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直接涂膜技术用于质子交换膜燃料电池膜电极制备 (Ⅱ) 被引量:3
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作者 蒋淇忠 Oumarou Savadogo 马紫峰 《化工学报》 EI CAS CSCD 北大核心 2004年第8期1324-1328,共5页
研究了直接涂膜过程中 ,催化剂液组成对电池性能的影响 .异丙醇在催化剂墨水中起到溶剂和造孔剂的作用 ,当催化剂墨水中催化剂、异丙醇的质量比为 1∶10时电池性能最好 .Nafion是催化剂层中良好的黏结剂和质子传导载体 .由于直接涂膜 ,... 研究了直接涂膜过程中 ,催化剂液组成对电池性能的影响 .异丙醇在催化剂墨水中起到溶剂和造孔剂的作用 ,当催化剂墨水中催化剂、异丙醇的质量比为 1∶10时电池性能最好 .Nafion是催化剂层中良好的黏结剂和质子传导载体 .由于直接涂膜 ,使Nafion液与Nafion膜直接接触 ,从而增加了质子传导性 .实验结果表明 ,最佳的Nafion含量 (干基 )为NFP =33% .通过对不同金属含量的Pt/C催化剂的研究发现 ,金属含量不同 ,异丙醇和Nafion的最优含量亦随之改变 .考察了催化剂层不同制备工艺对电池性能的影响 ,表明催化剂层数越多电池性能越好 。 展开更多
关键词 质子交换膜燃料电池 膜电极装备 直接涂膜技术
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直接涂膜技术用于质子交换膜燃料电池膜电极制备 被引量:1
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作者 蒋淇忠 马紫峰 Oumarou Savadogo 《磁流体发电情报》 EI CAS 2004年第3期488-492,共5页
A new membrane electrolyte assembly (MEA) preparation method for polymer electrolyte membrane fuel cell (PEMFC) was developed by applying the directly printing catalyst on membrane technique.This method was simple and... A new membrane electrolyte assembly (MEA) preparation method for polymer electrolyte membrane fuel cell (PEMFC) was developed by applying the directly printing catalyst on membrane technique.This method was simple and easy to be controlled as verified by repetition experiment. When the membrane with catalyst prepared by the new technique and the electrode with diffusion layer was only sandwiched but not hot pressed, this kind of MEA was called not-hot-press MEA (NPMEA) and its fuel cell performance was better than that of MEA which was hot pressed (HPMEA).The effects of 6 different kinds of solvents in catalyst mixture ink on the performance of fuel cell were assessed.It was discovered that iso-propanol was the best solvent in catalyst mixture ink and showed the best performance of fuel cell. Finally several MEAs prepared by different ways were tested on fuel cell station and it was reported that the performance of MEA prepared by the directly printing catalyst on membrane technique was the best in the whole voltage region. 展开更多
关键词 质子交换膜燃料电池 膜电极 直接涂膜技术 微观结构 电化学性能
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