A new one-dimensional compound [Cd(dafo)(SCN)2]n (dafo=4,5-diazafluoren-9-one) has been synthesized and characterized by single crystal X-ray diffraction. It crystallizes in the orthorhombic system; space group Pbca w...A new one-dimensional compound [Cd(dafo)(SCN)2]n (dafo=4,5-diazafluoren-9-one) has been synthesized and characterized by single crystal X-ray diffraction. It crystallizes in the orthorhombic system; space group Pbca with a=1.708 6(5), b=1.303 6(4), c=2.592 6(8) nm, V=5.775(3) nm3, and Z=16. The crystal structure revealed that the structure of [Cd(dafo)(SCN)2]n features μ-1,3-thiocyante bridges and 1D chains. It consists of octahedrally coordinated Cd atoms. Both Cd(1) and Cd(2) are surrounded by two nitrogen atoms from dafo, two S atoms and two N atoms from two di-μ-1,3 thiocyanato bridges. CCDC: 251185.展开更多
文摘A new one-dimensional compound [Cd(dafo)(SCN)2]n (dafo=4,5-diazafluoren-9-one) has been synthesized and characterized by single crystal X-ray diffraction. It crystallizes in the orthorhombic system; space group Pbca with a=1.708 6(5), b=1.303 6(4), c=2.592 6(8) nm, V=5.775(3) nm3, and Z=16. The crystal structure revealed that the structure of [Cd(dafo)(SCN)2]n features μ-1,3-thiocyante bridges and 1D chains. It consists of octahedrally coordinated Cd atoms. Both Cd(1) and Cd(2) are surrounded by two nitrogen atoms from dafo, two S atoms and two N atoms from two di-μ-1,3 thiocyanato bridges. CCDC: 251185.
基金The project was supported by the National Natural Science Foundation of China(200863009,U1033603)Natural Science Founda-tion of Yunnan Pro-vince(2008CD065)Specialized Research Fund for the Doctoral Program of Higher Education and Program for Innovative Research Team(in Science and Technology)in University of Yunnan Province(IRTSTYN),Science Research Fund of Department of Education of Yunnan Prov-ince(09Y0462)
