Organic electrode materials are promising for batteries.However,the reported organic electrodes are often facing the challenges of low specific capacity,low voltage,poor rate capability and vague charge storage mechan...Organic electrode materials are promising for batteries.However,the reported organic electrodes are often facing the challenges of low specific capacity,low voltage,poor rate capability and vague charge storage mechanisms,etc.Isomers are good platform to investigate the charge storage mechanisms and enhance the performance of batteries,which,however,have not been focused in batteries.Herein,two isomers are reported for batteries.As a result,the isomer tetrathiafulvalene(TTF)could store two monovalent anions reversibly,deriving an average discharge voltage of 1.05 V and a specific capacity of 220 mAh g−1 at a current density of 2 C.On the other hand,the other isomer tetrathianaphthalene could only reversibly store one monovalent anion and upon further oxidation,it would undergo an irreversible solid-state molecular rearrangement to TTF.The molecular rearrangement was confirmed by electrochemical performances,X-ray diffraction patterns,nuclear magnetic resonance spectra,and 1H detected heteronuclear multiple bond correlation spectra.These results suggested the small structural change could lead to a big difference in anion storage,and we hope this work will stimulate more attention to the structural design for boosting the performance of organic batteries.展开更多
A water-stable zinc-organic framework, Zn(bpda)(hip)·(DMF)(H2O)(1, H2bpda = N4,N4’-di(pyridin-4-yl)biphenyl-4,4’-dicarboxamide, H2 hip = 5-hydroxyisophthalic acid), has been synthesized via solvothermal reactio...A water-stable zinc-organic framework, Zn(bpda)(hip)·(DMF)(H2O)(1, H2bpda = N4,N4’-di(pyridin-4-yl)biphenyl-4,4’-dicarboxamide, H2 hip = 5-hydroxyisophthalic acid), has been synthesized via solvothermal reactions. Compound 1 exhibits strong fluorescence emission in water and can be used to detect various nitroaromatic explosives and antibiotics by means of fluorescence quenching in aqueous solution.展开更多
基金the National Natural Science Foundation of China(52173163 and 22205069)the National 1000-Talents Program,the Innovation Fund of WNLO,the China Postdoctoral Science Foundation(2021TQ0115 and 2021M701302)+1 种基金Hubei province Postdoctoral Innovation Research Post FundWenzhou Science and Technology Program(ZG2022020,G20220022 and G20220026).
文摘Organic electrode materials are promising for batteries.However,the reported organic electrodes are often facing the challenges of low specific capacity,low voltage,poor rate capability and vague charge storage mechanisms,etc.Isomers are good platform to investigate the charge storage mechanisms and enhance the performance of batteries,which,however,have not been focused in batteries.Herein,two isomers are reported for batteries.As a result,the isomer tetrathiafulvalene(TTF)could store two monovalent anions reversibly,deriving an average discharge voltage of 1.05 V and a specific capacity of 220 mAh g−1 at a current density of 2 C.On the other hand,the other isomer tetrathianaphthalene could only reversibly store one monovalent anion and upon further oxidation,it would undergo an irreversible solid-state molecular rearrangement to TTF.The molecular rearrangement was confirmed by electrochemical performances,X-ray diffraction patterns,nuclear magnetic resonance spectra,and 1H detected heteronuclear multiple bond correlation spectra.These results suggested the small structural change could lead to a big difference in anion storage,and we hope this work will stimulate more attention to the structural design for boosting the performance of organic batteries.
基金financially supported by the National Natural Science Foundation of China(No.21801111)Key Scientific Research Projects of Higher Education of He’nan Province(19A150034)
文摘A water-stable zinc-organic framework, Zn(bpda)(hip)·(DMF)(H2O)(1, H2bpda = N4,N4’-di(pyridin-4-yl)biphenyl-4,4’-dicarboxamide, H2 hip = 5-hydroxyisophthalic acid), has been synthesized via solvothermal reactions. Compound 1 exhibits strong fluorescence emission in water and can be used to detect various nitroaromatic explosives and antibiotics by means of fluorescence quenching in aqueous solution.