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Dietary supplementation of zinc oxide modulates intestinal functionality during the post-weaning period in clinically healthy piglets
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作者 Dirkjan Schokker Soumya K.Kar +3 位作者 Els Willems Alex Bossers Ruud A.Dekker Alfons J.M.Jansman 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2024年第1期313-328,共16页
Background To improve our understanding of host and intestinal microbiome interaction,this research investigated the effects of a high-level zinc oxide in the diet as model intervention on the intestinal microbiome an... Background To improve our understanding of host and intestinal microbiome interaction,this research investigated the effects of a high-level zinc oxide in the diet as model intervention on the intestinal microbiome and small intestinal functionality in clinically healthy post-weaning piglets.In study 1,piglets received either a high concentration of zinc(Zn)as zinc oxide(Zn O,Zn,2,690 mg/kg)or a low Zn concentration(100 mg/kg)in the diet during the post weaning period(d 14–23).The effects on the piglet's small intestinal microbiome and functionality of intestinal tissue were investigated.In study 2,the impact of timing of the dietary zinc intervention was investigated,i.e.,between d 0–14 and/or d 14–23 post weaning,and the consecutive effects on the piglet's intestinal functionality,here referring to microbiota composition and diversity and gene expression profiles.Results Differences in the small intestinal functionality were observed during the post weaning period between piglets receiving a diet with a low or high concentration Zn O content.A shift in the microbiota composition in the small intestine was observed that could be characterized as a non-pathological change,where mainly the commensals inter-changed.In the immediate post weaning period,i.e.,d 0–14,the highest number of differentially expressed genes(DEGs)in intestinal tissue were observed between animals receiving a diet with a low or high concentration Zn O content,i.e.,23 DEGs in jejunal tissue and 11 DEGs in ileal tissue.These genes are involved in biological processes related to immunity and inflammatory responses.For example,genes CD59 and REG3G were downregulated in the animals receiving a diet with a high concentration Zn O content compared to low Zn O content in both jejunum and ileum tissue.In the second study,a similar result was obtained regarding the expression of genes in intestinal tissue related to immune pathways when comparing piglets receiving a diet with a high concentration Zn O content compared to low Zn O content.Conclusions Supplementing a diet with a pharmaceutical level of Zn as Zn O for clinically healthy post weaning piglets influences various aspects intestinal functionality,in particular in the first two weeks post-weaning.The model intervention increased both the alpha diversity of the intestinal microbiome and the expression of a limited number of genes linked to the local immune system in intestinal tissue.The effects do not seem related to a direct antimicrobial effect of Zn O. 展开更多
关键词 Immune system Intestinal functionality MICROBIOTA PIGLETS zinc oxide
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Nanocomposite superstructure of zinc oxide mesocrystal/reduced graphene oxide with effective photoconductivity
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作者 Ahmad A.Ahmad Qais M.Al-Bataineh Ahmad B.Migdadi 《Journal of Semiconductors》 EI CAS CSCD 2024年第11期81-88,共8页
Metal oxide mesocrystals are the alignment of metal oxide nanoparticles building blocks into the ordered superstructure,which have potentially tunable optical,electronic,and electrical properties suitable for practica... Metal oxide mesocrystals are the alignment of metal oxide nanoparticles building blocks into the ordered superstructure,which have potentially tunable optical,electronic,and electrical properties suitable for practical applications.Herein,we report an effective method for synthesizing mesocrystal zinc oxide nanorods(ZnONRs).The crystal,surface,and internal structures of the zinc oxide mesocrystals were fully characterized.Mesocrystal zinc oxide nanorods/reduced graphene oxide(ZnONRs/rGO)nanocomposite superstructure were synthesized also using the hydrothermal method.The crystal,surface,chemical,and internal structures of the ZnONRs/rGO nanocomposite superstructure were also fully characterized.The optical absorption coefficient,bandgap energy,band structure,and electrical conductivity of the ZnONRs/rGO nanocomposite superstructure were investigated to understand its optoelectronic and electrical properties.Finally,the photoconductivity of the ZnONRs/rGO nanocomposite superstructure was explored to find the possibilities of using this nanocomposite superstructure for ultraviolet(UV)photodetection applications.Finally,we concluded that the ZnONRs/rGO nanocomposite superstructure has high UV sensitivity and is suitable for UV detector applications. 展开更多
关键词 MESOCRYSTALS SUPERSTRUCTURE mesocrystal zinc oxide nanorods(ZnONRs) meduced graphene oxide(rGO) ZnONRs/rGO nanocomposite superstructure UV photodetection
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Revealing the role of calcium ion intercalation of hydrated vanadium oxides for aqueous zinc-ion batteries
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作者 Tao Zhou Xuan Du Guo Gao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期9-19,I0001,共12页
Exploring suitable high-capacity V_(2)O_(5)-based cathode materials is essential for the rapid advancement of aqueous zinc ion batteries(ZIBs).However,the typical problem of slow Zn^(2+)diffusion kinetics has severely... Exploring suitable high-capacity V_(2)O_(5)-based cathode materials is essential for the rapid advancement of aqueous zinc ion batteries(ZIBs).However,the typical problem of slow Zn^(2+)diffusion kinetics has severely limited the feasibility of such materials.In this work,unique hydrated vanadates(CaVO,BaVO)were obtained by intercalation of Ca^(2+)or Ba^(2+)into hydrated vanadium pentoxide.In the CaVO//Zn and BaVO//Zn batteries systems,the former delivered up to a 489.8 mAh g^(-1)discharge specific capacity at 0.1 A g^(-1).Moreover,the remarkable energy density of 370.07 Wh kg^(-1)and favorable cycling stability yard outperform BaVO,pure V_(2)O_(5),and many reported cathodes of similar ionic intercalation compounds.In addition,pseudocapacitance analysis,galvanostatic intermittent titration(GITT)tests,and Trasatti analysis revealed the high capacitance contribution and Zn^(2+)diffusion coefficient of CaVO,while an in-depth investigation based on EIS elucidated the reasons for the better electrochemical performance of CaVO.Notably,ex-situ XRD,XPS,and TEM tests further demonstrated the Zn^(2+)insertion/extraction and Zn-storage mechanism that occurred during the cycle in the CaVO//Zn battery system.This work provides new insights into the intercalation of similar divalent cations in vanadium oxides and offers new solutions for designing cathodes for high-capacity aqueous ZIBs. 展开更多
关键词 Aqueous zinc ion batteries Cathode materials Ion pre-intercalation Vanadium oxides Energy storage mechanism
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Synergism of Zinc Oxide/Organoclay-Loaded Poly(lactic acid) Hybrid Nanocomposite Plasticized by Triacetin for Sustainable Active Food Packaging
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作者 Ponusa Songtipya Thummanoon Prodpran +1 位作者 Ladawan Songtipya Theerarat Sengsuk 《Journal of Renewable Materials》 EI CAS 2024年第5期951-967,共17页
The synergistic effect of organoclay(OC)and zinc oxide(ZnO)nanoparticles on the crucial properties of poly(lactic acid)(PLA)nanocompositefilms was systematically investigated herein.After their incorporation into PLA v... The synergistic effect of organoclay(OC)and zinc oxide(ZnO)nanoparticles on the crucial properties of poly(lactic acid)(PLA)nanocompositefilms was systematically investigated herein.After their incorporation into PLA via the solvent casting technique,the water vapor barrier property of the PLA/OC/ZnOfilm improved by a maximum of 86%compared to the neat PLAfilm without the deterioration of Young’s modulus or the tensile strength.Moreover,thefilm’s self-antibacterial activity against foodborne pathogens,including gram-negative(Escherichia coli,E.coli)and gram-positive(Staphylococcus aureus,S.aureus)bacteria,was enhanced by a max-imum of approximately 98–99%compared to the neat PLAfilm.Furthermore,SEM images revealed the homo-geneous dispersion of both nano-fillers in the PLA matrix.However,the thermal stability of thefilm decreased slightly after the addition of the OC and ZnO.Thefilm exhibited notable light barrier properties in the UV-Vis range.Moreover,the incorporation of a suitable biodegradable plasticizer significantly decreased the Tg and notably enhanced theflexibility of the nanocompositefilm by increasing the elongation at break approxi-mately 1.5-fold compared to that of the neat PLAfilm.This contributes to its feasibility as an active food packa-ging material. 展开更多
关键词 Poly(lactic acid)nanocomposite ORGANOCLAY zinc oxide barrier property antibacterial activity active food packaging
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Synthesis and characterization of LiFePO_4 coating with aluminum doped zinc oxide 被引量:6
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作者 汤昊 谭龙 许军 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第2期451-455,共5页
Aluminum doped zinc oxide (AZO), as an electrically conductive material, was applied to coating on the surface of olivine-type LiFePO4 synthesized by solid-state method. The charge-discharge test results show that t... Aluminum doped zinc oxide (AZO), as an electrically conductive material, was applied to coating on the surface of olivine-type LiFePO4 synthesized by solid-state method. The charge-discharge test results show that the rate performance and low-temperature performance of LiFePO4 are greatly improved by the surface treatment. Even at 20C rate, the discharge specific capacity of 100.9 mA.h/g was obtained by the AZO-coated LiFePO4 at room temperature. At -20 ℃, the discharge specific capacity at 0.2C for un-coated LiFePO4 and the coated one are 50.3 mA.h/g and 119.4 mA.h/g, respectively. It should be attributed to the electrically conductive AZO-coating which increases the electronic conductivity of LiFePO4. Furthermore, the surface-coating increases the tap-density of LiFePO4. The results indicate that the AZO-coated LiFePO4 is a good candidate of cathode material for applying in lithium power batteries. 展开更多
关键词 lithium ion battery LIFEPO4 COATING cathode material aluminum doped zinc oxide
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Electronic and thermal properties of Ag-doped single crystal zinc oxide via laser-induced technique 被引量:1
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作者 邢欢 王惠琼 +5 位作者 宋廷鲁 李纯莉 戴扬 傅耿明 康俊勇 郑金成 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第6期44-51,共8页
The doping of ZnO has attracted lots of attention because it is an important way to tune the properties of ZnO.Postdoping after growth is one of the efficient strategies.Here,we report a unique approach to successfull... The doping of ZnO has attracted lots of attention because it is an important way to tune the properties of ZnO.Postdoping after growth is one of the efficient strategies.Here,we report a unique approach to successfully dope the single crystalline ZnO with Ag by the laser-induced method,which can effectively further post-treat grown samples.Magnetron sputtering was used to coat the Ag film with a thickness of about 50 nm on the single crystalline ZnO.Neodymium-doped yttrium aluminum garnet(Nd:YAG)laser was chosen to irradiate the Ag-capped ZnO samples,followed by annealing at700℃for two hours to form ZnO:Ag.The three-dimensional(3D)information of the elemental distribution of Ag in ZnO was obtained through time-of-flight secondary ion mass spectrometry(TOF-SIMS).TOF-SIMS and core-level x-ray photoelectron spectroscopy(XPS)demonstrated that the Ag impurities could be effectively doped into single crystalline ZnO samples as deep as several hundred nanometers.Obvious broadening of core level XPS profiles of Ag from the surface to depths of hundred nms was observed,indicating the variance of chemical state changes in laser-induced Ag-doped ZnO.Interesting features of electronic mixing states were detected in the valence band XPS of ZnO:Ag,suggesting the strong coupling or interaction of Ag and ZnO in the sample rather than their simple mixture.The Ag-doped ZnO also showed a narrower bandgap and a decrease in thermal diffusion coefficient compared to the pure ZnO,which would be beneficial to thermoelectric performance. 展开更多
关键词 zinc oxide Ag-doping laser-induced technique XPS SIMS thermal diffusivity
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Maternal zinc alleviates tert-butyl hydroperoxide-induced mitochondrial oxidative stress on embryonic development involving the activation of Nrf2/PGC-1αpathway 被引量:1
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作者 Liang Huang Wei Gao +9 位作者 Xuri He Tong Yuan Huaqi Zhang Xiufen Zhang Wenxuan Zheng Qilin Wu Ju Liu Wence Wang Lin Yang Yongwen Zhu 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2023年第4期1730-1743,共14页
Background Mitochondrial dysfunction induced by excessive mitochondrial reactive oxygen species(ROS)damages embryonic development and leads to growth arrest.Objective The purpose of this study is to elucidate whether ... Background Mitochondrial dysfunction induced by excessive mitochondrial reactive oxygen species(ROS)damages embryonic development and leads to growth arrest.Objective The purpose of this study is to elucidate whether maternal zinc(Zn)exert protective effect on oxidative stress targeting mitochondrial function using an avian model.Result In ovo injected tert-butyl hydroperoxide(BHP)increases(P<0.05)hepatic mitochondrial ROS,malondialdehyde(MDA)and 8-hydroxy-2-deoxyguanosine(8-OHdG),and decreases(P<0.05)mitochondrial membrane potential(MMP),mitochondrial DNA(mtDNA)copy number and adenosine triphosphate(ATP)content,contributing to mitochondrial dysfunction.In vivo and in vitro studies revealed that Zn addition enhances(P<0.05)ATP synthesis and metallothionein 4(MT4)content and expression as well as alleviates(P<0.05)the BHP-induced mitochondrial ROS generation,oxidative damage and dysfunction,exerting a protective effect on mitochondrial function by enhancing antioxidant capacity and upregulating the mRNA and protein expressions of Nrf2 and PGC-1α.Conclusions The present study provides a new way to protect offspring against oxidative damage by maternal Zn supplementation through the process of targeting mitochondria involving the activation of Nrf2/PGC-1αsignaling. 展开更多
关键词 Embryonic development Maternal zinc Mitochondrial function Oxidative stress
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Efficient degradation of dye pollutants in wastewater via photocatalysis using a magnetic zinc oxide/graphene/iron oxide-based catalyst
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作者 Piyawan Nuengmatcha Arnannit Kuyyogsuy +3 位作者 Paweena Porrawatkul Rungnapa Pimsen Saksit Chanthai Prawit Nuengmatcha 《Water Science and Engineering》 EI CAS CSCD 2023年第3期243-251,共9页
In this paper, we present a proof-of-concept study of the enhancement of photocatalytic activity via a combined strategy of fabricating a visible-light responsive ternary heterostructure and improving overall photosta... In this paper, we present a proof-of-concept study of the enhancement of photocatalytic activity via a combined strategy of fabricating a visible-light responsive ternary heterostructure and improving overall photostability by incorporating magnetic zinc oxide/graphene/iron oxide (ZGF). A solvothermal approach was used to synthesize the catalyst. X-ray diffraction (XRD), scanning electron microscopic, energy dispersive X-ray, transmission electron microscopic, vibrating sample magnetometric, and ultraviolet–visible diffuse reflectance spectroscopic techniques were used to characterize the synthesized samples. The obtained optimal Zn(NO_(3))_(2) concentration, temperature, and heating duration were 0.10 mol/L, 600℃, and 1 h, respectively. The XRD pattern revealed the presence of peaks corresponding to zinc oxide, graphene, and iron oxide, indicating that the ZGF catalyst was effectively synthesized. Furthermore, when the developed ZGF was used for methylene blue dye degradation, the optimum irradiation time, dye concentration, catalyst dosage, irradiation intensity, and solution pH were 90 min, 10 mg/L, 0.03 g/L, 100 W, and 8.0, respectively. Therefore, the synthesized ZGF system could be used as a catalyst to degrade dyes in wastewater samples. This hybrid nanocomposite consisting of zinc oxide, graphene, and iron oxide could also be used as an effective photocatalytic degrader for various dye pollutants. 展开更多
关键词 Magnetic zinc oxide/graphene/iron oxide PHOTOCATALYSIS Dye pollutants CATALYST Degradation
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Effects of Zinc Oxide Particles with Different Sizes on Root Development in Oryza sativa
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作者 Monica RUFFINI CASTIGLIONE Stefania BOTTEGA +1 位作者 Carlo SORCE Carmelina SPANÒ 《Rice science》 SCIE CSCD 2023年第5期449-458,I0021,共11页
Given the consistent release of zinc oxide(ZnO)nanoparticles into the environment,it is urgent to study their impact on plants in depth.In this study,grains of rice were treated with two different concentrations of Zn... Given the consistent release of zinc oxide(ZnO)nanoparticles into the environment,it is urgent to study their impact on plants in depth.In this study,grains of rice were treated with two different concentrations of ZnO nanoparticles(NP-ZnO,10 and 100 mg/L),and their bulk counterpart(B-ZnO)were used to evaluate whether ZnO action could depend on particle size.To test this hypothesis,root growth and development assessment,oxidative stress parameters,indole-3-acetic acid(IAA)content and molecules/enzymes involved in IAA metabolism were analyzed.In situ localization of Zn in control and treated roots was also performed.Though Zn was visible inside root cells only following nanoparticle treatment,both materials(NP-ZnO and B-ZnO)were able to affect seedling growth and root morphology,with alteration in the concentration/pattern of localization of oxidative stress markers and with a different action depending on particle size.In addition,only ZnO supplied as bulk material induced a significant increase in both IAA concentration and lateral root density,supporting our hypothesis that bulk particles might enhance lateral root development through the rise of IAA concentration.Apparently,IAA concentration was influenced more by the activity of the catabolic peroxidases than by the protective action of phenols. 展开更多
关键词 zinc oxide indole-3-acetic acid lateral root RICE bulk particle NANOPARTICLE
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Multi-Objective Adaptive Optimization Model Predictive Control:Decreasing Carbon Emissions from a Zinc Oxide Rotary Kiln
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作者 Ke Wei Keke Huang +1 位作者 Chunhua Yang Weihua Gui 《Engineering》 SCIE EI CAS CSCD 2023年第8期96-105,共10页
The zinc oxide rotary kiln,as an essential piece of equipment in the zinc smelting industrial process,is presenting new challenges in process control.China’s strategy of achieving a carbon peak and carbon neutrality ... The zinc oxide rotary kiln,as an essential piece of equipment in the zinc smelting industrial process,is presenting new challenges in process control.China’s strategy of achieving a carbon peak and carbon neutrality is putting new demands on the industry,including green production and the use of fewer resources;thus,traditional stability control is no longer suitable for multi-objective control tasks.Although researchers have revealed the principle of the rotary kiln and set up computational fluid dynamics(CFD)simulation models to study its dynamics,these models cannot be directly applied to process control due to their high computational complexity.To address these issues,this paper proposes a multi-objective adaptive optimization model predictive control(MAO-MPC)method based on sparse identification.More specifically,with a large amount of data collected from a CFD model,a sparse regression problem is first formulated and solved to obtain a reduction model.Then,a two-layered control framework including real-time optimization(RTO)and model predictive control(MPC)is designed.In the RTO layer,an optimization problem with the goal of achieving optimal operation performance and the lowest possible resource consumption is set up.By solving the optimization problem in real time,a suitable setting value is sent to the MPC layer to ensure that the zinc oxide rotary kiln always functions in an optimal state.Our experiments show the strength and reliability of the proposed method,which reduces the usage of coal while maintaining high profits. 展开更多
关键词 zinc oxide rotary kiln Model reduction Sparse identification Real-time optimization Model predictive control Process control
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Silicon Mitigates Aluminum Toxicity of Tartary Buckwheat by Regulating Antioxidant Systems
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作者 Anyin Qi Xiaonan Yan +10 位作者 Yuqing Liu Qingchen Zeng Hang Yuan Huange Huang Chenggang Liang Dabing Xiang Liang Zou Lianxin Peng Gang Zhao Jingwei Huang Yan Wan 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第1期1-13,共13页
Aluminum (Al) toxicity is a considerable factor limiting crop yield and biomass in acidic soil. Tartary buckwheatgrowing in acidic soil may suffer from Al poisoning. Here, we investigated the influence of Al stress on... Aluminum (Al) toxicity is a considerable factor limiting crop yield and biomass in acidic soil. Tartary buckwheatgrowing in acidic soil may suffer from Al poisoning. Here, we investigated the influence of Al stress on the growthof tartary buckwheat seedling roots, and the alleviation of Al stress by silicon (Si), as has been demonstrated inmany crops. Under Al stress, root growth (total root length, primary root length, root tips, root surface area, androot volume) was significantly inhibited, and Al and malondialdehyde (MDA) accumulated in the root tips. At thesame time, catalase (CAT) and ascorbate peroxidase activities, polyphenols, flavonoids, and 1,1-diphenyl-2-picrylhydrazyl(DPPH) and 2,2′-azinobis-(3-ethylbenzthiazoline-6-sulphonate) (ABTS) free-radical scavenging abilitywere significantly decreased. After the application of Si, root growth, Al accumulation, and oxidative damage wereimproved. Compared to Al-treated seedlings, the contents of ·O2− and MDA decreased by 29.39% and 25.22%,respectively. This was associated with Si-induced increases in peroxidase and CAT enzyme activity, flavonoidcompounds, and free-radical scavenging (DPPH and ABTS). The application of Si therefore has positive effectson Al toxicity in tartary buckwheat roots by reducing Al accumulation in the roots and maintaining oxidationhomeostasis. 展开更多
关键词 Tartary buckwheat aluminum stress SILICON root growth oxidative stress
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Low-Frequency Noise in Amorphous Indium Zinc Oxide Thin Film Transistors with Aluminum Oxide Gate Insulator
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作者 Ya-Yi Chen Yuan Liu +4 位作者 Zhao-Hui Wu Li Wang Bin Li Yun-Fei En Yi-Qiang Chen 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第4期123-126,共4页
Low-frequency noise(LFN) in all operation regions of amorphous indium zinc oxide(a-IZO) thin film transistors(TFTs) with an aluminum oxide gate insulator is investigated. Based on the LFN measured results, we ex... Low-frequency noise(LFN) in all operation regions of amorphous indium zinc oxide(a-IZO) thin film transistors(TFTs) with an aluminum oxide gate insulator is investigated. Based on the LFN measured results, we extract the distribution of localized states in the band gap and the spatial distribution of border traps in the gate dielectric,and study the dependence of measured noise on the characteristic temperature of localized states for a-IZO TFTs with Al2 O3 gate dielectric. Further study on the LFN measured results shows that the gate voltage dependent noise data closely obey the mobility fluctuation model, and the average Hooge's parameter is about 1.18×10^-3.Considering the relationship between the free carrier number and the field effect mobility, we simulate the LFN using the △N-△μ model, and the total trap density near the IZO/oxide interface is about 1.23×10^18 cm^-3eV^-1. 展开更多
关键词 Low-Frequency Noise in Amorphous Indium zinc oxide Thin Film Transistors with aluminum oxide Gate Insulator AL
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Electrochemical and Photoelectrochemical Properties of Nano-Islands of Zinc and Niobium Oxides Deposited on Aluminum Thin Film by RF Magnetron Reactive Sputtering
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作者 Go Sajiki Yasuhiko Benino +1 位作者 Tokuro Nanba Hiroshi Okano 《Materials Sciences and Applications》 2015年第4期292-309,共18页
Zinc oxide (ZnO) and niobium oxide (NbOx) with a nano-island structure were deposited by a sputtering method on Al-coated glass substrates. Cells with a (ZnO or NbOx)/Al/glass|KNO3aq.|Al/ glass structure were assemble... Zinc oxide (ZnO) and niobium oxide (NbOx) with a nano-island structure were deposited by a sputtering method on Al-coated glass substrates. Cells with a (ZnO or NbOx)/Al/glass|KNO3aq.|Al/ glass structure were assembled, and electrochemical and photoelectrochemical properties were evaluated. The ZnO and NbOx electrodes had higher electrode potentials than the counter Al/glass electrode, and electron flows from the counter electrode to the ZnO and NbOx electrodes through the external circuit were commonly confirmed. In the ZnO-based cell, only faint photocurrent generation was seen, where Zn and Al elution from the ZnO electrode was found. In the NbOxbased cell, however, stable generation of electricity was successfully achieved, and electrode corrosion was not recognized even in microscopic observations. A photoelectrochemical conversion model was proposed based on potential-pH diagrams. In the case of nano-island structures formed at shorter NbOx deposition time, it was concluded that the photoelectrochemical reactions, which were proceeded in the immediate vicinity of the boundary among nano-islands, substrate, and electrolyte solution, were predominant for the photoelectrochemical conversion, and in the case of film structures with longer deposition time, the predominant reactions took place at the film surface. 展开更多
关键词 Nano-Island Electrochemistry PHOTOELECTROCHEMISTRY NIOBIUM and zinc oxide Corrosion
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Incorporation of Nano-Zinc Oxide in Lamellar Zirconium Phosphate: Synthesis and Characterization
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作者 Danielle Mattos Mariano Daniela França Silva Freitas +2 位作者 Gerson Alberto Valencia Albitres Luis Claudio Mendes Maria Ines Bruno Tavares 《Materials Sciences and Applications》 2023年第6期346-361,共16页
In order to provide ultraviolet barrier, antifungal and antibacterial properties, nano-zinc oxide (ZnO) was added to lamellar zirconium phosphate (ZrP). The phosphate was synthesized via reaction of zirconium oxychlor... In order to provide ultraviolet barrier, antifungal and antibacterial properties, nano-zinc oxide (ZnO) was added to lamellar zirconium phosphate (ZrP). The phosphate was synthesized via reaction of zirconium oxychloride octahydrate and phosphoric acid following its chemical modification with Jeffamine and nano-ZnO. Diffractometric, morphological, thermal, structural and relaxometric evaluations were conducted. Fourier transform infrared spectroscopy (FTIR) revealed increase of the area between 4000 - 3000 cm<sup>-1</sup> due to the formation of ionic specie PO? <sup>+</sup>NH<sub>3</sub>-[C-(H)(CH<sub>3</sub>)-CH<sub>2</sub>-O-(C-(H)(CH<sub>3</sub>)-CH<sub>2</sub>-O)<sub>8</sub>-(CH<sub>2</sub>-CH<sub>2</sub>-O-CH<sub>3</sub>)] and nano-ZnO particles. Wide-angle X-ray diffraction indicated that intercalation of Jeffamine was successful. Thermogravimetry confirmed that nano-ZnO particle forced the expulsion of Jeffamine outside ZrP galleries. Scanning electron microscopy evidenced the Jeffamine intercalation and sample heterogeneity. Hydrogen molecular relaxation indicated the increase of molecular rigidity owing to the formation of ionic specie and the addition of nano-ZnO particles. It was postulated that a multifunctional and miscellaneous material constituted by as prepared ZrP, some delaminated ZrP platelets and nano-ZnO particles was achieved. The material has potential for usage as filler in polymeric composites. 展开更多
关键词 Lamellar Zirconium Phosphate Jeffamine Nano-zinc oxide INTERCALATION
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Design and Analysis of MEMS Based Aluminum Nitride (AlN), Lithium Niobate (LiNbO<sub>3</sub>) and Zinc Oxide (ZnO) Cantilever with Different Substrate Materials for Piezoelectric Vibration Energy Harvesters Using COMSOL Multiphysics Software
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作者 Ahmad M.Alsaad Ahmad A.Ahmad +2 位作者 Qais M.Al-Bataineh Nermeen S.Daoud Mais H.Khazaleh 《Open Journal of Applied Sciences》 2019年第4期181-197,共17页
Interest in energy harvesters has grown rapidly over the last decade. The cantilever shaped piezoelectric energy harvesting beam is one of the most employed designs, due to its simplicity and flexibility for further p... Interest in energy harvesters has grown rapidly over the last decade. The cantilever shaped piezoelectric energy harvesting beam is one of the most employed designs, due to its simplicity and flexibility for further performance enhancement. The research effort in the MEMS Piezoelectric vibration energy harvester designed using three types of cantilever materials, Lithium Niobate (LiNbO3), Aluminum Nitride (AlN) and Zinc Oxide (ZnO) with different substrate materials: aluminum, steel and silicon using COMSOL Multiphysics package were designed and analyzed. Voltage, mechanical power and electrical power versus frequency for different cantilever materials and substrates were modeled and simulated using Finite element method (FEM). The resonant frequencies of the LiNbO3/Al, AlN/Al and ZnO/Al systems were found to be 187.5 Hz, 279.5 Hz and 173.5 Hz, respectively. We found that ZnO/Al system yields optimum voltage and electrical power values of 8.2 V and 2.8 mW, respectively. For ZnO cantilever on aluminum, steel and silicon substrates, we found the resonant frequencies to be 173.5 Hz, 170 Hz and 175 Hz, respectively. Interestingly, ZnO/steel yields optimal voltage and electrical power values of 9.83 V and 4.02 mW, respectively. Furthermore, all systems were studied at different differentiate frequencies. We found that voltage and electrical power have increased as the acceleration has increased. 展开更多
关键词 MEMS PIEZOELECTRIC Energy Harvester CANTILEVER Lithium Niobate (LiNbO3) aluminum Nitride (AlN) zinc oxide (ZnO) Aluminium SUBSTRATE Steel SUBSTRATE Silicon SUBSTRATE COMSOL Finite Element Method
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Enhanced visible-light photocatalytic activity of Z-scheme graphitic carbon nitride/oxygen vacancy-rich zinc oxide hybrid photocatalysts 被引量:15
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作者 刘亚男 王瑞霞 +5 位作者 杨正坤 杜虹 姜一帆 申丛丛 梁况 徐安武 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2015年第12期2135-2144,共10页
With the objectives of enhancing the stability,optical properties and visible-light photocatalytic activity of photocatalysts,we modified oxygen vacancy-rich zinc oxide(Vo-ZnO) with graphitic carbon nitride(g-C3N4... With the objectives of enhancing the stability,optical properties and visible-light photocatalytic activity of photocatalysts,we modified oxygen vacancy-rich zinc oxide(Vo-ZnO) with graphitic carbon nitride(g-C3N4). The resulting g-C3N4/Vo-ZnO hybrid photocatalysts showed higher visible-light photocatalytic activity than pure Vo-ZnO and g-C3N4. The hybrid photocatalyst with a g-C3N4 content of 1 wt% exhibited the highest photocatalytic degradation activity under visible-light irradiation(λ≥ 400 nm). In addition,the g-C3N4/Vo-ZnO photocatalyst was not deactivated after five cycles of methyl orange degradation,indicating that it is stable under light irradiation. Finally,a Z-scheme mechanism for the enhanced photocatalytic activity and stability of the g-C3N4/Vo-ZnO hybrid photocatalyst was proposed. The fast charge separation and transport within the g-C3N4/Vo-ZnO hybrid photocatalyst were attributed as the origins of its enhanced photocatalytic performance. 展开更多
关键词 Oxygen deficient zinc oxide Graphitic carbon nitride Hybrid photocatalysts PHOTODEGRADATION Z-scheme
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Mechano-chemical sulfidization of zinc oxide by grinding with sulfur and reductive additives 被引量:8
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作者 柴立元 梁彦杰 +5 位作者 柯勇 闵小波 唐崇俭 张海静 谢先德 袁翠玉 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第4期1129-1138,共10页
A novel process for sulfidation of ZnO by co-grinding with sulfur and reductive additives (P, Fe, A1, and Mg) was developed. The sulfidation extent of ZnO with the addition of P, Fe, A1 or Mg can reach 85.2%, 81.6%,... A novel process for sulfidation of ZnO by co-grinding with sulfur and reductive additives (P, Fe, A1, and Mg) was developed. The sulfidation extent of ZnO with the addition of P, Fe, A1 or Mg can reach 85.2%, 81.6%, 96.7% and 92.6% after grinding for 4, 6, 1 and 1 h, respectively. Based on the chemical phase composition analysis and morphological characteristics of sulfidized products by XRD, SEM and TEM, a possible reaction mechanism, mechanically induced self-propagating reaction (MSR), was proposed to explain the sulfidization reaction. In addition, the floatability of sulfidized products was investigated for the recovery of metal sulfide and ZnS can be concentrated with a high concentration ratio and concentrate grade. By using the sulfidizing process, it is expected that the recovery of zinc from the wastes or purification of heavy-metal-containing hazardous residues is technically feasible. 展开更多
关键词 mechano-chemical sulfidization zinc oxide reductive additives self-propagating reaction FLOTATION
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Determination of arsenic speciation in secondary zinc oxide and arsenic leachability 被引量:9
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作者 李玉虎 刘志宏 +3 位作者 赵忠伟 李启厚 刘智勇 曾理 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第5期1209-1216,共8页
The species of arsenic in secondary zinc oxide generated from fuming furnace were investigated. The results revealed that there are mainly three types of secondary zinc oxide based on three arsenic species. The main p... The species of arsenic in secondary zinc oxide generated from fuming furnace were investigated. The results revealed that there are mainly three types of secondary zinc oxide based on three arsenic species. The main phase of As is As2O3 in type Ⅰ, zinc arsenite (Zn(AsO2)2) in type Ⅱ and lead arsenate (Pb(As206), Pb4As2O9) in type Ⅲ, respectively. Selective leaching of zinc oxide of type Ⅱ was carried out. The leaching rate of As kept at 65%-70% with 30 g/L NaOH and L/S ratio of 3 at 20 ℃ for 1 h, while the losses of Pb and Zn were both below 1%. 展开更多
关键词 secondary zinc oxide arsenic species alkali leaching arsenic removal
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Leaching of low grade zinc oxide ores in Ida^(2-)-H_2O system 被引量:6
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作者 窦爱春 杨天足 +2 位作者 杨际幸 吴江华 王安 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第11期2548-2553,共6页
Ida2--H2O system(iminodiacetate aqueous solution) was used to leach a low grade zinc oxide ore for Zn extraction.The effects of leaching time,liquid-solid ratio(L/S),total concentration of Ida2-([Ida2-]T),leachi... Ida2--H2O system(iminodiacetate aqueous solution) was used to leach a low grade zinc oxide ore for Zn extraction.The effects of leaching time,liquid-solid ratio(L/S),total concentration of Ida2-([Ida2-]T),leaching temperature and pH on Zn leaching recovery and the dissolution of impurities such as Ca,Mg,Cu,Ni,Fe,Pb and Cd were investigated.Results show that Ca,Mg and Fe in ores were hardly dissolved in alkalescent iminodiacetate aqueous solution,while valuable metals such as Cu,Ni,Pb and Cd were partly dissolved into leaching liquor with Zn.The recovery of Zn reaches 76.6% when the ores were leached for 4 h at 70 ℃ by 0.9 mol/L iminodiacetate aqueous solution with pH of 8 and L/S of 5:1. 展开更多
关键词 Ida2- zinc oxide ore LEACHING
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Selective recovery of lead from zinc oxide dust with alkaline Na_2EDTA solution 被引量:8
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作者 刘青 杨声海 +2 位作者 陈永明 何静 薛浩天 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第4期1179-1186,共8页
The selective recovery of lead from the zinc oxide dust using an alkaline Na2EDTA solution was investigated. The effects of temperature, leaching time, Na2EDTA concentration and initial NaOH concentration on the leach... The selective recovery of lead from the zinc oxide dust using an alkaline Na2EDTA solution was investigated. The effects of temperature, leaching time, Na2EDTA concentration and initial NaOH concentration on the leaching rates of lead and zinc were studied. The following optimized leaching conditions were obtained: liquid-to-solid ratio 5:1 mL/g, stirring speed 650 r/min, Na2EDTA concentration 0.12 mol/L, initial NaOH concentration 0.5 mol/L, leaching temperature 70 ℃, leaching time 120 min. Under the optimized conditions, the average leaching rates of lead, zinc, fluoride and chloride are 89.92%, 0.94%, 62.84% and 90.02%, respectively. The filtrate was used to electrowin lead powders. The average current efficiency of electrowinning is about 93% and lead content is higher than 98% under the conditions of temperature of 60 ℃, current density of 200 A/m2, H3PO4 concentration of 1.5 g/L, and lead ion concentration of above 5 g/L. The consumption of Na2EDTA and the direct current are about respectively 0.218 kg and 0.958 kW·h for per kilogram of lead powder. 展开更多
关键词 LEAD zinc oxide dust alkaline Na2EDTA solution ELECTROWINNING LEACHING
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