Nitrogen⁃doped 3D graphene⁃carbon nanotube network for efficient lithium storage

A 3D nitrogen⁃doped graphene/multi⁃walled carbon nanotube(CS⁃GO⁃NCNT)crosslinked network mate⁃rial was successfully synthesized utilizing chitosan and melamine as carbon and nitrogen sources,concomitant with the incorporation of multi⁃wall carbon nanotubes and employing freeze drying technology.The material amalgamates the merits of 1D/2D hybrid carbon materials,wherein 1D carbon nanotubes confer robustness and expedited elec⁃tron transport pathways,while 2D graphene sheets facilitate rapid ion migration.Furthermore,the introduction of nitrogen heteroatoms serves to furnish additional active sites for lithium storage.When served as an anode material for lithium⁃ion batteries,the CS⁃GO⁃NCNT electrode delivered a reversible capacity surpassing 500 mAh·g^(-1),mark⁃edly outperforming commercial graphite anodes.Even after 300 cycles at a high current density of 1 A·g^(-1),it remained a reversible capacity of up to 268 mAh·g^(-1).

基于优化设计的螺旋千斤顶三维零件库的建立

本文在普通螺旋千斤顶的常规设计基础上建立了其优化设计模型,用VC++编程实现螺旋千斤顶的优化设计。利用UGNX软件建模功能完成螺旋千斤顶的三维参数化建模,利用UGNX3·0软件的部件族功能和二次开发模块,实现螺旋千斤顶零件库的建立。运用优化设计方法与参数化技术实现了千斤顶设计先进性和效率提高的结合。

三七总皂苷对凡纳滨对虾生长性能的影响

选取同一放养批次健康的凡纳滨对虾,随机分为5组。第1组为空白对照组,饲喂基础饲料,其他4组为三七总皂苷组,分别添加100、200、400和800mg/kg三七总皂苷试验饲料。每组3个重复,每重复40尾虾,试验期40d。结果表明:在饲料中添加适宜水平三七总皂苷能显著提高凡纳滨对虾的增重率和特定生长率,降低饲料系数,提高蛋白质效率,添加不同水平三七总皂苷对凡纳滨对虾肌肉粗蛋白、粗脂肪、灰分和水分含量无显著影响。

Z-scheme N-doped K4Nb6O17/g-C3N4 heterojunction with superior visible-light-driven photocatalytic activity for organic pollutant removal and hydrogen production

A simple calcination method was employed to prepare a Z-scheme N-doped K4Nb6O17/g-C3N4(KCN)heterojunction photocatalyst,in which the electronic structure of K4Nb6O17 was regulated by N-doping,and g-C3N4 was formed both on the surface and within the interlayer spaces of K4Nb6O17.The KCN composite showed profoundly improved photocatalytic activity for both H2 generation and RhB degradation compared to its counterparts.This improved performance was attributed to the synergistic effects of N-doping,which broadened its light harvesting ability,and heterojunction formation,which increased the charge separation rate.The relatively low BET specific surface area of the KCN composite had little effect on its photocatalytic activity.Based on ESR spectroscopy studies,•O2^−,•OH,and h^+are the main active species in the photocatalytic degradation of RhB.Thus,it is reasonable to propose a Z-scheme photocatalytic mechanism over the KCN composite,which exhibits the dual advantages of efficient charge separation and high redox ability.Our work provides a simple approach for constructing large-scale Z-scheme heterojunction photocatalysts with high photocatalytic performance.

An efficient and stable Cu/SiO_2 catalyst for the syntheses of ethylene glycol and methanol via chemoselective hydrogenation of ethylene carbonate

The efficient synthesis of methanol and ethylene glycol via the chemoselective hydrogenation of ethylene carbonate（EC） is important for the sustainable utilization of CO_2 to produce commodity chemicals and fuels. In this work, a series of β-cyclodextrin-modified Cu/SiO_2 catalysts were prepared by ammonia evaporation method for the selective hydrogenation of EC to co-produce methanol and ethylene glycol. The structure and physicochemical properties of the catalysts were characterized in detail by N_2 physisorption, XRD, N_2O titration, H_2-TPR, TEM, and XPS/XAES. Compared with the unmodified 25 Cu/SiO_2 catalyst, the involvement of β-cyclodextrin in 5β-25 Cu/SiO_2 could remarkably increase the catalytic activity—excellent activity of 1178 mgEC g_（cat）^（–1） h^（–1） with 98.8%ethylene glycol selectivity, and 71.6% methanol selectivity could be achieved at 453 K. The remarkably improved recyclability was primarily attributed to the remaining proportion of Cu~＋/（Cu^0＋Cu~＋）. Furthermore, the DFT calculation results demonstrated that metallic Cu^0 dissociated adsorbed H_2, while Cu~＋ activated the carbonyl group of EC and stabilized the intermediates. This study is a facile and efficient method to prepare highly dispersed Cu catalysts—this is also an effective and stable heterogeneous catalyst system for the sustainable synthesis of ethylene glycol and methanol via indirect chemical utilization of CO_2.

2D/2D S-scheme heterojunction with a covalent organic framework and g-C_(3)N_(4) nanosheets for highly efficient photocatalytic H2 evolution

The fabrication of S-scheme heterojunctions with fast charge transfer and good interface contacts,such as intermolecularπ–πinteractions,is a promising approach to improve photocatalytic performance.A unique two-dimensional/two-dimensional(2D/2D)S-scheme heterojunction containing TpPa-1-COF/g-C_(3)N_(4) nanosheets(denoted as TPCNNS)was developed.The established maximum interfacial interaction between TpPa-1-COF NS and g-C_(3)N_(4) NS may result in aπ–πconjugated heterointerface.Furthermore,the difference in the work functions of TpPa-1-COF and g-C_(3)N_(4) results in a large Fermi level gap,leading to upward/downward band edge bending.The spontaneous interfacial charge transfer from g-C_(3)N_(4) to TpPa-1-COF at theπ–πconjugated interface area results in the presence of a built-in electric field,according to the charge density difference analysis based on density functional theory calculations.Such an enhanced built-in electric field can efficiently drive directional charge migration via the S-scheme mechanism,which enhances charge separation and utilization.Thus,an approximately 2.8 and 5.6 times increase in the photocatalytic hydrogen evolution rate was recorded in TPCNNS-2(1153μmol g^(-1) h^(-1))compared to pristine TpPa-1-COF and g-C_(3)N_(4) NS,respectively,under visible light irradiation.Overall,this work opens new avenues in the fabrication of 2D/2Dπ–πconjugated S-scheme heterojunction photocatalysts with highly efficient hydrogen evolution performance.

预应力锚索边坡加固设计、施工技术

介绍了吉林长晖公路K115＋530～K116＋176处高边坡的不良地质情况及对该高边坡采取的加固措施，重点介绍了新型压力分散型预应力锚索加固高边坡的机理、施工工艺及锚索测试试验技术，可供同行们在处理同类型问题时参考。

A Deadlock-Avoidance Dispatching Method for Multiple-Load AGVs Based Transportation System

In recent years,multiple-load automatic guided vehicle(AGV)is increasingly used in the logistics transportation fields,owing to the advantages of smaller fleet size and fewer occurrences of traffic congestion.However,one main challenge lies in the deadlock-avoidance for the dispatching process of a multiple-load AGV system.To prevent the system from falling into a deadlock,a strategy of keeping the number of jobs in the system(NJIS)at a low level is adopted in most existing literatures.It is noteworthy that a low-level NJIS will make the processing machine easier to be starved,thereby reducing the system efficiency unavoidably.The motivation of the paper is to develop a deadlock-avoidance dispatching method for a multiple-load AGV system operating at a high NJIS level.Firstly,the deadlock-avoidance dispatching method is devised by incorporating a deadlock-avoidance strategy into a dispatching procedure that contains four sub-problems.In this strategy,critical tasks are recognized according to the status of workstation buffers,and then temporarily forbidden to avoid potential deadlocks.Secondly,three multiattribute dispatching rules are designed for system efficiency,where both the traveling distance and the buffer status are taken into account.Finally,a simulation system is developed to evaluate the performance of the proposed deadlock-avoidance strategy and dispatching rules at different NJIS levels.The experimental results demonstrate that our deadlock-avoidance dispatching method can improve the system efficiency at a high NJIS level and the adaptability to various system settings,while still avoiding potential deadlocks.

车轮转速的智能检测装置

介绍一种采用新型霍尔开关元件作轮速传感器的车轮转速检测装置。介绍了测量装置的构成，具体分析了转速、特别是在低转速时的高精度测量方法。

Chip Formation Mechanism of Deep?Hole Gun Drilling of Ti6Al4V Titanium Alloy

During the process of deep?hole gun drilling,the shape of the chip is a significant factor affecting the final quality.The relationship between chip forming mechanism and process parameters has always been a complicated problem in deep?hole drilling.This paper investigates Ti6Al4V titanium alloy to address this issue.First,the four processes and influencing factors of forming spiral chips are analyzed theoretically.Second,the fracture mechanism of chips in drilling Ti6Al4V titanium alloy is analyzed by scanning electron microscopy.Finally,the influences of cutting speed,feed rate and coolant oil pressure on chip shape are analyzed through drilling experiments and fluid simulation.The relationship between chip compression ratio and surface roughness is obtained through chip thickness measurement.This research can provide a guide for optimizing parameters of deep?hole gun drilling on Ti6Al4V titanium alloy.

Effects of different methods of introducing Mo on denitration performance and anti‐SO_(2)poisoning performance of CeO_(2)

Cerium‐based catalysts are very attractive for the catalytic abatement of nitrogen oxides(NOx)emitted from stationary sources.However,the main challenge is still achieving satisfactory catalytic activity in the low‐temperature range and tolerance to SO2 poisoning.In the present work,two series of Mo‐modified CeO_(2)catalysts were respectively obtained through a wet impregnation method(Mo‐CeO_(2))and a co‐precipitation method(MoCe‐cp),and the roles of the Mo species were systematically investigated.Activity tests showed that the Mo‐CeO_(2)catalyst displayed much higher NO conversion at low temperature and anti‐SO2 ability than MoCe‐cp.The optimal Mo‐CeO_(2)catalyst displayed over 80%NO elimination efficiency even at 150°C and remarkable SO2 resistance at 250°C(nearly no activity loss after 40 h test).The characterization results indicated that the introduced Mo species were highly dispersed on the Mo‐CeO_(2)catalyst surface,thereby providing more Brønsted acid sites and inhibiting the formation of stable adsorbed NOx species.These factors synergistically promote the selective catalytic reduction(SCR)reaction in accordance with the Eley‐Rideal(E‐R)reaction path on the Mo‐CeO_(2)catalyst.Additionally,the molybdenum surface could protect CeO_(2)from SO2 poisoning;thus,the reducibility of the Mo‐CeO_(2)catalyst declined slightly to an adequate level after sulfation.The results in this work indicate that surface modification with Mo species may be a simple method of developing highly efficient cerium‐based SCR catalysts with superior SO2 durability.

Well Dispersed SnO2 Nanoclusters Preparation and Modulation of Metal-Insulator Transition Induced by Ionic Liquid

Tin dioxide (SnO2) has attracted broad interest due to its particular gas-sensor property. Nano- or atom-scale SnO2 material has always been the aim in order to ultimately improve the sensitivity. However, until now, it remains difficult to synthesize SnO2 nanoclusters by using traditional methods. In the present work, we have achieved the preparation of SnO2 nanoclusters by using the cluster beam deposition technique. The obtained nanoclusters were well characterized by high resolution transmission electron microscope HR-TEM. Results indicated the formation of the well-dispersed SnO2 nanoclusters with uniform size distribution (5-7 nm). Furthermore, an obvious metal insulator transition was observed by gating with ionic liquid. Combined with theory calculation, the corresponding mechanism was systematically analyzed from oxygen vacancy induced electron doping.

First Principles Study of Atomic Adsorption on (111) and (100) Surfaces of Iridium

We have investigated the adsorption of nine different adatoms on the(111)and(100)surfaces of Iridium(Ir)using first principles density functional theory.The study explores surface functionalization of Ir which would provide important information for further study of its functionality in catalysis and other surface applications.The adsorption energy,stable geometry,density of states and magnetic moment are some of the physical quantities of our interest.The study reveals that the three-/four-fold hollow site is energetically the most favorable adsorption site on the(111)/(100)surface of Ir.The investigation on a wide range of coverages(from 0.04 to 1 monolayer)reveals the strong coverage dependence of adsorption energy of the adsorbate atoms.The adsorption energy is found to increase as the coverage increases,implying a repulsive interaction between the adsorbates.Strong hybridization between the adsorbates and the substrate electronic states is revealed to impact the adsorption,while the magnetic moment of the adsorbates is found to be suppressed.The Bader analysis reveals significant amount of charge transfers between the adsorbate atoms and the substrate.The binding of adsorbate atoms on the(100)surface is observed to be moderately stronger as compared to that on the(111)surface.

Influence of Coolant on Chip Forming in Gun⁃Drill Based on Fluid⁃Solid Coupling Method

Chip shape is one of the important factors that affect the processing quality of the deep hole.The flow field of 17 mm standard gun-drill is simulated by taking the coolant pressure as a single factor variable,and the influence of coolant pressure on chip forming is discussed by combining with experiments in this paper.The results show that at the initial stage of chip forming,the flow of cutting fluid will intensify the lateral crimp of chips,and then affect the crimp radius of the chip and the number of turns of the crimp screw.The lateral crimp degree increases first and then decreases with the increase of coolant pressure,and the crimp degree is the smallest at 3 MPa.In addition,during the chip removal process,the stream shrinking in the flow field is the main influencing factor that drive and force the chip to break again,and their influence on the chip removal and chip breaking is proportional to the coolant pressure.

Palladium-Carbon Composite Nanoparticle Films with Enhanced Electrocatalytic Activity for Hydrogen Peroxide Sensors

A nanocomposite electrocatalyst was prepared with the method of cluster beam deposition of palladium nanoparticle thin lms on carbon nanoparticle supporting layers and used as sensitive nonenzyme hydrogen peroxide sensors. An enhancement on the electrocatalytic activity of the palladium nanoparticles toward H2O2 reduction was observed, which was related to the coverage of the carbon nanoparticles. With one monolayer of carbon nanoparticles, the H2O2 detection sensitivity reached the maximum, which was more than twice of that of the pure Pd nanoparticles.

河北省科学技术进步二等奖“既有建筑效能提升关键技术及应用”简介

河北地质大学教授曹秀玲主持的“既有建筑效能提升关键技术及应用”项目获得2021年河北省科学技术进步二等奖。城市更新、效能提升、老旧小区改造是我国急需解决的重大民生问题。为此,我校曹秀玲教授团队以既有建筑效能提升为目的,经十几年潜心研究,系统研发了既有建筑效能提升关键技术,提升了既有建筑的安全性及品质,推动了抗震加固、节能减排、智能建筑等相关产业融合,申请专利20件,软件著作权6件,发表论文71篇;出版专著9部,建筑图集2部,为既有建筑效能提升提供技术支撑。

制药分离工程课堂教学方法探索

制药分离工程是制药工程专业的一门核心课程,通过对制药分离工程教学中积累的经验以及课程和专业学生的特点的相关分析,在实际的教学过程中对课程的内容、教学的方式、培养学生的自学能力等方面进行改进。在教学过程中多媒体的运用不仅可以增加课堂趣味性,也可以吸引学生的注意力,从而提高知识传授质量,从而达到更好的教学效果。

基于ARCS模型的英语词汇移动学习研究

英语单词难记易忘是困扰我国学生英语学习的一大难题,究其原因主要是单词分步记忆的不科学。本文基于ARCS模型,通过数据分析、测试及归纳探讨出适合我国学生英语词汇移动学习实践的策略,旨在帮助中国学生走出英语词汇记忆性学习的困境,并运用多元化的移动方式学习词汇,使用词汇,进一步帮助更多学生灵活地学好英语,应用好英语。

“绿色建筑设计工作室”——基于多学科协作的绿色建筑集成设计平台

随着我国对建筑的节能减排日益重视,已在建筑节能领域取得了长足进步,但,运用现有的模拟技术和软件尚不能有效的辅助实现基于建筑性能的整体建筑设计。"绿建设计工作室VDS-GB"(Virtual Design Studio for Green Building)正是1个为促进多学科集成设计而研发的软件平台,该平台可以在建筑设计全过程中协助建筑师、工程师和项目管理团队之间的合作,辅助建筑能耗及建筑环境的优化设计。该软件目前正在研发中,其开发需要满足和实现绿色建筑设计过程中各个学科的要求。本文主要阐述了:VDS-GB软件平台的研发目标和设计要求;与绿色建筑设计的设计流程、性能优化策略相关联的方法;并用1个简化的设计案例说明VDS-GB的用户工作流程。