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媒体融合背景下科技期刊OSID出版应用问题及出路探寻——以《太原理工大学学报》为例 被引量:1
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作者 薄小玲 贾丽红 《学报编辑论丛》 2021年第1期482-487,共6页
在信息技术迅速发展的大背景下,具体以《太原理工大学学报》为例,分析了媒体融合背景下科技期刊OSID出版发展的必要性,对比分析了OSID出版与传统出版的优劣,以及《太原理工大学学报》编辑部在出版应用过程中遇到的实际问题,针对问题提... 在信息技术迅速发展的大背景下,具体以《太原理工大学学报》为例,分析了媒体融合背景下科技期刊OSID出版发展的必要性,对比分析了OSID出版与传统出版的优劣,以及《太原理工大学学报》编辑部在出版应用过程中遇到的实际问题,针对问题提出相应的措施,为科技期刊更好地实现OSID出版提供借鉴和思路。 展开更多
关键词 媒体融合 科技期刊 OSID出版 开放计划 太原理工大学学报
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《太原理工大学学报》(社科版)荣获“全国优秀社科学报”奖
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《太原理工大学学报(社会科学版)》 2006年第3期44-44,共1页
经教育部社科司同意,中国人文社科学报学会于2006年1月至4月开展了第三届全国高校社科学报评优活动,旨在展示2002年教育部高校社科学报工作会议以来社科学报取得的成绩。在此次评优活动中,我刊荣获“全国优秀社科学报”奖。
关键词 高校社科学报 大学学报 社科版 原理 人文社科学报 评优活动 学报工作 教育部
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成形路径对Al/CFRTP/Al层板冲压成形特性的影响
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作者 王健 王重阳 +2 位作者 丁梓峻 熊浪 胥亮 《塑性工程学报》 CAS CSCD 北大核心 2024年第9期36-45,共10页
为提升纤维金属层板成形质量和成形精度,研究了不同成形路径对Al/CFRTP/Al层板冲压成形特性的影响规律。通过回弹角度测量、微观形貌分析以及三点弯曲试验,研究了制板成形、成形固化和混合共冲3种不同成形路径对纤维金属层板U形件成形... 为提升纤维金属层板成形质量和成形精度,研究了不同成形路径对Al/CFRTP/Al层板冲压成形特性的影响规律。通过回弹角度测量、微观形貌分析以及三点弯曲试验,研究了制板成形、成形固化和混合共冲3种不同成形路径对纤维金属层板U形件成形特性的影响。结果表明,混合共冲制备的试件回弹角度为1.34°,中间层内外侧0°方向碳纤维发生拉伸断裂,并形成了贫富树脂区和厚度不均匀等宏观缺陷。成形固化制备的试件回弹角度为2.84°,中间层内外侧0°方向碳纤维均发生拉伸断裂,厚度分布均匀,无宏观缺陷,综合性能较好,成形质量较为可控。 展开更多
关键词 Al/CFRTP/Al层板 冲压成形 成形路径 回弹角度 成形质量
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In-situ photodeposition of co-catalyst Ni_(2)P on CdS for photocatalytic conversion of ethanol for synergistic hydrogen production
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作者 LIU Yiming MIAO Jingjing +2 位作者 ZHANG Wanggang WEI Aili WANG Jian 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第11期1629-1640,共12页
In this study,Ni_(2)P/CdS composites were constructed by depositing non-precious metal co-catalyst Ni_(2)P on a one-dimensional network of CdS using a simple in-situ photodeposition method.The prepared photocatalysts ... In this study,Ni_(2)P/CdS composites were constructed by depositing non-precious metal co-catalyst Ni_(2)P on a one-dimensional network of CdS using a simple in-situ photodeposition method.The prepared photocatalysts promoted the decomposition of ethanol into high-value-added products while generating hydrogen.The composite photoanodes loaded with the Ni_(2)P co-catalysts showed significantly higher ethanol conversion and hydrogen production in the visible light region,which was almost three times higher than that of pure CdS.The main products of photocatalytic ethanol production are acetaldehyde(AA)and 2,3-butanediol(2,3-BDA).Compared with CdS,the selectivity of the composite photocatalysts for converting ethanol to acetaldehyde was significantly improved(62% to 78%).Characterization of the prepared photocatalysts confirmed that the loading of Ni_(2)P co-catalysts on CdS not only broadened the optical region of the catalysts for trapping light but also effectively promoted the separation and transfer of charge carriers,which significantly improved the photocatalytic efficiency of ethanol conversion and hydrogen production in the catalysts.It has been proven through Electron Paramagnetic Resonance testing that loading a Ni_(2)P co-catalyst on CdS is beneficial for the adsorption of hydroxyethyl radicals(*CH(OH)CH_(3)),thereby further improving the selectivity of acetaldehyde.This study plays an important role in the rational design of composite catalyst structures and the introduction of co-catalysts to improve catalyst performance,promote green chemistry,advocate a low-carbon society,and promote sustainable development. 展开更多
关键词 photocatalysis Ni_(2)P/CdS ethanol conversion hydrogen production
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Design Method for Optimizing the Interactive Interface of Live Broadcasting Platform for the Elderly Users
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作者 WEI Bi-ze FAN Wei DUAN Ying-ke 《印刷与数字媒体技术研究》 CAS 北大核心 2024年第4期167-178,共12页
In the era of network live broadcasting for everyone,the development of live broadcasting platforms is also more intelligent and diversified.However,in the face of a large group of elderly users,the interface interact... In the era of network live broadcasting for everyone,the development of live broadcasting platforms is also more intelligent and diversified.However,in the face of a large group of elderly users,the interface interaction design mode used is still mainly based on the interaction mode for young groups,and is not designed for elderly users.Therefore,a design method for optimizing the interaction interface of live broadcasting platform for elderly users was proposed in this study.Firstly,the case study method and Delphi expert survey method were used to determine the design needs of elderly users and the design mode was analysed.Secondly,the orthogonal design principle was used to design a test sample of the interactive interface of live broadcasting platform applicable for the elderly users,and then a user evaluation system was established to calculate the weights of the design elements using hierarchical analysis,and then the predictive relationship between the design mode of the interactive interface of live broadcasting platform and the elderly users was established by Quantitative Theory I.Finally,Genetic Algorithm was applied to generate the optimized design scheme.The results showed that the design method based on the Genetic Algorithm and the combination of Quantitative Theory can scientifically and effectively optimize the design of the interactive interface of the live broadcasting platform for the elderly users,and improve the experience of the elderly users. 展开更多
关键词 Live broadcasting platform Interaction design Elderly users Genetic Algorithm Quantitative Theory I
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The use of carbon-based particle electrodes in three-dimensional electrode reactors for wastewater treatment
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作者 LU Hua-yu LIU Wei-feng +1 位作者 QIN Lei LIU Xu-guang 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第5期973-991,共19页
The use of three-dimensional(3D)electrodes in water treatment is competitive because of their high catalytic efficiency,low energy consumption and promising development.The use of particle electrodes is a key research... The use of three-dimensional(3D)electrodes in water treatment is competitive because of their high catalytic efficiency,low energy consumption and promising development.The use of particle electrodes is a key research focus in this technology.They are usually in the form of particles that fill the space between the cathode and anode,and the selection of materials used is important.Carbon-based materials are widely used because of their large specific surface area,good adsorption performance,high chemical stability and low cost.The principles of 3D electrode technology are introduced and recent research on its use for degrading organic pollutants using carbon-based particle electrodes is summarized.The classification of particle electrodes is introduced and the challenges for the future development of carbon-based particle electrodes in wastewater treatment are discussed. 展开更多
关键词 Environmental pollution Three-dimensional electrode technology Carbon-based materials Carbon-based particle electrode
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镁/铝复合板热轧过程轧制力和厚度预测与分析
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作者 苏军 郝平菊 +2 位作者 刘元铭 王振华 王涛 《中国有色金属学报》 EI CAS CSCD 北大核心 2024年第8期2627-2640,共14页
热轧镁/铝复合板各层厚度直接决定了它能否满足不同环境条件下的使用要求,因此,研究决定各层厚度的轧制力和厚度预测模型对轧制过程控制和产品的性能提升具有重要的意义。本文建立了AZ31B镁合金和5052铝合金在轧制过程中变形抗力的PSO-B... 热轧镁/铝复合板各层厚度直接决定了它能否满足不同环境条件下的使用要求,因此,研究决定各层厚度的轧制力和厚度预测模型对轧制过程控制和产品的性能提升具有重要的意义。本文建立了AZ31B镁合金和5052铝合金在轧制过程中变形抗力的PSO-BP预测模型,高精度地表征其在不同温度、应变和应变速率下的变形特性。结果表明:镁合金对应模型的的R2、RMSE和AARE分别为0.99165、3.4251和0.56%,铝合金对应模型的R2、RMSE和AARE分别为0.99496、2.8092和1.43%,验证了PSO-BP模型用于描述两种金属材料的准确性和可靠性。在镁/铝复合板轧制过程中,轧制力随着压下率和入口总厚度的增加而增大,随着入口厚比的减小,轧制力呈增大的趋势。镁/铝复合板出口厚比随着压下率和入口总厚度的增大而减小,随着入口厚比的减小,出口厚比也呈减小的趋势。 展开更多
关键词 镁/铝复合板 PSO-BP神经网络 变形抗力 轧制力 各层厚度
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Hydrogen production performance of the non⁃platinum⁃based MoS_(2)/CuS cathode in microbial electrolytic cells
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作者 HAO Pingping LI Fangfang +5 位作者 WANG Yawen LI Houfen ZHANG Xiao LI Rui WANG Lei LIU Jianxin 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第9期1811-1824,共14页
MoS_(2)/CuS composite catalysts were successfully synthesized using a one-step hydrothermal method with sodium molybdate dihydrate,thiourea,oxalic acid,and copper nitrate trihydrate as raw materials.The hydrogen pro-d... MoS_(2)/CuS composite catalysts were successfully synthesized using a one-step hydrothermal method with sodium molybdate dihydrate,thiourea,oxalic acid,and copper nitrate trihydrate as raw materials.The hydrogen pro-duction performance of MoS_(2)/CuS prepared with different molar ratios of Mo to Cu precursors(n_(Mo)∶n_(Cu))as cathodic catalysts was investigated in the two-chamber microbial electrolytic cell(MEC).X-ray diffraction(XRD),X-ray pho-toelectron spectroscopy(XPS),scanning electron microscopy(SEM),transmission electron microscope(TEM),linear scanning voltammetry(LSV),electrochemical impedance analysis(EIS),and cyclic voltammetry(CV)were used to characterize the synthesized catalysts for testing and analyzing the hydrogen-producing performance.The results showed that the hydrogen evolution performance of MoS_(2)/CuS-20%(nMo∶nCu=5∶1)was better than that of platinum(Pt)mesh,and the hydrogen production rate of MoS_(2)/CuS-20%as a cathode in MEC was(0.2031±0.0237)m^(3)_(H_(2))·m^(-3)·d^(-1) for 72 h at an applied voltage of 0.8 V,which was slightly higher than that of Pt mesh of(0.1886±0.0134)m^(3)_(H_(2))·m^(-3)·d^(-1).The addition of a certain amount of CuS not only regulates the electron transfer ability of MoS_(2) but also increases the density of active sites. 展开更多
关键词 microbial electrolysis cell hydrogen evolution reaction MoS_(2)/CuS composite catalyst Pt mesh
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Polycrystalline ZSM-5 Aggregates Induced by Seed and Catalytic Performance in Methanol to Hydrocarbon
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作者 WANG Xuchang JIAO Chuyu +5 位作者 JI Zhuo JIAO Qirui QIN Bo DU Yanze ZHENG Jiajun LI Ruifeng 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2024年第8期945-954,I0010-I0013,共14页
Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use ... Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use of organic templates and the subsequent calcination procedure.This not only reduces the cost of synthesis,but also prevents environmental pollution from the combustion of organic templates,representing an eco-friendly approach.Despite this,literature suggests that even so-called template-free synthesis systems often involve trace amount of organic substances like alcohol.In the present work,a calcined commercial ZSM-5 zeolite was served as seed,with sodium aluminate as aluminum source and silica sol as silicon source,ensuring an entirely template-free synthesis system.Polycrystalline ZSM-5 aggregates consisted of rod-like nanocrystals were successfully prepared in the completely OSDA-free system.Effects of the Si/Al ratio in ZSM-5 seed,dosage and crystallization conditions such as crystallization temperature and crystallization time on ZSM-5 synthesis were investigated.The results show that a highly crystallinity ZSM-5 aggregate consisting of primary nano-sized crystals less than 100 nm is produced from a gel precursor with 5.6%(in mass)seed after hydrothermal treatment for 48 h.Furthermore,the Si/Al ratio in ZSM-5 seed has little effect on the topological structure and pore structure of the synthesized samples.However,the seeds with a low Si/Al ratio facilitate faster crystallization of zeolite and enhance the acidity,especially the strong acid centers,of the catalyst.The catalytic performance of the synthesized polycrystalline ZSM-5 was evaluated during dehydration of methanol and compared with a commercial reference ZSM-5r.The results exhibit that as compared with the reference catalyst,the fabricated sample has a longer catalytic lifetime(16 h vs 8 h)attributed to its hierarchical pores derived from the loosely packed primary nanoparticles.Additionally,the prepared polycrystalline catalyst also exhibits a higher aromatics selectivity(28.1%-29.8%vs 26.5%). 展开更多
关键词 ZSM-5 polycrystalline aggregate crystal seed structure guiding agent
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Effects ofslip mode on microstructure evolution and compressive flow behavior of extruded dilute Mg−0.5Bi−0.5Sn−0.5Mn alloy
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作者 Zhi-yong YOU Wei-li CHENG +6 位作者 Guo-lei LIU Jian LI Li-fei WANG Hui YU Hong-xia WANG Ze-qin CUI Jin-hui WANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第11期3599-3614,共16页
The influence of the slip mode on the microstructure evolution and compressive flow behavior at different strains in an extruded dilute Mg−0.5Bi−0.5Sn−0.5Mn alloy was analyzed through electron backscatter diffraction,... The influence of the slip mode on the microstructure evolution and compressive flow behavior at different strains in an extruded dilute Mg−0.5Bi−0.5Sn−0.5Mn alloy was analyzed through electron backscatter diffraction,X-ray diffraction,transmission electron microscopy,and hot compression tests.The results showed that at a low strain of 0.05,the basal,pyramidaland<c+a>slip modes were simultaneously activated.Nevertheless,at the middle stage of deformation(strain of 0.1,0.2 and 0.5),theslip mode was difficult to be activated and<c+a>slip mode became dominant.The deformation process between strains of 0.2 and 0.5 was primarily characterized by the softening effect resulting from the simultaneous occurrence of continuous dynamic recrystallization and discontinuous dynamic recrystallization.Ultimately,at strain of 0.8,a dynamic equilibrium was established,with the flow stress remaining constant due to the interplay between the dynamic softening brought about by discontinuous dynamic recrystallization and the work-hardening effect induced by the activation of the basalslip mode. 展开更多
关键词 dilute Mg−Bi−Sn−Mn alloy slip mode hot compression flow behavior dynamic recrystallization
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基于梯度下降的串联机械臂逆运动学求解
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作者 郑涧 史汉卿 +2 位作者 张金柱 王涛 黄庆学 《组合机床与自动化加工技术》 北大核心 2024年第11期78-82,共5页
将梯度下降法用于机械臂的逆运动学求解,解决了不同自由度串联机械臂逆运动学求解的问题;将求解过程中间解利用起来,在保证了系统性能的同时,完成了轨迹规划任务;针对使用梯度下降得到的轨迹较差的问题,采用改进的梯度下降对轨迹进行了... 将梯度下降法用于机械臂的逆运动学求解,解决了不同自由度串联机械臂逆运动学求解的问题;将求解过程中间解利用起来,在保证了系统性能的同时,完成了轨迹规划任务;针对使用梯度下降得到的轨迹较差的问题,采用改进的梯度下降对轨迹进行了优化。用OpenGL和C++搭建了仿真平台,对六自由度和七自由度机械臂进行了仿真,算法收敛精度可达到0.01 mm,实验结果表明将梯度下降用于机械臂逆运动学求解具有实用性。 展开更多
关键词 机械臂 梯度下降法 正逆运动学 轨迹规划
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Single atom doping induced charge-specific distribution of Cu1-TiO_(2) for selective aniline oxidation via a new mechanism
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作者 Jiaheng Qin Wantong Zhao +6 位作者 Jie Song Nan Luo Zheng-Lan Ma Baojun Wang Jiantai Ma Riguang Zhang Yu Long 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第9期98-111,共14页
Utilizing single atom sites doping into metal oxides to modulate their intrinsic active sites,achieving precise selectivity control in complex organic reactions,is a highly desirable yet challenging endeavor.Meanwhile... Utilizing single atom sites doping into metal oxides to modulate their intrinsic active sites,achieving precise selectivity control in complex organic reactions,is a highly desirable yet challenging endeavor.Meanwhile,identifying the active site also represents a significant obstacle,primarily due to the intricate electronic environment of single atom site doped metal oxide.Herein,a single atom Cu doped TiO_(2)catalyst(Cu_(1)-TiO_(2)) is prepared via a simple“colloid-acid treatment”strategy,which switches aniline oxidation selectivity of TiO_(2) from azoxybenzene to nitrosobenzene,without using additives or changing solvent,while other metal or nonmetal doped TiO_(2) did not possess.Comprehensive mechanistic investigations and DFT calculations unveil that Ti-O active site is responsible for triggering the aniline to form a new PhNOH intermediate,two PhNOH condense to azoxybenzene over TiO_(2) catalyst.As for Cu_(1)-TiO_(2),the charge-specific distribution between the isolated Cu and TiO_(2) generates unique Cu_(1)-O-Ti hybridization structure with nine catalytic active sites,eight of them make PhNOH take place spontaneous dissociation to produce nitrosobenzene.This work not only unveils a new mechanistic pathway featuring the PhNOH intermediate in aniline oxidation for the first time but also presents a novel approach for constructing single-atom doped metal oxides and exploring their intricate active sites. 展开更多
关键词 Single atom doped metal oxide Aniline oxidation Selectivity New mechanism Active site
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The relationship between the high-frequency performance of supercapacitors and the type of doped nitrogen in the carbon electrode
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作者 FAN Ya-feng YI Zong-lin +6 位作者 ZHOU Yi XIE Li-jing SUN Guo-hua WANG Zhen-bing Huang Xian-hong SU Fang-yuan CHEN Cheng-meng 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第5期1015-1026,共12页
Nitrogen doping has been widely used to improve the performance of carbon electrodes in supercapacitors,particularly in terms of their high-frequency response.However,the charge storage and electrolyte ion response me... Nitrogen doping has been widely used to improve the performance of carbon electrodes in supercapacitors,particularly in terms of their high-frequency response.However,the charge storage and electrolyte ion response mechanisms of different nitrogen dopants at high frequencies are still unclear.In this study,melamine foam carbons with different configurations of surfacedoped N were formed by gradient carbonization,and the effects of the configurations on the high-frequency response behavior of the supercapacitors were analyzed.Using a combination of experiments and first-principle calculations,we found that pyrrolic N,characterized by a higher adsorption energy,increases the charge storage capacity of the electrode at high frequencies.On the other hand,graphitic N,with a lower adsorption energy,increases the speed of ion response.We propose the use of adsorption energy as a practical descriptor for electrode/electrolyte design in high-frequency applications,offering a more universal approach for improving the performance of N-doped carbon materials in supercapacitors. 展开更多
关键词 High-frequency supercapacitors Carbon electrodes Doped nitrogen species Adsorption energy DESCRIPTOR
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难变形合金用轧辊感应加热温度控制策略及温辊轧制实验
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作者 张帅帅 李苒 +5 位作者 牛辉 王昊 卫俊鑫 袁振豪 贾燚 韩建超 《塑性工程学报》 CAS CSCD 北大核心 2024年第6期235-243,共9页
针对轧辊电磁感应加热温度控制方法展开研究,开发了轧辊温度控制策略,调控轧辊辊面工作区温度。通过DEFORM模拟轧辊感应加热过程辨识轧辊感应加热数学模型参数,结合自适应模糊PID控制算法使用Simulink进行控制器的搭建与仿真,并进行轧... 针对轧辊电磁感应加热温度控制方法展开研究,开发了轧辊温度控制策略,调控轧辊辊面工作区温度。通过DEFORM模拟轧辊感应加热过程辨识轧辊感应加热数学模型参数,结合自适应模糊PID控制算法使用Simulink进行控制器的搭建与仿真,并进行轧辊静态局部感应加热温度调控实验验证。结果表明,辊面温度围绕目标温度值小幅振荡,温度控制过程无超调,预设温度550℃时最大误差小于25℃。最后与传统包套轧制工艺进行对比,分析温辊轧制Ti/Ti Al复合板的显微组织,结果表明温辊轧制工艺使Ti Al侧具有更细小的晶粒尺寸,界面区域宽度为75μm,通过轧辊加热和减小包套厚度使界面宽度减小25%。 展开更多
关键词 轧辊感应加热 温度闭环控制 自适应模糊PID 温辊轧制
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High Sensitivity Submicron Scale Temperature Sensor Based on Perovskite Nanoplatelet Lasers
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作者 ZHAO Ruofan TAO Jianxun +7 位作者 XI Yuying CHEN Jiangzhao JI Ting WANG Wenyan WEN Rong CUI Yanxia CHEN Junsheng LI Guohui 《发光学报》 EI CAS CSCD 北大核心 2024年第9期1511-1520,共10页
Submicron scale temperature sensors are crucial for a range of applications,particularly in micro and na-noscale environments.One promising solution involves the use of active whispering gallery mode(WGM)microresonato... Submicron scale temperature sensors are crucial for a range of applications,particularly in micro and na-noscale environments.One promising solution involves the use of active whispering gallery mode(WGM)microresonators.These resonators can be remotely excited and read out using free-space structures,simplifying the process of sensing.In this study,we present a submicron-scale temperature sensor with a remarkable sensitivity up to 185 pm/℃based on a trian-gular MAPbI3 nanoplatelet(NPL)laser.Notably,as temperature changes,the peak wavelength of the laser line shifts lin-early.This unique characteristic allows for precise temperature sensing by tracking the peak wavelength of the NPL laser.The optical modes are confined within the perovskite NPL,which measures just 85 nm in height,due to total internal reflec-tion.Our NPL laser boasts several key features,including a high Q of~2610 and a low laser threshold of about 19.8μJ·cm^(−2).The combination of exceptional sensitivity and ultra-small size makes our WGM device an ideal candidate for integration into systems that demand compact temperature sensors.This advancement paves the way for significant prog-ress in the development of ultrasmall temperature sensors,opening new possibilities across various fields. 展开更多
关键词 temperature sensor submicron scale perovskite nanoplatelet
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Development of Ni_(x)/Mg_(1-x)-MOF-74 for highly efficient CO_(2)/N_(2) separation
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作者 ZHANG Xin LI Guoqiang +7 位作者 HONG Mei BAN Hongyan YANG Lixia LIU Xingchen LI Feng Ekaterina Vladimirovna Matus LI Congming LI Lei 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第11期1745-1758,共14页
To enhance the separation selectivity of Mg-MOF-74 towards CO_(2) in a CO_(2)/N_(2) mixture,a series of Mg-MOF-74 and Ni_(x)/Mg_(1-x)-MOF-74 adsorbents were prepared by solvothermal synthesis in this paper.It was foun... To enhance the separation selectivity of Mg-MOF-74 towards CO_(2) in a CO_(2)/N_(2) mixture,a series of Mg-MOF-74 and Ni_(x)/Mg_(1-x)-MOF-74 adsorbents were prepared by solvothermal synthesis in this paper.It was found that the adsorption capacity of Mg-MOF-74 for CO_(2) could be effectively increased by optimizing the amount of acetic acid.On this basis,the bimetal MOF-74 adsorbent was prepared by metal modification.The multi-component dynamic adsorption penetration analysis was utilized to examine the CO_(2) adsorption capacity and CO_(2)/N_(2) selectivity of the diverse adsorbent materials.The results showed that Ni0.11/Mg0.89-MOF-74 showed a CO_(2) adsorption capacity of 7.02 mmol/g under pure CO_(2) atmosphere and had a selectivity of 20.50 for CO_(2)/N_(2) under 15% CO_(2)/85%N_(2) conditions,which was 10.2% and 18.02% higher than that of Mg-MOF-74 respectively.Combining XPS,SEM and N_(2) adsorption-desorption characterization analysis,it was attributed to the effect of the more stable unsaturated metal sites Ni into the Mg-MOF-74 on the pore structure and the synergistic interaction between the two metals.Density Functional Theory(DFT)simulations revealed that the synergistic interaction between modulated the electrostatic potential strength and gradient of the material,which was more favorable for the adsorption of CO_(2) molecules with small diameters and large quadrupole moment.In addition,the Ni0.11/Mg0.89-MOF-74 showed commendable cyclic stability,underscoring its promising potential for practical applications. 展开更多
关键词 CO_(2)capture Mg-MOF-74 CO_(2)/N_(2)separation adsorption breakthrough curve density functional theory
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TiC_(p)/Ti复合材料环件成形数值模拟及实验研究
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作者 郭鹏坤 嵇祥 +4 位作者 连启豪 冯弘 韩建超 智少勇 张长江 《内蒙古工业大学学报(自然科学版)》 2024年第5期408-416,共9页
为了研究TiC_(p)/Ti复合材料环件成形能力,采用Deform-3D软件对不同温度预热后的坯料在不同冲孔速度下的环件成形过程进行数值模拟,分析了凸模载荷、最大主应力、金属流动速率和损伤值变化。结果表明,高的预热温度和低的冲孔速度有利于... 为了研究TiC_(p)/Ti复合材料环件成形能力,采用Deform-3D软件对不同温度预热后的坯料在不同冲孔速度下的环件成形过程进行数值模拟,分析了凸模载荷、最大主应力、金属流动速率和损伤值变化。结果表明,高的预热温度和低的冲孔速度有利于材料成形,综合考虑最终确定1000℃预热和30 mm/s冲孔速度为环件成形的最佳工艺。本研究通过1050℃镦拔锻造制备锻坯和1000℃、30 mm/s下冲孔,成功制备得到了TiC_(p)/Ti复合材料环件,所得环件微观组织比较均匀,由片层α相、等轴α相、残余β相和TiC_(p)构成。TiC_(p)/Ti复合材料环件的室温抗拉强度达1237.08 MPa,延伸率为5.0%,650℃下的抗拉强度达757.35 MPa,延伸率为7.8%,兼具优异的室高温力学性能,可满足航空航天工业对高温钛基材料环件日益增长的性能需求。 展开更多
关键词 复合材料 环件成形 数值模拟 力学性能
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带包覆层管道缺陷的脉冲涡流检测方法研究
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作者 李佳东 张彦杰 +4 位作者 邱俊杰 赵希来 邬宇 焦少妮 任思齐 《电子测量与仪器学报》 CSCD 北大核心 2024年第10期137-146,共10页
包覆层管道被广泛应用于化工、石油、燃气等行业,管道腐蚀引起的裂缝、局部腐蚀等都可能带来重大安全隐患,因此对管道缺陷的检测变得极其重要。但管道上较厚的包覆层导致常规的无损检测很难检测到管道的缺陷,而脉冲涡流无损检测技术因... 包覆层管道被广泛应用于化工、石油、燃气等行业,管道腐蚀引起的裂缝、局部腐蚀等都可能带来重大安全隐患,因此对管道缺陷的检测变得极其重要。但管道上较厚的包覆层导致常规的无损检测很难检测到管道的缺陷,而脉冲涡流无损检测技术因其具有强大的激励能量和出色的穿透能力,能够在不拆除包覆层的情况下对管道进行缺陷检测。本研究旨在分析不同信号特征下对缺陷检测的有效性,文章首先利用仿真软件建立带包覆层管道的三维有限元模型,其次选取差分电压峰值、差分电压峰值时间、差分电压过零时间、差分信号基频幅值作为信号特征,对信号特征与缺陷的关系进行分析,最终选取出更适合的评估信号。仿真结果表明:差分电压峰值与基频幅值随缺陷弧长增大而增大,随缺陷深度增大而增大。峰值时间、过零时间只与深度有关,且随外表面深度增大而增大、随内表面深度增大而减小。并通过信号特征与缺陷的拟合,选取出适用于缺陷分辨的信号。这项研究有助于优化脉冲涡流无损检测技术在包覆层管道缺陷检测中的应用,提高检测的准确性和效率。 展开更多
关键词 脉冲涡流 包覆层管道 有限元仿真 信号分析
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硫酸盐还原菌和酸性矿山废水的生物处理 被引量:66
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作者 李亚新 苏冰琴 《环境污染治理技术与设备》 CAS CSCD 2000年第5期1-11,共11页
本文论述了硫酸盐还原菌的代谢和所需要的碳源以及硫酸盐还原的影响因素和生物处理酸性矿山废水的研究进展。
关键词 硫酸盐还原菌 酸性矿山废水 生物处理 废水处理
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First-Principles Study of Magnetism in Transition Metal Doped Na0.5Bi0.5TiO3 System 被引量:1
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作者 鞠林 徐同帅 +1 位作者 张雍家 孙礼 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2016年第4期462-466,I0002,共6页
The origins of magnetism in transition-metal doped Na0.5Bi0.5TiO3 system are investigated by ab initio calculations. The calculated results indicate that a transition-metal atom sub- stitution for a Ti atom produces m... The origins of magnetism in transition-metal doped Na0.5Bi0.5TiO3 system are investigated by ab initio calculations. The calculated results indicate that a transition-metal atom sub- stitution for a Ti atom produces magnetic moments, which are due to the spin-polarization of transition-metal 3d electrons. The characteristics of exchange coupling are also calculated, which shows that in Cr-/Mn-/Fe-/Co- doped Na0.5Bi0.5TiO3 system, the antiferromagnetic coupling is favorable. The results can successfully explain the experimental phenomenon that, in Mn-/Fe- doped Nao.sBio.sTiO3 system, the ferromagnetism disappears at low tem- perature and the paramagnetic component becomes stronger with the increase of doping concentration of Mn/Fe/Co ions. Unexpectedly, we find the Na0.5Bi0.5Ti0.67V0.33iO3 sys- tem with ferromagnetic coupling is favorable and produces a magnetic moment of 2.00 P-B, which indicates that low temperature ferromagnetism materials could be made by intro- ducing V atoms in Na0.5Bi0.5TiO3. This may be a new way to produce low temperature multiferroic materials. 展开更多
关键词 Transition-metal atom SUBSTITUTION Magnetic moment First-principles calculation.
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