Excitation of metal-free graphitic carbon nitride(g-C3N4) under visible light can successfully achieve efficient activation of peroxymonosulfate(PMS). Synergistic effects and involved mechanism were systematically inv...Excitation of metal-free graphitic carbon nitride(g-C3N4) under visible light can successfully achieve efficient activation of peroxymonosulfate(PMS). Synergistic effects and involved mechanism were systematically investigated using a light-inert endocrine disrupting compound, dimethyl phthalate(DMP), as the target pollutant. Under visible light irradiation, DMP could not be degraded by direct g-C3 N4-mediated photocatalysis, while in the presence of PMS, the dominant radicals were converted from ·O2 to SO4·– and ·OH, resulting in effective DMP degradation and mineralization. Results showed that higher dosage of PMS or g-C3 N4 could increase the activation amount of PMS and corresponding DMP degradation efficiency, but the latter approach was more productive in terms of making the most of PMS. High DMP concentration hindered effective contact between PMS and g-C3 N4, but could provide efficient use of PMS. Higher DMP degradation efficiency was achieved at p H lower than the point of zero charge(5.4). Based on intermediates identification, the DMP degradation was found mainly through radical attack(·OH and SO4·–) of the benzene ring and oxidation of the aliphatic chains.展开更多
The alpine treeline ecotone is defined as a forest-grassland or forest-tundra transition boundary either between subalpine forest and treeless grassland,or between subalpine forest and treeless tundra.The alpine treel...The alpine treeline ecotone is defined as a forest-grassland or forest-tundra transition boundary either between subalpine forest and treeless grassland,or between subalpine forest and treeless tundra.The alpine treeline ecotone serves irreplaceable ecological functions and provides various ecosystem services.There are three lines associated with the alpine treeline ecotone,the tree species line(i.e.,the highest elevational limit of individual tree establishment and growth),the treeline(i.e.,the transition line between tree islands and isolated individual trees)and the timber line(i.e.,the upper boundary of the closed subalpine forest).The alpine treeline ecotone is the belt region between the tree species line and the timber line of the closed forest.The treeline is very sensitive to climate change and is often used as an indicator for the response of vegetation to global warming.However,there is currently no comprehensive review in the field of alpine treeline advance under global warming.Therefore,this review summarizes the literature and discusses the theoretical bases and challenges in the study of alpine treeline dynamics from the following four aspects:(1)Ecological functions and issues of treeline dynamics;(2)Methodology for monitoring treeline dynamics;(3)Treeline shifts in different climate zones;(4)Driving factors for treeline upward shifting.展开更多
Food processing and consumption by herbivores are affected differently by the availability of forage quality and quantity per unit of time. This demonstrates the “Allometric response concept”, and it is considered a...Food processing and consumption by herbivores are affected differently by the availability of forage quality and quantity per unit of time. This demonstrates the “Allometric response concept”, and it is considered a significant determinant in habitat use for foraging by grazers. The relevance of this approach has comprehensively been applied to herbivores of different body sizes, but little is known about its demonstration to explain patch use in herbivores with different digestive physiology and body size. We explain the use of patches by grazing herbivores of different digestive physiology and body sizes, Hippopotamus amphibius(hippopotamus, mega non-ruminant) and cattle(ruminant), by integrating foraging relationship herbivores. We analysed the significant relationships between species dropping densities and environmental variables across forty-eight 100 m×100 m plots in Bui National Park,Ghana, during the wet and dry seasons. We found that both species utilised areas closer to the river in the wet season, but the H. amphibius foraged further away from the river during the dry season. Sward height also determined patch use by both species, with the H. amphibius utilising shorter swards than the cattle. Considering the quality of food resources, the study revealed that patch selection of ruminants(cattle) was significantly influenced by nitrogen content. In contrast, acidic detergent fibre content was positively related to non-ruminant species(H.amphibius). The high seasonal effect of sward height and food quality on patch use is primarily due to the species digestive physiology and body size of hippopotamus and cattle at the Bui National Park.展开更多
基金supported by the Natural Science Foundation of Jiangsu Province(BK20160936,BK20160938)the National Natural Science Foundation of China(51708297)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)~~
文摘Excitation of metal-free graphitic carbon nitride(g-C3N4) under visible light can successfully achieve efficient activation of peroxymonosulfate(PMS). Synergistic effects and involved mechanism were systematically investigated using a light-inert endocrine disrupting compound, dimethyl phthalate(DMP), as the target pollutant. Under visible light irradiation, DMP could not be degraded by direct g-C3 N4-mediated photocatalysis, while in the presence of PMS, the dominant radicals were converted from ·O2 to SO4·– and ·OH, resulting in effective DMP degradation and mineralization. Results showed that higher dosage of PMS or g-C3 N4 could increase the activation amount of PMS and corresponding DMP degradation efficiency, but the latter approach was more productive in terms of making the most of PMS. High DMP concentration hindered effective contact between PMS and g-C3 N4, but could provide efficient use of PMS. Higher DMP degradation efficiency was achieved at p H lower than the point of zero charge(5.4). Based on intermediates identification, the DMP degradation was found mainly through radical attack(·OH and SO4·–) of the benzene ring and oxidation of the aliphatic chains.
基金The National Natural Science Foundation of China(41901361)The Six Talent Peaks Project of Jiangsu Province(TD-XYDXX-006)+1 种基金The Natural Science Foundation of Jiangsu Province(BK20180769)The Major Basic Research Project of the Natural Science Foundation of theJiangsu Higher Education Institutions(18KJB180009).
文摘The alpine treeline ecotone is defined as a forest-grassland or forest-tundra transition boundary either between subalpine forest and treeless grassland,or between subalpine forest and treeless tundra.The alpine treeline ecotone serves irreplaceable ecological functions and provides various ecosystem services.There are three lines associated with the alpine treeline ecotone,the tree species line(i.e.,the highest elevational limit of individual tree establishment and growth),the treeline(i.e.,the transition line between tree islands and isolated individual trees)and the timber line(i.e.,the upper boundary of the closed subalpine forest).The alpine treeline ecotone is the belt region between the tree species line and the timber line of the closed forest.The treeline is very sensitive to climate change and is often used as an indicator for the response of vegetation to global warming.However,there is currently no comprehensive review in the field of alpine treeline advance under global warming.Therefore,this review summarizes the literature and discusses the theoretical bases and challenges in the study of alpine treeline dynamics from the following four aspects:(1)Ecological functions and issues of treeline dynamics;(2)Methodology for monitoring treeline dynamics;(3)Treeline shifts in different climate zones;(4)Driving factors for treeline upward shifting.
基金The Priority Academic Program Development of Jiangsu Higher Education Institutions, China (2018-87)。
文摘Food processing and consumption by herbivores are affected differently by the availability of forage quality and quantity per unit of time. This demonstrates the “Allometric response concept”, and it is considered a significant determinant in habitat use for foraging by grazers. The relevance of this approach has comprehensively been applied to herbivores of different body sizes, but little is known about its demonstration to explain patch use in herbivores with different digestive physiology and body size. We explain the use of patches by grazing herbivores of different digestive physiology and body sizes, Hippopotamus amphibius(hippopotamus, mega non-ruminant) and cattle(ruminant), by integrating foraging relationship herbivores. We analysed the significant relationships between species dropping densities and environmental variables across forty-eight 100 m×100 m plots in Bui National Park,Ghana, during the wet and dry seasons. We found that both species utilised areas closer to the river in the wet season, but the H. amphibius foraged further away from the river during the dry season. Sward height also determined patch use by both species, with the H. amphibius utilising shorter swards than the cattle. Considering the quality of food resources, the study revealed that patch selection of ruminants(cattle) was significantly influenced by nitrogen content. In contrast, acidic detergent fibre content was positively related to non-ruminant species(H.amphibius). The high seasonal effect of sward height and food quality on patch use is primarily due to the species digestive physiology and body size of hippopotamus and cattle at the Bui National Park.