Use of NiO/SiO_2 catalysts for toluene total oxidation:Catalytic reaction at lower temperatures and repeated regeneration

We deposited NiO via atomic layer deposition on mesoporous SiO2 particles with diameters of several hundred micrometers and a mean mesopore size of -14 nm.NiO was deposited within the shell region of mesoporous SiO2 particles with a shell thickness of -11 mm.We annealed the as-prepared NiO/SiO2 at 450 and 600℃,respectively.These two samples were used as catalysts for the uptake of toluene molecules and their oxidative conversion to CO2.The sample annealed at450℃ was generally more reactive in toluene uptake and its subsequent conversion to CO2.When the NiO/SiO2 annealed at 450℃ was exposed to toluene vapor at 160℃ and then heated to 450℃,CO2 was emitted with almost no toluene desorption.We suggest that our catalysts can be used as building blocks for odor removal devices that operate below 200℃.These catalysts can be regularly regenerated at -450℃.

相互作用突然开启后的反铁磁海森伯模型

本文以反铁磁海森伯模型为对象,设想了一个相互作用在t=0时刻开启的非平衡体系.在低温近似下,本文利用重整化群流方程方法讨论了该体系可观测量随时间的演化趋势.本文根据此类体系的特点,给出了获得算符时间演化形式的路径,并成功将其应用于本文所讨论的模型中.其中,本文着重介绍了如何在非平衡自旋体系中应用流方程方法,并利用该方法得到了随时间演化的基态磁化强度,同时论证了该方法处理此类系统的有效性.同时,在与平衡体系基态磁化强度的对比中,发现非平衡可观测量随时间震荡而无法收敛,这一点有别于相互作用突然开启后的Luttinger液体.