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Process metallurgy and data-driven prediction and feedback of blast furnace heat indicators
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作者 Quan Shi Jue Tang Mansheng Chu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第6期1228-1240,共13页
The prediction and control of furnace heat indicators are of great importance for improving the heat levels and conditions of the complex and difficult-to-operate hour-class delay blast furnace(BF)system.In this work,... The prediction and control of furnace heat indicators are of great importance for improving the heat levels and conditions of the complex and difficult-to-operate hour-class delay blast furnace(BF)system.In this work,a prediction and feedback model of furnace heat indicators based on the fusion of data-driven and BF ironmaking processes was proposed.The data on raw and fuel materials,process op-eration,smelting state,and slag and iron discharge during the whole BF process comprised 171 variables with 9223 groups of data and were comprehensively analyzed.A novel method for the delay analysis of furnace heat indicators was established.The extracted delay variables were found to play an important role in modeling.The method that combined the genetic algorithm and stacking efficiently im-proved performance compared with the traditional machine learning algorithm in improving the hit ratio of the furnace heat prediction model.The hit ratio for predicting the temperature of hot metal in the error range of±10℃ was 92.4%,and that for the chemical heat of hot metal in the error range of±0.1wt%was 93.3%.On the basis of the furnace heat prediction model and expert experience,a feedback model of furnace heat operation was established to obtain quantitative operation suggestions for stabilizing BF heat levels.These sugges-tions were highly accepted by BF operators.Finally,the comprehensive and dynamic model proposed in this work was successfully ap-plied in a practical BF system.It improved the BF temperature level remarkably,increasing the furnace temperature stability rate from 54.9%to 84.9%.This improvement achieved considerable economic benefits. 展开更多
关键词 blast furnace furnace heat genetic algorithm stacking prediction and feedback
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Effect of titanium on the sticking of pellets based on hydrogen metallurgy shaft furnace:Behavior analysis and mechanism evolution
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作者 Jinge Feng Jue Tang +4 位作者 Zichuan Zhao Mansheng Chu Aijun Zheng Xiaobing Li Xiao’ai Wang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第2期282-291,共10页
Direct reduction based on hydrogen metallurgical gas-based shaft furnace is a promising technology for the efficient and low-carbon smelting of vanadium-titanium magnetite.However,in this process,the sticking of pelle... Direct reduction based on hydrogen metallurgical gas-based shaft furnace is a promising technology for the efficient and low-carbon smelting of vanadium-titanium magnetite.However,in this process,the sticking of pellets occurs due to the aggregation of metal-lic iron between the contact surfaces of adjacent pellets and has a serious negative effect on the continuous operation.This paper presents a detailed experimental study of the effect of TiO2 on the sticking behavior of pellets during direct reduction under different conditions.Results showed that the sticking index(SI)decreased linearly with the increasing TiO2 addition.This phenomenon can be attributed to the increase in unreduced FeTiO3 during reduction,leading to a decrease in the number and strength of metallic iron interconnections at the sticking interface.When the TiO2 addition amount was raised from 0 to 15wt%at 1100°C,the SI also increased from 0.71%to 59.91%.The connection of the slag phase could be attributed to the sticking at a low reduction temperature,corresponding to the low sticking strength.Moreover,the interconnection of metallic iron became the dominant factor,and the SI increased sharply with the increase in re-duction temperature.TiO2 had a greater effect on SI at a high reduction temperature than at a low reduction temperature. 展开更多
关键词 TITANIUM sticking index hydrogen metallurgy direct reduction PELLETS
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Low-temperature chlorination roasting technology for the simultaneous recovery of valuable metals from spent LiCoO_(2)cathode material
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作者 Junjie Shi Changle Hou +2 位作者 Jingjing Dong Dong Chen Jianzhong Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期80-91,共12页
With the continuous increase in the disposal volume of spent lithium-ion batteries(LIBs),properly recycling spent LIBs has become essential for the advancement of the circular economy.This study presents a systematic ... With the continuous increase in the disposal volume of spent lithium-ion batteries(LIBs),properly recycling spent LIBs has become essential for the advancement of the circular economy.This study presents a systematic analysis of the chlorination roasting kinetics and proposes a new two-step chlorination roasting process that integrates thermodynamics for the recycling of LIB cathode materials.The activation energy for the chloride reaction was 88.41 kJ/mol according to thermogravimetric analysis–derivative thermogravimetry data obtained by using model-free,model-fitting,and Z(α)function(αis conversion rate).Results indicated that the reaction was dominated by the first-order(F1)model when the conversion rate was less than or equal to 0.5 and shifted to the second-order(F2)model when the conversion rate exceeded 0.5.Optimal conditions were determined by thoroughly investigating the effects of roasting temperature,roasting time,and the mass ratio of NH_(4)Cl to LiCoO_(2).Under the optimal conditions,namely 400℃,20 min,and NH_(4)Cl/LiCoO_(2)mass ratio of 3:1,the leaching efficiency of Li and Co reached 99.43% and 99.05%,respectively.Analysis of the roasted products revealed that valuable metals in LiCoO_(2)transformed into CoCl_(2) and LiCl.Furthermore,the reaction mechanism was elucidated,providing insights for the establishment of a novel low-temperature chlorination roasting technology based on a crystal structure perspective.This technology can guide the development of LIB recycling processes with low energy consumption,low secondary pollution,high recovery efficiency,and high added value. 展开更多
关键词 spent lithium-ion battery thermodynamics chlorination roasting kinetics circular economy
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Preparation of FeCoNi medium entropy alloy from Fe^(3+)-Co^(2+)-Ni^(2+)solution system
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作者 Zongyou Cheng Qing Zhao +3 位作者 Mengjie Tao Jijun Du Xingxi Huang Chengjun Liu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期92-101,共10页
In recent years,medium entropy alloys have become a research hotspot due to their excellent physical and chemical performances.By controlling reasonable elemental composition and processing parameters,the medium entro... In recent years,medium entropy alloys have become a research hotspot due to their excellent physical and chemical performances.By controlling reasonable elemental composition and processing parameters,the medium entropy alloys can exhibit similar properties to high entropy alloys and have lower costs.In this paper,a FeCoNi medium entropy alloy precursor was prepared via sol-gel and coprecipitation methods,respectively,and FeCoNi medium entropy alloys were prepared by carbothermal and hydrogen reduction.The phases and magnetic properties of FeCoNi medium entropy alloy were investigated.Results showed that FeCoNi medium entropy alloy was produced by carbothermal and hydrogen reduction at 1500℃.Some carbon was detected in the FeCoNi medium entropy alloy prepared by carbothermal reduction.The alloy prepared by hydrogen reduction was uniform and showed a relatively high purity.Moreover,the hydrogen reduction product exhibited better saturation magnetization and lower coercivity. 展开更多
关键词 medium entropy alloy SOL-GEL CO-PRECIPITATION carbothermal hydrogen reduction
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Research and development trends of hydrometallurgy:An overview based on Hydrometallurgy literature from 1975 to 2019 被引量:13
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作者 Li-pan JIA Jiang-jiang HUANG +5 位作者 Ze-long MA Xu-heng LIU Xing-yu CHEN Jiang-tao LI Li-hua HE Zhong-wei ZHAO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第11期3147-3160,共14页
Modern hydrometallurgy has been developing for more than 100 years and the related articles keep piling up.Based on a bibliometric analysis of the articles in Hydrometallurgy,the most authoritative journal in the fiel... Modern hydrometallurgy has been developing for more than 100 years and the related articles keep piling up.Based on a bibliometric analysis of the articles in Hydrometallurgy,the most authoritative journal in the field of hydrometallurgy,we try to catch the research and development trends from a global perspective.Firstly,keywords burstness shows that rare earth,recycling,lithium,ionic liquid,and thorium are the hotspots in recent years,and the economic and technological reasons behind them were discussed in depth.Secondly,the proportion of biohydrometallurgy grows fast from 5%to 13%and the related articles are almost all about bioleaching.There are some new directions such as direct preparation of materials in hydrometallurgical processes and ion-imprinted techniques.Thirdly,the advanced instrument analysis methods such as XAFS(X-ray absorption fine structure),gene sequencing,and micro-CT promote the deep understanding of hydrometallurgy mechanism.Finally,the cooperation network and contribution of the main institutes were mapped. 展开更多
关键词 development trends LEACHING solvent extraction BIOHYDROMETALLURGY electro-hydrometallurgy CiteSpace
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New development of powder metallurgy in automotive industry 被引量:9
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作者 TAN Zhao-qiang ZHANG Qing +3 位作者 GUO Xue-yi ZHAO Wei-jiang ZHOU Cheng-shang LIU Yong 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第6期1611-1623,共13页
The driving force for using powder metallurgy(PM)mostly relies on its near net-shape ability and cost-performance ratio.The automotive application is a main market of PM industry,requiring parts with competitive mecha... The driving force for using powder metallurgy(PM)mostly relies on its near net-shape ability and cost-performance ratio.The automotive application is a main market of PM industry,requiring parts with competitive mechanical or functional performance in a mass production scale.As the automobile technology transforms from traditional internal combustion engine vehicles to new energy vehicles,PM technology is undergoing significant changes in manufacturing and materials development.This review outlines the challenges and opportunities generated by the changes in the automotive technology for PM.Low-cost,high-performance and light-weight are critical aspects for future PM materials development.Therefore,the studies on PM lean-alloyed steel,aluminum alloys,and titanium alloy materials were reviewed.In addition,PM soft magnetic composite applied to new energy vehicles was discussed.Then new opportunities for advanced processing,such as metal injection molding(MIM)and additive manufacturing(AM),in automotive industry were stated.In general,the change in automotive industry raises sufficient development space for PM.While,emerging technologies require more preeminent PM materials.Iron-based parts are still the main PM products due to their mechanical performance and low cost.MIM will occupy the growing market of highly flexible and complex parts.AM opens a door for fast prototyping,great flexibility and customizing at low cost,driving weight and assembling reduction. 展开更多
关键词 AUTOMOTIVE powder metallurgy lean alloy Al alloy Ti alloy metal injection molding additive manufacturing
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Leaching of iron concentrate separated from kiln slag in zinc hydrometallurgy with hydrochloric acid and its mechanism 被引量:7
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作者 Hong-jun WANG Zhi-yong LIU +4 位作者 Zhi-hong LIU Yu-hu LI Si-wei LI Wen-Hai ZHANG Qi-hou LI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第4期901-907,共7页
It is taken as a novel prospective process to treat iron concentrate from hydrometallurgical zinc kiln slag forcomprehensive utilization of valuable metals by a hydrochloric acid leaching-spray pyrolysis method.The le... It is taken as a novel prospective process to treat iron concentrate from hydrometallurgical zinc kiln slag forcomprehensive utilization of valuable metals by a hydrochloric acid leaching-spray pyrolysis method.The leaching mechanism ofdifferent valuable metals was studied.The results revealed that the leaching rates of Ag,Pb,Cu,Fe,As and Zn were99.91%,99.25%,95.12%,90.15%,87.58%and58.15%,respectively with6mol/L HCl and L/S ratio of10:1at60°C for120min.The actionof SiO2in leaching solution was also studied.The results showed that the precipitation and settlement of SiO2(amorphous)adsorbedpart of metal ions in solution,which greatly inhibited the leaching of Cu,Fe,As and Zn,so it is crucial to control the precipitation ofamorphous SiO2. 展开更多
关键词 kiln slag iron concentrate hydrochloric acid leaching amorphous silica
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Regeneration of Al-doped LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode material by simulated hydrometallurgy leachate of spent lithium-ion batteries 被引量:7
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作者 Fang-cheng LI Gang ZHANG +4 位作者 Zong-liang ZHANG Jian YANG Fang-yang LIU Ming JIA Liang-xing JIANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第2期593-603,共11页
A uniform Al-doped LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode material was prepared using a coprecipitation method to take advantage of the positive effect of Al on regenerated NCM(Ni,Co,Mn)cathode materials and ameliora... A uniform Al-doped LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode material was prepared using a coprecipitation method to take advantage of the positive effect of Al on regenerated NCM(Ni,Co,Mn)cathode materials and ameliorate cumbersome and high-cost impurity removal processes during lithium-ion battery recycling.When the Al^(3+) content in the leachate was 1 at.%with respect to the total amount of transition metals(Ni,Co,and Mn),the produced Al-doped NCM cathode material increased concentrations of lattice oxygen and Ni^(2+).The initial specific capacity at 0.1C was 167.4 mA·h/g,with a capacity retention of 79.1%after 400 cycles at 1C.Further,this Al-doped sample showed improved rate performance and a smaller electrochemical impedance.These findings provide a reference for developing industrial processes to resynthesize cathode materials with improved electrochemical performance by incorporating Al^(3+) impurities produced during lithium-ion battery recycling. 展开更多
关键词 spent lithium-ion battery REGENERATION Al doping ternary cathode material coprecipitation
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Lithium and manganese extraction from manganese-rich slag originated from pyrometallurgy of spent lithium-ion battery 被引量:5
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作者 Guo-xing REN Cai-bin LIAO +1 位作者 Zhi-hong LIU Song-wen XIAO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第8期2746-2756,共11页
Mn and Li were selectively extracted from the manganese-rich slag by sulfation roasting−water leaching.The extraction mechanisms of Mn and Li were investigated by means of XRD,TG−DSC,and SEM−EDS.73.71%Mn and 73.28%Li ... Mn and Li were selectively extracted from the manganese-rich slag by sulfation roasting−water leaching.The extraction mechanisms of Mn and Li were investigated by means of XRD,TG−DSC,and SEM−EDS.73.71%Mn and 73.28%Li were leached under optimal experimental conditions:acid concentration of 82 wt.%,acid-to-slag mass ratio of 1.5:1,roasting temperature of 800°C,and roasting time of 2 h.During the roasting process,the manganese-rich slag first reacted with concentrated sulfuric acid,producing MnSO_(4),MnSO_(4)·H_(2)O,Li_(2)Mg(SO_(4))_(2),Al_(2)(SO_(4))_(3),and H_(4)SiO_(4).With the roasting temperature increasing,H_(4)SiO_(4) and Al_(2)(SO_(4))_(3) decomposed successively,resulting in generation of mullite and spinel.The mullite formation aided in decreasing the leaching efficiencies of Al and Si,while increasing the Li leaching efficiency.The formation of spinel,however,decreased the leaching efficiencies of Mn and Li. 展开更多
关键词 spent lithium-ion battery manganese-rich slag sulfation roasting manganese recovery lithium recovery
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In vitro degradation and cytotoxicity of Mg-5Zn-0.3Ca/n HA biocomposites prepared by powder metallurgy 被引量:7
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作者 Neda ABOUDZADEH Changiz DEHGHANIAN Mohammad Ali SHOKRGOZAR 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第9期1745-1754,共10页
Mg-5Zn-0.3Ca/nHA biocomposites were prepared from pure Mg,Zn,Ca and nano-hydroxyapatite(nHA)powders by powder metallurgy method.The effect of various mass fractions of nHA(1%,2.5%,5%)as reinforcement on the corrosion ... Mg-5Zn-0.3Ca/nHA biocomposites were prepared from pure Mg,Zn,Ca and nano-hydroxyapatite(nHA)powders by powder metallurgy method.The effect of various mass fractions of nHA(1%,2.5%,5%)as reinforcement on the corrosion properties of Mg-5Zn-0.3Ca alloy was investigated.The corrosion resistance of biocomposite samples was investigated by immersion tests and electrochemical techniques in SBF solution.The results showed that the corrosion resistance of Mg alloy was improved by adding 1%and 2.5%nHA.Bioactive nHA motivated the formation of stable phosphate and carbonate layers on surface and improved corrosion resistance of nanocomposites.However,addition of large contents of nHA in Mg alloy as reinforcement increased the density of this precipitated layer,so gases produced from localized corrosion were accumulated underneath this layer and decreased its adhesiveness and lowered its corrosion resistance.Indirect cytotoxicity evaluation for Mg alloy and its nanocomposites also showed that their extraction was not toxic and nanocomposite with 1%nHA indicated almost similar behavior as negative control. 展开更多
关键词 powder metallurgy metal biocomposite corrosion MAGNESIUM
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Progress,challenges,and prospects of spent lithium-ion batteries recycling:A review 被引量:3
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作者 Pengwei Li Shaohua Luo +7 位作者 Lin Zhang Qiuyue Liu Yikai Wang Yicheng Lin Can Xu Jia Guo Peam Cheali Xiaoning Xia 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期144-171,I0005,共29页
The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,batter... The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,battery recycling technology still faces challenges in terms of efficiency,effectiveness and environmental sustainability.This review aims to systematically review and analyze the current status of spent LIB recycling,and conduct a detailed comparison and evaluation of different recycling processes.In addition,this review introduces emerging recycling techniques,including deep eutectic solvents,molten salt roasting,and direct regeneration,with the intent of enhancing recycling efficiency and diminishing environmental repercussions.Furthermore,to increase the added value of recycled materials,this review proposes the concept of upgrading recycled materials into high value-added functional materials,such as catalysts,adsorbents,and graphene.Through life cycle assessment,the paper also explores the economic and environmental impacts of current battery recycling and highlights the importance that future recycling technologies should achieve a balance between recycling efficiency,economics and environmental benefits.Finally,this review outlines the opportunities and challenges of recycling key materials for next-generation batteries,and proposes relevant policy recommendations to promote the green and sustainable development of batteries,circular economy,and ecological civilization. 展开更多
关键词 Spent li-ion batteries RECYCLE Direct regeneration High-value conversion Functional materials
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Effect of electrical parameters and slag system on macrostructure of electroslag ingot 被引量:1
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作者 Bing-jie Wang Yu Wang +3 位作者 Meng-jun Wang Lei Zhao Li-zhong Chang Xiao-fang Shi 《China Foundry》 SCIE EI CAS CSCD 2024年第1期44-50,共7页
To investigate the influence of electric parameters and slag system on the solidification quality of electroslag ingot during electroslag remelting,different power supply modes,current strengths and remelting slag sys... To investigate the influence of electric parameters and slag system on the solidification quality of electroslag ingot during electroslag remelting,different power supply modes,current strengths and remelting slag systems were used to conduct electroslag remelting experiments on 304L austenitic stainless steel,and the macrostructure of electroslag ingots was analyzed.The results indicate that the depth of the metal pool decreases with the reduction of remelting frequency in the low frequency power supply mode.The effects of different power supply modes,such as low-frequency,direct current straight polarity(DCSP),and direct current reverse polarity(DCRP),on reducing the depth of the metal pool increase in that order.By reducing the remelting current strength in the same power supply mode,the depth of metal pool is reduced.When compared to the binary slag system of 70%CaF2+30%Al2O3,the ternary slag system of 60%CaF2+20%Al2O3+20%CaO is more effective in reducing the depth of the metal pool during remelting.Utilizing the 60%CaF2+20%Al2O3+20%CaO ternary slag system results in a shallower and flatter metal pool,with columnar crystal growth occurring closer to the axial crystal.This effect is observed for both low frequency and direct current(DC)power supply modes. 展开更多
关键词 electroslag remelting FREQUENCY slag system solidification quality
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In-situ coating and surface partial protonation co-promoting performance of single-crystal nickel-rich cathode in all-solid-state batteries 被引量:1
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作者 Maoyi Yi Jie Li +5 位作者 Mengran Wang Xinming Fan Bo Hong Zhian Zhang Aonan Wang Yanqing Lai 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期137-143,I0005,共8页
The poor electrochemical performance of all-solid-state batteries(ASSBs),which is assemblied by Ni-rich cathode and poly(ethylene oxide)(PEO)-based electrolytes,can be attributed to unstable cathodic interface and poo... The poor electrochemical performance of all-solid-state batteries(ASSBs),which is assemblied by Ni-rich cathode and poly(ethylene oxide)(PEO)-based electrolytes,can be attributed to unstable cathodic interface and poor crystal structure stability of Ni-rich cathode.Several coating strategies are previously employed to enhance the stability of the cathodic interface and crystal structure for Ni-rich cathode.However,these methods can hardly achieve simplicity and high efficiency simultaneously.In this work,polyacrylic acid(PAA)replaced traditional PVDF as a binder for cathode,which can achieve a uniform PAA-Li(LixPAA(0<x≤1))coating layer on the surface of single-crystal LiNi_(0.83)Co_(0.12)Mn_(0.05)O_(2)(SC-NCM83)due to H^(+)/Li^(+)exchange reaction during the initial charging-discharging process.The formation of PAA-Li coating layer on cathode can promote interfacial Li^(+)transport and enhance the stability of the cathodic interface.Furthermore,the partially-protonated surface of SC-NCM83 casued by H^(+)/Li^(+)exchange reaction can restrict Ni ions transport to enhance the crystal structure stability.The proposed SC-NCM83-PAA exhibits superior cycling performance with a retention of 92%compared with that(57.3%)of SC-NCM83-polyvinylidene difluoride(PVDF)after 200 cycles.This work provides a practical strategy to construct high-performance cathodes for ASSBs. 展开更多
关键词 Single-crystal LiNi_(0.83)Co_(0.12)Mn_(0.05)O_(2) In-situ coating PAA-Li Partial protonation
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High-chromium vanadium-titanium magnetite all-pellet integrated burden optimization and softening-melting behavior based on flux pellets 被引量:1
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作者 Bojian Chen Tao Jiang +4 位作者 Jing Wen Guangdong Yang Tangxia Yu Fengxiang Zhu Peng Hu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期498-507,共10页
High-chromium vanadium-titanium magnetite(HVTM)is a crucial polymetallic-associated resource to be developed.The allpellet operation is a blast furnace trend that aims to reduce carbon dioxide emissions in the future.... High-chromium vanadium-titanium magnetite(HVTM)is a crucial polymetallic-associated resource to be developed.The allpellet operation is a blast furnace trend that aims to reduce carbon dioxide emissions in the future.By referencing the production data of vanadium-titanium magnetite blast furnaces,this study explored the softening-melting behavior of high-chromium vanadium-titanium magnetite and obtained the optimal integrated burden based on flux pellets.The results show that the burden with a composition of 70wt%flux pellets and 30wt%acid pellets exhibits the best softening-melting properties.In comparison to that of the single burden,the softening-melting characteristic temperature of this burden composition was higher.The melting interval first increased from 307 to 362℃and then decreased to 282℃.The maximum pressure drop(ΔPmax)decreased from 26.76 to 19.01 kPa.The permeability index(S)dropped from 4643.5 to 2446.8 kPa·℃.The softening-melting properties of the integrated burden were apparently improved.The acid pellets played a role in withstanding load during the softening process.The flux pellets in the integrated burden exhibited a higher slag melting point,which increased the melting temperature during the melting process.The slag homogeneity and the TiC produced by over-reduction led to the gas permeability deterioration of the single burden.The segregation of the flux and acid pellets in the HVTM proportion and basicity mainly led to the better softening-melting properties of the integrated burden. 展开更多
关键词 high-chromium vanadium-titanium magnetite softening-melting properties all pellets integrated burden flux pellets
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Trace Cobalt Doping and Defect Engineering of High Surface Area α-Ni(OH)_(2) for Electrocatalytic Urea Oxidation 被引量:1
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作者 Yi Liu Zhihui Yang +2 位作者 Yuqin Zou Shuangyin Wang Junying He 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期111-118,共8页
Owing to the intrinsically sluggish kinetics of urea oxidation reaction(UOR)involving a six-electron transfer process,developing efficient UOR electrocatalyst is a great challenge remained to be overwhelmed.Herein,by ... Owing to the intrinsically sluggish kinetics of urea oxidation reaction(UOR)involving a six-electron transfer process,developing efficient UOR electrocatalyst is a great challenge remained to be overwhelmed.Herein,by taking advantage of 2-Methylimidazole,of which is a kind of alkali in water and owns strong coordination ability to Co^(2+)in methanol,trace Co(1.0 mol%)addition was found to induce defect engineering onα-Ni(OH)_(2)in a dual-solvent system of water and methanol.Physical characterization results revealed that the synthesized electrocatalyst(WM-Ni_(0.99)Co_(0.01)(OH)_(2))was a kind of defective nanosheet with thickness around 5-6 nm,attributing to the synergistic effect of Co doping and defect engineering,its electron structure was finely altered,and its specific surface a rea was tremendously enlarged from 68 to 172.3 m^(2)g^(-1).With all these merits,its overpotential to drive 10 mA cm^(-2)was reduced by 110 mV.Besides,the interfacial behavior of UOR was also well deciphered by operando electrochemical impedance spectroscopy. 展开更多
关键词 defect engineering ELECTROCATALYSIS small molecule oxidation
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Effect of inorganic salt impurities on seeded precipitation of silica hydrate from sodium silicate solution
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作者 Xiao-bin LI Xiao-bing GAO +5 位作者 Qiu-sheng ZHOU Yi-lin WANG Tian-gui QI Lei-ting SHEN Gui-hua LIU Zhi-hong PENG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期3016-3028,共13页
To clarify the precipitation of silica hydrate from the real desilication solutions of aluminosilicate solid wastes by adding seeds and improve integrated waste utilization,the seeded precipitation was studied using s... To clarify the precipitation of silica hydrate from the real desilication solutions of aluminosilicate solid wastes by adding seeds and improve integrated waste utilization,the seeded precipitation was studied using synthesized sodium silicate solution containing different inorganic salt impurities.The results show that sodium chloride,sodium sulfate,sodium carbonate,or calcium chloride can change the siloxy group structure.The number of high-polymeric siloxy groups decreases with increasing sodium chloride or sodium sulfate concentration,which is detrimental to seeded precipitation.Calcium chloride favors the polymerization of silicate ions,and even the chain groups precipitate with the precipitation of high-polymeric sheet and cage-like siloxy groups.The introduced sodium cations in sodium carbonate render a more open network structure of high-polymeric siloxy groups,although the carbonate ions favor the polymerization of siloxy groups.No matter how the four impurities affect the siloxy group structure,the precipitates are always amorphous opal-A silica hydrate. 展开更多
关键词 ALUMINOSILICATE sodium silicate solution siloxy group IMPURITY silica hydrate
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Efficient Preparation and Electrochemical Properties of BiOCl/Graphite by One-step Solvothermal Method
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作者 门丽娟 FEI Chi +3 位作者 LIU An 陈春钰 ZHOU Jiankang JU Dianchun 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期651-657,共7页
We used the surface-pretreated graphite paper(Gp)as a carrier and loaded BiOCl with high selectivity to Cl^(-)on its surface by solvothermal method to form BiOCl@Gp electrode.The morphology,structure,and composition o... We used the surface-pretreated graphite paper(Gp)as a carrier and loaded BiOCl with high selectivity to Cl^(-)on its surface by solvothermal method to form BiOCl@Gp electrode.The morphology,structure,and composition of the materials were characterized by scanning electron microscopy and nitrogen adsorption/desorption,and the results showed that the spherical BiOCl particles were uniformly dispersed on the surface of the Gp,forming a mesoporous BiOCl@Gp composite with a specific surface area of 22.82 m^(2)/g and a pore volume of 0.043 cm3/g.Furthermore,cyclic voltammetry and electrochemical impedance spectroscopy were used to test the electrochemical properties of the composites,and the stability of BiOCl and the high conductivity of Gp were synergistic,the BiOCl@Gp exhibited a specific capacitance of 30.2 F·g^(-1) at a current density of 0.5 A·g^(-1),and the selectivity of the BiOCl@Gp materials for Cl^(-)was significantly higher than that of SO_(4)^(2-),NO_(2)^(-),and HCO_(3)^(-).Therefore,BiOCl@Gp composite electrode materials can be used for the selective adsorption of Cl^(-)in wastewater,in order to achieve efficient wastewater recycling. 展开更多
关键词 solvothermal method bismuth oxychloride ELECTROCHEMISTRY electrode materials
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Effects of iron oxide on crystallization behavior and spatial distribution of spinel in stainless steel slag
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作者 Zihang Yan Qing Zhao +3 位作者 Chengzhi Han Xiaohui Mei Chengjun Liu Maofa Jiang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第2期292-300,共9页
Chromium plays a vital role in stainless steel due to its ability to improve the corrosion resistance of the latter.However,the re-lease of chromium from stainless steel slag(SSS)during SSS stockpiling causes detrimen... Chromium plays a vital role in stainless steel due to its ability to improve the corrosion resistance of the latter.However,the re-lease of chromium from stainless steel slag(SSS)during SSS stockpiling causes detrimental environmental issues.To prevent chromium pollution,the effects of iron oxide on crystallization behavior and spatial distribution of spinel were investigated in this work.The results revealed that FeO was more conducive to the growth of spinels compared with Fe2O3 and Fe3O4.Spinels were found to be mainly distrib-uted at the top and bottom of slag.The amount of spinel phase at the bottom decreased with the increasing FeO content,while that at the top increased.The average particle size of spinel in the slag with 18wt%FeO content was 12.8μm.Meanwhile,no notable structural changes were observed with a further increase in FeO content.In other words,the spatial distribution of spinel changed when the content of iron oxide varied in the range of 8wt%to 18wt%.Finally,less spinel was found at the bottom of slag with a FeO content of 23wt%. 展开更多
关键词 stainless steel slag SPINEL CHROMIUM waste remediation ferrous oxide
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Interphase migration and enrichment of lead and zinc during copper slag depletion
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作者 Jun HAO Zhi-he DOU +2 位作者 Xing-yuan WAN Ting-an ZHANG Kun WANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期3029-3041,共13页
An interphase migration and enrichment model of lead and zinc during molten copper slag depletion was established.The occurrence of various components in copper slag was predicted using sulfur-oxygen potential calcula... An interphase migration and enrichment model of lead and zinc during molten copper slag depletion was established.The occurrence of various components in copper slag was predicted using sulfur-oxygen potential calculations and confirmed through high-temperature experiments.The recovery rate of copper can reach 90.13%under the optimal conditions of 1200°C,an iron to silicon mass ratio of 1.0,3 wt.%ferrous sulfide,and a duration of 45 min.Lead(54.07 wt.%)and zinc(17.42 wt.%)are found in the flue dust as lead sulfate,lead sulfide,and zinc oxide,while copper matte contains lead(14.44 wt.%)and zinc sulfide(1.29 wt.%).The remaining lead and zinc are encapsulated as oxides within the fayalite phase. 展开更多
关键词 depletion LEAD copper slag STIRRING ZINC
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Phase equilibria relations in the V_(2)O_(5)-rich part of the Fe_(2)O_(3-)TiO_(2)-V_(2)O_(5) system at 1200℃ related to converter vanadium-bearing slag
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作者 Junjie Shi Yumo Zhai +6 位作者 Yuchao Qiu Changle Hou Jingjing Dong Maoxi Yao Haolun Li Yongrong Zhou Jianzhong Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期2017-2024,共8页
The efficient recycling of vanadium from converter vanadium-bearing slag is highly significant for sustainable development and circular economy.The key to developing novel processes and improving traditional routes li... The efficient recycling of vanadium from converter vanadium-bearing slag is highly significant for sustainable development and circular economy.The key to developing novel processes and improving traditional routes lies in the thermodynamic data.In this study,the equilibrium phase relations for the Fe_(2)O_(3)-TiO_(2)-V_(2)O_(5)system at 1200℃in air were investigated using a high-temperature equilibrium-quenching technique,followed by analysis using scanning electron microscopy-energy dispersive X-ray spectrometer and X-ray photoelectron spectroscopy.One liquid-phase region,two two-phase regions(liquid-rutile and liquid-ferropseudobrookite),and one three-phase region(liquid-rutile-ferropseudobrookite)were determined.The variation in the TiO_(2)and V_(2)O_(5)contents with the Fe_(2)O_(3)content was examined for rutile and ferropseudobrookite solid solutions.However,on further comparison with the predictions of FactSage 8.1,significant discrepancies were identified,highlighting that greater attention must be paid to updating the current thermodynamic database related to vanadium-bearing slag systems. 展开更多
关键词 vanadium-bearing slag thermodynamics FactSage phase equilibria recovery
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