上市公司治理结构与审计绩效关系研究--基于中国信息技术行业上市公司数据

本文选取信息技术行业上市公司作为研究样本,对公司治理与审计绩效之间的关系进行了实证分析。结果表明,国有股比例与审计绩效呈显著负相关,流通股比例与审计绩效呈正相关,内部人控制度对审计绩效有一定的影响作用,但影响不明显。因此要提高审计绩效,应该从完善公司内部治理结构入手。

In-situ Micro-CT analysis of deformation behavior in sandwich-structured meta-stable beta Ti−35Nb alloy

Beta Ti−35Nb sandwich-structured composites with various reinforcing layers were designed and produced using additive manufacturing(AM)to achieve a balance between light weight and high strength.The impact of reinforcing layers on the compressive deformation behavior of porous composites was investigated through micro-computed tomography(Micro-CT)and finite element method(FEM)analyses.The results indicate that the addition of reinforcement layers to sandwich structures can significantly enhance the compressive yield strength and energy absorption capacity of porous metal structures;Micro-CT in-situ observation shows that the strain of the porous structure without the reinforcing layer is concentrated in the middle region,while the strain of the porous structure with the reinforcing layer is uniformly distributed;FEM analysis reveals that the reinforcing layers can alter stress distribution and reduce stress concentration,thereby promoting uniform deformation of the porous structure.The addition of reinforcing layer increases the compressive yield strength of sandwich-structured composite materials by 124%under the condition of limited reduction of porosity,and the yield strength increases from 4.6 to 10.3 MPa.

Improvement of ionic conductivity of solid polymer electrolyte based on Cu-Al bimetallic metal-organic framework fabricated through molecular grafting

A composite solid electrolyte comprising a Cu-Al bimetallic metal-organic framework(CAB),lithium salt(LiTFSI)and polyethylene oxide(PEO)was fabricated through molecular grafting to enhance the ionic conductivity of the PEO-based electrolytes.Experimental and molecular dynamics simulation results indicated that the electrolyte with 10 wt.%CAB(PL-CAB-10%)exhibits high ionic conductivity(8.42×10~(-4)S/cm at 60℃),high Li+transference number(0.46),wide electrochemical window(4.91 V),good thermal stability,and outstanding mechanical properties.Furthermore,PL-CAB-10%exhibits excellent cycle stability in both Li-Li symmetric battery and Li/PL-CAB-10%/LiFePO4 asymmetric battery setups.These enhanced performances are primarily attributable to the introduction of the versatile CAB.The abundant metal sites in CAB can react with TFSI~-and PEO through Lewis acid-base interactions,promoting LiTFSI dissociation and improving ionic conductivity.Additionally,regular pores in CAB provide uniformly distributed sites for cation plating during cycling.

Censored Composite Conditional Quantile Screening for High-Dimensional Survival Data

In this paper,we introduce the censored composite conditional quantile coefficient(cC-CQC)to rank the relative importance of each predictor in high-dimensional censored regression.The cCCQC takes advantage of all useful information across quantiles and can detect nonlinear effects including interactions and heterogeneity,effectively.Furthermore,the proposed screening method based on cCCQC is robust to the existence of outliers and enjoys the sure screening property.Simulation results demonstrate that the proposed method performs competitively on survival datasets of high-dimensional predictors,particularly when the variables are highly correlated.

Fabrication of lightweight 3D interpenetrated NiTi@Mg composite with superior bending properties

A NiTi@Mg interpenetrating phase composite with high strength and lightweight was prepared by additive manufacturing(AM)and infiltration technology,and the interface bonding,three-point bending properties and cyclic compressive properties of NiTi@Mg composites were investigated.The results show that the metallurgically bonded interface is formed at the NiTi/Mg interfaces.The bending strength and compressive strength of the NiTi@Mg composite are 2.5 and 1.7 times higher than those of the NiTi scaffold,respectively.During the bending deformation process,a large number of dislocations are observed to accumulate in the soft Mg area at the interface.Furthermore,the finite element model showed that the stress accumulation area,where the bending crack is initiated,is located at the interface of NiTi and Mg.The strengthening mechanism of NiTi@Mg composites is attributed to the twinning strengthening of Mg and heterogeneous structure strengthening.

雷击变电站地网引起的地电位干扰及防护措施研究

变电站遭受雷击后,易导致电力系统的微机保护和综合自动化设备损坏,严重影响了电力系统的正常运行。分析了雷击地网干扰侵入自动化系统的途径,利用EMTP软件仿真模型,分析了雷击变电站时地网电位的分布情况以及二次电缆不同接地方式的屏蔽效果。结果表明:采用方孔地网,增加垂直接地极,采用二次电缆屏蔽层两端接地的方式,可以有效地屏蔽雷击引起的地电位干扰,提高变电站运行的安全性和可靠性。

Hydrothermal synthesis and enhanced photocatalytic activity of hierarchical flower-like Fe-doped BiVO_4

Fe-doped BiVO4with hierarchical flower-like structure was prepared via a hydrothermal method using sodium dodecylbenzene sulfonate(SDBS)as structure directing agent.X-ray diffraction(XRD),scanning electron microscope(SEM),transmissionelectron microscope(TEM),high resolution transmission electron microscope(HRTEM),X-ray photoelectron spectroscopy(XPS)and UV-Vis were applied for characterization of the as-prepared samples.The formation mechanism of flower-like structure wasproposed based on the evolution of morphology as a function of hydrothermal time.Fe-doped into substitutional sites of BiVO4effectively improved the migration and separation of photogenerated carrier and enhanced the utilization of visible light.Flower-likeFe-doped BiVO4showed much higher visible-light-driven photocatalytic efficiency for degradation of methyl blue compared withthe pristine BiVO4.And the sample with a Fe/Bi mole ratio of2.5%showed the highest photocatalytic efficiency.

Hydrogen storage properties of magnesium hydride catalyzed by Ni-based solid solutions

The Ni−25%X(X=Fe,Co,Cu,molar fraction)solid solutions were prepared and then doped into MgH_(2) through high-energy ball milling.The initial dehydrogenation temperatures of MgH_(2)/Ni−25%X composites are all decreased by about 90℃relative to the as-milled pristine MgH_(2).The Ni−25%Co solid solution exhibits the most excellent catalytic effect,and the milled MgH_(2)/Ni−25%Co composite can release 5.19 wt.%hydrogen within 10 min at 300℃,while the as-milled pristine MgH_(2) can only release 1.78 wt.%hydrogen.More importantly,the dehydrogenated MgH_(2)/Ni−25%Co composite can absorb 5.39 wt.%hydrogen at 275℃within 3 min.The superior hydrogen sorption kinetics of MgH_(2)/Ni−25%Co can be ascribed to the actual catalytic effect of in-situ formed Mg_(2)Ni(Co)compounds.First-principles calculations show that the hydrogen absorption/desorption energy barriers of Mg/MgH_(2) systems decrease significantly after doping with transition metal atoms,which interprets well the improved hydrogen sorption properties of MgH_(2) catalyzed by Ni-based solid solutions.

Photochemical synthesis and enhanced photocatalytic activity of MnO_x/BiPO_4 heterojunction

Monoclinic BiPO4with rod-like shape was prepared via a CTAB-assisted hydrothermal route.MnOx nanoparticles were loaded on the surfaces of BiPO4rods by a photo-deposition process to form MnOx/BiPO4heterojunctions.The as-prepared samples were characterized by XRD,SEM,TEM,XPS,FL,and UV-Vis diffuse reflectance measurements.The results showed that MnOx nanoparticles were strongly anchored to the surfaces of BiPO4rods when the mole ratio of Mn to Bi was controlled at a low level,forming MnOx/BiPO4heterojunctions with effective and sound interfaces.The MnOx/BiPO4heterojunctions exhibited higher photoactivity than pristine BiPO4for photodegradation of methyl blue under UV irradiation,which could be attributed to the efficient charge transfer at the heterojunction interfaces.The higher light absorption ability of MnOx/BiPO4in the range of300?420nm compared with pristine BiPO4was also responsible for the enhanced photocatalytic activities of MnOx/BiPO4heterojunctions.

风力机桨叶超声波除冰实验技术研究及其应用

利用人工环境实验室、模态分析系统、自行设计的两套超声波除冰设备和嵌有压电陶瓷片的风力机桨叶建立风力机桨叶超声波除冰实验台,对不同覆冰状态下的桨叶进行了模态分析,从桨叶的曲率模态参数中提取风力机桨叶覆冰区域与覆冰厚度参数,并利用压电陶瓷片产生的超声波横向剪切应力给风力机桨叶除冰。实验表明,根据所获得的覆冰区域与覆冰厚度参数能较准确地诊断风力机桨叶覆冰状态,超声波除冰技术适用于风力机覆冰桨叶。通过对实验数据分析,提出了除冰时间与覆冰厚度、除冰能耗与覆冰温度和除冰能耗与覆冰厚度之间的定量关系式,为设计超声波桨叶除冰系统提供实验依据。

Effect of elevated-temperature annealing on microstructure and properties of Cu−0.15Zr alloy

Cu−0.15Zr(wt.%)alloy with uniform and fine microstructure was fabricated by rapid solidification followed by hot forging.Evolution of microstructure,mechanical properties and electrical conductivity of the alloy during elevated-temperature annealing were investigated.The alloy exhibits good thermal stability,and its strength decreases slightly even after annealing at 700℃ for 2 h.The nano-sized Cu_(5)Zr precipitates show significant pinning effect on dislocation moving,which is the main reason for the high strength of the alloy.Additionally,the large-size Cu_(5)Zr precipitates play a major role in retarding grain growth by pinning the grain boundaries during annealing.After annealing at 700℃ for 2 h,the electrical conductivity of samples reaches the peak value of 88%(IACS),which is attributed to the decrease of vacancy defects,dislocations,grain boundaries and Zr solutes.

Novel SiO2 nanoparticle-decorated BiOCl nanosheets exhibiting high photocatalytic performances for the removal of organic pollutants

Novel SiO2/BiOCl composites were fabricated by decorating BiOCl nanosheets with SiO2 nanoparticles via a simple hydrothermal process. The as-prepared pure BiOCl and SiO2/BiOCl composites were intensively characterized by various techniques such as XRD, FT-IR, SEM/TEM, BET, UV-vis, DRS, XPS, and photocurrent measurements. The SiO2/BiOCl composite nanosheets displayed high photocatalytic activity and excellent stability in the degradation of organic pollutants such as phenol, bisphenol A (BPA), and rhodamine B (RhB). With respect to those over bare BiOCl, the degradation rates of RhB, BPA, and phenol over 1.88% SiO2/BiOCl increased 16.5%, 29.0%, and 38.7%, respectively. Radical capturing results suggested that h^+ is the major reactive species and that hydroxyl (·OH) and superoxide (·O2^-) radicals could also be involved in the degradation of organic pollutants. The enhanced photocatalytic performances of SiO2/BiOCl composites can be mainly attributed to the improved texture and the formation of intimate SiO2/BiOCl interfaces, which largely promoted the adsorption of organic pollutants, enhanced the light harvesting, and accelerated the separation of e^– and h^+.

TiC strengthened CoCrNi medium entropy alloy:Dissolution and precipitation of TiC and its effect on microstructure and performance

In order to improve the strength and corrosion resistance of CoCrNi medium entropy alloy,TiC strengthened CoCrNi medium entropy alloy(CoCrNi/(TiC)_(x)(x=0.1,0.2,0.4))was designed by addition of different amounts of TiC.The effects of TiC content on the microstructure,mechanical properties,and corrosion resistance of the alloy were investigated.It was found that the precipitation morphologies of TiC changed from lamellar eutectic to needle structure with the increase of TiC content,and finally formed mixed needled and bulk TiC particles.TiC appears as a dissolution−precipitation phenomenon in the CoCrNi alloy,which is important for the mechanical properties and corrosion resistance of the CoCrNi/(TiC)_(x) alloy.The strength of alloy was enhanced obviously after the addition of TiC.The compressive yield strength of CoCrNi/(TiC)_(0.4) alloy reached 746 MPa,much larger than that of the CoCrNi medium entropy alloy,108 MPa.Additionally,the addition of TiC was found to improve the corrosion resistance of CoCrNi medium entropy alloy in the salt solution.

Preparation and properties of porous ceramics from spodumene flotation tailings by low-temperature sintering

Porous ceramics were prepared with spodumene flotation talings(SFT),kaolin and low-melting point glass(LPG)powder,whose pores were formed by the chemical reaction of hydrogen peroxide(H_(2)O_(2)).LPG was used to reduce the sintering temperature of porous ceramics and kaolin was used to realize the adsorption to methylene blue(MB)of porous ceramics.The average flexural strength,compressive strength,apparent porosity,water absorption and maximum MB adsorption capacity were 5.60 MPa,4.66 MPa,52.27%,44.32%and 0.7 mg/g,respectively.Moreover,the results of orthogonal experiments present that the sintering temperature and the dosage of H_(2)O_(2)had great influence on the mechanical properties and apparent porosity of porous ceramics,respectively.The main reason for the improvement of mechanical properties of porous ceramics was that LPG gradually became soft with increasing the sintering temperature,which made the mineral particles adhere to each other closely.Kaolinite was not completely converted into metakaolin at 550℃,which might be the main reason why porous ceramics had adsorption properties.

Influence of Shape and Size of Threshing Frame and Tobacco Grade on Leaf Strip Structure

This paper focused on the influence of the shape and size of threshing frames as well as the grades of tobacco leaves on the structure of threshed leaves.The testing tobacco leaves all came from the hilly ecological region of Nanling and belonged to burnt sweet,alcoholic sweet and scent category.The comprehensive evaluating value S was taken as the test index.Results showed that,without considering the influence of tobacco grade on leaf structure,the shapes of first-stage thresher five-link frames were all hexagons,and the combination with the sizes of 3.5,3.0,3.5,3.0,3.0 inches had the highest evaluating value S of 2.49.For tobacco grade C2FH,the shapes of first-stage thresher five-link frames were also hexagons,and the evaluating value S reached the highest value of 3.40 with sizes of 3.5,3.0,3.5,3.0,3.0 inches.Comprehensive analysis showed that:3.0 inch frame performed better in controlling the percentage of large-sized strips than 3.5 inch frame did;rhombic frames were better than hexagon frames in reducing the breakage rate of tobacco leaves;different shapes or sizes of nonadjacent two-link frames can help to improve the threshing quality.

C(sp^2)-H/O-H cross-dehydrogenative coupling of quinoxalin-2(1H)-ones with alcohols under visible-light photoredox catalysis

An efficient and practical route to various 3-alkoxylquinoxalin-2(1 H)-ones through visible-light photocatalytic C(sp^2)-H/O-H cross-dehydrogenation coupling of quinoxalin-2(1 H)-ones and alcohols,employing ambient air as an oxidant at room temperature under metal-free conditions,was developed.

Sustainable electrochemical cross‐dehydrogenative coupling of4‐quinolones and diorganyl diselenides

An environmentally friendly method for the synthesis of 3‐organylselenyl quinolones through theelectrochemical cross‐dehydrogenative coupling of 4‐quinolones and diorganyl diselenides wasdeveloped.As a green,atom economic and self‐separating process,the present reaction requiresneither external oxidants nor electrolytes,forming a recyclable catalytic system.

车辆动力学稳定性协同控制CAN网络系统硬件设计

利用网络控制和分层协同控制思想,搭建了车辆动力学稳定性协同控制CAN网络系统,并设计了智能节点硬件电路.在设计过程中充分考虑了电磁干扰对系统的影响,从硬件方面提高了系统的抗干扰能力,从而保证了系统具有良好的稳定性和可靠性.

基于遗传算法的Pareto多目标配电网重构

配电网重构一般采用对单一目标优化,而配电网重构却是一个多目标优化问题。因此,在此提出了基于小生境思想的遗传算法,以配电网的经济性、安全性和供电可靠性为目标,并采用Pareto寻优方式,得出Pareto最优解集,实现了和以往不同的另一种寻优方式,即先寻优后决策。在寻优过程中,通过小生境环境和交叉率和变异率的自适应机制,提高了遗传算法的全局收敛能力和收敛速度,并通过算例验证了方法的有效性。

N-Radical enabled cyclization of 1,n-enynes

Compared to the widely used carbon-centered radicals,N-radicals have been relatively unexplored owing to the lack of practical and convenient production methods.Over the past few years,benefitting from the resurgence of reliable and controllable radical chemistry,N-radicals have been produced via thermal decomposition,oxidants,metal salts,or electrocatalysis.Therefore,numerous N-radical enabled cyclization of 1,n-enynes methods have been developed,providing a versatile and concise synthetic platform for the preparation of complex cyclic systems and natural products containing elaborate ring frameworks.In this review,we will summarize recent advances in the promising field of radical chemistry focusing on the production methods of N-radicals and their cyclization patterns,associated mechanisms,unmet challenges,and future opportunities.