The absorption spectrum of N2＋ has been studied using optical-heterodyne velocity mod- ulation spectroscopy in the near-infrared region. The observed spectral lines were assigned to the （3,1）, （4,2）, （5,3）, （...The absorption spectrum of N2＋ has been studied using optical-heterodyne velocity mod- ulation spectroscopy in the near-infrared region. The observed spectral lines were assigned to the （3,1）, （4,2）, （5,3）, （8,5） bands of the A2Ⅱu-X2∑g＋ system and the line lists were pro- vided. The （5,3） band was studied for the first time. Fourteen rotational-resolved bands in literatures were fitted together with our observed bands and the molecular constants were obtained for VA=0-9 and vx=0-5.展开更多
The special mass shift coefficient and field parameter factor of four multiples,3s^4P→3p4P°,3s^4P→3p^4D°,3s^2D→5p^2D°,and 3s^2P→3p^2P°,of ^14N and ^15N were studied using the multi-configuratio...The special mass shift coefficient and field parameter factor of four multiples,3s^4P→3p4P°,3s^4P→3p^4D°,3s^2D→5p^2D°,and 3s^2P→3p^2P°,of ^14N and ^15N were studied using the multi-configuration Dirac-Hartree-Fock method and the relativistic configuration interaction approach.The normal mass shifts,special mass shifts,field shifts,and isotope shifts of N(I)were derived from the theoretical calculated normal mass shift parameter,special mass shift parameter and field parameter factor,and compared with the reported experimental measurements and theoretical results.展开更多
基金This project was supported by the National Natural Science Foundation of China （No.11004062）.
文摘The absorption spectrum of N2＋ has been studied using optical-heterodyne velocity mod- ulation spectroscopy in the near-infrared region. The observed spectral lines were assigned to the （3,1）, （4,2）, （5,3）, （8,5） bands of the A2Ⅱu-X2∑g＋ system and the line lists were pro- vided. The （5,3） band was studied for the first time. Fourteen rotational-resolved bands in literatures were fitted together with our observed bands and the molecular constants were obtained for VA=0-9 and vx=0-5.
基金supported by the National Natural Science Foundation of China(No.11674096,No.11874151,and No.11834003)Shanghai Pujiang Talents Plan(No.18PJ1403100).
文摘The special mass shift coefficient and field parameter factor of four multiples,3s^4P→3p4P°,3s^4P→3p^4D°,3s^2D→5p^2D°,and 3s^2P→3p^2P°,of ^14N and ^15N were studied using the multi-configuration Dirac-Hartree-Fock method and the relativistic configuration interaction approach.The normal mass shifts,special mass shifts,field shifts,and isotope shifts of N(I)were derived from the theoretical calculated normal mass shift parameter,special mass shift parameter and field parameter factor,and compared with the reported experimental measurements and theoretical results.
