A zinc（Ⅱ） compound [ZnCl2（mpcm）2]（1,mpcm = methyl-3-pyridylcarbamate） was prepared by solvothermal reaction and characterized by elemental analysis,IR spectroscopy,TGA and single-crystal X-ray diffraction.The c...A zinc（Ⅱ） compound [ZnCl2（mpcm）2]（1,mpcm = methyl-3-pyridylcarbamate） was prepared by solvothermal reaction and characterized by elemental analysis,IR spectroscopy,TGA and single-crystal X-ray diffraction.The crystal is of monoclinic system,space group P21/n,C14H16ZnCl2N4O4,Mr = 440.58,a = 8.7893（7）,b = 24.978（2）,c = 9.2510（8）,β = 109.318（1）°,V = 1916.6（3）3,Z = 4,θ = 1.63～25.20°,Dc = 1.527 g/cm3,μ = 1.585 mm-1,F（000） = 896,the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with Ⅰ 〉 2σ（Ⅰ）.The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry.Two [ZnCl2（mpcm）2] subunits are held together by a pair of hydrogen bonds,forming a 32-membered macrocyclic dimer,which is further extended into a 3D tubular structure via hydrogen bonding.展开更多
基金Supported by the National Natural Science Foundation of China (No. 20872149)
文摘A zinc（Ⅱ） compound [ZnCl2（mpcm）2]（1,mpcm = methyl-3-pyridylcarbamate） was prepared by solvothermal reaction and characterized by elemental analysis,IR spectroscopy,TGA and single-crystal X-ray diffraction.The crystal is of monoclinic system,space group P21/n,C14H16ZnCl2N4O4,Mr = 440.58,a = 8.7893（7）,b = 24.978（2）,c = 9.2510（8）,β = 109.318（1）°,V = 1916.6（3）3,Z = 4,θ = 1.63～25.20°,Dc = 1.527 g/cm3,μ = 1.585 mm-1,F（000） = 896,the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with Ⅰ 〉 2σ（Ⅰ）.The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry.Two [ZnCl2（mpcm）2] subunits are held together by a pair of hydrogen bonds,forming a 32-membered macrocyclic dimer,which is further extended into a 3D tubular structure via hydrogen bonding.
