The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites (MGMCs) containing beryllium (Be) with the nominal composition of Tia7Zr19Cu5V12B...The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites (MGMCs) containing beryllium (Be) with the nominal composition of Tia7Zr19Cu5V12Be17 (mole fraction, %) were investigated using XRD, SEM, EBSD, TEM, EDS and three-dimensional reconstruction method. Moreover, visualized at the nanoscale, Be distribution is confirmed to be only present in the matrix using scanning transmission electron microscopy-electron energy loss spectroscopy (STEM-EELS). Based on these findings, it has been obtained that the accurate chemical compositions are Wi28.3Zr19.7Cu8V6.4Be37.6 (mole fraction, %) for glass matrix and Wi62.nZr18.aCu2.6V16.6 (mole fraction, %) for the dendritic phases, and the volume fractions are 38.5% and 61.5%, respectively. It is believed that the results are of particular importance for the designing of Be-containing MGMCs.展开更多
基金Project(11374028)supported by the National Natural Science Foundation of ChinaProject supported by the Cheung Kong Scholars Program of China
文摘The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites (MGMCs) containing beryllium (Be) with the nominal composition of Tia7Zr19Cu5V12Be17 (mole fraction, %) were investigated using XRD, SEM, EBSD, TEM, EDS and three-dimensional reconstruction method. Moreover, visualized at the nanoscale, Be distribution is confirmed to be only present in the matrix using scanning transmission electron microscopy-electron energy loss spectroscopy (STEM-EELS). Based on these findings, it has been obtained that the accurate chemical compositions are Wi28.3Zr19.7Cu8V6.4Be37.6 (mole fraction, %) for glass matrix and Wi62.nZr18.aCu2.6V16.6 (mole fraction, %) for the dendritic phases, and the volume fractions are 38.5% and 61.5%, respectively. It is believed that the results are of particular importance for the designing of Be-containing MGMCs.