Identification of origin of insulating polymer maneuvered photoredox catalysis

Solid non-conjugated polymers have long been regarded as insulators due to deficiency of delocalizedπelectrons along the molecular chain framework.Up to date,origin of insulating polymer regulated charge transfer has not yet been uncovered.In this work,we unleash the root origin of charge transport capability of insulating polymer in photocatalysis.We ascertain that insulating polymer plays crucial roles in fine tuning of electronic structure of transition metal chalcogenides(TMCs),which mainly include altering surface electron density of TMCs for accelerating charge transport kinetics,triggering the generation of defect over TMCs for prolonging carrier lifetime,and acting as hole-trapping mediator for retarding charge recombination.These synergistic roles contribute to the charge transfer of insulating polymer.Our work opens a new vista of utilizing solid insulating polymers for maneuvering charge transfer toward solar energy conversion.

塑性变形对Al0.5FeCoCrNi高熵合金组织结构和性能的影响

通过真空电弧熔炼制备了Al0.5FeCoCrNi高熵合金,采用轧制方法获得轧制变形量分别为30%、60%和90%的塑性变形合金,利用金相显微镜、X射线衍射分析仪、扫描电镜及附带能谱分析仪、透射电镜、硬度计和摩擦磨损试验机,研究塑性变形对合金组织结构和性能的影响。结果表明,塑性变形后合金的枝晶相被压扁拉长,枝晶间相沿轧制方向被拉长。合金的加工硬化能力强,轧制变形量分别为30%、60%和90%的合金的显微硬度分别为268.8HV,348.4HV和393.9HV,但耐磨性下降。

等离子喷枪内电弧动力学与等离子体特性的三维数值模拟

基于局域热力学平衡假设,建立三维非稳态等离子电弧的湍流模型,应用计算流体力学软件ANSYS CFX模拟了氩/氢等离子喷枪内阳极弧根的再附着过程、电弧与气流的相互作用以及等离子体温度和速度分布。结果表明,在冷气流推动下,阳极弧根向喷嘴下游移动,电弧被拉长,弧电压升高,电场强度增大。当电弧向下游移动到电场强度足够大时,电弧击穿并形成新的弧根。喷枪内电弧波动导致喷枪出口等离子体最大温度和最大速度发生波动,滞后时间为10μs。喷枪内的流动与传热具有明显的三维特征,与温度分布相比,速度分布的三维特征更明显且更向中心处集中。