2D carbon ribbon/Al_(2)O_(3) was synthesized with two-dimensional metal organic frameworks 2D-MOFs as precursors using the solvothermal and calcination methods.Batch experiments of adsorption parameters such as pH,liq...2D carbon ribbon/Al_(2)O_(3) was synthesized with two-dimensional metal organic frameworks 2D-MOFs as precursors using the solvothermal and calcination methods.Batch experiments of adsorption parameters such as pH,liquid/solid ratio,adsorption kinetics,adsorption thermodynamics,and anions competitions were investigated to understand the adsorptive behavior of fluoride on carbon ribbon/Al_(2)O_(3) and nitrogen-doped carbon ribbon/Al_(2)O_(3).The adsorption of fluoride on carbon ribbon/Al_(2)O_(3) could be described as the chemical and multilayer adsorption,while the adsorption of fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) followed the chemical and monolayer adsorption phenomenon.The fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) had a much faster adsorption rate of 3.1×10^(−7) m/s than carbon ribbon/Al_(2)O_(3),which was 1.2×10^(−7) m/s.The nitrogen-doping on carbon ribbon enhances structural defects and improves the adsorption performance of fluoride.Also,the diacetylene linkages(—C≡C—)and pyridinic-N were studied to understand their influences on removing fluoride.The result indicates that carbon ribbon and nitrogen-doped ribbon could serve as good adsorbents for removing fluoride.展开更多
基金the financial supports from the Key R&D Program of Hunan Province,China(No.2018SK2026)the National Key R&D Program of China(No.2018YFC1802204)the National Natural Science Foundation of China(No.51634010).
文摘2D carbon ribbon/Al_(2)O_(3) was synthesized with two-dimensional metal organic frameworks 2D-MOFs as precursors using the solvothermal and calcination methods.Batch experiments of adsorption parameters such as pH,liquid/solid ratio,adsorption kinetics,adsorption thermodynamics,and anions competitions were investigated to understand the adsorptive behavior of fluoride on carbon ribbon/Al_(2)O_(3) and nitrogen-doped carbon ribbon/Al_(2)O_(3).The adsorption of fluoride on carbon ribbon/Al_(2)O_(3) could be described as the chemical and multilayer adsorption,while the adsorption of fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) followed the chemical and monolayer adsorption phenomenon.The fluoride on nitrogen-doped carbon ribbon/Al_(2)O_(3) had a much faster adsorption rate of 3.1×10^(−7) m/s than carbon ribbon/Al_(2)O_(3),which was 1.2×10^(−7) m/s.The nitrogen-doping on carbon ribbon enhances structural defects and improves the adsorption performance of fluoride.Also,the diacetylene linkages(—C≡C—)and pyridinic-N were studied to understand their influences on removing fluoride.The result indicates that carbon ribbon and nitrogen-doped ribbon could serve as good adsorbents for removing fluoride.
