应用等温流动微量热技术测定了298.15 K下D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的稀释焓,利用M cM illan理论计算了D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中焓相互作用系数.结果表明,D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中...应用等温流动微量热技术测定了298.15 K下D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的稀释焓,利用M cM illan理论计算了D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中焓相互作用系数.结果表明,D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的二阶焓相互作用系数均为正值,并随着卤离子半径的变化而相应变化;且同种溶剂中,D-甘露醇的二阶焓相互作用系数要大于D-山梨醇的.结合两分子结构的差异,通过溶质-溶质相互作用和溶剂-溶质相互作用对这一结果进行了讨论.展开更多
The rational design of efficient and stable carbon-based electrocatalysts for oxygen reduction and oxygen evolution reactions is crucial for improving energy density and long-term stability of rechargeable zinc-air ba...The rational design of efficient and stable carbon-based electrocatalysts for oxygen reduction and oxygen evolution reactions is crucial for improving energy density and long-term stability of rechargeable zinc-air batteries(ZABs).Herein,a general and controllable synthesis method was developed to prepare three-dimensional(3D)porous carbon composites embedded with diverse metal phosphide nanocrystallites by interfacial coordination of transition metal ions with phytic acid-doped polyaniline networks and subsequent pyrolysis.Phytic acid as the dopant of polyaniline provides favorable anchoring sites for metal ions owing to the coordination interaction.Specifically,adjusting the concentration of adsorbed cobalt ions can achieve the phase regulation of transition metal phosphides.Thus,with abundant cobalt phosphide nanoparticles and nitrogen-and phosphorus-doping sites,the obtained carbon-based electrocatalysts exhibited efficient electrocatalytic activities toward oxygen reduction and evolution reactions.Consequently,the fabricated ZABs exhibited a high energy density,high power density of 368 mW cm^(-2),and good cycling/mechanical stability,which could power water splitting for integrated device fabrication with high gas yields.展开更多
为了模拟药物香豆素在十二烷基硫酸钠(SDS)和十六烷基磺基甜菜碱(SB-16)复配体系中的分配规律,采用分子动力学的方法模拟了香豆素分子(C-343)在SB-16水溶液中的增溶行为,在上述溶液的基础上又继续添加了表面活性剂SDS,并研究了SDS对香...为了模拟药物香豆素在十二烷基硫酸钠(SDS)和十六烷基磺基甜菜碱(SB-16)复配体系中的分配规律,采用分子动力学的方法模拟了香豆素分子(C-343)在SB-16水溶液中的增溶行为,在上述溶液的基础上又继续添加了表面活性剂SDS,并研究了SDS对香豆素在SB-16胶束增溶行为影响。研究结果表明,在298 K,101.3 k Pa下的平衡条件下,C-343可以自发地增溶到SB-16球形胶束中。SDS分子的烷基尾链部分插入到SB-16球形胶束内部,并在SB-16表面形成一层疏水基团在内,亲水基团在外的SDS分子薄层。C-343分子在SDS分子的疏水作用和静电作用下,从SB-16胶束内部逐步迁移至SDS胶束的外层表面上。从理论证实了添加表面活性剂可以对药物分子在胶束溶液中的增溶与释放过程进行有效控制,以期为该类体系的试验研究提供理论依据。展开更多
基金supported by the National Natural Science Foundation of China(21473084,21073081,21373106,ZR2012BQ013)Scientific Research(LDSY2014008) and Experimental Technology Science Research Project(314011402)of Liaocheng University,China~~
文摘应用等温流动微量热技术测定了298.15 K下D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的稀释焓,利用M cM illan理论计算了D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中焓相互作用系数.结果表明,D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的二阶焓相互作用系数均为正值,并随着卤离子半径的变化而相应变化;且同种溶剂中,D-甘露醇的二阶焓相互作用系数要大于D-山梨醇的.结合两分子结构的差异,通过溶质-溶质相互作用和溶剂-溶质相互作用对这一结果进行了讨论.
文摘The rational design of efficient and stable carbon-based electrocatalysts for oxygen reduction and oxygen evolution reactions is crucial for improving energy density and long-term stability of rechargeable zinc-air batteries(ZABs).Herein,a general and controllable synthesis method was developed to prepare three-dimensional(3D)porous carbon composites embedded with diverse metal phosphide nanocrystallites by interfacial coordination of transition metal ions with phytic acid-doped polyaniline networks and subsequent pyrolysis.Phytic acid as the dopant of polyaniline provides favorable anchoring sites for metal ions owing to the coordination interaction.Specifically,adjusting the concentration of adsorbed cobalt ions can achieve the phase regulation of transition metal phosphides.Thus,with abundant cobalt phosphide nanoparticles and nitrogen-and phosphorus-doping sites,the obtained carbon-based electrocatalysts exhibited efficient electrocatalytic activities toward oxygen reduction and evolution reactions.Consequently,the fabricated ZABs exhibited a high energy density,high power density of 368 mW cm^(-2),and good cycling/mechanical stability,which could power water splitting for integrated device fabrication with high gas yields.
文摘为了模拟药物香豆素在十二烷基硫酸钠(SDS)和十六烷基磺基甜菜碱(SB-16)复配体系中的分配规律,采用分子动力学的方法模拟了香豆素分子(C-343)在SB-16水溶液中的增溶行为,在上述溶液的基础上又继续添加了表面活性剂SDS,并研究了SDS对香豆素在SB-16胶束增溶行为影响。研究结果表明,在298 K,101.3 k Pa下的平衡条件下,C-343可以自发地增溶到SB-16球形胶束中。SDS分子的烷基尾链部分插入到SB-16球形胶束内部,并在SB-16表面形成一层疏水基团在内,亲水基团在外的SDS分子薄层。C-343分子在SDS分子的疏水作用和静电作用下,从SB-16胶束内部逐步迁移至SDS胶束的外层表面上。从理论证实了添加表面活性剂可以对药物分子在胶束溶液中的增溶与释放过程进行有效控制,以期为该类体系的试验研究提供理论依据。
