The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X ray diffraction. The crystal of the title compound, [Mn(CHZ) 3](ClO 4) 2, belongs t...The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X ray diffraction. The crystal of the title compound, [Mn(CHZ) 3](ClO 4) 2, belongs to space group P2 1/n with the crystal parameters a=1.019 7(2) nm, b=0.859 3(1) nm, c=2.141 2(3) nm, β=100.86(1)°; V=1.842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.展开更多
A new supermolecule coordination compound of perchlorate di(4- amino- 1,2,4- tri azole- 5- one)silver(I) was synthesized. It was characterized by element analysis, FT- IR, X- ray crystallogram and single crystal diffr...A new supermolecule coordination compound of perchlorate di(4- amino- 1,2,4- tri azole- 5- one)silver(I) was synthesized. It was characterized by element analysis, FT- IR, X- ray crystallogram and single crystal diffraction. The titled complex was also studied by means of TG- DTG and DSC under conditions of linear temperature increase. The thermal decomposition remainders were determined by infrared spectroscopic analysis. Thermal decomposition mechanism of the title coordination compound was suggested.展开更多
文摘The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X ray diffraction. The crystal of the title compound, [Mn(CHZ) 3](ClO 4) 2, belongs to space group P2 1/n with the crystal parameters a=1.019 7(2) nm, b=0.859 3(1) nm, c=2.141 2(3) nm, β=100.86(1)°; V=1.842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.
文摘A new supermolecule coordination compound of perchlorate di(4- amino- 1,2,4- tri azole- 5- one)silver(I) was synthesized. It was characterized by element analysis, FT- IR, X- ray crystallogram and single crystal diffraction. The titled complex was also studied by means of TG- DTG and DSC under conditions of linear temperature increase. The thermal decomposition remainders were determined by infrared spectroscopic analysis. Thermal decomposition mechanism of the title coordination compound was suggested.
