The direct catalytic conversion of syngas to aromatics offers a promising route to manufacture fine chemicals by employing non-petroleum carbon resources,because aromatic constituents are the key platform for producin...The direct catalytic conversion of syngas to aromatics offers a promising route to manufacture fine chemicals by employing non-petroleum carbon resources,because aromatic constituents are the key platform for producing polymers.However,this remains a great challenge due to the low yield of aromatics and poor catalyst stability,which restrict further development.In recent years,extensive research has been reported on the design of effective catalysts and the optimization of operating conditions to obtain better catalytic performance.In this review,we focus on these related achievements and present a comprehensive overview of different kinds of catalysts,mainly including modified Fischer-Tropsch(FT)catalysts and composite catalysts,as well as their performance and reaction mechanisms.The thermodynamic analysis of the reactions involved in this innovative conversion process and the comparison of different methods are also described in detail in this updated review.Finally,the challenges and prospects for direct syngas conversion are discussed to provide general guidelines for the construction of a well-designed reaction route.展开更多
The present paper is a response to the current problematic situation of oral English teaching at the tertiary level in China and the increasing popularity of web-based mobile oral English learning in oral English clas...The present paper is a response to the current problematic situation of oral English teaching at the tertiary level in China and the increasing popularity of web-based mobile oral English learning in oral English classes.Our paper focuses on the use of mobile-phone-based educational software known as“English Fun Dubbing”(EFD)and its advantages in terms of teaching and learning phonetics and oral English in the college classroom.The starting point was a needs analysis which revealed the lack of practice regarding English speaking.In this study,an action research method was adopted,involving 40 second-year students,who employed“classroom teaching+English Fun Dubbing”model as the intervention.Extensive examples from this model were used to build up a picture of the blended learning processes at work.Several imitation tasks,a conversational activity and a speech-delivering task were designed and implemented.Direct observation and the results of the questionnaire survey provided the evidence of the improvement in the students’oral performance.It is our aim to develop the present project to incorporate oral proficiency.The main results of this action research were reflected in the adjustments in the pedagogical treatment,the changes in the role of the teacher and the student,and the shifts in the students’attitudes towards their learning process.展开更多
基金the National Key R&D Program of China(2016YFA0202804)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB17020400)+2 种基金the Youth Innovation Promotion Association CAS for financial supportthe National Natural Science Foundation of China(21506204,21476226)Dalian Science Foundation for Distinguished Young Scholars(2016RJ04)~~
文摘The direct catalytic conversion of syngas to aromatics offers a promising route to manufacture fine chemicals by employing non-petroleum carbon resources,because aromatic constituents are the key platform for producing polymers.However,this remains a great challenge due to the low yield of aromatics and poor catalyst stability,which restrict further development.In recent years,extensive research has been reported on the design of effective catalysts and the optimization of operating conditions to obtain better catalytic performance.In this review,we focus on these related achievements and present a comprehensive overview of different kinds of catalysts,mainly including modified Fischer-Tropsch(FT)catalysts and composite catalysts,as well as their performance and reaction mechanisms.The thermodynamic analysis of the reactions involved in this innovative conversion process and the comparison of different methods are also described in detail in this updated review.Finally,the challenges and prospects for direct syngas conversion are discussed to provide general guidelines for the construction of a well-designed reaction route.
文摘The present paper is a response to the current problematic situation of oral English teaching at the tertiary level in China and the increasing popularity of web-based mobile oral English learning in oral English classes.Our paper focuses on the use of mobile-phone-based educational software known as“English Fun Dubbing”(EFD)and its advantages in terms of teaching and learning phonetics and oral English in the college classroom.The starting point was a needs analysis which revealed the lack of practice regarding English speaking.In this study,an action research method was adopted,involving 40 second-year students,who employed“classroom teaching+English Fun Dubbing”model as the intervention.Extensive examples from this model were used to build up a picture of the blended learning processes at work.Several imitation tasks,a conversational activity and a speech-delivering task were designed and implemented.Direct observation and the results of the questionnaire survey provided the evidence of the improvement in the students’oral performance.It is our aim to develop the present project to incorporate oral proficiency.The main results of this action research were reflected in the adjustments in the pedagogical treatment,the changes in the role of the teacher and the student,and the shifts in the students’attitudes towards their learning process.