TIG welding-brazing process with high frequency induction hot wire technology was presented to create joints between 5A06 aluminum alloy and SUS32! stainless steel using ER1100 filler wire with different temperature. ...TIG welding-brazing process with high frequency induction hot wire technology was presented to create joints between 5A06 aluminum alloy and SUS32! stainless steel using ER1100 filler wire with different temperature. The joints were evaluated by mechanical test and microstructural analyses. The welding procedure using hot fiUer wire （400 ℃ ） significantly increases strength stability by 71% and average value of tensile strength by 30. 8 % of the joints, compared with cold wire. The research of microstructures in interfaces and welded seams reveals that using 400 ℃ hot filler wire can decrease the thickness of intermetallic compounds （ IMCs ） from 6 to 3.5 txm approximately, which is the main reason of mechanical property improvement.展开更多
A protecting zinc and aluminum coating on the surface of AZ91D magnesium alloys was obtained by thermal spraying to improve the corrosion and wear resistance performances. In order to enhance the combination between m...A protecting zinc and aluminum coating on the surface of AZ91D magnesium alloys was obtained by thermal spraying to improve the corrosion and wear resistance performances. In order to enhance the combination between magnesium alloy matrix and zinc and aluminum coating, the sample was heat-treated at 300℃for 2 h, then, the cross-section patterns, XRD pattern, micro-hardness, wear and corrosion resistance abilities were researched. The results indicate that the interface between the coating and substrate is metallurgical bond, and a transitional fusion layer is formed by diffusion. The micro-scale abrasion test and polarization test in 3% NaCl solution show that the diffusion-treated specimen has better wear and corrosion resistance performances in comparison with the undiffusion-treated and substrate magnesium alloys; in addition, it has relatively higher micro-hardness than the undiffusion-treated magnesium alloys.展开更多
Zinc phosphate coatings formed on 6061-Al alloy, after dipping in phosphating solutions containing different amounts of Y2O3（yttrium oxide）, were studied by scanning electron microscopy （SEM）, X-ray diffraction （...Zinc phosphate coatings formed on 6061-Al alloy, after dipping in phosphating solutions containing different amounts of Y2O3（yttrium oxide）, were studied by scanning electron microscopy （SEM）, X-ray diffraction （XRD） and electrochemical measurements. Significant variations in the morphology and corrosion resistance afforded by zinc phosphate coating were especially observed as Y2O3 in phosphating solution varied from 0 to 40 mg/L. The addition of Y2O3 changed the initial potential of the interface between aluminum alloy substrate and phosphating solution and increased the number of nucleation sites. The phosphate coating thereby was less porous structure and covered the surface of aluminum alloy completely within short phosphating time. Phosphate coating was mainly composed of Zn3（PO4）2·4H2O （hopeite） and AlPO4（aluminum phosphate）. Y2O3, as an additive of phosphatization, accelerated precipitation and refined the gain size of phosphate coating. The corrosion resistance of zinc phosphate coating in 3% NaCl solution was improved as shown by polarization measurement. In the present research, the optimal amount of Y2O3 was 10-20 mg/L, and the optimal phosphating time was 600 s.展开更多
Zn-Mg alloy coatings were obtained by physical vapor deposition （PVD） on electroplated steel sheets. Study on the formation of intermetallic phases in the coatings was conducted through the use of X-ray diffraction ...Zn-Mg alloy coatings were obtained by physical vapor deposition （PVD） on electroplated steel sheets. Study on the formation of intermetallic phases in the coatings was conducted through the use of X-ray diffraction （XRD） ,scanning electron microscope （SEM） and glow discharge optical emission spectrometry （GDOES）. It is found that MgZn2 is the main Zn-Mg alloy phase formed after heat treatment. The formation of Mg-Zn intermetallic phases is controlled not only by thermodynamics, but also by kinetics. MgZn2 has different morphologies, such as laminar structure,porous structure and floc-like structure,which are mainly determined by the annealing temperature. Obvious diffusion of Mg starts at 350 ℃, and the diffusion of iron increases significantly when the temperature is elevated to 380℃.展开更多
Pre-painted steel is one of the most important structural material of the 20th century well known for its excellent corrosion resistance and wide ranging applications.A typical pre-painted steel usually consists of a ...Pre-painted steel is one of the most important structural material of the 20th century well known for its excellent corrosion resistance and wide ranging applications.A typical pre-painted steel usually consists of a layer of metal coating system,preferably zinc or zinc alloy coating and a combination of layers of inorganic - organic coatings usually referred to as paint system.The corrosion resistance of the metal coating as well as the paint system may vary considerably based on their composition and the environment.For optimal corrosion performance of pre-painted steel,a judicious selection of both metal and inorganic-organic coating systems are essential.This paper reviews different types of possible corrosion issues in pre-painted steels and methods to optimise their performance.展开更多
基金Acknowledgement The authors would like to appreciate the financial support from the National Natural Science Foundation of China （Grant No. 50874033 ）.
文摘TIG welding-brazing process with high frequency induction hot wire technology was presented to create joints between 5A06 aluminum alloy and SUS32! stainless steel using ER1100 filler wire with different temperature. The joints were evaluated by mechanical test and microstructural analyses. The welding procedure using hot fiUer wire （400 ℃ ） significantly increases strength stability by 71% and average value of tensile strength by 30. 8 % of the joints, compared with cold wire. The research of microstructures in interfaces and welded seams reveals that using 400 ℃ hot filler wire can decrease the thickness of intermetallic compounds （ IMCs ） from 6 to 3.5 txm approximately, which is the main reason of mechanical property improvement.
基金Projects(2005BB4079, 2004BA4002) supported by the Natural Science Foundation of Chongqing City,China
文摘A protecting zinc and aluminum coating on the surface of AZ91D magnesium alloys was obtained by thermal spraying to improve the corrosion and wear resistance performances. In order to enhance the combination between magnesium alloy matrix and zinc and aluminum coating, the sample was heat-treated at 300℃for 2 h, then, the cross-section patterns, XRD pattern, micro-hardness, wear and corrosion resistance abilities were researched. The results indicate that the interface between the coating and substrate is metallurgical bond, and a transitional fusion layer is formed by diffusion. The micro-scale abrasion test and polarization test in 3% NaCl solution show that the diffusion-treated specimen has better wear and corrosion resistance performances in comparison with the undiffusion-treated and substrate magnesium alloys; in addition, it has relatively higher micro-hardness than the undiffusion-treated magnesium alloys.
基金supported by the Natural Science Foundation of Henan Province (200510476009)
文摘Zinc phosphate coatings formed on 6061-Al alloy, after dipping in phosphating solutions containing different amounts of Y2O3（yttrium oxide）, were studied by scanning electron microscopy （SEM）, X-ray diffraction （XRD） and electrochemical measurements. Significant variations in the morphology and corrosion resistance afforded by zinc phosphate coating were especially observed as Y2O3 in phosphating solution varied from 0 to 40 mg/L. The addition of Y2O3 changed the initial potential of the interface between aluminum alloy substrate and phosphating solution and increased the number of nucleation sites. The phosphate coating thereby was less porous structure and covered the surface of aluminum alloy completely within short phosphating time. Phosphate coating was mainly composed of Zn3（PO4）2·4H2O （hopeite） and AlPO4（aluminum phosphate）. Y2O3, as an additive of phosphatization, accelerated precipitation and refined the gain size of phosphate coating. The corrosion resistance of zinc phosphate coating in 3% NaCl solution was improved as shown by polarization measurement. In the present research, the optimal amount of Y2O3 was 10-20 mg/L, and the optimal phosphating time was 600 s.
文摘Zn-Mg alloy coatings were obtained by physical vapor deposition （PVD） on electroplated steel sheets. Study on the formation of intermetallic phases in the coatings was conducted through the use of X-ray diffraction （XRD） ,scanning electron microscope （SEM） and glow discharge optical emission spectrometry （GDOES）. It is found that MgZn2 is the main Zn-Mg alloy phase formed after heat treatment. The formation of Mg-Zn intermetallic phases is controlled not only by thermodynamics, but also by kinetics. MgZn2 has different morphologies, such as laminar structure,porous structure and floc-like structure,which are mainly determined by the annealing temperature. Obvious diffusion of Mg starts at 350 ℃, and the diffusion of iron increases significantly when the temperature is elevated to 380℃.
文摘Pre-painted steel is one of the most important structural material of the 20th century well known for its excellent corrosion resistance and wide ranging applications.A typical pre-painted steel usually consists of a layer of metal coating system,preferably zinc or zinc alloy coating and a combination of layers of inorganic - organic coatings usually referred to as paint system.The corrosion resistance of the metal coating as well as the paint system may vary considerably based on their composition and the environment.For optimal corrosion performance of pre-painted steel,a judicious selection of both metal and inorganic-organic coating systems are essential.This paper reviews different types of possible corrosion issues in pre-painted steels and methods to optimise their performance.
