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脉冲激光沉积具有锂离子储存能力的CeO_2薄膜 被引量:6
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作者 蒋立中 周鸣飞 +1 位作者 刘先年 秦启宗 《物理化学学报》 SCIE CAS CSCD 北大核心 1999年第8期752-756,共5页
CeO2 then films have been fabricated on stainless steel substrate heated at 700℃ in an oxygen ambient by pulsed laser deposition. SEM showed that as-deposited films are mainly com- posed of uniform nanocrystalline pa... CeO2 then films have been fabricated on stainless steel substrate heated at 700℃ in an oxygen ambient by pulsed laser deposition. SEM showed that as-deposited films are mainly com- posed of uniform nanocrystalline particles. Films were characterized by X-ray diffraction from which the oxygen deficient polycrystalline Ce6O11, with a modified monoclinic strUcture has been demon- strated. The electrochemical properties of the films were measured with cyclic voltammetry and galvonostatic charge /discharge techniques. Our results showed that the CeO2 film exhibits good cy- clibility with a reversible capacity of 45mC. cm-2(in the range of 0.1 to 1.5V at current density 40μA. cm-2). It can be suggested that CeO2 thin film is suitable for the anode of Li rechargeable microbattery. 展开更多
关键词 阳极 锂离子电池 锂离子嵌入 氧化铈薄膜 储存
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