Large size single crystals of SO4have been successfully grown by a hydrothermalprocess at 160℃for 24h, using CuSO4·5H2O, ethylene diamine and reductive Zn powder as reactants. The diameters of the single crystal...Large size single crystals of SO4have been successfully grown by a hydrothermalprocess at 160℃for 24h, using CuSO4·5H2O, ethylene diamine and reductive Zn powder as reactants. The diameters of the single crystals are range from 0.5mm to 1mm, and lengths reach up to 20mm. The single crystals were characterized by XRD analysis, FTIR and UV Vis spectrum absorption measurements. The single crystal was confirmed to beSO4 by performing powder diffraction of the single crystal. X ray diffraction of the single crystals shows (100) face to be cleavage face. The diffraction peaks are sharp and rockingcurve for 200 diffraction has a narrow FWHM (the full width at half maximum), which indicate the single crystal of SO4 is perfect with less lattice distortion and defects. The single crystal appears transparent,and has constant weak absorption in UV Vis spectrum region,whichcould be used as a novel optical crystal material.展开更多
A Zn(II) coordination polymer [Zn(pht)(pzH)2]n (where pht2-=dianion of o-phthalic acid, pzH=pyrazole) has been synthesized and the structure was determined by X-ray diffraction. The complex crystallizes in the monocli...A Zn(II) coordination polymer [Zn(pht)(pzH)2]n (where pht2-=dianion of o-phthalic acid, pzH=pyrazole) has been synthesized and the structure was determined by X-ray diffraction. The complex crystallizes in the monoclinic space group P21/c, a=0.821 39(10) nm, b=1.662 2(2) nm, c=1.156 42(14) nm, β=100.349(2)°, V=1.553 2(3) nm3, Z=4. Both carboxylate groups of the phthalate dianion coordinated in a monodentate mode bridged two Zn(II) atoms forming the structure of 1-D chain. The pyrazole ligands play two different roles: one only coordinates the metal atom and the other joins the coordination polymer into a 2-D sheet via N-H...O and C-H...O hydrogen bonds besides the coordination property. A blue photoluminescence peak at 435 nm was observed in solid state at room temperature. CCDC: 227946.展开更多
文摘Large size single crystals of SO4have been successfully grown by a hydrothermalprocess at 160℃for 24h, using CuSO4·5H2O, ethylene diamine and reductive Zn powder as reactants. The diameters of the single crystals are range from 0.5mm to 1mm, and lengths reach up to 20mm. The single crystals were characterized by XRD analysis, FTIR and UV Vis spectrum absorption measurements. The single crystal was confirmed to beSO4 by performing powder diffraction of the single crystal. X ray diffraction of the single crystals shows (100) face to be cleavage face. The diffraction peaks are sharp and rockingcurve for 200 diffraction has a narrow FWHM (the full width at half maximum), which indicate the single crystal of SO4 is perfect with less lattice distortion and defects. The single crystal appears transparent,and has constant weak absorption in UV Vis spectrum region,whichcould be used as a novel optical crystal material.
文摘A Zn(II) coordination polymer [Zn(pht)(pzH)2]n (where pht2-=dianion of o-phthalic acid, pzH=pyrazole) has been synthesized and the structure was determined by X-ray diffraction. The complex crystallizes in the monoclinic space group P21/c, a=0.821 39(10) nm, b=1.662 2(2) nm, c=1.156 42(14) nm, β=100.349(2)°, V=1.553 2(3) nm3, Z=4. Both carboxylate groups of the phthalate dianion coordinated in a monodentate mode bridged two Zn(II) atoms forming the structure of 1-D chain. The pyrazole ligands play two different roles: one only coordinates the metal atom and the other joins the coordination polymer into a 2-D sheet via N-H...O and C-H...O hydrogen bonds besides the coordination property. A blue photoluminescence peak at 435 nm was observed in solid state at room temperature. CCDC: 227946.
