A theoretical model that takes into account the flee-volume aided cooperative shearing of shear transformation zones （STZs） is developed to quantitatively understand the ductile-to-brittle transition （DBT） of meta...A theoretical model that takes into account the flee-volume aided cooperative shearing of shear transformation zones （STZs） is developed to quantitatively understand the ductile-to-brittle transition （DBT） of metallic glasses. The STZ dilatational strain is defined as the ratio of STZ-activated free volume to STZ volume itself. The model demonstrates that the STZ dilatational strain will increase drastically and exceed the characteristic shear strain of STZ as temperature decreases below a critical value. This critical temperature is in good agreement with the experimentally measured DBT temperature. Our results suggest that the DBT of metallic glasses is underpinned by the transition of atomic-cluster motions from STZ-tvpe rearrangements to dilatational processes （termed tension transformation zones （TrZs））.展开更多
基金supported by the National Nature Science Foundation of China (Grant Nos.11522221,11372315,11472287,and 51171138)the National Basic Research Program of China (Grant No.2012CB937500)+1 种基金the CAS/SAFEA International Partnership Program for Creative Research Teamspartially also by DFG
文摘A theoretical model that takes into account the flee-volume aided cooperative shearing of shear transformation zones （STZs） is developed to quantitatively understand the ductile-to-brittle transition （DBT） of metallic glasses. The STZ dilatational strain is defined as the ratio of STZ-activated free volume to STZ volume itself. The model demonstrates that the STZ dilatational strain will increase drastically and exceed the characteristic shear strain of STZ as temperature decreases below a critical value. This critical temperature is in good agreement with the experimentally measured DBT temperature. Our results suggest that the DBT of metallic glasses is underpinned by the transition of atomic-cluster motions from STZ-tvpe rearrangements to dilatational processes （termed tension transformation zones （TrZs））.
