To study the relationship between the microstructure and tensile properties of the novel metastable β titanium alloy Ti-5.5Cr-5Al-4Mo-3Nb-2Zr,a heat treatment process of ABFCA(solid solution in α+βregion with subse...To study the relationship between the microstructure and tensile properties of the novel metastable β titanium alloy Ti-5.5Cr-5Al-4Mo-3Nb-2Zr,a heat treatment process of ABFCA(solid solution in α+βregion with subsequent furnace cooling followed by aging treatment finally)was designed,by which α phases of different sizes can be precipitated in the β matrix.The results show that the microstructure obtained by this heat treatment process is composed of primary α(α_(p))phase,submicro rod-like α(α_(r))phase and secondary α(α_(s))phase.The alloy with multi-scale α phase has an excellent balance between strength and ductility.The elongation is about 18.3% at the ultimate tensile strength of 1125.4 MPa.The relationship between the strength of the alloy and the α phase was established.The strength of the alloy is proportional to the power of‒1/2 of the average spacing and width of α phase.The α_(s) phase with a smaller size and phase spacing can greatly improve the strength of the alloy by hindering dislocation slip.The transmission electron microscope analysis shows that there is a large amount of dislocation accumulation at the α/β interfaces,and many deformation twins are found in the α_(p) phase after tensile deformation.When the dislocation slip is hindered,twins occur at the stress concentration location,and twins can initiate some dislocations that are difficult to slip.Meanwhile,the plastic strain is distributed uniformly among the α_(p),α_(r),α_(s) phases and β matrix,thereby enhancing the ductility of the alloy.展开更多
Since the magnesium and magnesium alloys have good load transmission,exceptional biosafety,unique biodegradability,etc,they have significant application possibilities in the field of medical implantation.Furthermore,e...Since the magnesium and magnesium alloys have good load transmission,exceptional biosafety,unique biodegradability,etc,they have significant application possibilities in the field of medical implantation.Furthermore,excellent corrosion resistance is one of the paramount prerequisites for magnesium and magnesium alloys as medical implants.However,magnesium alloys exhibit poor corrosion resistance,leading to rapid degradation in physiological environments due to high corrosion rates.This premature degradation,before completing their intended service life,compromises their structural integrity,severely limiting their clinical applications.Surface modification treatment of magnesium alloy to improve corrosion resistance has become a research hotspot of medical magnesium alloy.This study primarily focused on the research advancements in the corrosion resistance enhancement of medical magnesium alloys.The developmental trajectory and characteristics of medical magnesium alloys were outlined.Additionally,surface modification techniques such as micro-arc oxidation and ion implantation,as well as microstructure and properties of magnesium alloy surfaces after surface modification were reviewed.The formation mechanisms of various coatings were discussed,and their structures and properties were analyzed.The impact of coatings on the degradation rate of magnesium alloys was elucidated,aiming to identify key issues and potential solutions in the implementation and application of surface modification for medical magnesium alloys.Recommendations were also provided,presenting the research directions for surface modification of medical magnesium alloys.展开更多
基金National Natural Science Foundation of China(52104379,U21A20117,52071219,52271249)。
文摘To study the relationship between the microstructure and tensile properties of the novel metastable β titanium alloy Ti-5.5Cr-5Al-4Mo-3Nb-2Zr,a heat treatment process of ABFCA(solid solution in α+βregion with subsequent furnace cooling followed by aging treatment finally)was designed,by which α phases of different sizes can be precipitated in the β matrix.The results show that the microstructure obtained by this heat treatment process is composed of primary α(α_(p))phase,submicro rod-like α(α_(r))phase and secondary α(α_(s))phase.The alloy with multi-scale α phase has an excellent balance between strength and ductility.The elongation is about 18.3% at the ultimate tensile strength of 1125.4 MPa.The relationship between the strength of the alloy and the α phase was established.The strength of the alloy is proportional to the power of‒1/2 of the average spacing and width of α phase.The α_(s) phase with a smaller size and phase spacing can greatly improve the strength of the alloy by hindering dislocation slip.The transmission electron microscope analysis shows that there is a large amount of dislocation accumulation at the α/β interfaces,and many deformation twins are found in the α_(p) phase after tensile deformation.When the dislocation slip is hindered,twins occur at the stress concentration location,and twins can initiate some dislocations that are difficult to slip.Meanwhile,the plastic strain is distributed uniformly among the α_(p),α_(r),α_(s) phases and β matrix,thereby enhancing the ductility of the alloy.
基金Key R&D Plan Projects in Shaanxi Province(2020ZDLGY13-05,2022SF-294,2023-YBSF-354)Xi'an City Research Science and Technology Project(22GXFW0143)+1 种基金Weiyang District Research Science and Technology Project(202106)Northwest Institute for Nonferrous Metal Research Science and Technology Project(YK2113,YK2119)。
文摘Since the magnesium and magnesium alloys have good load transmission,exceptional biosafety,unique biodegradability,etc,they have significant application possibilities in the field of medical implantation.Furthermore,excellent corrosion resistance is one of the paramount prerequisites for magnesium and magnesium alloys as medical implants.However,magnesium alloys exhibit poor corrosion resistance,leading to rapid degradation in physiological environments due to high corrosion rates.This premature degradation,before completing their intended service life,compromises their structural integrity,severely limiting their clinical applications.Surface modification treatment of magnesium alloy to improve corrosion resistance has become a research hotspot of medical magnesium alloy.This study primarily focused on the research advancements in the corrosion resistance enhancement of medical magnesium alloys.The developmental trajectory and characteristics of medical magnesium alloys were outlined.Additionally,surface modification techniques such as micro-arc oxidation and ion implantation,as well as microstructure and properties of magnesium alloy surfaces after surface modification were reviewed.The formation mechanisms of various coatings were discussed,and their structures and properties were analyzed.The impact of coatings on the degradation rate of magnesium alloys was elucidated,aiming to identify key issues and potential solutions in the implementation and application of surface modification for medical magnesium alloys.Recommendations were also provided,presenting the research directions for surface modification of medical magnesium alloys.