Aiming at a series of existing problems of ecological landscape in farmland and in residential district at northern villages,and problems like low recovery rate of wastes,uncertain evaluation index of ecological lands...Aiming at a series of existing problems of ecological landscape in farmland and in residential district at northern villages,and problems like low recovery rate of wastes,uncertain evaluation index of ecological landscape,managers' low consciousnesses and insufficient organization and management at northern villages;the corresponding planning suggestions were proposed.Scientific farming,developing ecological agriculture and perfecting ecological corridor system were of great significance to ecological landscape of farmland.Reasonable ecological construction,fully utilizing renewable energy sources,overall planning,improving land utilization rate and highlighting regional characteristic of ecological landscape were of great significance to ecological landscape of residential district.Tourism agriculture development should be emphasized,ecological landscape theory study enhanced,administrative organization perfected and reasonable ecological evaluation carried out,respecting the principle of ecology,fully exploring regional characteristics,strengthening government's guidance and considering villagers' will,so as to construct a society in which man and nature were in harmony.展开更多
Selective hydrogenolysis of glycerol to 1,3‐propanediol（1,3‐PD） is an important yet challenging method for the transformation of biomass into value‐added chemicals due to steric hindrance and unfavorable thermody...Selective hydrogenolysis of glycerol to 1,3‐propanediol（1,3‐PD） is an important yet challenging method for the transformation of biomass into value‐added chemicals due to steric hindrance and unfavorable thermodynamics. In previous studies, chemoselective performances were found de‐manding and sensitive to H2 pressure. In this regard, we manipulate the chemical/physical charac‐teristics of the catalyst supports via doping Nb into WOx and prepared 1D needle‐, 2D flake‐, and 3D sphere‐stack mesoporous structured Nb‐WOx with increased surface acid sites. Moreover, Nb dop‐ing can successfully inhibit the over‐reduction of active W species during glycerol hydrogenolysis and substantially broaden the optimal H2 pressure from 1 to 5 MPa. When Nb doping is 2%, sup‐ported Pt catalysts showed promising performance for the selective hydrogenolysis of glycerol to 1,3‐PD over an unprecedentedly wide H2 pressure range, which will guarantee better catalyst sta‐bility in the long run, as well as expand their applications to other hydrogen‐related reactions.展开更多
文摘Aiming at a series of existing problems of ecological landscape in farmland and in residential district at northern villages,and problems like low recovery rate of wastes,uncertain evaluation index of ecological landscape,managers' low consciousnesses and insufficient organization and management at northern villages;the corresponding planning suggestions were proposed.Scientific farming,developing ecological agriculture and perfecting ecological corridor system were of great significance to ecological landscape of farmland.Reasonable ecological construction,fully utilizing renewable energy sources,overall planning,improving land utilization rate and highlighting regional characteristic of ecological landscape were of great significance to ecological landscape of residential district.Tourism agriculture development should be emphasized,ecological landscape theory study enhanced,administrative organization perfected and reasonable ecological evaluation carried out,respecting the principle of ecology,fully exploring regional characteristics,strengthening government's guidance and considering villagers' will,so as to construct a society in which man and nature were in harmony.
基金supported by the National Natural Science Foundation of China (2169008, 21690084, 21673228, 21303187, 21403218)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB17020100)+1 种基金DICP ZZBS 201612Key Projects for Fundamental Research and Development of China (2016YFA0202801)~~
文摘Selective hydrogenolysis of glycerol to 1,3‐propanediol（1,3‐PD） is an important yet challenging method for the transformation of biomass into value‐added chemicals due to steric hindrance and unfavorable thermodynamics. In previous studies, chemoselective performances were found de‐manding and sensitive to H2 pressure. In this regard, we manipulate the chemical/physical charac‐teristics of the catalyst supports via doping Nb into WOx and prepared 1D needle‐, 2D flake‐, and 3D sphere‐stack mesoporous structured Nb‐WOx with increased surface acid sites. Moreover, Nb dop‐ing can successfully inhibit the over‐reduction of active W species during glycerol hydrogenolysis and substantially broaden the optimal H2 pressure from 1 to 5 MPa. When Nb doping is 2%, sup‐ported Pt catalysts showed promising performance for the selective hydrogenolysis of glycerol to 1,3‐PD over an unprecedentedly wide H2 pressure range, which will guarantee better catalyst sta‐bility in the long run, as well as expand their applications to other hydrogen‐related reactions.
