Three zinc(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ)coordination polymers,namely[Zn(μ^(3-)cpna)(μ-dpea)_(0.5)]_(n)(1),[Co(μ^(3-)cpna)(μ-dpey)_(0.5)]_(n)(2),and[Ni(μ^(3-)cpna)(μ-dpey)_(0.5)(H_(2)O)]_(n)(3),have been construc...Three zinc(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ)coordination polymers,namely[Zn(μ^(3-)cpna)(μ-dpea)_(0.5)]_(n)(1),[Co(μ^(3-)cpna)(μ-dpey)_(0.5)]_(n)(2),and[Ni(μ^(3-)cpna)(μ-dpey)_(0.5)(H_(2)O)]_(n)(3),have been constructed hydrothermally using H_(2)cpna(5-(4-carboxyphenoxy)nicotinic acid),dpea(1,2-di(4-pyridyl)ethane),dpey(1,2-di(4-pyridyl)ethylene),and zinc,cobalt,and nickel chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the triclinic system,space group P1.Compounds 1-3 show 2D layer structures.The catalytic activities in the Knoevenagel condensation reaction of these compounds were investigated.Compounds 1 and 2 exhibit effective catalytic activities in the Knoevenagel condensa-tion reaction at room temperature.For this reaction,various parameters were optimized,followed by the investiga-tion of the substrate scope.CCDC:2335676,1;2335677,2;2335678,3.展开更多
The production of renewable fuels through water splitting via photocatalytic hydrogen production holds significant promise.Nonetheless,the sluggish kinetics of hydrogen evolution and the inadequate water adsorption on...The production of renewable fuels through water splitting via photocatalytic hydrogen production holds significant promise.Nonetheless,the sluggish kinetics of hydrogen evolution and the inadequate water adsorption on photocatalysts present notable challenges.In this study,we have devised a straightforward hydrothermal method to synthesize Bi_(2)O_(3)(BO)derived from metal‐organic frameworks(MOFs),loaded with flower-like ZnIn_(2)S_(4)(ZIS).This approach substantially enhances water adsorption and surface catalytic reactions,resulting in a remarkable enhancement of photocatalytic activity.By employing triethanolamine(TEOA)as a sacrificial agent,the hydrogen evolution rate achieved with 15%(mass fraction)ZIS loading on BO reached an impressive value of 1610μmol∙h^(−1)∙g^(−1),marking a 6.34-fold increase compared to that observed for bare BO.Furthermore,through density functional theory(DFT)and ab initio molecular dynamics(AIMD)calculations,we have identified the reactions occurring at the ZIS/BO S-scheme heterojunction interface,including the identification of active sites for water adsorption and catalytic reactions.This study provides valuable insights into the development of high-performance composite photocatalytic materials with tailored electronic properties and wettability.展开更多
Background,aim,and scope Yardang is a kind of typical wind-eroded landform in arid zones both on Earth and other planets.Their geomorphic process records the surface changes and climate,which may play a vital role in ...Background,aim,and scope Yardang is a kind of typical wind-eroded landform in arid zones both on Earth and other planets.Their geomorphic process records the surface changes and climate,which may play a vital role in exploring the coupled landform-atmosphere system in arid zones.Recently,significant progresses have been made in this research field,and a review is still absent,which is the aim of the paper.Materials and methods Previous studies on the distribution,composition,morphology,and climatic driving force of yardang landform were reviewed.Results Earth yardang’s three evolutionary models were generalized:morphology evolution model,altitude evolution model and climate driven evolution model.Extraterrestrial yardang and its evolution are also summarized:the morphology is dominated by long ridges on Venus and Titan,and three yardang evolution hypotheses and an indirect dating method based on stratigraphic contact have been studied on Mars.Discussion In this study,firstly,the definition and morphology of yardang were described to define its characteristics.Secondly,we argue that yardang evolution has two dimensions:short-term variation and longterm variation.In the short-term variation,the morphological evolution of yardang on earth can be divided into four stages:embryonic stage,juvenile stage,mature stage,and demise stage.In the long-term variation,the evolution of yardang on earth is climate-driven,i.e.,it is controlled by atmospheric circulation changes during glacial-interglacial periods.Thirdly,yardang research on extraterrestrial bodies was also summarized:yardang has been found on Mars,Venus,and Titan,and the research focus by far are on geomorphology only.Conclusions(1)Yardang landform is an erosion landform with alternating ridges and troughs,with main form of whale back shape and fluctuations in the range of aspect ratios;(2)the short-term variation of yardang is manifested in its morphological evolution and height change,while the long-term variation is climate-driven;(3)based on Earth yardang,extraterrestrial yardang research has been carried out on Mars,Venus,and Titan.Recommendations and perspectives We then proposed that:(1)yardang formation ages,due to the erosion characteristics,are difficult to constraint;(2)the wind erosion capacity in the yardang areas might have been severely underestimated,making it essential to re-evaluate the previous paleoclimate reconstruction in the closed basins with limited chronological data;(3)yardang evolution is driven by climate change,but the coupling relationship between the yardang geomorphy and the air circulation is still unclear.Finally,future research directions:(1)more chronological data are needed,as well as the wind erosion capacity for yardang initiation and development;(2)the co-evolution of mid-low latitude landforms involved in yardang long-term variation and its relationship with global atmospheric circulation.展开更多
Enlightened by natural photosynthesis,developing efficient S-scheme heterojunction photocatalysts for deleterious pollutant removal is of prime importance to restore environment.Herein,novel TaON/Bi_(2)WO_(6) S-scheme...Enlightened by natural photosynthesis,developing efficient S-scheme heterojunction photocatalysts for deleterious pollutant removal is of prime importance to restore environment.Herein,novel TaON/Bi_(2)WO_(6) S-scheme heterojunction nanofibers were designed and developed by in-situ growing Bi_(2)WO_(6) nanosheets with oxygen vacancies(OVs)on TaON nanofibers.Thanks to the efficiently spatial charge disassociation and preserved great redox power by the unique S-scheme mechanism and OVs,as well as firmly interfacial contact by the core-shell 1D/2D fibrous hetero-structure via the in-situ growth,the optimized TaON/Bi_(2)WO_(6) heterojunction unveils exceptional visible-light photocatalytic property for abatement of tetracycline(TC),levofloxacin(LEV),and Cr(Ⅵ),respectively by 2.8-fold,1.0-fold,and 1.9-fold enhancement compared to the bare Bi_(2)WO_(6),while maintaining satisfactory stability.Furthermore,the systematic photoreaction tests indicate Ta-ON/Bi_(2)WO_(6) has the high practicality in the elimination of pollutants in aquatic environment.The degradation pathway of tetracycline and intermediate eco-toxicity were determined based on HPLC–MS combined with QSAR calculation,and a possible photocatalytic mechanism was elucidated.This work provides a guideline for designing high-performance TaON-based S-scheme photocatalysts with defects for environment protection.展开更多
Marine phytoplankton plays a very important role in marine ecology,environment and global climate change,and it is an indicative organism for measuring water quality.The Bohai Sea and the Yellow Sea in China have uniq...Marine phytoplankton plays a very important role in marine ecology,environment and global climate change,and it is an indicative organism for measuring water quality.The Bohai Sea and the Yellow Sea in China have unique geographical locations.Therefore,the characteristics of phytoplankton population distribution in the Bohai Sea and the Yellow Sea are of great significance to the study of marine ecology in China.In this work,the pigment data obtained from the Yellow Sea and Bohai Sea in August 2015 were analyzed by HPLC(High-Performance Liquid Chromatography).Then the pigment data were analyzed statistically by the CHEMTAX software,so that the phytoplankton community structure information was obtained.Results show that in summer 2015,from the perspective of sea area,the biomass of phytoplankton in the surface of Bohai Sea is higher than that in the Yellow Sea,while the phytoplankton biomass in the surface of North Yellow Sea is higher than that in the South.From the perspective of dominant species of phytoplankton,the surface waters of the Yellow Sea and Bohai Sea were dominated by diatoms,prymnesiophytes and chlorophytes,accounting for 55.76%,14.56%and 14.55%respectively.Among them,diatoms accounted for the absolute advantage.展开更多
文摘Three zinc(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ)coordination polymers,namely[Zn(μ^(3-)cpna)(μ-dpea)_(0.5)]_(n)(1),[Co(μ^(3-)cpna)(μ-dpey)_(0.5)]_(n)(2),and[Ni(μ^(3-)cpna)(μ-dpey)_(0.5)(H_(2)O)]_(n)(3),have been constructed hydrothermally using H_(2)cpna(5-(4-carboxyphenoxy)nicotinic acid),dpea(1,2-di(4-pyridyl)ethane),dpey(1,2-di(4-pyridyl)ethylene),and zinc,cobalt,and nickel chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the triclinic system,space group P1.Compounds 1-3 show 2D layer structures.The catalytic activities in the Knoevenagel condensation reaction of these compounds were investigated.Compounds 1 and 2 exhibit effective catalytic activities in the Knoevenagel condensa-tion reaction at room temperature.For this reaction,various parameters were optimized,followed by the investiga-tion of the substrate scope.CCDC:2335676,1;2335677,2;2335678,3.
文摘The production of renewable fuels through water splitting via photocatalytic hydrogen production holds significant promise.Nonetheless,the sluggish kinetics of hydrogen evolution and the inadequate water adsorption on photocatalysts present notable challenges.In this study,we have devised a straightforward hydrothermal method to synthesize Bi_(2)O_(3)(BO)derived from metal‐organic frameworks(MOFs),loaded with flower-like ZnIn_(2)S_(4)(ZIS).This approach substantially enhances water adsorption and surface catalytic reactions,resulting in a remarkable enhancement of photocatalytic activity.By employing triethanolamine(TEOA)as a sacrificial agent,the hydrogen evolution rate achieved with 15%(mass fraction)ZIS loading on BO reached an impressive value of 1610μmol∙h^(−1)∙g^(−1),marking a 6.34-fold increase compared to that observed for bare BO.Furthermore,through density functional theory(DFT)and ab initio molecular dynamics(AIMD)calculations,we have identified the reactions occurring at the ZIS/BO S-scheme heterojunction interface,including the identification of active sites for water adsorption and catalytic reactions.This study provides valuable insights into the development of high-performance composite photocatalytic materials with tailored electronic properties and wettability.
文摘Background,aim,and scope Yardang is a kind of typical wind-eroded landform in arid zones both on Earth and other planets.Their geomorphic process records the surface changes and climate,which may play a vital role in exploring the coupled landform-atmosphere system in arid zones.Recently,significant progresses have been made in this research field,and a review is still absent,which is the aim of the paper.Materials and methods Previous studies on the distribution,composition,morphology,and climatic driving force of yardang landform were reviewed.Results Earth yardang’s three evolutionary models were generalized:morphology evolution model,altitude evolution model and climate driven evolution model.Extraterrestrial yardang and its evolution are also summarized:the morphology is dominated by long ridges on Venus and Titan,and three yardang evolution hypotheses and an indirect dating method based on stratigraphic contact have been studied on Mars.Discussion In this study,firstly,the definition and morphology of yardang were described to define its characteristics.Secondly,we argue that yardang evolution has two dimensions:short-term variation and longterm variation.In the short-term variation,the morphological evolution of yardang on earth can be divided into four stages:embryonic stage,juvenile stage,mature stage,and demise stage.In the long-term variation,the evolution of yardang on earth is climate-driven,i.e.,it is controlled by atmospheric circulation changes during glacial-interglacial periods.Thirdly,yardang research on extraterrestrial bodies was also summarized:yardang has been found on Mars,Venus,and Titan,and the research focus by far are on geomorphology only.Conclusions(1)Yardang landform is an erosion landform with alternating ridges and troughs,with main form of whale back shape and fluctuations in the range of aspect ratios;(2)the short-term variation of yardang is manifested in its morphological evolution and height change,while the long-term variation is climate-driven;(3)based on Earth yardang,extraterrestrial yardang research has been carried out on Mars,Venus,and Titan.Recommendations and perspectives We then proposed that:(1)yardang formation ages,due to the erosion characteristics,are difficult to constraint;(2)the wind erosion capacity in the yardang areas might have been severely underestimated,making it essential to re-evaluate the previous paleoclimate reconstruction in the closed basins with limited chronological data;(3)yardang evolution is driven by climate change,but the coupling relationship between the yardang geomorphy and the air circulation is still unclear.Finally,future research directions:(1)more chronological data are needed,as well as the wind erosion capacity for yardang initiation and development;(2)the co-evolution of mid-low latitude landforms involved in yardang long-term variation and its relationship with global atmospheric circulation.
文摘Enlightened by natural photosynthesis,developing efficient S-scheme heterojunction photocatalysts for deleterious pollutant removal is of prime importance to restore environment.Herein,novel TaON/Bi_(2)WO_(6) S-scheme heterojunction nanofibers were designed and developed by in-situ growing Bi_(2)WO_(6) nanosheets with oxygen vacancies(OVs)on TaON nanofibers.Thanks to the efficiently spatial charge disassociation and preserved great redox power by the unique S-scheme mechanism and OVs,as well as firmly interfacial contact by the core-shell 1D/2D fibrous hetero-structure via the in-situ growth,the optimized TaON/Bi_(2)WO_(6) heterojunction unveils exceptional visible-light photocatalytic property for abatement of tetracycline(TC),levofloxacin(LEV),and Cr(Ⅵ),respectively by 2.8-fold,1.0-fold,and 1.9-fold enhancement compared to the bare Bi_(2)WO_(6),while maintaining satisfactory stability.Furthermore,the systematic photoreaction tests indicate Ta-ON/Bi_(2)WO_(6) has the high practicality in the elimination of pollutants in aquatic environment.The degradation pathway of tetracycline and intermediate eco-toxicity were determined based on HPLC–MS combined with QSAR calculation,and a possible photocatalytic mechanism was elucidated.This work provides a guideline for designing high-performance TaON-based S-scheme photocatalysts with defects for environment protection.
基金supported by Liao Ning Revitalization Talents Program No. XLYC1807161Dalian High-level Talents Innovation Support Plan No. 2017RQ063+4 种基金Dalian Ocean University “Zhanlan scholar”ProgramThe National Natural Science Foundation of China under contract Nos. 41206013 and 41430963the Public Science and Technology Research Funds Projects of Ocean under contract No. 201205018the National Science and Technology Support Program under contract No. 2014BAB12B02Projects of Institute of Marine Industry Technology of Liaoning Universities
文摘Marine phytoplankton plays a very important role in marine ecology,environment and global climate change,and it is an indicative organism for measuring water quality.The Bohai Sea and the Yellow Sea in China have unique geographical locations.Therefore,the characteristics of phytoplankton population distribution in the Bohai Sea and the Yellow Sea are of great significance to the study of marine ecology in China.In this work,the pigment data obtained from the Yellow Sea and Bohai Sea in August 2015 were analyzed by HPLC(High-Performance Liquid Chromatography).Then the pigment data were analyzed statistically by the CHEMTAX software,so that the phytoplankton community structure information was obtained.Results show that in summer 2015,from the perspective of sea area,the biomass of phytoplankton in the surface of Bohai Sea is higher than that in the Yellow Sea,while the phytoplankton biomass in the surface of North Yellow Sea is higher than that in the South.From the perspective of dominant species of phytoplankton,the surface waters of the Yellow Sea and Bohai Sea were dominated by diatoms,prymnesiophytes and chlorophytes,accounting for 55.76%,14.56%and 14.55%respectively.Among them,diatoms accounted for the absolute advantage.
