Studies on Benign Working Pairs for Adsorption Refrigeration

Water and ethanol were selected as refrigerants, 13x molecular sieve, silica gel, activated carbon and adsorbents NA and NB prepared by authors were selected as adsorbents, and the performance of adsorption working pairs in adsorption refrigeration system was studied. The adsorption isotherms of adsorbents (NA and NB) were obtained by high vacuum gravimetric method. Desorption properties of adsorbents were analyzed and compared by thermal analysis method. The performance parameters of adsorption refrigerat...

Vapor-Liquid Equilibrium Prediction of Ammonia-Ionic Liquid Working Pairs of Absorption Cycle Using UNIFAC Model

On the basis of reported experimental vapor-liquid equilibrium （VLE） data of NH3-1-ethyl-3-methylimidazolium acetate （NH3-[Emim]Ac）, NH3-1-butyl-3-methylimidazolium tetrafluoroborate （NH3-[Bmim][BF4]）, NH3-1,3-dimethylimidazolium dimethyl phosphate （NH3-[Mmim]DMP） and NH3-1-ethyl-3-methylimidazolium ethylsulfate （NH3-[Emim]EtOSO3） binary systems, the interaction parameters of 14 new groups have been regressed by means of the UNIFAC model. To validate the reliability of the method, these parameters have been used to calculate the VLE data with the average relative deviation of pressures of less than 9.35%. The infinite dilution activity coefficient （ γ1∞ ） and the absorption potential （ φ1 ） are important evaluation criterions of the affinity between working pair species of the absorption cycle. The UNIFAC model is implemented to predict the values of and φ1 of t6 sets of NH3-ionic liquid （1L） systems. The work found that the φ1 gradually increases following the impact order： φ1（[Cnmim][BF4]）〈φ1（[Cnmim]EtOSO3）〈φ1（[Cnmim]DMP）〈φ1（[Cnmim]Ac） （n= 1, 2, 3, … ） at a given cation of IL species and constant temperature, and φ1（[Mmim]X）〈φ1（[Emim]X）〈φ1（[Pmim]X）〈 φ1（[Bmim]X）（X= Ac, [BF4], DMP or EtOSO3） at a given anion of IL species and constant temperature. Furthermore, the φ1 gradually increases with increasing temperature. Then, it could be concluded that the working pair NH3-[BmimlAc has the best potential research value relatively.

Phase Equilibrium Characteristics of CO_(2)and Ionic Liquids with[FAP]-Anion Used for Absorption-Compression Refrigeration Working Pairs

The study of the phase equilibrium characteristics of CO_(2)-ionic liquids(ILs)as new absorption-compression type refrigeration working pairs is of great importance.Three kinds of ILs,i.e.,[emim][FAP],[bmim][FAP]and[hmim][FAP],were chosen as potential absorbents.The solubility of CO_(2)in these ILs was measured experimentally within 0 to 5.0 MPa at temperatures of 293.15 K to 333.15 K,and the effects of temperature,pressure,IL anion and cation structure and stirring action on CO_(2)solubility were also discussed and analyzed.The results showed that the longer alkyl chains in an identical IL family,the alkyl fluoride group in IL anions and the stirring action by a magnetic stirrer had positive effects on the solubility of CO_(2).In the three ILs,[hmim][FAP]possessed the best performance for CO_(2)absorption;the solubility of CO_(2)reached 0.7641 at a pressure of 5 MPa and temperature of 293.15 K,the maximum solubility measured in this work.The CO_(2)-[hmim][FAP]binary mixture is recommended as a potentially applicable working pair for CO_(2)absorption-compression refrigeration systems.

Comparative Study on Two-Stage Absorption Refrigeration Systems with Different Working Pairs

The objective of this paper is to present a simulation study on the two-stage absorption refrigeration systems of 2.5 kW capacity using LiBr-H2O,NH3-H2O and R124-DMAC as working pairs.Under the design condition that the generating,absorbing,evaporating and condensing temperatures are 75℃,45℃,5℃and 40℃,respectively,the high and low pressure side solution circulation ratios and the coefficient of performance(COP)for the systems are calculated.Then the influences of medium,generating,absorbing,evaporating and condensing temperatures on system performances are analyzed.The results show that under the design condition,the COP of the LiBr-H2Osystem can reach 0.49,superior to those of the NH3-H2O and R124-DMAC systems,which are 0.32 and 0.31,respectively.Furthermore,the medium temperature for higher COP lies in an interval of 64-67℃for the LiBr-H2O.NH3-H2O and R124-DMAC systems.High generating temperature and low absorbing temperature can decrease the high and low pressure side solution circulation ratios,and can also increase the COP.High evaporating temperature can decrease the low pressure side solution circulation ratio and increase the COP.Low condensing temperature can decrease the high pressure side solution circulation ratio and increase the COP.

An Investigation into Pair Work and Group Work Using Corpus

This English teaching in language classroom essay is based on an investigation into the use of pair work and group work in middle school China by means of a corpus to throw some light on the interaction patterns of our English teaching

Vapor Pressure Measurement of Water+1,3-Dimethylimidazolium Tetrafluoroborate System

In absorption cycles,ionic liquid(IL)1,3-dimethylimidazolium tetrafluoroborate([Dmim]BF4)may be a promising absorbent of working pair using water as refrigerant.The vapor pressures of[Dmim]BF4 aqueous solution were measured with the boiling-point method in the temperature range from 312.25 to 403.60 K and in the mass concentration range of 65%to 90%of[Dmim]BF4.The experimental data were correlated with an Antoine-type equation and the Non-Random Two-Liquid(NRTL)model,and the average absolute deviations between the experimental and calculated values were 1.06%and 1.15%,respectively.For the[Dmim]BF4 aqueous solution,the experimental vapor pressures show negative deviations from the calculated data with Raoult's law.For higher mass concentration of the IL,the deviation is more negative.In addition,the vapor pressures,the hydrophilicity and the solubility of[Dmim]BF4 aqueous solutions were compared with those of[Dmim]Cl aqueous solutions and [Bmim]BF4 aqueous solutions at IL-mole fraction of 0.20.

Who Is to Work With Whom When It Comes to Pair Work？ A Learner＇s Perspective

The present paper reports on a small-scale project that investigates two main questions： （1） whether EFL （English as a Foreign Language） learners prefer working in pairs or small groups; and （2） what factors they take into consideration when they are free to choose their partners in pair work activities. To investigate the research questions, a questionnaire was developed and distributed among 96 Iranian intermediate EFL students who participated in the study on a voluntary basis. The findings showed that 45% of the participants preferred pair work, 26% preferred group work, and 29% reported it made no difference to them. The results also indicated that learners select their partners based on four factors： age, proficiency, familiarity and language learning motivation. Gender and popularity with the whole class were among the factors that the participants did not pay attention to when opting for a partner.

Absorption heat pump for waste heat reuse： current states and future development

Absorption heat pump attracts increasing attention due to its advantages in low grade thermal energy utilization. It can be applied for waste heat reuse to save energy consumption, reduce environment pollution, and bring considerable economic benefit. In this paper, three important aspects for absorption heat pump for waste heat reuse are reviewed. In the first part, different absorption heat pump cycles are classified and introduced. Absorption heat pumps for heat amplification and absorp- tion heat transformer for temperature upgrading are included. Both basic single effect cycles and advanced cycles for better performance are introduced. In the second part, different working pairs, including the water based working pairs, ammonia based working pairs, alcohol based working pairs, and halogenated hydrocarbon based working pairs, for absorption heat pump are classified based on the refrigerant. In the third part, the applications of the absorption heat pump and absorption heat transformer for waste heat reuse in different industries are introduced. Based on the reviews in the three aspects, essential summary and future perspective are presented at last.