoam-enabled bonding strategy is generally compatible with various polymers.The resulting interlocked hybrids have a 28-fold improved interfacial toughness compared to directly stacked hybrids.These electrodes achieve firm attachment to the skin and low contact impedance using tissue-adhesive hydrogels.They have been successfully integrated into an epidermal sleeve to distinguish hand gestures by sensing mus-cle contractions.Interlocked nanocomposite/hydrogel hybrids reported here offer a promising platform to combine the benefits of both materials for epidermal devices and systems. 展开更多
关键词 Stretchable electronics Epidermal electronics Silver nanowire Conductive nanocomposites HYDROGEL
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Bio-inspired Hydroxyapatite/Gelatin Transparent Nanocomposites
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作者 谭军军 WU Mingchen +2 位作者 LI Yuzhe PENG Jiamei 熊焰 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期298-308,共11页
Hydroxyapatite(HA)nanoparticles impart outstanding mechanical properties to organicinorganic nanocomposites in bone.Inspired by the composite structure of HA nanoparticles and collagen in bone,a high performance HA/ge... Hydroxyapatite(HA)nanoparticles impart outstanding mechanical properties to organicinorganic nanocomposites in bone.Inspired by the composite structure of HA nanoparticles and collagen in bone,a high performance HA/gelatin nanocomposite was first developed.The nanocomposites have much better mechanical properties(elongation at break 29.9%,tensile strength 90.7 MPa,Young’s modulus 5.24 GPa)than pure gelatin films(elongation at break 9.3%,tensile strength 90.8 MPa,Young’s modulus 2.5 GPa).In addition,the composite films keep a high transmittance in visible wavelength range from 0%to 60%of the HA solid content.These differences in properties are attributed to the homogeneous distribution of HA nanoparticles in the gelatin polymer matrix and the strong interaction between the particle surfaces and the gelatin molecules.This protocol should be promising for HA-based nanocomposites with enhanced mechanical properties for biomedical applications. 展开更多
关键词 HYDROXYAPATITE nanocompositeS sodium citrate GELATIN colloidal stability
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Increasing the toughness while reducing the viscosity of carbon nanotube/ polyether imide/polyether ether ketone nanocomposites
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作者 SONG Jiu-peng ZHAO Yan +3 位作者 LI Xue-kuan XIONG Shu LI Shuang WANG Kai 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第4期715-728,共14页
Polyether ether ketone(PEEK)has good mechanical properties.However,its high viscosity when molten limits its use because it is hard to process.PEEK nanocomposites containing both carbon nanotubes(CNTs)and polyether im... Polyether ether ketone(PEEK)has good mechanical properties.However,its high viscosity when molten limits its use because it is hard to process.PEEK nanocomposites containing both carbon nanotubes(CNTs)and polyether imide(PEI)were pre-pared by a direct wet powder blending method using a vertical injection molding machine.The addition of an optimum amount of PEI lowered the viscosity of the molten PEEK by approximately 50%while producing an increase in the toughness of the nanocom-posites,whose strain to failure increased by 129%,and fracture energy increased by 97%.The uniformly dispersed CNT/PEI powder reduced the processing difficulty of PEEK nanocomposites without affecting the thermal resistance.This improvement of the strength and viscosity of PEEK facilitate its use in the preparation of thermoplastic composites. 展开更多
关键词 nanocompositeS Mechanical properties Rheological properties Microstructural analysis
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Using Electrodeposition of Carboxylated Chitosan for Green Preparation of Copper Nanoclusters and Nanocomposite Films
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作者 ZHANG Xiaoli LI Tingxue +4 位作者 WANG Qinghua YANG Yan ZHANG Chenyu LIU Yaning WANG Yifeng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1348-1357,共10页
On the basis of coordinated electrodeposition of carboxylated chitosan(CCS),we presented a green method to prepare Cu NCs and Cu NCs/CCS nanocomposite films.The method shows a range of benefits,such as the convenient ... On the basis of coordinated electrodeposition of carboxylated chitosan(CCS),we presented a green method to prepare Cu NCs and Cu NCs/CCS nanocomposite films.The method shows a range of benefits,such as the convenient and eco-friendly process,mild conditions,and simple post-treatment.The experimental results reveal that a homogeneous deposited film(Cu NCs/CCS nanocomposite film)is generated on the Cu plate(the anode)after electrodeposition,which exhibits an obvious red florescence.The results from TEM observation suggest there are nanoparticles(with the average particle size of 2.3 nm)in the deposited film.Spectral analysis results both demonstrate the existence of Cu NCs in the deposited film.Moreover,the Cu NCs/CCS film modified electrode is directly created through electrodeposition of CCS,which enables promising application in the electrochemical sensing.By means of fluorescence properties of Cu NCs,the Cu NCs/CCS film also owns the potential in fluorescence detection.Therefore,this work builds a novel method for the green synthesis of Cu NCs,meanwhile it offers a convenient and new electrodeposition strategy to prepare polysaccharide-based Cu NCs nanocomposites for uses in functional nanocomposites and bioelectronic devices. 展开更多
关键词 nanocomposite films copper nanoclusters ELECTRODEPOSITION carboxylated chitosan POLYSACCHARIDES
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Predicting the Mechanical Behavior of a Bioinspired Nanocomposite through Machine Learning
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作者 Xingzi Yang Wei Gao +1 位作者 Xiaodu Wang Xiaowei Zeng 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第8期1299-1313,共15页
The bioinspired nacre or bone structure represents a remarkable example of tough,strong,lightweight,and multifunctional structures in biological materials that can be an inspiration to design bioinspired high-performa... The bioinspired nacre or bone structure represents a remarkable example of tough,strong,lightweight,and multifunctional structures in biological materials that can be an inspiration to design bioinspired high-performance materials.The bioinspired structure consists of hard grains and soft material interfaces.While the material interface has a very low volume percentage,its property has the ability to determine the bulk material response.Machine learning technology nowadays is widely used in material science.A machine learning model was utilized to predict the material response based on the material interface properties in a bioinspired nanocomposite.This model was trained on a comprehensive dataset of material response and interface properties,allowing it to make accurate predictions.The results of this study demonstrate the efficiency and high accuracy of the machine learning model.The successful application of machine learning into the material property prediction process has the potential to greatly enhance both the efficiency and accuracy of the material design process. 展开更多
关键词 Bioinspired nanocomposite computational model machine learning finite element material interface
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Efficacy of graphene nanocomposites for air disinfection in dental clinics: A randomized controlled study
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作者 Ya-Qiong Ju Xiang-Hua Yu +3 位作者 Jing Wu Ying-Hui Hu Xiang-Yong Han Dan Fang 《World Journal of Clinical Cases》 SCIE 2024年第28期6173-6179,共7页
BACKGROUND Aerosols containing disease-causing microorganisms are produced during oral diagnosis and treatment can cause secondary contamination.AIM To investigate the use of graphene material for air disinfection in ... BACKGROUND Aerosols containing disease-causing microorganisms are produced during oral diagnosis and treatment can cause secondary contamination.AIM To investigate the use of graphene material for air disinfection in dental clinics by leveraging its adsorption and antibacterial properties.METHODS Patients who received ultrasonic cleaning at our hospital from April 2023 to April 2024.They were randomly assigned to three groups(n=20 each):Graphene nanocomposite material suction group(Group A),ordinary filter suction group(Group B),and no air suction device group(Group C).The air quality and air colony count in the clinic rooms were assessed before,during,and after the procedure.Additionally,bacterial colony counts were obtained from the air outlets of the suction devices and the filter screens in Groups A and B.RESULTS Before ultrasonic cleaning,no significant differences in air quality PM2.5 and colony counts were observed among the three groups.However,significant differences in air quality PM2.5 and colony counts were noted among the three groups during ultrasonic cleaning and after ultrasonic treatment.Additionally,the number of colonies on the exhaust port of the suction device and the surface of the filter were significantly lower in Group A than in Group B(P=0.000 and P=0.000,respectively).CONCLUSION Graphene nanocomposites can effectively sterilize the air in dental clinics by exerting their antimicrobial effects and may be used to reduce secondary pollution. 展开更多
关键词 GRAPHENE nanocompositeS Oral clinic Air disinfection Secondary contamination
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Lightweight Dual‑Functional Segregated Nanocomposite Foams for Integrated Infrared Stealth and Absorption‑Dominant Electromagnetic Interference Shielding
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作者 Zhonglei Ma Ruochu Jiang +8 位作者 Jiayao Jing Songlei Kang Li Ma Kefan Zhang Junxian Li Yu Zhang Jianbin Qin Shuhuan Yun Guangcheng Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期38-55,共18页
Lightweight infrared stealth and absorption-dominant electromagnetic interference(EMI)shielding materials are highly desirable in areas of aerospace,weapons,military and wearable electronics.Herein,lightweight and hig... Lightweight infrared stealth and absorption-dominant electromagnetic interference(EMI)shielding materials are highly desirable in areas of aerospace,weapons,military and wearable electronics.Herein,lightweight and high-efficiency dual-functional segregated nanocomposite foams with microcellular structures are developed for integrated infrared stealth and absorption-dominant EMI shielding via the efficient and scalable supercritical CO_(2)(SC-CO_(2))foaming combined with hydrogen bonding assembly and compression molding strategy.The obtained lightweight segregated nanocomposite foams exhibit superior infrared stealth performances benefitting from the synergistic effect of highly effective thermal insulation and low infrared emissivity,and outstanding absorption-dominant EMI shielding performances attributed to the synchronous construction of microcellular structures and segregated structures.Particularly,the segregated nanocomposite foams present a large radiation temperature reduction of 70.2℃ at the object temperature of 100℃,and a significantly improved EM wave absorptivity/reflectivity(A/R)ratio of 2.15 at an ultralow Ti_(3)C_(2)T_(x) content of 1.7 vol%.Moreover,the segregated nanocomposite foams exhibit outstanding working reliability and stability upon dynamic compression cycles.The results demonstrate that the lightweight and high-efficiency dual-functional segregated nanocomposite foams have excellent potentials for infrared stealth and absorption-dominant EMI shielding applications in aerospace,weapons,military and wearable electronics. 展开更多
关键词 Segregated nanocomposite foams Microcellular structures Infrared stealth EMI shielding Low infrared emissivity
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Advanced Nanocomposite Arabic Gum Polyacrylic Acid Hydrogels for Flexible Supercapacitors
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作者 Borhan Albiss Asala Saleh 《Journal of Renewable Materials》 EI CAS 2024年第7期1219-1236,共18页
In this work,the fabrication and characterization of the nanocomposite hydrogel,as a solid electrode in electro-chemical cell and gel electrolyte material using Indium titanium oxide/polyethylene terephthalate(ITO/PET... In this work,the fabrication and characterization of the nanocomposite hydrogel,as a solid electrode in electro-chemical cell and gel electrolyte material using Indium titanium oxide/polyethylene terephthalate(ITO/PET)flex-ible substrate for double-layer supercapacitors have been reported.The nanocomposite hydrogel composed of Arabic gum(AG),Acrylic acid(AA),reduced graphene oxide(RGO),and silver nanoparticles(AgNPs)was fab-ricated via a physical cross-linked polymerization reaction,in which the ascorbic acid was used as a reducing agent to generate AgNPs and to convert Graphene oxide(GO)to RGO during the polymerization reaction.The morphology and structural characteristics of nanocomposite hydrogel were investigated using atomic force microscopy(AFM),scanning electron microscope(SEM),Fourier transfer infrared(FTIR),and X-rayfluores-cence(XRF).Additionally,the effect of RGO and AgNPs on hydrogel stability was assessed through Thermogra-vimetric analysis(TGA)and differential scanning calorimetry(DSC),while its mechanical properties were studied using the nanoindentation test.Electrochemical impedance spectroscopy(EIS),and cyclic voltammetry(CV)were also conducted to study the electrochemical properties of the prepared hydrogel.The effects of AgNPs,RGO,and water content were all considered in the study of supercapacitor performance.The microstructural tests showed that the nanocomposite hydrogel has a relatively high swelling rate,which has a crucial effect on the capa-citance.Furthermore,the effects of increasing AgNP concentration and water content in the hydrogel matrix showed a significant improvement in its electrochemical performance,compared with that for Arabic gum poly acrylic acid(AGPAA)hydrogel itself,were the specific capacitance exhibited a significant enhancement,convert-ing from a low value to a substantially higher capacitance value.Moreover,when the nanocomposite hydrogel was used as the working electrode in an electrochemical cell with a hydrochloric acid(HCl)electrolyte solution,it exhibited good electrode performance.Additionally,using(ITO/PET)as aflexible substrate for nanocomposite hydrogel shows an improvement in their suitability for supercapacitor applications.Therefore,it is suggested that the fabricated hydrogel supercapacitor has potential applications in thefield of renewable and clean energy harvesting. 展开更多
关键词 SUPERCAPACITOR energy harvesting nanocomposite hydrogel reduced graphene oxide
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Assembly of functional carboxymethyl cellulose/polyethylene oxide/anatase TiO_(2) nanocomposites and tuning the dielectric relaxation, optical, and photoluminescence performances
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作者 Asmaa M.Ismail Abeer A.Reffaee Fawzy G.El Desouky 《Journal of Semiconductors》 EI CAS CSCD 2024年第7期26-38,共13页
Nanocomposite films consisting of carboxymethyl cellulose,polyethylene oxide(CMC/PEO),and anatase titanium diox-ide(TO)were produced by the use of sol-gel and solution casting techniques.TiO2 nanocrystals were effecti... Nanocomposite films consisting of carboxymethyl cellulose,polyethylene oxide(CMC/PEO),and anatase titanium diox-ide(TO)were produced by the use of sol-gel and solution casting techniques.TiO2 nanocrystals were effectively incorporated into CMC/PEO polymers,as shown by X-ray diffraction(XRD)and attenuated total reflectance fourier transform infrared(ATR-FTIR)analysis.The roughness growth is at high levels of TO nanocrystals(TO NCs),which means increasing active sites and defects in CMC/PEO.In differential scanning calorimetry(DSC)thermograms,the change in glass transition temperature(Tg)val-ues verifies that the polymer blend interacts with TO NCs.The increment proportions of TO NCs have a notable impact on the dielectric performances of the nanocomposites,as observed.The electrical properties of the CMC/PEO/TO nanocomposite undergo significant changes.The nanocomposite films exhibit a red alteration in the absorption edge as the concentration of TO NCs increases in the polymer blend.The decline in the energy gap is readily apparent as the weight percentage of TO NCs increases.The photoluminescence(PL)emission spectra indicate that the sites of the luminescence peak maximums show slight variation;peaks get wider,while their intensities decrease dramatically as the concentration of TO increases.These nanocomposite materials show potential for multifunctional applications including optoelectronics,antireflection coatings,pho-tocatalysis,light emitting diodes,and solid polymer electrolytes. 展开更多
关键词 anatase TiO_(2) CMC/PEO nanocomposites optical PHOTOLUMINESCENT electrical optoelectronics
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DLP printing of BT/HA nanocomposite ceramic scaffolds using low refractive index BT crystals
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作者 Ruixuan Xue Peimei Yuan +7 位作者 Bo Zhao Fei Jing Xuyuan Kou Wangyang Yue Yan wang Dongmei Wang Galhenage Asha Sewvandi Dengwei Hu 《Journal of Materiomics》 SCIE CSCD 2024年第5期1036-1048,共13页
Biological piezoelectric materials have significant potential for bone repair and energy harvesting owing to their excellent biocompatibility and piezoelectric effect.The BaTiO3/Ca10(PO4)6(OH)2(BT/HA)composite materia... Biological piezoelectric materials have significant potential for bone repair and energy harvesting owing to their excellent biocompatibility and piezoelectric effect.The BaTiO3/Ca10(PO4)6(OH)2(BT/HA)composite material is an outstanding representative of biological piezoelectric materials,which has not been individually designed using digital light processing(DLP)3D printing because of the large difference in the refractive index of its components.Therefore,in this work,double-sided-tooth plate-like BT crystals with high curvature were prepared via a hydrothermal process,and BT/HA ceramic slurries were grinded out using dispersed intermittent ball milling scheme,and BT/HA nanocomposite ceramic scaffolds were fabricated by DLP 3D printing technology.The nanostructure,dielectric properties,and piezoelectric energy harvesting performance of the BT/HA nanocomposite ceramic scaffolds were evaluated.The influences of different morphologies and contents for BT on the piezoelectric potential and stress distribution were analyzed based on a multi-physics coupling finite element simulation.The cell proliferation and adhesion abilities were investigated also.The BT/HA nanocomposite ceramic scaffolds present excellent dielectric properties,cell proliferation and adhesion abilities,and an open circuit voltage of 8 V during piezoelectric energy harvesting.The material properties and multi-physics coupling finite element analysis imply that the double-sided-tooth plate-like BT plays an important role for the fastness structure and electric field distribution in the BT/HA nanocomposite.Thus,this work provides a strategy for the application of the customized BT/HA nanocomposite ceramic scaffolds in new-generation orthopedic implants and biological energy harvesting. 展开更多
关键词 3D printing BT/HA nanocomposite ceramics Bio-piezoelectric scaffolds Energy harvesting
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Photocatalytic ozonation-based degradation of phenol by ZnO—TiO_(2)nanocomposites in spinning disk reactor
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作者 Xueqing Ren Jiahao Niu +5 位作者 Yan Li Lei Li Chao Zhang Qiang Guo Qiaoling Zhang Weizhou Jiao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第8期74-84,共11页
Spinning disk reactor(SDR)has emerged as a novel process intensification photocatalytic reactor,and it has higher mass transfer efficiency and photon utilization for the degradation of toxic organic pollutants by adva... Spinning disk reactor(SDR)has emerged as a novel process intensification photocatalytic reactor,and it has higher mass transfer efficiency and photon utilization for the degradation of toxic organic pollutants by advanced oxidation processes(AOPs).In this study,ZnO—TiO_(2)nanocomposites were prepared by solgel method,and coated on the disk of SDR by impregnation-pull-drying-calcination method.The performance of catalyst was characterized by X-ray diffraction,scanning electron microscope,X-ray photoelectron spectroscopy,photoluminescence and ultraviolet—visible diffuse reflectance spectroscopy.Photocatalytic ozonation in SDR was used to remove phenol,and various factors on degradation effect were studied in detail.The results showed that the rate of degradation and mineralization reached 100%and 83.4%under UV light irradiation after 50 min,compared with photocatalysis and ozonation,the removal rate increased by 69.3%and 34.7%,and mineralization rate increased by 56.7%and 62.9%,which indicated that the coupling of photocatalysis and ozonation had a synergistic effect.The radical capture experiments demonstrated that the active species such as photogenerated holes(h^(+)),hydroxyl radicals(·OH),superoxide radical(·O_(2)-)were responsible for phenol degradation,and·OH played a leading role in the degradation process,while h+and·O_(2)^(-)played a non-leading role. 展开更多
关键词 Spinning disk reactor Photocatalytic ozonation ZnO-TiO_(2)nanocomposites Advanced oxidation processes
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Phase field model for electric-thermal coupled discharge breakdown of polyimide nanocomposites under high frequency electrical stress
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作者 韩智云 李庆民 +3 位作者 李俊科 王梦溪 任瀚文 邹亮 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第2期114-124,共11页
In contrast to conventional transformers, power electronic transformers, as an integral component of new energy power system, are often subjected to high-frequency and transient electrical stresses, leading to heighte... In contrast to conventional transformers, power electronic transformers, as an integral component of new energy power system, are often subjected to high-frequency and transient electrical stresses, leading to heightened concerns regarding insulation failures. Meanwhile, the underlying mechanism behind discharge breakdown failure and nanofiller enhancement under high-frequency electrical stress remains unclear. An electric-thermal coupled discharge breakdown phase field model was constructed to study the evolution of the breakdown path in polyimide nanocomposite insulation subjected to high-frequency stress. The investigation focused on analyzing the effect of various factors, including frequency, temperature, and nanofiller shape, on the breakdown path of Polyimide(PI) composites. Additionally, it elucidated the enhancement mechanism of nano-modified composite insulation at the mesoscopic scale. The results indicated that with increasing frequency and temperature, the discharge breakdown path demonstrates accelerated development, accompanied by a gradual dominance of Joule heat energy. This enhancement is attributed to the dispersed electric field distribution and the hindering effect of the nanosheets. The research findings offer a theoretical foundation and methodological framework to inform the optimal design and performance management of new insulating materials utilized in high-frequency power equipment. 展开更多
关键词 dielectric discharge breakdown high frequency power electronic transformer polyimide nanocomposites phase field model
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Enhancing Defect-Induced Dipole Polarization Strategy of SiC@MoO_(3)Nanocomposite Towards Electromagnetic Wave Absorption
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作者 Ting Wang Wenxin Zhao +8 位作者 Yukun Miao Anguo Cui Chuanhui Gao Chang Wang Liying Yuan Zhongning Tian Alan Meng Zhenjiang Li Meng Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第12期406-426,共21页
Defect engineering in transition metal oxides semiconductors(TMOs)is attracting considerable interest due to its potential to enhance conductivity by intentionally introducing defects that modulate the electronic stru... Defect engineering in transition metal oxides semiconductors(TMOs)is attracting considerable interest due to its potential to enhance conductivity by intentionally introducing defects that modulate the electronic structures of the materials.However,achieving a comprehensive understanding of the relationship between micro-structures and electromagnetic wave absorption capabilities remains elusive,posing a substantial challenge to the advancement of TMOs absorbers.The current research describes a process for the deposition of a MoO_(3)layer onto SiC nanowires,achieved via electro-deposition followed by high-temperature calcination.Subsequently,intentional creation of oxygen vacancies within the MoO_(3)layer was carried out,facilitating the precise adjustment of electromagnetic properties to enhance the microwave absorption performance of the material.Remarkably,the SiC@MO-t4 sample exhibited an excellent minimum reflection loss of-50.49 dB at a matching thickness of 1.27 mm.Furthermore,the SiC@MO-t6 sample exhibited an effective absorption bandwidth of 8.72 GHz with a thickness of 2.81 mm,comprehensively covering the entire Ku band.These results not only highlight the pivotal role of defect engineering in the nuanced adjustment of electromagnetic properties but also provide valuable insight for the application of defect engineering methods in broadening the spectrum of electromagnetic wave absor ption effectiveness.SiC@MO-t samples with varying concentrations of oxygen vacancies were prepared through in-situ etching of the SiC@MoO_(3)nanocomposite.The presence of oxygen vacancies plays a crucial role in adjusting the band gap and local electron distribution,which in turn enhances conductivity loss and induced polarization loss capacity.This finding reveals a novel strategy for improving the absorption properties of electromagnetic waves through defect engineering. 展开更多
关键词 Defect engineering Oxygen vacancies SiC@MoO_(3)nanocomposite Electromagnetic wave absorption Induced dipole polarization
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Synergism of Zinc Oxide/Organoclay-Loaded Poly(lactic acid) Hybrid Nanocomposite Plasticized by Triacetin for Sustainable Active Food Packaging
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作者 Ponusa Songtipya Thummanoon Prodpran +1 位作者 Ladawan Songtipya Theerarat Sengsuk 《Journal of Renewable Materials》 EI CAS 2024年第5期951-967,共17页
The synergistic effect of organoclay(OC)and zinc oxide(ZnO)nanoparticles on the crucial properties of poly(lactic acid)(PLA)nanocompositefilms was systematically investigated herein.After their incorporation into PLA v... The synergistic effect of organoclay(OC)and zinc oxide(ZnO)nanoparticles on the crucial properties of poly(lactic acid)(PLA)nanocompositefilms was systematically investigated herein.After their incorporation into PLA via the solvent casting technique,the water vapor barrier property of the PLA/OC/ZnOfilm improved by a maximum of 86%compared to the neat PLAfilm without the deterioration of Young’s modulus or the tensile strength.Moreover,thefilm’s self-antibacterial activity against foodborne pathogens,including gram-negative(Escherichia coli,E.coli)and gram-positive(Staphylococcus aureus,S.aureus)bacteria,was enhanced by a max-imum of approximately 98–99%compared to the neat PLAfilm.Furthermore,SEM images revealed the homo-geneous dispersion of both nano-fillers in the PLA matrix.However,the thermal stability of thefilm decreased slightly after the addition of the OC and ZnO.Thefilm exhibited notable light barrier properties in the UV-Vis range.Moreover,the incorporation of a suitable biodegradable plasticizer significantly decreased the Tg and notably enhanced theflexibility of the nanocompositefilm by increasing the elongation at break approxi-mately 1.5-fold compared to that of the neat PLAfilm.This contributes to its feasibility as an active food packa-ging material. 展开更多
关键词 Poly(lactic acid)nanocomposite ORGANOCLAY zinc oxide barrier property antibacterial activity active food packaging
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Nanocomposite superstructure of zinc oxide mesocrystal/reduced graphene oxide with effective photoconductivity
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作者 Ahmad A.Ahmad Qais M.Al-Bataineh Ahmad B.Migdadi 《Journal of Semiconductors》 EI CAS CSCD 2024年第11期81-88,共8页
Metal oxide mesocrystals are the alignment of metal oxide nanoparticles building blocks into the ordered superstructure,which have potentially tunable optical,electronic,and electrical properties suitable for practica... Metal oxide mesocrystals are the alignment of metal oxide nanoparticles building blocks into the ordered superstructure,which have potentially tunable optical,electronic,and electrical properties suitable for practical applications.Herein,we report an effective method for synthesizing mesocrystal zinc oxide nanorods(ZnONRs).The crystal,surface,and internal structures of the zinc oxide mesocrystals were fully characterized.Mesocrystal zinc oxide nanorods/reduced graphene oxide(ZnONRs/rGO)nanocomposite superstructure were synthesized also using the hydrothermal method.The crystal,surface,chemical,and internal structures of the ZnONRs/rGO nanocomposite superstructure were also fully characterized.The optical absorption coefficient,bandgap energy,band structure,and electrical conductivity of the ZnONRs/rGO nanocomposite superstructure were investigated to understand its optoelectronic and electrical properties.Finally,the photoconductivity of the ZnONRs/rGO nanocomposite superstructure was explored to find the possibilities of using this nanocomposite superstructure for ultraviolet(UV)photodetection applications.Finally,we concluded that the ZnONRs/rGO nanocomposite superstructure has high UV sensitivity and is suitable for UV detector applications. 展开更多
关键词 MESOCRYSTALS SUPERSTRUCTURE mesocrystal zinc oxide nanorods(ZnONRs) meduced graphene oxide(rGO) ZnONRs/rGO nanocomposite superstructure UV photodetection
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Removal of Dye Using Lignin-Based Biochar/Poly(ester amide urethane)Nanocomposites from Contaminated Wastewater
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作者 Annesha Kar Niranjan Karak 《Journal of Renewable Materials》 EI CAS 2024年第9期1507-1540,共34页
The pursuit of incorporating eco-friendly reinforcing agents in polymer composites has accentuated the exploration of various natural biomass-derived materials.The burgeoning environmental crisis spurred by the discha... The pursuit of incorporating eco-friendly reinforcing agents in polymer composites has accentuated the exploration of various natural biomass-derived materials.The burgeoning environmental crisis spurred by the discharge of synthetic dyes into wastewater has catalyzed the search for effective and sustainable treatment technologies.Among the various sorbent materials explored,biochar,being renewable,has gained prominence due to its excellent adsorption properties and environmental sustainability.It has also emerged as a focal point for its potential to replace other conventional reinforcing agents,viz.,fumed silica,aluminum oxide,treated clays,etc.This study introduces a novel class of polymer nanocomposites comprising of lignin-based biochar particles and poly(ester amide urethane)matrix via a feasible method.The structural evaluation of these nanocomposites was accomplished using Fourier-transform infrared spectroscopy,X-ray photoelectron spectroscopy,and powder X-ray diffraction.The polymer nanocomposites exhibited superior mechanical properties with an increment in tensile strength factor by 45%in comparison to its pristine matrix,along with an excellent toughness value of 90.22 MJm^(−3)at a low loading amount of only 1 wt%.The composites showed excellent improvement in thermal properties with a sharp rise in the glass transition temperature(Tg)value from−28.15℃to 84℃,while also championing sustainability through inherent biodegradability attributes.Beyond their structural prowess,these polymer nanocomposites demonstrated excellent potential as adsorbents,displaying efficient removal of malachite green and tartrazine dyes from aqueous systems with a removal efficiency of 87.25%and 73.98%,respectively.The kinetics study revealed the pseudo second order model to be the precision tool to assess the dye removal study.Complementing this,the Langmuir adsorption isotherm provided a framework to assess the sorption features of the polymer nanocomposites.Overall,these renewable biochar integrated polymer matrices boast remarkable recovery capabilities up to seven cycles of usage with an excellent dye recovery percentage of 95.21%for the last cycle,thereby defining sustainability as well as economic feasibility. 展开更多
关键词 Reinforcing agents BIOCHAR polymer nanocomposites poly(ester amide urethane) dye removal adsorption kinetics pseudo second order model langmuir isotherm
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基于YOLOv7的木材缺陷检测模型Wood-Net的研究 被引量:2
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作者 王正 江莺 +3 位作者 严飞 孙佑鹏 张园 张柳磊 《林业工程学报》 CSCD 北大核心 2024年第1期132-140,共9页
为改善利用人工方式识别木材缺陷存在的效率低、人工成本高的问题,同时实现在木材加工过程中使用新兴方式对不同的缺陷进行快速准确检测以提高木材利用率,针对现有的目标检测网络在木材缺陷检测方面存在诸如检测精度低、报错率高以及识... 为改善利用人工方式识别木材缺陷存在的效率低、人工成本高的问题,同时实现在木材加工过程中使用新兴方式对不同的缺陷进行快速准确检测以提高木材利用率,针对现有的目标检测网络在木材缺陷检测方面存在诸如检测精度低、报错率高以及识别种类少等局限,设计了用于木材缺陷检测的深度学习网络Wood-Net。Wood-Net将注意力机制ECA(efficient channel attention module)引入YOLOv7的主干网络,以便更好地区分木材缺陷之间的细微差别;将ECA与Res2Net结合后形成ECA-Res2Net模块,ECA-Res2Net模块克服了单纯的Res2Net跨通道交流能力不足的问题,增强了网络对更细粒度特征的提取能力;将ECA-Res2Net模块与SPPCSPC(spatial pyramid pooling and channel spatial pyramid convolution)并联形成ResSPPCSPC模块,增加了描述图像本身特征数量的能力,由此构成新方法Wood-Net。本研究将准确度、召回值、mAP@0.5以及mAP@0.5∶mAP@0.95 4个数值作为系统性能的评价指标。利用自建数据集训练Wood-Net,得到试验数据。试验结果表明:Wood-Net模型比基准模型YOLOv7在木材优选上精确率提高了4.52%,mAP@0.5∶mAP@0.95提高了6.62%;比基准模型YOLOv5s在木材优选上精确率提高了6.79%,mAP@0.5∶mAP@0.95提高了5.67%。ECA注意力机制能够有效提升E-ELAN的通道间信息交互能力;Res2Net模块具有很强的细粒度特征提取能力,在网络中引入Res2Net模块后,网络各项性能指标收敛速度快,在Res2Net中加入ECA后能够使单纯的Res2Net考虑多通道特征之间的关系,完成信息融合,提高检测性能。 展开更多
关键词 wood-Net 木材优选 ECA-Res2Net ECA Res2Net
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Magnesium-based nanocomposites:A review from mechanical,creep and fatigue properties 被引量:5
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作者 S.Abazari A.Shamsipur +5 位作者 H.R.Bakhsheshi-Rad J.W.Drelich J.Goldman S.Sharif A.F.Ismail M.Razzaghi 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第8期2655-2687,共33页
The addition of nanoscale additions to magnesium(Mg)based alloys can boost mechanical characteristics without noticeably decreasing ductility.Since Mg is the lightest structural material,the Mg-based nanocomposites(NC... The addition of nanoscale additions to magnesium(Mg)based alloys can boost mechanical characteristics without noticeably decreasing ductility.Since Mg is the lightest structural material,the Mg-based nanocomposites(NCs)with improved mechanical properties are appealing materials for lightweight structural applications.In contrast to conventional Mg-based composites,the incorporation of nano-sized reinforcing particles noticeably boosts the strength of Mg-based nanocomposites without significantly reducing the formability.The present article reviews Mg-based metal matrix nanocomposites(MMNCs)with metallic and ceramic additions,fabricated via both solid-based(sintering and powder metallurgy)and liquid-based(disintegrated melt deposition)technologies.It also reviews strengthening models and mechanisms that have been proposed to explain the improved mechanical characteristics of Mg-based alloys and nanocomposites.Further,synergistic strengthening mecha-nisms in Mg matrix nanocomposites and the dominant equations for quantitatively predicting mechanical properties are provided.Furthermore,this study offers an overview of the creep and fatigue behavior of Mg-based alloys and nanocomposites using both traditional(uniaxial)and depth-sensing indentation techniques.The potential applications of magnesium-based alloys and nanocomposites are also surveyed. 展开更多
关键词 Magnesium-based nanocomposites Nanoreinforcement Strengthening mechanisms Creep properties Fatigue properties
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The roles of polymer-graphene interface and contact resistance among nanosheets in the effective conductivity of nanocomposites 被引量:1
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作者 Y.ZARE K.Y.RHEE 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第11期1941-1956,共16页
The effective conductivity of graphene-based nanocomposites is suggested by the characteristics of polymer-filler interfacial areas as well as the contact resistance between the neighboring nanosheets.The interfacial ... The effective conductivity of graphene-based nanocomposites is suggested by the characteristics of polymer-filler interfacial areas as well as the contact resistance between the neighboring nanosheets.The interfacial properties are expressed by the effective levels of the inverse aspect ratio and the filler volume fraction.Moreover,the resistances of components in the contact regions are used to define the contact resistance,which inversely affects the effective conductivity.The obtained model is utilized to predict the effective conductivity for some examples.The discrepancy of the effective conductivity at various ranks of all factors is clarified.The interfacial conductivity directly controls the effective conductivity,while the filler conductivity plays a dissimilar role in the effective conductivity,due to the incomplete interfacial adhesion.A high operative conductivity is also achieved by small contact distances and high interfacial properties.Additionally,big contact diameters and little tunnel resistivity decrease the contact resistance,thus enhancing the effective conductivity. 展开更多
关键词 polymer nanocomposite operative conductivity GRAPHENE interfacial property contact region
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