High quality nano-sized zirconium carbide (ZrC) powders were successfully fabricated via a developed chemical active dilution self-propagating high-temperature synthesis (SHS) method assisted by ball milling pretr...High quality nano-sized zirconium carbide (ZrC) powders were successfully fabricated via a developed chemical active dilution self-propagating high-temperature synthesis (SHS) method assisted by ball milling pretreatment process using traditional cheap zirconium dioxide powder (ZrO2), magnesium powder (Mg) and sucrose (C12H22Oll) as raw materials. FSEM, TEM, HRTEM, SAED, XRD, FTIR and Raman, ICP- AES, laser particle size analyzer, oxygen and nitrogen analyzer, carbon/sulfur determinator and TG-DSC were employed for the characterization of the morphology, structure, chemical composition and thermal stability of the as-synthesized ZrC samples. The as-synthesized samples demonstrated high purity, low oxygen content and evenly distributed ZrC nano-powders with an average particle size of 50nm. In addition, the effects of endothermic rate and the possible chemical reaction mechanism were also discussed.展开更多
A new polymer,polyzirconoxanesal(PZS),is synthesized from the reaction of zirconium oxychloride octahydrate (ZrOCl;-8H;O) with acetylacetone(Hacac) and salicyl alcohol(SA) by one-pot protocol.The polymer is so...A new polymer,polyzirconoxanesal(PZS),is synthesized from the reaction of zirconium oxychloride octahydrate (ZrOCl;-8H;O) with acetylacetone(Hacac) and salicyl alcohol(SA) by one-pot protocol.The polymer is soluble in common organic solvents,such as ethanol,methanol,acetone,tetrahydrofuran and chloroform,and exhibits rheology with viscosity of 100- 300 mpa s at 25℃.These properties are suitable for uses in fabrication of ceramic matrix fiber composites.Pyrolysis of this polymer at 1300℃in argon provides nanosized ZrC with spherical morphology and size of 20-100 nm.展开更多
Zirconium carbide(ZrC) exhibits considerable potential for applications as aerospace thermal protection and the Generation-Ⅳ nuclear fuel inert materials due to its high melting point,exceptional hardness,good abla...Zirconium carbide(ZrC) exhibits considerable potential for applications as aerospace thermal protection and the Generation-Ⅳ nuclear fuel inert materials due to its high melting point,exceptional hardness,good ablation resistance and low neutron absorption cross-section.Nevertheless,low sinterability of ZrC powders and poor fracture toughness and reliability of bulk ceramics limit their wide applications in extreme environments.This paper reviews the state of the art of preparation and properties of ZrC composites.Optimizing the sintering process and tailoring the chemical constituents of raw powders and sintering aids could improve sinterability to produce dense bulk ceramics.Different additives such as refractory metals,carbides,silicides,oxides,or carbon fibers are introduced into the ZrC matrix in order to improve fracture toughness,oxidation resistance or thermal shock resistance,etc.Further studies are needed to explore the effects of intrinsic defects(vacancies,dislocations,and grain or phase boundaries,etc.) and additives on microstructure and properties at elevated temperatures.展开更多
Experimental works have been conducted the objective of which was to improve mechanical properties of boron carbide by introduction of doping elements into the system. Titanium and Zirconium were selected as doping el...Experimental works have been conducted the objective of which was to improve mechanical properties of boron carbide by introduction of doping elements into the system. Titanium and Zirconium were selected as doping elements, which were introduced into the system in the form of TiB2 and ZrB2. Four types of boron carbide-titanium and zirconium mixture with various titanium and zirconium diboride content were used in experiments. Optimal process parameters, as well as doping elements concentration, necessary to provide required high mechanical parameters in the composite were defined.展开更多
A preceramic polymer, polyzirconosaal (PZSA), was synthesized by the ligand-exchange reaction between polyzirconoxane (PZO) and salicyl alcohol (SA). The precursor was air-stable and exhibited excellent solubili...A preceramic polymer, polyzirconosaal (PZSA), was synthesized by the ligand-exchange reaction between polyzirconoxane (PZO) and salicyl alcohol (SA). The precursor was air-stable and exhibited excellent solubility and rheology. These properties are useful for the processing of C/C-ZrC composites v/a precursor infiltration and pyrolysis (PIP) process. The polymer to ceramic conversion was investigated by TG, XRD and TEM. Nanosized ZrC was formed by pyrolysis of this precursor at 1300 ℃ in argon with ceramic yield of 57.8%.展开更多
Using zircon,boric acid and carbon black as starting materials,ZrB_(2)-ZrO_(2)-SiC composite powder was synthesized by calcining at 1500℃in flowing argon atmosphere.The effects of the soaking time(3,6 and 9 h)and the...Using zircon,boric acid and carbon black as starting materials,ZrB_(2)-ZrO_(2)-SiC composite powder was synthesized by calcining at 1500℃in flowing argon atmosphere.The effects of the soaking time(3,6 and 9 h)and the addition of additive AlF_(3)(0,0.5%,1.0%,1.5%,2.0%and 2.5%,by mass)on the phase composition and the microstructure of the synthesized products were investigated.The results show that:(1)ZrB_(2)-ZrO_(2)-SiC composite powder can be synthesized by carbothermal reduction at 1500℃in flowing argon atmosphere;ZrB_(2) and ZrO_(2) are granular-like,and SiC crystals are fiberous;(2)with the soaking time increasing,the amount of ZrB_(2) increases,the amounts of m-ZrO_(2) and SiC decrease,and the total amount of non-oxides ZrB_(2),SiC and ZrC gradually increases;the optimal soaking time is 3 h;(3)compared with the sample without AlF_(3),the sample with 0.5% AlF_(3) has decreased m-ZrO_(2)amount,noticeably increased ZrB_(2) amount but decreased SiC amount;however,when the addition of AlF_(3) increases from 0.5%to 2.5%,the m-ZrO_(2) amount increases,the ZrB_(2)amount decreases,and the SiC amount changes slightly;the optimum AlF_(3)addition is 0.5%.展开更多
CaZrO 3 containing the highest content of CaO in system CaO ZrO 2 is a potential refractory material, which has been applied in anti Al 2O 3 clogging submerged nozzle for steel continuous casting.Thermodynamic analyse...CaZrO 3 containing the highest content of CaO in system CaO ZrO 2 is a potential refractory material, which has been applied in anti Al 2O 3 clogging submerged nozzle for steel continuous casting.Thermodynamic analyses and experiment results show that at high temperature CaZrO 3 ZrB 2 system is stable, but extreme reactions will occur between CaZrO 3 and SiC mixtures while firing.展开更多
基金Funded by the Program for New Century Excellent Talents in University(No.NCET-12-0655)the Guangxi Natural Science Foundation(No.2014GXNSFFA118004)the Self-determined and Innovative Research Funds of WUT(Nos.136643002 and No.2013IV058)
文摘High quality nano-sized zirconium carbide (ZrC) powders were successfully fabricated via a developed chemical active dilution self-propagating high-temperature synthesis (SHS) method assisted by ball milling pretreatment process using traditional cheap zirconium dioxide powder (ZrO2), magnesium powder (Mg) and sucrose (C12H22Oll) as raw materials. FSEM, TEM, HRTEM, SAED, XRD, FTIR and Raman, ICP- AES, laser particle size analyzer, oxygen and nitrogen analyzer, carbon/sulfur determinator and TG-DSC were employed for the characterization of the morphology, structure, chemical composition and thermal stability of the as-synthesized ZrC samples. The as-synthesized samples demonstrated high purity, low oxygen content and evenly distributed ZrC nano-powders with an average particle size of 50nm. In addition, the effects of endothermic rate and the possible chemical reaction mechanism were also discussed.
文摘A new polymer,polyzirconoxanesal(PZS),is synthesized from the reaction of zirconium oxychloride octahydrate (ZrOCl;-8H;O) with acetylacetone(Hacac) and salicyl alcohol(SA) by one-pot protocol.The polymer is soluble in common organic solvents,such as ethanol,methanol,acetone,tetrahydrofuran and chloroform,and exhibits rheology with viscosity of 100- 300 mpa s at 25℃.These properties are suitable for uses in fabrication of ceramic matrix fiber composites.Pyrolysis of this polymer at 1300℃in argon provides nanosized ZrC with spherical morphology and size of 20-100 nm.
基金Financial supports from the National Natural Science Foundation of China ( Nos. 51172052 and 51321061 )Program for New Century Excellent Talents in University ( No. NCET 13 - 0177)
文摘Zirconium carbide(ZrC) exhibits considerable potential for applications as aerospace thermal protection and the Generation-Ⅳ nuclear fuel inert materials due to its high melting point,exceptional hardness,good ablation resistance and low neutron absorption cross-section.Nevertheless,low sinterability of ZrC powders and poor fracture toughness and reliability of bulk ceramics limit their wide applications in extreme environments.This paper reviews the state of the art of preparation and properties of ZrC composites.Optimizing the sintering process and tailoring the chemical constituents of raw powders and sintering aids could improve sinterability to produce dense bulk ceramics.Different additives such as refractory metals,carbides,silicides,oxides,or carbon fibers are introduced into the ZrC matrix in order to improve fracture toughness,oxidation resistance or thermal shock resistance,etc.Further studies are needed to explore the effects of intrinsic defects(vacancies,dislocations,and grain or phase boundaries,etc.) and additives on microstructure and properties at elevated temperatures.
文摘Experimental works have been conducted the objective of which was to improve mechanical properties of boron carbide by introduction of doping elements into the system. Titanium and Zirconium were selected as doping elements, which were introduced into the system in the form of TiB2 and ZrB2. Four types of boron carbide-titanium and zirconium mixture with various titanium and zirconium diboride content were used in experiments. Optimal process parameters, as well as doping elements concentration, necessary to provide required high mechanical parameters in the composite were defined.
基金supported by"the Fundamental Research Funds for the Central Universities"(No. 2011QNA20)
文摘A preceramic polymer, polyzirconosaal (PZSA), was synthesized by the ligand-exchange reaction between polyzirconoxane (PZO) and salicyl alcohol (SA). The precursor was air-stable and exhibited excellent solubility and rheology. These properties are useful for the processing of C/C-ZrC composites v/a precursor infiltration and pyrolysis (PIP) process. The polymer to ceramic conversion was investigated by TG, XRD and TEM. Nanosized ZrC was formed by pyrolysis of this precursor at 1300 ℃ in argon with ceramic yield of 57.8%.
基金supported by National Natural Science Foundation of China(52172031 and 51872266)Henan Provincial Science and Technology Research Project(222102230030).
文摘Using zircon,boric acid and carbon black as starting materials,ZrB_(2)-ZrO_(2)-SiC composite powder was synthesized by calcining at 1500℃in flowing argon atmosphere.The effects of the soaking time(3,6 and 9 h)and the addition of additive AlF_(3)(0,0.5%,1.0%,1.5%,2.0%and 2.5%,by mass)on the phase composition and the microstructure of the synthesized products were investigated.The results show that:(1)ZrB_(2)-ZrO_(2)-SiC composite powder can be synthesized by carbothermal reduction at 1500℃in flowing argon atmosphere;ZrB_(2) and ZrO_(2) are granular-like,and SiC crystals are fiberous;(2)with the soaking time increasing,the amount of ZrB_(2) increases,the amounts of m-ZrO_(2) and SiC decrease,and the total amount of non-oxides ZrB_(2),SiC and ZrC gradually increases;the optimal soaking time is 3 h;(3)compared with the sample without AlF_(3),the sample with 0.5% AlF_(3) has decreased m-ZrO_(2)amount,noticeably increased ZrB_(2) amount but decreased SiC amount;however,when the addition of AlF_(3) increases from 0.5%to 2.5%,the m-ZrO_(2) amount increases,the ZrB_(2)amount decreases,and the SiC amount changes slightly;the optimum AlF_(3)addition is 0.5%.
文摘CaZrO 3 containing the highest content of CaO in system CaO ZrO 2 is a potential refractory material, which has been applied in anti Al 2O 3 clogging submerged nozzle for steel continuous casting.Thermodynamic analyses and experiment results show that at high temperature CaZrO 3 ZrB 2 system is stable, but extreme reactions will occur between CaZrO 3 and SiC mixtures while firing.