Morphological, mechanical and thermal properties of cyanate ester/benzoxazine resin composites reinforced by silane treated natural hemp fibers

This present study deals with the reinforcement of thermosetting resin blends composed of cyanate ester(CE) and benzoxazine(BOZ) resins with natural hemp fibers(NHFs). These NHFs were initially treated by using a silane coupling agent(SCA) in order to chiefly enhance their distributions as well as adhesions within the CE/BOZ resin matrix,then incorporated with various weight amounts ranging from 5 wt% to 20 wt% with a regular interval of 5 wt%. The obtained results showed that at the maximum treated fiber loading(20 wt%), distinctive enhancements in the mechanical properties in terms of flexural strength and microhardness were obtained. Besides, the thermal stability and glass transition temperature(Tg) were appreciably enhanced and were higher than those of the pure CE/BOZ resin properties. With respect to the astonishing properties of the NHFs, these enhancements could be possibly due to the good dispersion and adhesion of the treated NHFs inside the CE/BOZ resin achieved upon using the SCA. Therefore,we believe herein that these renewable and cheap NHFs have considerable potential to be used as reinfocer materials for CE/BOZ resin composites to be used in various industrial sectors.

Influence of Fabric Parameters on Microstructure,Mechanical Properties and Failure Mechanisms in Carbon-Fibre Reinforced Composites

The effects of fibre/matrix bonding, fabric density, fibre volume fraction and bundle size on microstructure, mechanical properties and failure mechanisms in carbon fibre reinforced composites （plastic and carbon matrix） have been investigated. The microstructure of unloaded and cracked samples was studied by optical microscopy and scanning electron microscopy （SEM）, respectively whereas the mechanical behaviour was examined by 3- point bending experiments. Exclusively one type of experimental resole type phenolic resin was applied. A strong fibre/matrix bonding, which is needed for high strength of carbon fibre reinforced plastic （CFRP） materials leads to severe composite damages during the pyrolysis resulting in low strength, brittle failure and a very low utilisation of the fibres strain to failure in C/C composites. Inherent fabric parameters such as an increasing fabric density or bundle size or a reduced fibre volume fraction introduce inhomogenities to the CFRP＇s microstructure. Results are lower strength and stiffness whereas the strain to failure increases or remains unchanged. Toughness is almost not affected. In C/C composites inhomogenities due to a reduced bundle size reduce strain to failure, strength, stiffness and toughness. Vice versa a declining fibre volume fraction leads to exactly the opposite behaviour. Increasing the fabric density （weight per unit area） causes similar effects as in CFRPs.

In vitro toxicologic study of chitin short fiber reinforced polycaprolactone composite

Objective: To investigate the cytotoxicity and cytocompatibility of chitin fiber reinforced polycaprolactone composite in vitro in order to provide useful scientific basis for clinical application. Methods: Cell morphology observation, MTT and DNA assay were used to evaluate the influence of the composite on the morphology, growth and proliferation of cultured L-929 cells. Results: The composite did not impair the morphology of cultured cells in vitro. MTT and DNA assay demonstrated that the growth and proliferation of the cultured cells were not significantly inhibited by the composite. Conclusion : The composites have fine cytocompatibility and are safe for clinical use of reconstruction of chest wall defects.

Wear resistance and corrosion resistance of VC_p particle reinforced stainless steel composites

The VC_p reinforced stainless steel composite was produced by in-situ reaction casting. The composite was tested for its wear resistance under the wet abrasive condition and corrosion resistance, compared with the wear-resistant white iron and stainless steel. The results show that the wear resistance of the composite is slightly inferior to that of the white iron, but much better than that of the stainless steel under the wet grinding abrasive condition. The corrosion resistance of the composite is much better than that of the white iron in the acid medium, and a little worse than that of the stainless steel. Thus the composite exhibits superior properties of wear resistance and corrosion resistance.

Low-Velocity Impact and Compression after Impact(CAI)Behaviors of Carbon-Aramid/Epoxy Hybrid Braided Composite Laminates

Low-velocity impact and in-plane axial compression after impact(CAI)behaviors of carbon-aramid/epoxy hybrid braided composite laminates were investigated experimentally.The following three different types of carbon-aramid/epoxy hybrid braided composite laminates were produced and tested:(a)inter-hybrid laminates,(b)sandwich-like inter-hybrid laminates,and(c)unsymmetric-hybrid laminates.At the same time,carbon/epoxy braided composite laminates were used for comparisons.Impact properties and impact resistance were studied.Internal damages and damage mechanisms of laminates were detected by ultrasonic C-scan and B-scan methods.The results show that the ductility index(DI)values of three kinds of hybrid laminates aforementioned are 37%,4%and 120%higher than those of carbon/epoxy laminates,respectively.The peak load of inter-hybrid laminates is higher than that of sandwich-like inter-hybrid laminates and unsymmetric-hybrid laminates.The average damage area and dent depths of inter-hybrid laminates are 64%and 69%smaller than those of carbon/epoxy laminates.Those results show that carbon-aramid/epoxy hybrid braided composite laminates could significantly improve the impact properties and toughness of non-hybrid braided composite laminates.

Influence of technological parameters on coating speed of Pb-GF composite wire

The technological parameters have important effects on molding process of lead-clad glass fiber composite wire. If the extrusion force, temperature and gap size are too large or small, a dead zone will form in the front of the inlet mold orifice, and the continuous clad extrusion and coating speed will be influenced. Under the condition of equal flow, the maximum and minimum theoretical values of the extrusion force, temperature and gap size are studied. The results show that the gap size is a key parameter that affects the continuous clad extrusion and coating speed when the extrusion force and temperature are kept constant. The maximum value (H_ max) of gap size is 0.50mm and the minimum one (H_ min) is 0.12mm. At a gap size of 0.17mm or 0.29mm, the maximum of metal extrusion per unit time and optimal coating speed can be obtained when the extrusion temperature is 300℃ and the extrusion force is 450kN.

Studies of multilayer structure in depth direction by soft X-ray spectroscopy

It is demonstrated that two kinds of soft X-ray spectroscopy are useful as nondestructive methods to in- vestigate multilayer structures modified by interdiffusion or by chemical reaction of adjoining layers in depth direc- tion. One is the total electron yield (TEY) spectroscopy involving angular dependence measurement. Using this method, it was found that in LiF/Si/LiF trilayers, the Si layers exhibited a characteristic similar to porous Si, and in CaF2/Si/CaF2 trilayers, it was found that CaF2 segregated through the Si layer. Moreover, it has been shown that the thickness of the top layer of a Mo/Si X-ray multilayer can be determined by analyzing TEY signals generated by the standing wave. The other is the soft X-ray emission spectroscopy involving spectral shape analysis. Using this method, it was found that in Mo/Si X-ray multilayers, the interdiffusion or chemical reaction giving rise to deterioration of re- flectance character occurs in as-deposited samples as well as in heated samples. In antiferromagnetic Fe/Si multilay- ers, it was confirmed that there was no existence of pure Si layers, but insulating FeSi2 layers were present. This result suggests that the source of antiferromagnetic coupling is not conduction electrons but quantum wave interference.

Basic design of beamline and polarization control

The basic concept of synchrotron radiation beamlines for vacuum ultraviolet and X-ray experiments has been introduced to beginning users and designers of beamlines. The beamline defined here is composed of a front end, pre-mirrors, and a monochromator with refocusing mirrors, which are connected by beam pipes, providing monochromatic light for the experiments. Firstly, time characteristics of the synchrotron radiation are briefly reviewed. Secondly, the basic technology is introduced as the fundamental knowledge required to both users and designers. The topics are photoabsorption by air and solids, front ends and beam pipes, mirrors, monochromators, and filters. Thirdly, the design consideration is described mainly for the designers. The topics are design principle, principle of ray tracing, optical machinery and control, and vacuum. Fourthly, polarization control is considered. The topics are polarizers, polarization diagnosis of beamline, and circularly-polarized light generation. Finally, a brief summary is given introducing some references for further knowledge of the users and the designers.

Modeling Locking Angle of the Multi-layered Biaxial Weft Knitted Fabric in Shear Deformation

This paper introduces the construction of the multi-layered biaxial weft knitted fabric （MBWK fabric） and studies the locking angle of this kind of fabric. Moreover, a locking angle model of the MBWK fabric is established for the first time according to its unique construction. Two kinds of locking angles are considered under different restraint conditions: the locking angle θ1 controlled by the inserting yarns and the locking angle θ2 controlled by the stitch yarns. It is concluded that the ultimate value of the locking angle θ is the larger one of the two angles.

Multilayer polarization elements and their applications to polarimetric studies in vacuum ultraviolet and soft X-ray regions

Multilayer polarization elements and their applications to polarimetric studies in 20～400 eV region are mainly reviewed. General principle of selecting material combinations to get high linear polarizance multilayers of reflection type is given with practical examples,with periodic or non-periodic layer structures depending on the usage. Transmission type is introduced as linear polarizer and phase shifter. Their applications include polarization diagnosis of laboratory optical systems and synchrotron radiation beamlines of linear and circular polarization,magnetic rotation experiments such as Faraday rotation and magnetic Kerr rotation on magnetic films and multilayers,and ellipsometry to measure optical constants of thin films precisely. Polarization analysis of soft X-ray fluorescence using multilayer-coated grating is also mentioned. Finally this review is summarized with outlook of further developments.

Core decompression and implantation of calcium phosphate cement/Danshen drug delivery system for treating ischemic necrosis of femoral head at Stages Ⅰ,Ⅱ and Ⅲ of antigen reactive cell opsonization

Objective: To introduce a new method using calcium phosphate cement/Danshen drug delivery system for treating ischemic necrosis of the femoral head and evaluate its curative effect.Methods: From May 2000 to June 2005, 48 adult patients (54 hips) with ischemic necrosis of the femoral head at Stages Ⅰ,Ⅱ and Ⅲ of antigen reactive cell opsonization (ARCO) were treated with implantation of calcium phosphate cement/Danshen drug delivery system in the involved femoral head. The operation consisted of removal of the necrotic bone under weight-loading cartilage and the implantation of phosphate cement/Danshen drug delivery system, and all manipulations were made percutaneously through a bone tunnel in the trochanter. The functions of the hip joint were evaluated and X-ray films were taken preoperatively and postoperatively.Results: Postoperative follow-up was 45.5 months on average, ranging from 27 to 78 months. According to the evaluation criterion of "Dandong 1995" for therapeutic effect of adult ischemic necrosis of the femoral head, the therapeutic effects were excellent in 33 hips, good in 17, fair in 3 and poor in 1, with the excellent and good rate of 92.6 %.Conclusions: This method is relatively simple with little invasion. It not only improves the microcirculation of the femoral head by local application of traditional Chinese medicine, but also provides mechanic buttress in the weightloading area to prevent collapse during repairing, which is beneficial to repair and reconstruction of femoral head. It may be a choice of minimal invasion surgery for ischemic necrosis of the femoral head at Stages Ⅰ, Ⅱ and Ⅲ of ARCO.

Spatial discretization error in an artificial benchmark model of oblique laser incidence by finite volume approximation for radiative heat transfer

The spatial discretization error in a finite volume method approximation for radiative heat transfer is investigated. An artificial benchmark model for oblique laser incidence on a two-dimensional rectangle containing a semi-transparent medium is proposed, in addition to using reference data from the Monte Carlo method. Within the framework of the current model, it is shown that numerical scattering in the finite volume method is affected by the spatial grid values and the different spatial discretization schemes to a large degree. Numerical scattering also varies with the degree of absorption coefficient deviation. Numerical scattering is distributed in a symmetrical profile along the laser incidence direction, and all of the schemes show symmetrical cross-scattering.