Developing multifunctional electrocatalysts with high catalytic activity,longterm stability,and low cost is essential for electrocatalytic energy conversion.Herein,sea urchinlike NiMoO_(4) nanorod arrays grown on nick...Developing multifunctional electrocatalysts with high catalytic activity,longterm stability,and low cost is essential for electrocatalytic energy conversion.Herein,sea urchinlike NiMoO_(4) nanorod arrays grown on nickel foam has been developed as a bifunctional electrocatalyst for urea oxidation and hydrogen evolution.The NiMoO_(4)‐200/NF catalyst exhibits efficient activity toward hydrogen evolution reaction with a low overpotential of only 68 mV in 1.0 mol/L KOH to gain a current density of 10 mA cm^(–2).The NiMoO_(4)‐300/NF catalyst exhibits a prominent oxygen evolution reaction(OER)catalytic activity with an overpotential of 288 mV at 50 mA cm^(–2),as well as for urea oxidation reaction with an ultralow potential of 1.36 V at 10 mA cm^(–2).The observed difference in electrocatalytic activity and selectivity,derived by temperature variation,is ascribed to different lattice oxygen contents.The lattice oxygen of NiMoO_(4)‐300/NF is more than that of NiMoO_(4)‐200/NF,and the lattice oxygen is conducive to the progress of OER.A urea electrolyzer was assembled with Ni‐MoO_(4)‐200/NF and NiMoO_(4)‐300/NF as cathode and anode respectively,delivering a current density of 10 mA cm^(–2)at a cell voltage of merely 1.38 V.The NiMoO_(4)nanorod arrays has also been successfully applied for photovoltage‐driven urea electrolysis and hydrogen production,revealing its great potential for solar‐driven energy conversion.展开更多
Theoretical calculations have been carried out to investigate the possible dissociation channels of isoprene. We focus on the major fragment ions of C5H7＋, C5H5＋, C4H5＋, C3H6＋, C3H5＋, C3H4＋, C3H3＋ and C2H3＋, w...Theoretical calculations have been carried out to investigate the possible dissociation channels of isoprene. We focus on the major fragment ions of C5H7＋, C5H5＋, C4H5＋, C3H6＋, C3H5＋, C3H4＋, C3H3＋ and C2H3＋, which were observed experimentally from the isoprene dissociative photoionization. The energy calculations were performed with the CBS-QB3 model. All the geometries and energies of the fragments, intermediates and transition states involved in the dissociations channels were determined. Finally, the mechanisms of the dissociation pathways were discussed on the comparison of theoretical and experimental results.展开更多
A graph G possesses Hamiltonian s-properties when G is Hamilton-connected if s=1,Hamiltonian if s=0,and traceable if s=-1.Let S_A(G)=λ_n(G)-λ_1(G)and S_L(G)=μ_n(G)-μ_2(G)be the spread and the Laplacian spread of G...A graph G possesses Hamiltonian s-properties when G is Hamilton-connected if s=1,Hamiltonian if s=0,and traceable if s=-1.Let S_A(G)=λ_n(G)-λ_1(G)and S_L(G)=μ_n(G)-μ_2(G)be the spread and the Laplacian spread of G,respectively,whereλ_n(G)andλ_1(G)are the largest and smallest eigenvalues of G,andμ_n(G)andμ_2(G)are the largest and second smallest Laplacian eigenvalues of G,respectively.In this paper,we shall present two sufficient conditions involving S_A(G)and S_L(G)for a k-connected graph to possess Hamiltonian s-properties,respectively.We also derive a sufficient condition on the Laplacian eigenratio■for a k-connected graph to possess Hamiltonian s-properties.展开更多
文摘Developing multifunctional electrocatalysts with high catalytic activity,longterm stability,and low cost is essential for electrocatalytic energy conversion.Herein,sea urchinlike NiMoO_(4) nanorod arrays grown on nickel foam has been developed as a bifunctional electrocatalyst for urea oxidation and hydrogen evolution.The NiMoO_(4)‐200/NF catalyst exhibits efficient activity toward hydrogen evolution reaction with a low overpotential of only 68 mV in 1.0 mol/L KOH to gain a current density of 10 mA cm^(–2).The NiMoO_(4)‐300/NF catalyst exhibits a prominent oxygen evolution reaction(OER)catalytic activity with an overpotential of 288 mV at 50 mA cm^(–2),as well as for urea oxidation reaction with an ultralow potential of 1.36 V at 10 mA cm^(–2).The observed difference in electrocatalytic activity and selectivity,derived by temperature variation,is ascribed to different lattice oxygen contents.The lattice oxygen of NiMoO_(4)‐300/NF is more than that of NiMoO_(4)‐200/NF,and the lattice oxygen is conducive to the progress of OER.A urea electrolyzer was assembled with Ni‐MoO_(4)‐200/NF and NiMoO_(4)‐300/NF as cathode and anode respectively,delivering a current density of 10 mA cm^(–2)at a cell voltage of merely 1.38 V.The NiMoO_(4)nanorod arrays has also been successfully applied for photovoltage‐driven urea electrolysis and hydrogen production,revealing its great potential for solar‐driven energy conversion.
基金This work was supported by the National Natural Science Foundation of China （No.91544228, No.21307137, No.41575125, No.41375127, No.U1232209） and the Outstanding Youth Science Foundation of Fujian Province of China （No.2015J06009）.
文摘Theoretical calculations have been carried out to investigate the possible dissociation channels of isoprene. We focus on the major fragment ions of C5H7＋, C5H5＋, C4H5＋, C3H6＋, C3H5＋, C3H4＋, C3H3＋ and C2H3＋, which were observed experimentally from the isoprene dissociative photoionization. The energy calculations were performed with the CBS-QB3 model. All the geometries and energies of the fragments, intermediates and transition states involved in the dissociations channels were determined. Finally, the mechanisms of the dissociation pathways were discussed on the comparison of theoretical and experimental results.
基金Supported by NSFC(Nos.12171089,12271235)NSF of Fujian Province(No.2021J02048)。
文摘A graph G possesses Hamiltonian s-properties when G is Hamilton-connected if s=1,Hamiltonian if s=0,and traceable if s=-1.Let S_A(G)=λ_n(G)-λ_1(G)and S_L(G)=μ_n(G)-μ_2(G)be the spread and the Laplacian spread of G,respectively,whereλ_n(G)andλ_1(G)are the largest and smallest eigenvalues of G,andμ_n(G)andμ_2(G)are the largest and second smallest Laplacian eigenvalues of G,respectively.In this paper,we shall present two sufficient conditions involving S_A(G)and S_L(G)for a k-connected graph to possess Hamiltonian s-properties,respectively.We also derive a sufficient condition on the Laplacian eigenratio■for a k-connected graph to possess Hamiltonian s-properties.
