Theoretical and experimental study of 3-D initial fracture and its significance to faulting

The experimental results of 3-D fracture under compression are introduced in brief and the theory of stress criterion of 3-D fracture is studied. Methods to imitate initial fractures are developed. It is pointed that there are important defects in the extreme value （EV） method ever proposed by Palaniswamy and Knauss. The major defect lies in that only two Euler angles （2EA） are considered, but another one is neglected. If the variation of all the three Euler angles （3EA） are considered, one can get better result which is consistent with the observation of faulting that extends on curved surfaces but not on planes. The method of evaluating maximal normal stress direction vector （NSDV） is proposed and further proved to be equivalent to the 3EA method. It is proved that the NSDV method can be further optimized to the method of composition of the first principal differential plane （CFPDP）. The results from CFPDP method can fit the curved surfaces of initial growth observed in the experiments of 3-D fracture. The CFPDP method can also be used to interpret the 3-D fractures of the slipping section between the asperities in the buried fault plane that is modeled as ellipse crack. The results of 3-D fracture can be applied to interpreting the related problems of faulting including the mechanism of a lot of shatter rocks with different dimensions, the cause of earthquakes occurred at the edge of plate under low shear stress, and the mechanism of anisotropy caused by the extensive dilatancy anisotropy （EDA） cracks.

Membrane Separator Interface for Mass-Spectrometric Analysis of Desflurane, Propofol and Fentanyl in Plasma and Cerebrospinal Fluid

Mass-spectrometric interface for the measurement of anaesthetic agent concentration in biological fluids (blood plasma and cerebrospinal fluid) is described. Sampling of biological fluids was performed during balanced inhalational (desflurane, fentanyl) anaesthesia and total intravenous (propofol, fentanyl) anaesthesia. The described method for drug concentration measurement in biologic fluids does not require long-term sample processing before injecting the sample into mass-spectrometer interface, in contrast to chromatographic methods. A hydrophobic membrane was used in the interface to separate anaesthetic agents from biological fluids: inhalational anaesthetic desflurane, hypnotic propofol, analgesic fentanyl. A possibility to use the interface for measurement of desflurane and propofol absolute concentration in blood plasma and cerebrospinal fluid was demonstrated for the study of blood-brain barrier (BBB) properties.

用NMR研究洋葱碳吸附水后的抗磁性（英文）

对洋葱状碳缺陷位吸附水分子的1H化学位移进行测试,并比较块状水和石墨烯、氧化石墨烯和纳米金刚石吸附水的化学位移。纳米金刚石和氧化石墨烯绝缘体的1H共振位置与块状水接近,然而石墨烯和洋葱碳吸附水呈现明显的化学位偏移,这是由导电的石墨烯片层抗磁屏蔽效应所致。质子的化学位移和抗磁性之间存在显著的相关性。

The descent of pieces of the Tunguska cosmic body

There is a hypothesis that fragments of a body from outer space fell to Earth as a result of the Tunguska event. During decades of investigations at the site of the disaster, stone or iron pieces from a cosmic body were not found. In spite of this, the number of adherents of this hypothesis is growing. For one thing, it was determined that the formation of swamp craters at the epicentre of the disaster is contempory with the Tunguska event. Secondly, it was proven that the swamp craters are the result of thermokarst processes: their formation is connected with heat exchange in a permafrost zone. Now we can affirm that fragments of the Tunguska cosmic body (as a comet) with a mass of 10-3 ≤ M ≤ 10 kg reached the Earth’s surface, but they did not form craters. This conclusion was made from the isotopes and composition of element in peat deposits as determined by Kolesnikov’s group and L’vov.

Space-Time Properties as Quantum Effects. Restrictions Imposed by Grothendieck’s Scheme Theory

In this paper we consider properties of the four-dimensional space-time manifold M caused by the proposition that, according to the scheme theory, the manifold M is locally isomorphic to the spectrum of the algebra A, M ≅Spec (A), where A is the commutative algebra of distributions of quantum-field densities. Points of the manifold M are defined as maximal ideals of density distributions. In order to determine the algebra A, it is necessary to define multiplication on densities and to eliminate those densities, which cannot be multiplied. This leads to essential restrictions imposed on densities and on space-time properties. It is found that the only possible case, when the commutative algebra A exists, is the case, when the quantum fields are in the space-time manifold M with the structure group SO (3, 1) (Lorentz group). The algebra A consists of distributions of densities with singularities in the closed future light cone subset. On account of the local isomorphism M ≅Spec (A) , the quantum fields exist only in the space-time manifold with the one-dimensional arrow of time. In the fermion sector the restrictions caused by the possibility to define the multiplication on the densities of spinor fields can explain the chirality violation. It is found that for bosons in the Higgs sector the charge conjugation symmetry violation on the densities of states can be observed. This symmetry violation can explain the matter-antimatter imbalance. It is found that in theoretical models with non-abelian gauge fields instanton distributions are impossible and tunneling effects between different topological vacua | n> do not occur. Diagram expansion with respect to the -algebra variables is considered.

Surface brightens up Si quantum dots: direct bandgap-like size-tunable emission

Colloidal semiconductor quantum dots(QDs)constitute a perfect material for ink-jet printable large area displays,photovoltaics,light-emitting diode,bio-imaging luminescent markers and many other applications.For this purpose,efficient light emission/absorption and spectral tunability are necessary conditions.These are currently fulfilled by the direct bandgap materials.Si-QDs could offer the solution to major hurdles posed by these materials,namely,toxicity(e.g.,Cd-,Pb-or As-based QDs),scarcity(e.g.,QD with In,Se,Te)and/or instability.Here we show that by combining quantum confinement with dedicated surface engineering,the biggest drawback of Si—the indirect bandgap nature—can be overcome,and a‘direct bandgap’variety of Si-QDs is created.We demonstrate this transformation on chemically synthesized Si-QDs using state-of-the-art optical spectroscopy and theoretical modelling.The carbon surface termination gives rise to drastic modification in electron and hole wavefunctions and radiative transitions between the lowest excited states of electron and hole attain‘direct bandgap-like’(phonon-less)character.This results in efficient fast emission,tunable within the visible spectral range by QD size.These findings are fully justified within a tight-binding theoretical model.When the C surface termination is replaced by oxygen,the emission is converted into the well-known red luminescence,with microsecond decay and limited spectral tunability.In that way,the‘direct bandgap’Si-QDs convert into the‘traditional’indirect bandgap form,thoroughly investigated in the past.