Na2WO4‐acidic ionic liquid was used as a simple, ecofriendly, recyclable and efficient catalytic system for the one‐pot conversion of cyclohexanol to ε‐caprolactam. The effect of the structure of the ionic liquid ...Na2WO4‐acidic ionic liquid was used as a simple, ecofriendly, recyclable and efficient catalytic system for the one‐pot conversion of cyclohexanol to ε‐caprolactam. The effect of the structure of the ionic liquid on the catalytic activity of this system was investigated, and the results revealed that sulfonic acid‐functionalized ionic liquids with HSO4? as an anion gave the best results. The highly efficient performance of this catalyst system was attributed to the phase‐transfer behavior of the cation of the ionic liquid, the improved coordination of the substrate to bisperoxotungstate duringthe oxidation reaction, and the stabilization of the intermediate formed during the Beckmann rearrangement.展开更多
基金supported by the National Natural Science Foundation of China (20636030, 2090618, 21236001)the Natural Science Foundation of Hebei Province (B2017202226)~~
文摘Na2WO4‐acidic ionic liquid was used as a simple, ecofriendly, recyclable and efficient catalytic system for the one‐pot conversion of cyclohexanol to ε‐caprolactam. The effect of the structure of the ionic liquid on the catalytic activity of this system was investigated, and the results revealed that sulfonic acid‐functionalized ionic liquids with HSO4? as an anion gave the best results. The highly efficient performance of this catalyst system was attributed to the phase‐transfer behavior of the cation of the ionic liquid, the improved coordination of the substrate to bisperoxotungstate duringthe oxidation reaction, and the stabilization of the intermediate formed during the Beckmann rearrangement.
